*2025/05/15 13:13:27.52 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2024/06/26 07:42:50.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 47DDD957 NUMBER OF CHANNELS : 29 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 13 2 Bottle:Firing_Sequence n/a 1 13 3 Pressure decibar 2.05 388.44 4 Depth metres 3.121 385.681 5 Temperature:Primary 'deg C (ITS90)' 4.8853 10.1916 6 Transmissivity %/metre 38.7 58.2 7 Transmissivity:Green %/metre 55.8 90.5 8 Fluorescence:URU:Seapoint mg/m^3 0.25E-01 2.409 9 Fluorescence:URU:Wetlabs mg/m^3 0.27E-01 2.344 10 PAR uE/m^2/sec 0 0.342 11 Salinity:T0:C0 PSS-78 31.9271 33.9 12 Oxygen:Dissolved:SBE mL/L 1.374 6.289 13 Oxygen:Dissolved:SBE umol/kg 59.8 274.1 14 Conductivity:Primary S/m 3.258001 3.524069 15 Number_of_bin_records n/a 241 241 16 Sample_Number n/a 426 438 17 Temperature:Draw 'deg C (ITS90)' 6.5 11.7 18 Chlorophyll:Extracted mg/m^3 1.11 2.55 19 Flag:Chlorophyll:Extracted n/a 20 Phaeo-Pigment:Extracted mg/m^3 0.61 0.77 21 Oxygen:Dissolved mL/L 1.389 6.4 22 Oxygen:Dissolved umol/kg 60.42427 279.0544 23 Flag:Oxygen:Dissolved n/a 24 Nitrate_plus_Nitrite umol/L 6.17 40.14 25 Flag:Nitrate_plus_Nitrite n/a 26 Silicate umol/L 11.36 77.68 27 Flag:Silicate n/a 28 Phosphate umol/L 0.78 2.635 29 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 7 F ' ' 1 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 10 F ' ' 5 15 -99 ' ' 5 I I 0 16 -99 ' ' 5 I I 0 17 -99 ' ' 6 F R4 1 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 8 F R4 3 22 -99 ' ' 6 F ' ' 1 23 n/a ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 8 F R4 3 29 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2024-069 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : IOS Moorings SCIENTIST : Spear D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : BC Coast STATION : Q37 EVENT NUMBER : 147 LATITUDE : 54 34.25000 N ! (deg min) LONGITUDE : 132 56.48000 W ! (deg min) WATER DEPTH : 390 ALTIMETER (M) : 3.57 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2754 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 5130 Conductivity:2 ' ' 1766 'Oxygen:SBE 43' ' ' 4372 Fluorometer:Seapoint ' ' 4186 Altimeter ' ' 76341 PAR/Irradiance:Biospherical/Licor ' ' 70613 'Fluorometer:WET Labs ECO-AFL/FL' ' ' FLRTD-2216 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2025/04/17 16:11:39 3133 3133 CLEAN 5.3 2025/04/17 16:11:57 3133 3133 ADDSAMP 3.6 2025/04/17 16:12:12 3133 3133 BINAVE 4.2.1 2025/04/17 16:12:21 3133 13 MERGE 3.6 2025/04/17 16:12:44 13 13 CLEAN 5.3 2025/05/15 12:38:28 13 13 CALIB 12.1 2025/05/15 12:39:24 13 13 CALIB 12.1 2025/05/15 12:40:15 13 13 SORT 3.6 2025/05/15 12:40:31 13 13 REMOVECH 8.2 2025/05/15 12:47:28 13 13 CHGUNITS 3.2 2025/05/15 13:03:54 13 13 CHGUNITS 3.2 2025/05/15 13:05:26 13 13 REORDER 1.3.1 2025/05/15 13:08:59 ? ? HDREDIT2 3.2 2025/05/15 13:13:27 ? ? $END $REMARKS -CLEAN functions: 2025/04/17 16:11:48 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: E:\Telework\2024-069\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2025/04/17 16:12:44 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : E:\Telework\2024-069\Processing\hydro\2024-069-0147.samavg Secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0147.mrgcln1s 13 secondary records matched to primary records. Comments from secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0147.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2025/04/16 10:33:46 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2025/05/15 12:38:26 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2025/05/15 12:39:24 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2024-069\Processing\doc\2024-069-recalsil.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 33 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2025/05/15 12:40:15 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2024-069\Processing\doc\2024-069-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Pressure decibar 10 -0.1100000E+01 0.1000000E+01 19 Salinity:T0:C0 PSS-78 10 -0.1500000E-02 0.1000000E+01 20 Salinity:T1:C1 PSS-78 10 -0.7000000E-03 0.1000000E+01 21 Oxygen:Dissolved:SBE mL/L 10 0.3000000E-01 0.9870000E+00 -SORT parameters: 2025/05/15 12:40:31 Sorted in ascending order of channel Pressure -REMOVECH 2025/05/15 12:47:28 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2025/05/15 13:13:27 Applied edit header: E:\Telework\2024-069\Processing\doc\HYDRO\2024-069-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 17: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 19: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 23: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Pad: 0 ==> n/a