*2025/05/15 13:13:26.99 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2024/06/22 06:41:08.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 4299DB0B NUMBER OF CHANNELS : 27 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 13 2 Bottle:Firing_Sequence n/a 1 13 3 Pressure decibar 1.94 513.05 4 Depth metres 3.01 508.961 5 Temperature:Primary 'deg C (ITS90)' 7.0917 12.4841 6 Transmissivity %/metre 19.5 57.5 7 Transmissivity:Green %/metre 25.2 88.2 8 Fluorescence:URU:Seapoint mg/m^3 0.37E-01 7.434 9 Fluorescence:URU:Wetlabs mg/m^3 0.27E-01 10.118 10 PAR uE/m^2/sec 0 0.298 11 Salinity:T0:C0 PSS-78 26.6139 33.0999 12 Oxygen:Dissolved:SBE mL/L 3.018 8.593 13 Oxygen:Dissolved:SBE umol/kg 131.4 376.2 14 Conductivity:Primary S/m 3.131077 3.39183 15 Number_of_bin_records n/a 71 241 16 Sample_Number n/a 190 202 17 Salinity:Bottle PSS-78 33.0987 33.0987 18 Flag:Salinity:Bottle n/a 19 Chlorophyll:Extracted mg/m^3 0.92 16.23 20 Flag:Chlorophyll:Extracted n/a 21 Phaeo-Pigment:Extracted mg/m^3 0.81 3.32 22 Nitrate_plus_Nitrite umol/L 3.01 28.48 23 Flag:Nitrate_plus_Nitrite n/a 24 Silicate umol/L 4.67 52.17 25 Flag:Silicate n/a 26 Phosphate umol/L 0.363 2.004 27 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 7 F ' ' 1 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 10 F ' ' 5 15 -99 ' ' 5 I I 0 16 -99 ' ' 5 I I 0 17 -99 ' ' 9 F R4 4 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 7 F R4 2 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 3 27 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2024-069 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : IOS Moorings SCIENTIST : Spear D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : BC Coast STATION : WC50 EVENT NUMBER : 70 LATITUDE : 53 17.76000 N ! (deg min) LONGITUDE : 129 8.85000 W ! (deg min) WATER DEPTH : 515 ALTIMETER (M) : 4.44 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2754 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 5130 Conductivity:2 ' ' 1766 'Oxygen:SBE 43' ' ' 4372 Fluorometer:Seapoint ' ' 4186 Altimeter ' ' 76341 PAR/Irradiance:Biospherical/Licor ' ' 70613 'Fluorometer:WET Labs ECO-AFL/FL' ' ' FLRTD-2216 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2025/04/17 16:11:34 2963 2963 CLEAN 5.3 2025/04/17 16:11:53 2963 2963 ADDSAMP 3.6 2025/04/17 16:12:07 2963 2963 BINAVE 4.2.1 2025/04/17 16:12:19 2963 13 MERGE 3.6 2025/04/17 16:12:43 13 13 CLEAN 5.3 2025/05/15 12:38:27 13 13 CALIB 12.1 2025/05/15 12:39:24 13 13 CALIB 12.1 2025/05/15 12:40:15 13 13 SORT 3.6 2025/05/15 12:40:31 13 13 REMOVECH 8.2 2025/05/15 12:47:27 13 13 CHGUNITS 3.2 2025/05/15 13:03:53 13 13 CHGUNITS 3.2 2025/05/15 13:05:25 13 13 REORDER 1.3.1 2025/05/15 13:08:58 ? ? HDREDIT2 3.2 2025/05/15 13:13:26 ? ? $END $REMARKS -CLEAN functions: 2025/04/17 16:11:48 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: E:\Telework\2024-069\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2025/04/17 16:12:43 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : E:\Telework\2024-069\Processing\hydro\2024-069-0070.samavg Secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0070.mrgcln1s 13 secondary records matched to primary records. Comments from secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0070.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2025/04/16 10:33:45 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2025/05/15 12:38:26 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2025/05/15 12:39:24 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2024-069\Processing\doc\2024-069-recalsil.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 32 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2025/05/15 12:40:15 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2024-069\Processing\doc\2024-069-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Pressure decibar 10 -0.1100000E+01 0.1000000E+01 19 Salinity:T0:C0 PSS-78 10 -0.1500000E-02 0.1000000E+01 20 Salinity:T1:C1 PSS-78 10 -0.7000000E-03 0.1000000E+01 21 Oxygen:Dissolved:SBE mL/L 10 0.3000000E-01 0.9870000E+00 -SORT parameters: 2025/05/15 12:40:31 Sorted in ascending order of channel Pressure -REMOVECH 2025/05/15 12:47:27 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2025/05/15 13:13:26 Applied edit header: E:\Telework\2024-069\Processing\doc\HYDRO\2024-069-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 18: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 20: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 23: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 25: Flag:Silicate [n/a] Units: ==> n/a Channel 27: Flag:Phosphate [n/a] Units: ==> n/a Channel 10: PAR [uE/m^2/sec] Units: