*2023/11/03 13:18:32.57 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2023/05/14 01:49:08.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : BE429FA0 NUMBER OF CHANNELS : 30 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 17 2 Bottle:Firing_Sequence n/a 1 17 3 Pressure decibar 1.13 350.73 4 Depth metres 1.128 347.444 5 Temperature:Primary 'deg C (ITS90)' 8.0228 16.9227 6 Transmissivity %/metre 9.9 65 7 Transmissivity:Green %/metre 10.2 86.5 8 Fluorescence:URU:Seapoint mg/m^3 0.105 5.726 9 PAR uE/m^2/sec 0 409.968 10 Salinity:T0:C0 PSS-78 25.3412 30.8279 11 Oxygen:Dissolved:SBE mL/L 3.422 10.467 12 Oxygen:Dissolved:SBE umol/kg 149.3 457.4 13 Conductivity:Primary S/m 3.193528 3.412758 14 Number_of_bin_records n/a 94 241 15 Sample_Number n/a 706 722 16 Temperature:Draw 'deg C (ITS90)' 8.9 17.7 17 Salinity:Bottle PSS-78 30.7284 30.7284 18 Flag:Salinity:Bottle n/a 19 Chlorophyll:Extracted mg/m^3 0.65 5.71 20 Flag:Chlorophyll:Extracted n/a 21 Phaeo-Pigment:Extracted mg/m^3 0.45 3.08 22 Oxygen:Dissolved mL/L 3.43 10.069 23 Oxygen:Dissolved umol/kg 149.6262 440.0357 24 Flag:Oxygen:Dissolved n/a 25 Nitrate_plus_Nitrite umol/L 0 30.9 26 Flag:Nitrate_plus_Nitrite n/a 27 Silicate umol/L 4 70.89 28 Flag:Silicate n/a 29 Phosphate umol/L 0.172 2.763 30 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 5 14 -99 ' ' 5 I I 0 15 -99 ' ' 5 I I 0 16 -99 ' ' 6 F R4 1 17 -99 ' ' 9 F R4 4 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 8 F R4 3 23 -99 ' ' 6 F ' ' 1 24 n/a ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 0 ' ' 3 NQ C ' ' 29 -99 ' ' 8 F R4 3 30 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2023-066 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : 12 EVENT NUMBER : 120 LATITUDE : 49 43.67000 N ! (deg min) LONGITUDE : 124 40.77000 W ! (deg min) WATER DEPTH : 353 ALTIMETER (M) : 3.79 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2663 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 2106 Conductivity:2 ' ' 2754 Fluorometer:Seapoint ' ' 3640 'Oxygen:SBE 43' ' ' 3791 PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' ' ' 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2023/09/07 10:19:19 3950 3950 CLEAN 5.3 2023/09/07 10:24:20 3950 3950 ADDSAMP 3.6 2023/09/07 10:42:14 3950 3950 BINAVE 4.2.1 2023/09/07 10:42:32 3950 17 MERGE 3.6 2023/11/03 10:02:43 17 17 CLEAN 5.3 2023/11/03 10:02:49 17 17 CALIB 12.1 2023/11/03 10:03:57 17 17 CALIB 12.1 2023/11/03 10:04:12 17 17 SORT 3.6 2023/11/03 10:04:22 17 17 REMOVECH 8.2 2023/11/03 10:04:36 17 17 CHGUNITS 3.2 2023/11/03 10:04:46 17 17 CHGUNITS 3.2 2023/11/03 10:04:58 17 17 REORDER 1.3.1 2023/11/03 10:05:15 ? ? HDREDIT2 3.2 2023/11/03 13:18:32 ? ? $END $REMARKS -CLEAN functions: 2023/09/07 10:24:11 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2023-066\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2023/11/03 10:02:43 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Sample_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : E:\Telework\2023-066\Processing\hydro\2023-066-0120.samavg Secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0120.mrgcln1s 17 secondary records matched to primary records. Comments from secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0120.mrgcln1s ------------------------------------------------------------ -CLEAN functions: 2023/11/03 10:01:56 20 Reduce header to sections: FIL HIS COM Remarks removed from kept sections. Reset #RECS, MIN & MAX values in header. -SORT parameters: 2023/11/03 10:02:11 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2023/11/03 10:02:46 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. -CALIB parameters: 2023/11/03 10:03:57 