*2024/05/29 16:20:20.33 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2023/10/06 11:13:28.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 1 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : ACAFFD97 NUMBER OF CHANNELS : 26 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 1 2 Bottle:Firing_Sequence n/a 1 1 3 Pressure decibar 125.413 125.413 4 Depth metres 124.319 124.319 5 Temperature:Primary 'deg C (ITS90)' 7.5986 7.5986 6 Transmissivity %/metre 39.4 39.4 7 Transmissivity:Green %/metre 49.9 49.9 8 Fluorescence:URU:Seapoint mg/m^3 0.123 0.123 9 PAR uE/m^2/sec 0 0 10 PAR:Reference uE/m^2/sec 11.049 11.049 11 Salinity:T0:C0 PSS-78 33.8137 33.8137 12 Oxygen:Dissolved:SBE mL/L 1.133 1.133 13 Oxygen:Dissolved:SBE umol/kg 49.3 49.3 14 Conductivity:Primary S/m 3.479014 3.479014 15 Number_of_bin_records n/a 241 241 16 Sample_Number n/a 1 1 17 Temperature:Draw 'deg C (ITS90)' 9.05 9.05 18 Oxygen:Dissolved mL/L 1.107 1.107 19 Oxygen:Dissolved umol/kg 48.17726 48.17726 20 Flag:Oxygen:Dissolved n/a 21 Nitrate_plus_Nitrite umol/L 35.22 35.22 22 Flag:Nitrate_plus_Nitrite n/a 23 Silicate umol/L 59.62 59.62 24 Flag:Silicate n/a 25 Phosphate umol/L 2.775 2.775 26 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 7 F ' ' 1 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 10 F ' ' 5 15 -99 ' ' 5 I I 0 16 -99 ' ' 5 I I 0 17 -99 ' ' 6 F R4 1 18 -99 ' ' 8 F R4 3 19 -99 ' ' 6 F ' ' 1 20 n/a ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 0 ' ' 3 NQ C ' ' $END $REMARKS This file converted from Sea-Bird file: E:\Telework\2023-081\Processing\hydro\2023-081-0025.ros REPLACE Quality flags have the following significance: 0123456789012345678901234567890123456789012345678901234567890123456789012345678901234567890123456789 ---------------------------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2023-081 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Acoustic Moorings & Oceanography SCIENTIST : O'Neill C. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LB08 EVENT NUMBER : 25 LATITUDE : 48 25.33000 N ! (deg min) LONGITUDE : 125 28.70000 W ! (deg min) WATER DEPTH : 152 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 1515 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 6754 Conductivity ' ' 6141 'Pressure:Digiquartz with TC' ' ' 1515 Temperature:2 ' ' 6736 Conductivity:2 ' ' 6146 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3950 PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 79487 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG Unavailable ' ' ' ' SPAR:Biospherical/Licor ' ' 16504 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2024/05/24 12:40:40 241 241 CLEAN 5.3 2024/05/24 12:40:48 241 241 ADDSAMP 3.6 2024/05/24 13:01:50 241 241 BINAVE 4.2.1 2024/05/24 13:02:10 241 1 MERGE 3.6 2024/05/24 13:38:05 1 1 CLEAN 5.3 2024/05/29 14:04:26 1 1 CALIB 12.1 2024/05/29 14:10:12 1 1 CALIB 12.1 2024/05/29 14:10:40 1 1 SORT 3.6 2024/05/29 16:00:32 1 1 REMOVECH 8.2 2024/05/29 16:01:15 1 1 CHGUNITS 3.2 2024/05/29 16:14:24 1 1 CHGUNITS 3.2 2024/05/29 16:15:09 1 1 REORDER 1.3.1 2024/05/29 16:15:32 ? ? HDREDIT2 3.2 2024/05/29 16:20:20 ? ? $END $REMARKS -CLEAN functions: 2024/05/24 12:40:48 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: E:\Telework\2023-081\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2024/05/24 13:38:05 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Sample_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide_7890GC, Flag:Dimethyl_Sulphide_7890GC, Dimethyl_Sulphide_8890GC, Flag:Dimethyl_Sulphide_8890GC, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : E:\Telework\2023-081\Processing\hydro\2023-081-0025.samavg Secondary file: E:\Telework\2023-081\Processing\hydro\2023-081-0025.mrgcln1s 1 secondary records matched to primary records. Comments from secondary file: E:\Telework\2023-081\Processing\hydro\2023-081-0025.