*2025/12/03 15:52:26.22 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2024/10/06 16:14:14.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 10 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : CED82DDE NUMBER OF CHANNELS : 29 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 10 2 Bottle:Firing_Sequence n/a 1 10 3 Pressure decibar 1.632 123.014 4 Depth metres 1.619 121.942 5 Temperature:Secondary 'deg C (ITS90)' 8.0449 10.4704 6 Transmissivity %/metre 47.8 53.8 7 Fluorescence:URU:Seapoint mg/m^3 0.298 1.241 8 PAR uE/m^2/sec 0.66E-01 334.411 9 PAR:Reference uE/m^2/sec 643.548 2001.48 10 pH:SBE:Nominal n/a 8.506 8.67 11 Salinity:T1:C1 PSS-78 31.4488 33.3387 12 Oxygen:Dissolved:SBE mL/L 2.055 4.113 13 Oxygen:Dissolved:SBE umol/kg 89.5 179.4 14 Conductivity:Secondary S/m 3.475625 3.514567 15 Number_of_bin_records n/a 241 241 16 Sample_Number n/a 260 269 17 Temperature:Draw 'deg C (ITS90)' 9.1 11.9 18 Chlorophyll:Extracted mg/m^3 0.49 3.84 19 Flag:Chlorophyll:Extracted n/a 20 Phaeo-Pigment:Extracted mg/m^3 0.67 0.81 21 Oxygen:Dissolved mL/L 2.042 4.103 22 Oxygen:Dissolved umol/kg 88.90189 178.9586 23 Flag:Oxygen:Dissolved n/a 24 Nitrate_plus_Nitrite umol/L 24.7 32.82 25 Flag:Nitrate_plus_Nitrite n/a 26 Silicate umol/L 45.61 50.42 27 Flag:Silicate n/a 28 Phosphate umol/L 2.154 2.5 29 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 10 F ' ' 5 15 -99 ' ' 5 I I 0 16 -99 ' ' 5 I I 0 17 -99 ' ' 6 F R4 1 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 8 F R4 3 22 -99 ' ' 6 F ' ' 1 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 8 F R4 3 29 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2024-010 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Salish Sea Biophysical Survey SCIENTIST : Bluteau C. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Juan de Fuca Strait & Strait of Georgia STATION : 65 EVENT NUMBER : 77 LATITUDE : 48 15.90000 N ! (deg min) LONGITUDE : 123 9.82000 W ! (deg min) WATER DEPTH : 127 ALTIMETER (M) : 5.03 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 1453 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 3500 'Pressure:Digiquartz with TC' ' ' 1453 Temperature:2 ' ' 6565 Conductivity:2 ' ' 5043 'Oxygen:SBE 43' ' ' 1438 Fluorometer:Seapoint ' ' 3640 Altimeter ' ' 73171 pH ' ' 0691 PAR/Irradiance:Biospherical/Licor ' ' 4615 'Transmissometer:WET Labs C-Star' ' ' 1201DR Unavailable ' ' ' ' SPAR:Biospherical/Licor ' ' 20518 $END $REMARKS Software Version Seasave V 7.26.7.121 Comments from secondary file: E:\Telework\2024-010\Processing\hydro\2024-010-0077.mrgcln1s ------------------------------------------------------------ Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2025/11/12 15:40:54 2410 2410 CLEAN 5.3 2025/11/12 15:41:08 2410 2410 ADDSAMP 3.6 2025/11/13 16:51:34 2410 2410 HDREDIT2 3.2 2025/11/18 11:17:38 ? ? BINAVE 4.2.1 2025/11/18 11:40:06 2410 10 MERGE 3.6 2025/11/18 14:29:38 10 10 CLEAN 5.3 2025/12/03 11:27:07 10 10 CALIB 12.1 2025/12/03 11:27:27 10 10 SORT 3.6 2025/12/03 12:47:07 10 10 REMOVECH 8.2 2025/12/03 12:50:07 10 10 CHGUNITS 3.2 2025/12/03 15:06:56 10 10 CHGUNITS 3.2 2025/12/03 15:06:59 10 10 REORDER 1.3.1 2025/12/03 15:24:26 ? ? HDREDIT2 3.2 2025/12/03 15:52:26 ? ? $END $REMARKS -CLEAN functions: 2025/11/12 15:41:01 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: E:\Telework\2024-010\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -HEADER EDITS: 2025/11/18 11:17:38 Channel 3: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2025/11/18 14:29:38 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : E:\Telework\2024-010\Processing\hydro\2024-010-0077.samavg