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-066\Processing\doc\2023-066-recal-SIL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 34 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2023/11/03 10:04:12 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-066\Processing\doc\2023-066-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Pressure decibar 10 0.8000000E+00 0.1000000E+01 5 Depth:Salt_Water metres 10 0.8000000E+00 0.1000000E+01 20 Oxygen:Dissolved:SBE mL/L 10 -0.9400000E-02 0.1011500E+01 -SORT parameters: 2023/11/03 10:04:22 Sorted in ascending order of channel Pressure [decibar] -REMOVECH 2023/11/03 10:04:36 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary [deg C (ITS90)] Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2023/11/03 13:18:32 Applied edit header: E:\Telework\2023-066\Processing\doc\HYDRO\2023-066-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 16: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 18: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 20: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 24: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Pad: 0 ==> n/a Channel 26: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 28: Flag:Silicate [n/a] Units: ==> n/a Channel 30: Flag:Phosphate [n/a] Units: ==> n/a Channel 9: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 13: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 $END *COMMENTS Comments from secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0120.mrgcln1s ------------------------------------------------------------ Comments from secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0120.chl ------------------------------------------------------- Sample_Number 722: CHL: CV%>10, particulate in tube of 722A during analysis. Comments from secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0120.oxy ------------------------------------------------------- Sample_Number 709: OXY-2: Aborted - Titration did not go above 1.3 V. Duplicate intended, only OXY-1 reported. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 2.5 weeks after the cruise on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For details see worksheet “CV%” in file QF2023-066_CHL*.xlsx. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2023-066OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 18 - 34 days after collection. For details including a duplicate analysis, see document QF2023-066SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2023-066nuts*.xlsx. The minimum detectable level for DMS is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more details including method, raw data and duplicates, see document "DMS Summary (2023-066).xls”. Detailed notes on analysis are in file 2023-066 DMS report*.doc. 7890 DMS System was used for all stations except P26 for which the new 8890 System was used. The minimum detectable level for DMSP is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more details including method, raw data and duplicates, see document "DMSP 2023-066 Summary*.xls”. Detailed notes on analysis are in file 2023-066 DMS report*.doc. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. Two CTDs were used for this cruise (Events #1-58 and #60-153). The CTD data were affected by frequent pressure spikes that were not resolved by replacing the CTD with a new one. Most large spikes were below 1000db and were removed in processing. None were noted during stops for bottles. For Events #1-39 the configuration file was set as follows: Number of Scans Averaged by the Deck Unit = 24 Normally each scan is recorded individually and averaging is not done until after fine-tuning of settings for alignment and removal of bad records. The quality of CTD data from casts #1-39 is considered