Channel 25: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 27: Flag:Silicate [n/a] Units: ==> n/a Channel 29: Flag:Phosphate [n/a] Units: ==> n/a Channel 10: PAR [uE/m^2/sec] Units: umol/m^2/sec ==> uE/m^2/sec Format: F11.3 ==> F7.1 Channel 14: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 9: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:URU:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs $END *COMMENTS Comments from secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0147.mrgcln1s ------------------------------------------------------------ Comments from secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0147.nut ------------------------------------------------------- Sample_Number 427: NUTS: Sample intended as duplicate, however, only one sample processed Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 2-4 weeks after the collection on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For further details on methodology, see document QF2024-069_CHL*.xlsx Methodology sheet. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876, a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2024-069OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 10-15 days after collection. For details see document QF2024-069SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2024-069nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers ---------------------------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Fluorescence and Transmissivity data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. CTD primary channels were unavailable above 200db for event #160. That includes channel Oxygen:Dissolved:SBE. For details on the processing see the report: 2024-069_Processing_Report.doc. ---------------------------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Pressure decibar 10 -99 () (-1.1 1) Salinity:T0:C0 PSS-78 10 -99 () (-0.15E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (-0.7E-03 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.3E-01 0.987) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- ---8--- ---9--- --10-- ---11--- --12-- --13- ----14--- -15- -16- --17- --18-- 19 --20-- ---21-- --22- 23 --24-- 25 --26-- 27 ---28-- 29 !Bo Bo Pressu Depth Temperat Trans Trans Fluores Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi cence: cence: :T0:C0 : n: ity: er_o le_ ratur phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~u ~u Primary vity vity: URU: URU: Dissol Disso Primary ~bin Numb e: Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !mb en Green Seapoin Wetlabs ved: lved: _rec er Draw ted ct Extrac lved lv Nitrit ri ca ha !er ce t SBE SBE ords ed ted ed e te te te !-- -- ------ ------ -------- ----- ----- ------- ------- ------ -------- ------ ----- --------- ---- ---- ----- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 13 13 2.0 3.1 10.1916 38.9 55.8 2.369 2.330 0.3 31.9271 6.29 274.1 3.52407 241 438 11.7 2.50 0 0.64 6.400 279.1 0 6.17 0 11.36 0 0.781 0 12 12 3.4 4.5 10.1445 38.7 55.8 2.409 2.344 0.2 31.9286 6.28 273.9 3.52015 241 437 11.6 2.55 0 0.77 6.350 276.9 0 6.55 0 12.24 0 0.780 0 11 11 9.4 10.4 9.6377 41.2 59.6 2.270 2.245 0.0 32.0075 6.00 261.6 3.48388 241 436 11.0 2.18 6 0.76 6.044 263.5 0 9.00 0 15.49 0 0.964 0 10 10 24.1 25.0 8.5688 51.7 77.3 0.961 1.005 0.0 32.2864 5.19 226.2 3.41820 241 435 9.9 1.11 0 0.61 5.195 226.4 6 14.86 0 24.08 0 1.372 0 9 9 49.7 50.3 7.7427 54.8 83.6 0.360 0.446 0.0 32.5636 4.47 194.8 3.37340 241 434 9.1 -99.00 0 -99.00 4.471 194.8 0 20.30 0 33.01 0 1.699 0 8 8 73.8 74.2 7.0062 56.4 86.4 0.155 0.154 0.0 32.8495 3.89 169.5 3.33660 241 433 8.5 -99.00 0 -99.00 3.881 169.0 0 24.90 6 39.40 6 1.808 6 7 7 99.3 99.5 6.3668 56.7 87.1 0.061 0.063 0.0 33.2009 3.03 132.1 3.31366 241 432 8.0 -99.00 0 -99.00 3.019 131.4 0 30.26 0 50.06 0 2.111 0 6 6 149.3 149.0 6.0218 57.1 88.1 0.044 0.038 0.0 33.4272 2.68 116.8 3.30586 241 431 7.6 -99.00 0 -99.00 2.680 116.6 0 32.69 0 53.36 0 2.209 0 5 5 199.5 198.7 5.7192 57.8 89.7 0.035 0.030 0.0 33.6235 2.44 106.0 3.29888 241 430 7.3 -99.00 0 -99.00 2.457 106.9 6 34.50 0 57.53 0 2.307 0 4 4 249.4 248.1 5.4082 58.2 90.5 0.025 0.027 0.0 33.7433 2.16 94.1 3.28425 241 429 7.0 -99.00 0 -99.00 2.167 94.3 0 36.30 0 62.90 0 2.368 0 3 3 299.2 297.3 5.2031 55.9 85.9 0.025 0.031 0.0 33.8114 1.83 79.6 3.27434 241 428 6.8 -99.00 0 -99.00 1.837 79.9 0 38.02 6 68.88 6 2.478 6 2 2 349.1 346.7 5.0898 55.5 85.4 0.025 0.032 0.0 33.8425 1.66 72.2 3.26928 241 427 6.7 -99.00 0 -99.00 1.669 72.6 0 38.85 2 71.37 2 2.635 2 1 1 388.4 385.7 4.8853 50.2 76.4 0.033 0.048 0.0 33.9000 1.37 59.8 3.25800 241 426 6.5 -99.00 0 -99.00 1.389 60.4 0 40.14 0 77.68 0 2.629 0