*2025/04/24 15:07:31.64 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2024/03/08 21:48:36.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 18 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : CD9DE31B NUMBER OF CHANNELS : 26 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 18 2 Bottle:Firing_Sequence n/a 1 18 3 Pressure decibar 1.4 448.1 4 Depth metres 2.5 444.9 5 Temperature:Primary 'deg C (ITS90)' 6.6146 8.019 6 Transmissivity %/metre 34.7 51.3 7 Transmissivity:Green %/metre 48.4 78.1 8 Fluorescence:URU:Seapoint mg/m^3 0.246 0.378 9 Fluorescence:URU:Wetlabs mg/m^3 0.67E-01 1.433 10 Salinity:T0:C0 PSS-78 29.2806 31.3827 11 Oxygen:Dissolved:SBE mL/L 2.8906 6.2371 12 Oxygen:Dissolved:SBE umol/kg 125.809 272.279 13 Conductivity:Primary S/m 2.97339 3.30267 14 Number_of_bin_records n/a 46 241 15 Sample_Number n/a 55 72 16 Salinity:Bottle PSS-78 29.2805 31.378 17 Flag:Salinity:Bottle n/a 18 Chlorophyll:Extracted mg/m^3 0.87 1.15 19 Flag:Chlorophyll:Extracted n/a 20 Phaeo-Pigment:Extracted mg/m^3 0.47 0.54 21 Nitrate_plus_Nitrite umol/L 25.77 31.37 22 Flag:Nitrate_plus_Nitrite n/a 23 Silicate umol/L 53.55 60.55 24 Flag:Silicate n/a 25 Phosphate umol/L 2.067 2.703 26 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 5 14 -99 ' ' 5 I I 0 15 -99 ' ' 5 I I 0 16 -99 ' ' 9 F R4 4 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2024-032 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Strait of Georgia Ecosystem Survey SCIENTIST : Johannessen S. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : B.C. Inlets STATION : KN4 EVENT NUMBER : 11 LATITUDE : 50 40.76300 N ! (deg min) LONGITUDE : 125 55.88000 W ! (deg min) WATER DEPTH : 450 ALTIMETER (M) : 4.57 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0433 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2754 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 5130 Conductivity:2 ' ' 1766 'Oxygen:SBE 43' ' ' 4372 Fluorometer:Seapoint ' ' 2228 'Fluorometer:WET Labs ECO-AFL/FL' ' ' FLRTD-2216 Altimeter ' ' 76341 'Transmissometer:WET Labs C-Star' ' ' 1201DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2024/10/01 09:42:09 3399 3399 CLEAN 5.3 2024/10/01 09:45:35 3399 3399 ADDSAMP 3.6 2024/10/01 10:11:33 3399 3399 BINAVE 4.2.1 2024/10/01 10:11:47 3399 18 MERGE 3.6 2024/10/01 10:54:39 18 18 CLEAN 5.3 2024/10/01 11:00:35 18 18 CALIB 12.1 2024/10/30 11:15:58 18 18 CALIB 12.1 2024/10/30 12:01:20 18 18 SORT 3.6 2024/11/01 16:10:20 18 18 REMOVECH 8.2 2024/11/01 16:12:39 18 18 CHGUNITS 3.2 2024/11/01 16:13:24 18 18 CHGUNITS 3.2 2024/11/01 16:13:47 18 18 REORDER 1.3.1 2024/11/01 16:14:29 ? ? HDREDIT2 3.2 2024/11/01 16:56:21 ? ? CALIB 12.1 2025/04/24 15:01:44 18 18 HDREDIT2 3.2 2025/04/24 15:07:31 ? ? $END $REMARKS -CLEAN functions: 2024/10/01 09:45:33 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: E:\Telework\2024-001\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2024/10/01 10:54:39 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : E:\Telework\2024-001\Processing\hydro\2024-001-0011.samavg Secondary file: E:\Telework\2024-001\Processing\hydro\2024-001-0011.mrgcln1s 18 secondary records matched to primary records. Comments from secondary file: E:\Telework\2024-001\Processing\hydro\2024-001-0011.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2024/10/01 10:54:06 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2024/10/01 11:00:30 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2024/10/30 11:15:58 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2024-001\Processing\doc\2024-001-rcalsil.