lower than usual. Fluorescence data were removed from Events #26-39 due to fluorometer malfunction. A new fluorometer was installed for Events #41-153. NOTE: While the SBE fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. For details on the processing see the report: 2023-066_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Pressure decibar 10 -99 () (0.8 1) Depth:Salt_Water metres 10 -99 () (0.8 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.94E-02 1.0115) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- ---8--- --9--- ---10--- --11-- --12- ----13--- -14- -15- --16- ---17--- 18 --19-- 20 --21-- ---22-- --23- 24 --25-- 26 --27-- 28 ---29-- 30 !Bo Bo Pressu Depth Temperat Trans Trans Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi cence: :T0:C0 : n: ity: er_o le_ ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~u ~u Primary vity vity: URU: Dissol Disso Primary ~bin Numb e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !mb en Green Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitrit ri ca ha !er ce t SBE SBE ords le ed ted ed e te te te !-- -- ------ ------ -------- ----- ----- ------- ------ -------- ------ ----- --------- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 16 16 1.1 1.1 16.8887 10.0 10.4 3.227 410.0 25.3473 9.62 421.9 3.35123 94 721 17.7 -99.0000 0 -99.00 0 -99.00 9.568 419.8 0 -99.00 0 -99.00 0 -99.000 0 17 17 1.1 1.1 16.9227 9.9 10.2 3.116 386.2 25.3412 9.62 421.9 3.35306 241 722 -99.0 -99.0000 0 2.42 36 0.45 -99.000 -99.0 0 0.00 0 14.26 0 0.172 0 15 15 5.9 5.8 12.2990 36.0 43.6 2.777 41.5 29.0994 10.47 457.4 3.41276 241 720 12.5 -99.0000 0 5.02 0 1.46 10.069 440.0 0 1.19 0 4.00 0 0.585 0 14 14 10.8 10.7 10.5830 26.9 30.7 5.726 6.2 29.3889 8.51 371.7 3.30245 241 719 10.5 -99.0000 0 5.71 0 3.08 6.271 273.9 0 12.72 0 28.56 0 1.694 0 13 13 21.0 20.8 8.7005 62.8 82.5 0.586 0.2 29.8354 5.06 220.8 3.19353 241 718 10.1 -99.0000 0 0.65 0 0.95 5.095 222.4 0 21.52 0 47.51 0 2.251 0 12 12 30.9 30.7 8.6465 63.7 83.9 0.408 0.0 29.8896 5.00 218.3 3.19476 241 717 9.7 -99.0000 0 -99.00 0 -99.00 4.941 215.7 0 22.67 0 49.49 0 2.281 0 11 11 40.8 40.5 8.8580 62.1 82.0 0.387 0.0 30.0240 4.88 213.2 3.22548 241 716 9.9 -99.0000 0 -99.00 0 -99.00 4.834 211.0 0 24.23 0 51.65 0 2.287 0 10 10 51.3 50.9 8.8819 60.7 79.2 0.383 0.0 30.1119 4.58 200.0 3.23640 241 715 9.7 -99.0000 0 -99.00 0 -99.00 4.571 199.5 0 25.34 6 53.81 6 2.346 6 9 9 76.4 75.8 8.7212 61.3 79.8 0.270 0.0 30.2484 4.37 190.7 3.23741 241 714 9.6 -99.0000 0 -99.00 0 -99.00 4.237 184.9 0 28.87 0 57.99 0 2.517 0 8 8 101.3 100.4 8.4203 62.8 84.9 0.144 0.0 30.4088 3.90 170.1 3.22902 241 713 9.3 -99.0000 0 -99.00 0 -99.00 3.897 170.0 0 30.90 0 60.86 0 2.634 0 7 7 126.4 125.3 8.1735 65.0 86.5 0.118 0.0 30.5237 4.23 184.5 3.22064 241 712 9.1 -99.0000 0 -99.00 0 -99.00 4.302 187.7 0 30.28 0 58.09 0 2.536 0 6 6 151.5 150.1 8.0228 63.4 84.3 0.113 0.0 30.6013 4.67 203.7 3.21657 241 711 8.9 -99.0000 0 -99.00 0 -99.00 4.632 202.1 0 29.23 0 56.10 0 2.429 0 5 5 176.1 174.6 8.1966 63.6 84.4 0.110 0.0 30.6652 4.23 184.3 3.23807 241 710 9.2 -99.0000 0 -99.00 0 -99.00 4.259 185.8 6 29.79 0 59.47 0 2.510 0 4 4 201.6 199.8 8.1537 63.1 83.7 0.106 0.0 30.6896 4.34 189.2 3.23788 241 709 9.1 -99.0000 0 -99.00 0 -99.00 4.308 187.9 2 29.51 0 59.33 0 2.570 0 3 3 251.2 248.9 8.2503 62.7 83.3 0.105 0.0 30.7310 4.12 179.9 3.25190 241 708 9.1 30.7284 0 -99.00 0 -99.00 4.120 179.7 0 29.81 0 60.73 0 2.604 0 2 2 301.3 298.5 8.3442 61.6 82.1 0.105 0.0 30.7586 3.95 172.4 3.26442 241 707 9.2 -99.0000 0 -99.00 0 -99.00 3.962 172.8 0 29.85 0 62.38 0 2.632 0 1 1 350.7 347.4 8.5859 54.8 70.7 0.114 0.0 30.8279 3.42 149.3 3.29328 241 706 9.5 -99.0000 0 -99.00 0 -99.00 3.430 149.6 0 30.30 6 70.89 6 2.763 6