Secondary file: E:\Telework\2024-010\Processing\hydro\2024-010-0077.mrgcln1s 10 secondary records matched to primary records. Comments from secondary file: E:\Telework\2024-010\Processing\hydro\2024-010-0077.mrgcln1s ------------------------------------------------------------ -DATCNV: 2025/11/13 12:22:38 Converted raw CTD cast (.hex) to .ros format. Output contained 2410 records with instrument channels. -CONVERT OXYGEN: 2025/11/13 12:22:38 Converted Oxygen data from Voltage to ml/L and umol/Kg Output contained 2410 records of Oxygen data -AV1: 2025/11/13 12:22:38 Averaged CTD data around each bottle position. Channel 'Number_of_bin_records' was added to file. Records reduced from 2410 to 10 (one row per bottle). -ADDSAMP: 2025/11/13 12:24:08 Merge Sample numbers assigned from Compiled Rosette Sheets into AV1 Niskin# column renamed to bottle position for consistency with AV1. 10 AV1 records successfully annotated with Sample_Number. -RENAME: 2025/11/13 12:24:08 Standardized and reordered channel names for CHE output. 17 Columns renamed and reordered successfully -MERGE: 2025/11/13 12:24:08 Merged Lab chemistry data into AV1 output. Merge key: Sample_Number Merge Scheme Used: Add Secondary to Matching Primary Primary Channels to Include: ALL Secondary Channels to Include: Station Chlorophyll:Extracted Flag:Chlorophyll:Extracted Phaeo-Pigment:Extracted Station_OXY Oxygen:Dissolved Flag:Oxygen:Dissolved Temperature:Draw Station_NUTS Depth_NUTS Nitrate_plus_Nitrite Flag:Nitrate_plus_Nitrite Silicate Flag:Silicate Phosphate Flag:Phosphate 10 secondary lab records matched to primary records. -HEADER EDITS: 2025/11/18 11:30:24 Channel 1: Bottle_Number [Number] Name: Bottle ==> Bottle_Number -CLEAN functions: 2025/11/18 11:30:59 20 Reset #RECS, MIN & MAX values in header. Set header Start and End times from the data. *FAILED* -SORT parameters: 2025/11/18 11:31:13 Sorted in ascending order of channel Sample_Number -CLEAN functions: 2025/12/03 11:27:01 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2025/12/03 11:27:27 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2024-010\Processing\doc\2024-010-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 21 Oxygen:Dissolved:SBE mL/L 10 0.7000000E-02 0.1032400E+01 -SORT parameters: 2025/12/03 12:47:07 Sorted in ascending order of channel Pressure -REMOVECH 2025/12/03 12:50:07 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2025/12/03 15:52:26 Applied edit header: E:\Telework\2024-010\Processing\doc\HYDRO\2024-010-bot-hdr.txt Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 11: Salinity:T1:C1 [PSS-78] Format: F11.4 ==> F9.4 Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Conductivity:Secondary [S/m] Format: F11.6 ==> F10.5 Channel 15: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 17: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 20: Phaeo-Pigment:Extracted [mg/m^3] Units: n/a ==> mg/m^3 Channel 21: Oxygen:Dissolved [mL/L] Format: F7.2 ==> F8.3 Channel 8: PAR [uE/m^2/sec] Units: umol/m^2/sec ==> uE/m^2/sec Format: F11.3 ==> F7.1 Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 $END *COMMENTS Comments from secondary file: E:\Telework\2024-010\Processing\hydro\2024-010-0077.mrgcln1s ------------------------------------------------------------ Comments from secondary file: C:/Users/BEDARDJ/Desktop/Data_Processing/bottle_data/2024-010/lab_data/2024-010_CHL.csv ------------------------------------------------------- Sample_Number 266: CHL: large (~50mL) spill, estimated volume filtered = 245mL. Comments from secondary file: C:/Users/BEDARDJ/Desktop/Data_Processing/bottle_data/2024-010/lab_data/2024-010_OXY.csv ------------------------------------------------------- Sample_Number 265: OXY: sample overtitrated. Sample_Number 262: OXY: replicate outlier by Chauvenet's criterion. ---------------------------------------------------------------------------------------------------- Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were analyzed at sea on CCGC Vector 1 week following the cruise on a Turner Trilogy7200-000 fluorometer, using methods described in Holm-Hansen et al. (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For further details including a precisions analysis, see document QF2024-010_CHL*.xlsx. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876, a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2024-010_OXY*.xlsx. Salinity samples were collected in 200mL or 250mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 2-8 days after collection. For details see document QF2024-010_SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2024-010nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers ---------------------------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Fluorescence and Transmissivity data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on the processing see the report: 2024-010_Processing_Report.doc. ---------------------------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.7E-02 1.0324) $END !1- 2- --3--- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10-- ---11--- --12-- --13- ----14--- -15- -16- --17- --18-- 19 --20-- ---21-- --22- 23 --24-- 25 --26-- 27 ---28-- 29 !Bo Bo Pressu Depth Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: Refere Nominal :T1:C1 : n: ity: er_o le_ ratur phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~u ~u Secondar vity URU: nce Dissol Disso Secondary ~bin Numb e: Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !mb en y Seapoin ved: lved: _rec er Draw ted ct Extrac lved lv Nitrit ri ca ha !er ce t SBE SBE ords ed ted ed e te te te !-- -- ------ ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- --------- ---- ---- ----- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 10 10 1.6 1.6 10.4601 51.4 1.094 334.4 736.8 8.670 31.4488 4.11 179.4 3.49950 241 269 11.5 3.38 6 0.76 4.100 179.0 0 24.70 0 46.10 0 2.154 0 9 9 5.1 5.0 10.4704 51.4 1.241 161.3 877.8 8.667 31.4574 4.08 178.0 3.50140 241 268 11.5 3.84 0 0.67 4.090 178.4 0 24.77 0 45.74 0 2.173 0 8 8 10.0 10.0 10.4204 52.7 1.034 92.5 802.4 8.651 31.5334 3.90 170.2 3.50489 241 267 11.4 2.83 0 0.68 3.870 168.8 0 25.19 6 45.61 6 2.178 6 7 7 20.1 20.0 10.1383 53.8 0.811 19.6 687.6 8.621 31.7146 3.53 154.0 3.49887 241 266 11.1 0.49 4 0.81 3.520 153.3 0 26.10 0 46.09 0 2.173 0 6 6 30.1 29.8 10.0808 52.8 0.718 5.1 643.5 8.609 31.8379 3.42 149.2 3.50653 241 265 11.0 -99.00 0 -99.00 3.420 149.0 2 26.56 0 46.59 0 2.286 0 5 5 40.0 39.7 9.9908 51.9 0.632 1.4 678.9 8.597 31.9943 3.29 143.4 3.51457 241 264 11.9 -99.00 0 -99.00 3.290 143.4 0 27.07 0 46.83 0 2.357 0 4 4 50.1 49.6 9.7158 53.0 0.559 0.5 871.6 8.581 32.1461 3.11 135.4 3.50586 241 263 11.6 -99.00 0 -99.00 3.120 135.9 0 27.80 0 47.82 0 2.469 0 3 3 75.0 74.4 8.9100 52.5 0.422 0.1 879.7 8.543 32.6768 2.60 113.2 3.48752 241 262 9.8 -99.00 0 -99.00 2.600 113.4 46 30.36 0 49.49 0 2.426 0 2 2 100.2 99.3 8.1768 49.7 0.311 0.1 1760.6 8.509 33.2338 2.14 93.1 3.47653 241 261 9.2 -99.00 0 -99.00 2.120 92.4 0 32.34 0 50.30 0 2.494 0 1 1 123.0 121.9 8.0449 47.8 0.298 0.1 2001.5 8.506 33.3387 2.06 89.5 3.47562 241 260 9.1 -99.00 0 -99.00 2.040 88.9 0 32.82 0 50.42 0 2.500 0