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 31 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T1:C1 -CALIB parameters: 2024/10/30 12:01:20 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2024-001\Processing\doc\2024-001-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Pressure decibar 10 -0.1100000E+01 0.1000000E+01 20 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1022000E+01 -SORT parameters: 2024/11/01 16:10:20 Sorted in ascending order of channel Pressure -REMOVECH 2024/11/01 16:12:39 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2024/11/01 16:56:21 Applied edit header: E:\Telework\2024-001\Processing\doc\HYDRO\2024-001-bot-hdr0443.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 17: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 19: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 22: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 24: Flag:Silicate [n/a] Units: ==> n/a Channel 26: Flag:Phosphate [n/a] Units: ==> n/a Channel 13: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 9: Fluorescence:URU:Wetlabs [mg/m^3] Name: Fluorescence:URU:Wetlabs:ECO-AFL ==> Fluorescence:URU:Wetlabs -CALIB parameters: 2025/04/24 15:01:44 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\FinishedJobs\2024-001\Corrections\Archive\DOC\2024-001-recal2.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE [mL/L] mL/L 10 0.0000000E+00 0.9700000E+00 12 Oxygen:Dissolved:SBE [umol/kg umol/kg 10 0.0000000E+00 0.9700000E+00 -HEADER EDITS: 2025/04/24 15:07:31 Applied edit header: E:\Telework\FinishedJobs\2024-001\Processing\doc\2024-001-HDR0443-corr.TXT $END *COMMENTS Comments from secondary file: E:\Telework\2024-001\Processing\hydro\2024-001-0011.mrgcln1s ------------------------------------------------------------ Comments from secondary file: E:\Telework\2024-001\Processing\hydro\2024-001-0011.chl ------------------------------------------------------- Sample_Number 69: CHL: sample #69B lost 3-5mL, estimated volume filtered = 291mL. Compares well with duplicate (CV% = 3) Comments from secondary file: E:\Telework\2024-001\Processing\hydro\2024-001-0011.nut ------------------------------------------------------- Sample_Number 57: SIL: Data from frozen Sample_Number 58: SIL: Data from frozen Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 3-5 weeks after the collection on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For further details on methodology, see document QF2024-001_CHL*.xlsx Methodology sheet. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at IOS immediately following the cruise using an automated Winkler titration system (Metrohm Dosimat model 876, a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2023-001OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 4 - 13 days after collection. For details see document QF2024-001SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2024-001nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers ---------------------------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Fluorescence and Transmissivity data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. There were 4 casts with calibration sampling for dissolved oxygen while sensor 4372 was in use; most of those samples came from areas where flushing of Niskin bottles is likely to be poor. Based on deep samples from sections where vertical DO gradients were fairly low, DO values were estimated to be low by about 2.2%. Recalibration was applied based on that estimate. For details on the processing see the report: 2024-001_Processing_Report.doc. ---------------------------------------------------------------------------------------------------- ---------------------------------------------------------------------------------------------------- The correction originally applied to DO sensor #4372 on CTD #0443 was found to be inappropriate. Results of COMPARE for 2024-006 and 2024-069 plus a post-cruise calibration showed unusual calibration drift for this sensor with CTD DO drifting to higher values. The results from inlets are too unreliable to estimate how much drift had occurred by March 2024, but there was likely to be some, so all SBE DO values were multiplied by 0.97 to cancel the earlier +2.2% correction and reduce values by a further 1% based on 2024-006 results. ---------------------------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !-------------------------------- --------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T1:C1) (0.904 0.3E-02 25) Pressure decibar 10 -99 () (-1.1 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.022) 'Oxygen:Dissolved:SBE [mL/L]' mL/L 10 -99 () (0 0.97) 'Oxygen:Dissolved:SBE [umol/kg]' umol/kg 10 -99 () (0 0.97) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- ---8--- ---9--- ---10--- --11-- --12- ----13--- -14- -15- ---16--- 17 --18-- 19 --20-- --21-- 22 --23-- 24 ---25-- 26 !Bo Bo Pressu Depth Temperat Trans Trans Fluores Fluores Salinity Oxygen Oxyge Conductiv Numb Samp Salinity Fl Chloro Fl Phaeo- Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi cence: cence: :T0:C0 : n: ity: er_o le_ :Bottle ag phyll: ag Pigmen e_ ag te ag te ag !~u ~u Primary vity vity: URU: URU: Dissol Disso Primary ~bin Numb ~o Extrac ~a t: plus_ ~t ~i ~p !mb en Green Seapoin Wetlabs ved: lved: _rec er tt ted ct Extrac Nitrit ri ca ha !er ce t SBE SBE ords le ed ted e te te te !-- -- ------ ------ -------- ----- ----- ------- ------- -------- ------ ----- --------- ---- ---- -------- -- ------ -- ------ ------ -- ------ -- ------- -- *END OF HEADER 18 18 1.4 2.5 6.6202 42.5 61.5 0.365 1.395 29.2812 6.24 272.3 2.97390 241 72 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 16 16 1.4 2.5 6.6146 42.4 61.5 0.367 1.395 29.2806 6.23 272.1 2.97339 55 70 -99.0000 0 1.10 0 0.54 25.77 0 53.76 0 2.067 0 17 17 1.4 2.5 6.6228 42.5 61.2 0.363 1.423 29.2810 6.23 272.1 2.97409 62 71 29.2805 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 15 15 3.7 4.8 6.6250 42.5 61.4 0.365 1.290 29.2945 6.22 271.6 2.97559 241 69 -99.0000 0 1.15 26 0.54 25.93 0 53.70 0 2.077 0 14 14 8.9 9.9 6.8159 43.3 62.9 0.378 1.433 29.4794 6.03 263.5 3.00793 241 68 -99.0000 0 0.87 0 0.47 26.32 6 53.55 6 2.146 6 13 13 23.6 24.5 7.4161 46.4 68.3 0.322 0.738 30.0966 5.39 235.4 3.11409 241 67 -99.0000 0 -99.00 0 -99.00 27.18 0 53.88 0 2.204 0 11 11 49.0 49.6 7.8140 47.7 70.5 0.343 0.378 30.4994 4.92 214.7 3.18553 54 65 30.4889 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 12 12 49.0 49.6 7.8152 47.7 70.6 0.344 0.369 30.5005 4.92 214.4 3.18574 241 66 -99.0000 0 -99.00 0 -99.00 27.97 0 54.37 0 2.317 0 10 10 74.2 74.7 7.9173 47.5 70.4 0.337 0.273 30.6238 4.71 205.7 3.20687 241 64 -99.0000 0 -99.00 0 -99.00 28.44 0 54.77 0 2.370 0 9 9 99.3 99.5 7.9880 48.3 72.1 0.333 0.187 30.7818 4.37 190.5 3.22872 241 63 -99.0000 0 -99.00 0 -99.00 28.93 0 55.42 0 2.411 0 8 8 148.7 148.5 7.9842 51.3 78.1 0.317 0.086 30.9936 3.61 157.4 3.25051 241 62 -99.0000 0 -99.00 0 -99.00 30.56 0 56.28 0 2.494 0 7 7 198.8 198.1 7.9901 49.5 74.9 0.306 0.081 31.2637 3.17 138.3 3.27865 241 61 -99.0000 0 -99.00 0 -99.00 30.90 0 57.51 0 2.591 0 6 6 249.3 248.1 8.0042 49.3 74.5 0.305 0.067 31.3341 3.03 132.1 3.28860 241 60 -99.0000 0 -99.00 0 -99.00 30.66 6 58.04 6 2.621 6 5 5 298.8 297.1 8.0064 46.5 69.5 0.303 0.070 31.3691 2.96 128.9 3.29415 241 59 -99.0000 0 -99.00 0 -99.00 31.16 0 59.08 0 2.655 0 4 4 398.7 396.0 8.0134 40.8 58.3 0.256 0.085 31.3814 2.90 126.6 3.30004 241 58 -99.0000 0 -99.00 0 -99.00 31.20 0 60.06 3 2.683 0 2 2 448.1 444.9 8.0190 34.7 48.4 0.250 0.085 31.3826 2.89 125.8 3.30266 46 56 31.3780 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 3 3 448.1 444.9 8.0190 35.2 48.8 0.246 0.084 31.3826 2.89 125.8 3.30267 241 57 -99.0000 0 -99.00 0 -99.00 31.37 0 60.55 3 2.703 0 1 1 448.1 444.9 8.0190 35.2 48.9 0.254 0.085 31.3827 2.89 125.8 3.30267 49 55 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0