umol/m^2/sec ==> uE/m^2/sec Format: F11.3 ==> F7.1 Channel 14: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 9: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:URU:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs $END *COMMENTS Comments from secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0070.mrgcln1s ------------------------------------------------------------ Comments from secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0070.sal ------------------------------------------------------- Sample_Number 192: SAL: Likely error in Rosette & Sample Master lists. Intended sample likely 190. Comments from secondary file: E:\Telework\2024-069\Processing\hydro\2024-069-0070.chl ------------------------------------------------------- Sample_Number 199: CHL: zooplankton on filter. Sample_Number 200: CHL: %CV > 10% Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 2-4 weeks after the collection on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For further details on methodology, see document QF2024-069_CHL*.xlsx Methodology sheet. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876, a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2024-069OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 10-15 days after collection. For details see document QF2024-069SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2024-069nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers ---------------------------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Fluorescence and Transmissivity data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. CTD primary channels were unavailable above 200db for event #160. That includes channel Oxygen:Dissolved:SBE. For details on the processing see the report: 2024-069_Processing_Report.doc. ---------------------------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Pressure decibar 10 -99 () (-1.1 1) Salinity:T0:C0 PSS-78 10 -99 () (-0.15E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (-0.7E-03 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.3E-01 0.987) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- ---8--- ---9--- --10-- ---11--- --12-- --13- ----14--- -15- -16- ---17--- 18 --19-- 20 --21-- --22-- 23 --24-- 25 ---26-- 27 !Bo Bo Pressu Depth Temperat Trans Trans Fluores Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Samp Salinity Fl Chloro Fl Phaeo- Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi cence: cence: :T0:C0 : n: ity: er_o le_ :Bottle ag phyll: ag Pigmen e_ ag te ag te ag !~u ~u Primary vity vity: URU: URU: Dissol Disso Primary ~bin Numb ~o Extrac ~a t: plus_ ~t ~i ~p !mb en Green Seapoin Wetlabs ved: lved: _rec er tt ted ct Extrac Nitrit ri ca ha !er ce t SBE SBE ords le ed ted e te te te !-- -- ------ ------ -------- ----- ----- ------- ------- ------ -------- ------ ----- --------- ---- ---- -------- -- ------ -- ------ ------ -- ------ -- ------- -- *END OF HEADER 13 13 1.9 3.0 12.4841 19.5 26.3 5.560 7.333 0.3 26.6139 8.59 376.2 3.16234 241 202 -99.0000 0 15.62 0 2.48 3.01 0 4.67 0 0.363 0 12 12 3.5 4.6 10.3594 20.7 25.2 7.434 10.118 0.1 27.8774 7.24 316.5 3.13108 241 201 -99.0000 0 16.23 0 3.32 4.57 0 7.01 0 0.489 0 11 11 8.9 9.9 8.9960 39.7 55.4 1.922 3.962 0.0 29.8063 5.03 219.6 3.21452 241 200 -99.0000 0 1.97 36 1.11 18.91 0 30.81 0 1.468 0 10 10 23.2 24.1 8.3717 53.3 79.4 0.401 0.573 0.0 31.5197 4.18 182.4 3.32809 241 199 -99.0000 0 0.92 2 0.81 21.23 6 35.87 6 1.774 6 9 9 48.9 49.6 8.1517 55.9 84.8 0.122 0.153 0.0 32.0479 4.17 181.6 3.36042 241 198 -99.0000 0 -99.00 0 -99.00 21.62 0 35.83 0 1.696 0 8 8 73.9 74.3 7.9271 57.5 88.2 0.052 0.056 0.0 32.5072 3.87 168.3 3.38525 241 197 -99.0000 0 -99.00 0 -99.00 23.51 0 41.03 0 1.726 0 7 7 98.9 99.1 7.8275 57.0 87.4 0.050 0.049 0.0 32.6587 3.64 158.5 3.39183 241 196 -99.0000 0 -99.00 0 -99.00 23.87 0 42.67 0 1.708 0 6 6 198.9 198.1 7.3323 56.7 87.1 0.037 0.027 0.0 32.9737 3.51 152.7 3.38202 241 195 -99.0000 0 -99.00 0 -99.00 25.62 0 41.63 0 1.801 0 5 5 248.7 247.4 7.1795 56.7 87.1 0.038 0.037 0.0 33.0246 3.19 138.9 3.37544 241 194 -99.0000 0 -99.00 0 -99.00 27.37 0 45.97 0 1.873 0 4 4 298.8 297.0 7.1380 56.7 87.0 0.038 0.036 0.0 33.0446 3.11 135.5 3.37582 241 193 -99.0000 0 -99.00 0 -99.00 27.87 6 47.46 6 1.958 6 3 3 398.9 396.1 7.1010 56.0 85.6 0.038 0.054 0.0 33.0739 3.05 132.8 3.37956 241 192 -99.0000 9 -99.00 0 -99.00 27.76 0 48.39 0 1.904 0 1 1 513.0 509.0 7.0917 54.6 83.3 0.038 0.029 0.0 33.0999 3.02 131.4 3.38603 71 190 33.0987 0 -99.00 0 -99.00 28.48 0 52.03 0 2.004 0 2 2 513.0 509.0 7.0922 54.6 83.3 0.037 0.035 0.0 33.0998 3.02 131.4 3.38606 241 191 -99.0000 0 -99.00 0 -99.00 28.22 0 52.17 0 1.922 0