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2024/05/24 13:37:18 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2024/05/29 14:04:26 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2024/05/29 14:10:12 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-081\Processing\doc\2023-081-recalsil.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 30 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2024/05/29 14:10:40 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-081\Processing\doc\2023-081-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Salinity:T0:C0 PSS-78 10 0.1060000E-01 0.1000000E+01 20 Salinity:T1:C1 PSS-78 10 0.8600000E-02 0.1000000E+01 21 Oxygen:Dissolved:SBE mL/L 10 0.3190000E-01 0.1014800E+01 -SORT parameters: 2024/05/29 16:00:32 Sorted in ascending order of channel Pressure [decibar] -REMOVECH 2024/05/29 16:01:15 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2024/05/29 16:20:20 Applied edit header: E:\Telework\2023-081\Processing\doc\HYDRO\2023-081-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 17: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 20: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Pad: 0 ==> n/a Channel 22: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 24: Flag:Silicate [n/a] Units: ==> n/a Channel 26: Flag:Phosphate [n/a] Units: ==> n/a Channel 9: PAR [uE/m^2/sec] Units: umol/m^2/sec ==> uE/m^2/sec Format: F11.3 ==> F7.1 Channel 10: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 14: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 $END *COMMENTS Comments from secondary file: E:\Telework\2023-081\Processing\hydro\2023-081-0025.mrgcln1s ------------------------------------------------------------ Comments from secondary file: E:\Telework\2023-081\Processing\hydro\2023-081-0025.oxy ------------------------------------------------------- Sample_Number 1: OXY-1: zooplankton in flask but curve looks good. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 3 weeks after the cruise on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For details on methodology, see document QF2023-081_CHL*.xlsx Methodology sheet. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2023-081OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 25 days after collection. For details including a duplicate analysis, see document QF2023-081SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Insitute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in "IOS Nutrient Methods (1996) Barwell-Clarke and Whitney". For details including a duplicate analysis, see document QF2023-081nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers ---------------------------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the SBE fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. There was little dissolved oxygen sampling below 200db, but it was sufficient to show consistency with cruise (2023-026) when there was more sampling, so recalibration of SBE dissolved oxygen nwas based on 2023-026. For details on the processing see the report: 2023-081_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Salinity:T0:C0 PSS-78 10 -99 () (0.106E-01 1) Salinity:T1:C1 PSS-78 10 -99 () (0.86E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.319E-01 1.0148) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- ---8--- --9--- --10-- ---11--- --12-- --13- ----14--- -15- -16- --17- ---18-- --19- 20 --21-- 22 --23-- 24 ---25-- 26 !Bo Bo Pressu Depth Temperat Trans Trans Fluores PAR PAR: Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi cence: Refere :T0:C0 : n: ity: er_o le_ ratur Dissolv n: ag e_ ag te ag te ag !~u ~u Primary vity vity: URU: nce Dissol Disso Primary ~bin Numb e: ed Disso ~o plus_ ~t ~i ~p !mb en Green Seapoin ved: lved: _rec er Draw lved lv Nitrit ri ca ha !er ce t SBE SBE ords ed e te te te !-- -- ------ ------ -------- ----- ----- ------- ------ ------ -------- ------ ----- --------- ---- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 1 1 125.4 124.3 7.5986 39.4 49.9 0.123 0.0 11.0 33.8137 1.13 49.3 3.47901 241 1 9.1 1.107 48.2 26 35.22 6 59.62 6 2.775 6