*2023/11/03 13:18:32.49 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2023/05/13 22:58:38.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : C5C7A6BD NUMBER OF CHANNELS : 30 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 17 2 Bottle:Firing_Sequence n/a 1 17 3 Pressure decibar 1.38 310.46 4 Depth metres 1.37 307.583 5 Temperature:Primary 'deg C (ITS90)' 8.2659 15.6359 6 Transmissivity %/metre 34.2 65.6 7 Transmissivity:Green %/metre 38.3 87.6 8 Fluorescence:URU:Seapoint mg/m^3 0.104 2.411 9 PAR uE/m^2/sec 0 1434.271 10 Salinity:T0:C0 PSS-78 28.0474 30.7489 11 Oxygen:Dissolved:SBE mL/L 3.66 10.223 12 Oxygen:Dissolved:SBE umol/kg 159.7 446.9 13 Conductivity:Primary S/m 3.220655 3.569529 14 Number_of_bin_records n/a 99 241 15 Sample_Number n/a 689 705 16 Temperature:Draw 'deg C (ITS90)' 9.1 15.8 17 Salinity:Bottle PSS-78 30.743 30.743 18 Flag:Salinity:Bottle n/a 19 Chlorophyll:Extracted mg/m^3 0.68 2.7 20 Flag:Chlorophyll:Extracted n/a 21 Phaeo-Pigment:Extracted mg/m^3 0.49 2.28 22 Oxygen:Dissolved mL/L 3.662 9.254 23 Oxygen:Dissolved umol/kg 159.7801 404.578 24 Flag:Oxygen:Dissolved n/a 25 Nitrate_plus_Nitrite umol/L 0 31.58 26 Flag:Nitrate_plus_Nitrite n/a 27 Silicate umol/L 6.36 63.33 28 Flag:Silicate n/a 29 Phosphate umol/L 0.239 2.725 30 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 5 14 -99 ' ' 5 I I 0 15 -99 ' ' 5 I I 0 16 -99 ' ' 6 F R4 1 17 -99 ' ' 9 F R4 4 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 8 F R4 3 23 -99 ' ' 6 F ' ' 1 24 n/a ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 0 ' ' 3 NQ C ' ' 29 -99 ' ' 8 F R4 3 30 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2023-066 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : 14 EVENT NUMBER : 118 LATITUDE : 49 53.04000 N ! (deg min) LONGITUDE : 124 59.61000 W ! (deg min) WATER DEPTH : 313 ALTIMETER (M) : 5.13 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2663 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 2106 Conductivity:2 ' ' 2754 Fluorometer:Seapoint ' ' 3640 'Oxygen:SBE 43' ' ' 3791 PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' ' ' 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2023/09/07 10:19:18 3955 3955 CLEAN 5.3 2023/09/07 10:24:19 3955 3955 ADDSAMP 3.6 2023/09/07 10:42:13 3955 3955 BINAVE 4.2.1 2023/09/07 10:42:32 3955 17 MERGE 3.6 2023/11/03 10:02:43 17 17 CLEAN 5.3 2023/11/03 10:02:49 17 17 CALIB 12.1 2023/11/03 10:03:57 17 17 CALIB 12.1 2023/11/03 10:04:12 17 17 SORT 3.6 2023/11/03 10:04:22 17 17 REMOVECH 8.2 2023/11/03 10:04:36 17 17 CHGUNITS 3.2 2023/11/03 10:04:46 17 17 CHGUNITS 3.2 2023/11/03 10:04:58 17 17 REORDER 1.3.1 2023/11/03 10:05:15 ? ? HDREDIT2 3.2 2023/11/03 13:18:32 ? ? $END $REMARKS -CLEAN functions: 2023/09/07 10:24:11 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2023-066\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2023/11/03 10:02:43 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Sample_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : E:\Telework\2023-066\Processing\hydro\2023-066-0118.samavg Secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0118.mrgcln1s 17 secondary records matched to primary records. Comments from secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0118.mrgcln1s ------------------------------------------------------------ -CLEAN functions: 2023/11/03 10:01:56 20 Reduce header to sections: FIL HIS COM Remarks removed from kept sections. Reset #RECS, MIN & MAX values in header. -SORT parameters: 2023/11/03 10:02:11 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2023/11/03 10:02:46 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. -CALIB parameters: 2023/11/03 10:03:57 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-066\Processing\doc\2023-066-recal-SIL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 34 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2023/11/03 10:04:12 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-066\Processing\doc\2023-066-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Pressure decibar 10 0.8000000E+00 0.1000000E+01 5 Depth:Salt_Water metres 10 0.8000000E+00 0.1000000E+01 20 Oxygen:Dissolved:SBE mL/L 10 -0.9400000E-02 0.1011500E+01 -SORT parameters: 2023/11/03 10:04:22 Sorted in ascending order of channel Pressure [decibar] -REMOVECH 2023/11/03 10:04:36 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary [deg C (ITS90)] Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2023/11/03 13:18:32 Applied edit header: E:\Telework\2023-066\Processing\doc\HYDRO\2023-066-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 14: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 16: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 18: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 20: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 24: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Pad: 0 ==> n/a Channel 26: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 28: Flag:Silicate [n/a] Units: ==> n/a Channel 30: Flag:Phosphate [n/a] Units: ==> n/a Channel 9: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 13: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 $END *COMMENTS Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 2.5 weeks after the cruise on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For details see worksheet “CV%” in file QF2023-066_CHL*.xlsx. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2023-066OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 18 - 34 days after collection. For details including a duplicate analysis, see document QF2023-066SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2023-066nuts*.xlsx. The minimum detectable level for DMS is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more details including method, raw data and duplicates, see document "DMS Summary (2023-066).xls”. Detailed notes on analysis are in file 2023-066 DMS report*.doc. 7890 DMS System was used for all stations except P26 for which the new 8890 System was used. The minimum detectable level for DMSP is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more details including method, raw data and duplicates, see document "DMSP 2023-066 Summary*.xls”. Detailed notes on analysis are in file 2023-066 DMS report*.doc. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. Two CTDs were used for this cruise (Events #1-58 and #60-153). The CTD data were affected by frequent pressure spikes that were not resolved by replacing the CTD with a new one. Most large spikes were below 1000db and were removed in processing. None were noted during stops for bottles. For Events #1-39 the configuration file was set as follows: Number of Scans Averaged by the Deck Unit = 24 Normally each scan is recorded individually and averaging is not done until after fine-tuning of settings for alignment and removal of bad records. The quality of CTD data from casts #1-39 is considered lower than usual. Fluorescence data were removed from Events #26-39 due to fluorometer malfunction. A new fluorometer was installed for Events #41-153. NOTE: While the SBE fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. For details on the processing see the report: 2023-066_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Pressure decibar 10 -99 () (0.8 1) Depth:Salt_Water metres 10 -99 () (0.8 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.94E-02 1.0115) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- ---8--- --9--- ---10--- --11-- --12- ----13--- -14- -15- --16- ---17--- 18 --19-- 20 --21-- ---22-- --23- 24 --25-- 26 --27-- 28 ---29-- 30 !Bo Bo Pressu Depth Temperat Trans Trans Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi cence: :T0:C0 : n: ity: er_o le_ ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~u ~u Primary vity vity: URU: Dissol Disso Primary ~bin Numb e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !mb en Green Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitrit ri ca ha !er ce t SBE SBE ords le ed ted ed e te te te !-- -- ------ ------ -------- ----- ----- ------- ------ -------- ------ ----- --------- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 16 16 1.4 1.4 15.6359 39.1 44.5 0.573 1433.4 28.0483 8.96 392.2 3.56953 99 704 15.8 -99.0000 0 -99.00 0 -99.00 9.236 404.2 0 -99.00 0 -99.00 0 -99.000 0 17 17 1.4 1.4 15.6316 39.5 44.6 0.572 1434.3 28.0474 8.94 391.2 3.56907 241 705 -99.0 -99.0000 0 1.60 0 0.49 -99.000 -99.0 0 0.00 0 6.36 0 0.239 0 15 15 5.8 5.7 12.8359 34.2 38.3 2.411 346.7 28.9243 10.22 446.9 3.43813 241 703 13.9 -99.0000 0 2.70 0 0.96 9.254 404.6 0 0.94 0 9.83 0 0.476 0 14 14 11.0 10.9 11.1286 44.2 54.4 1.932 59.7 29.1978 7.53 329.1 3.32747 241 702 11.7 -99.0000 0 2.01 0 2.28 7.254 316.9 6 7.53 0 24.11 0 1.309 0 13 13 21.1 21.0 9.3643 60.3 79.9 0.680 5.7 29.5896 5.90 257.8 3.22358 241 701 10.3 -99.0000 0 0.68 6 1.62 5.811 253.8 0 16.44 0 40.16 0 1.985 0 12 12 30.9 30.6 9.1495 61.4 80.2 0.570 1.4 29.8241 5.28 230.3 3.22947 241 700 10.0 -99.0000 0 -99.00 0 -99.00 4.985 217.6 0 21.50 0 47.94 0 2.185 0 11 11 41.1 40.8 8.9411 61.8 80.5 0.390 0.3 29.9042 4.72 206.1 3.22065 241 699 10.1 -99.0000 0 -99.00 0 -99.00 4.612 201.3 0 23.76 0 51.63 0 2.306 0 10 10 51.1 50.6 8.8390 62.2 81.4 0.342 0.0 30.0269 4.49 195.8 3.22461 241 698 9.8 -99.0000 0 -99.00 0 -99.00 4.436 193.6 0 24.96 6 53.94 6 2.364 6 9 9 76.2 75.5 8.6654 61.9 81.1 0.248 0.0 30.2684 4.14 180.5 3.23472 241 697 9.9 -99.0000 0 -99.00 0 -99.00 4.109 179.3 0 27.89 0 57.79 0 2.526 0 8 8 100.8 99.9 8.4168 65.1 86.9 0.135 0.0 30.5140 3.66 159.7 3.23880 241 696 9.3 -99.0000 0 -99.00 0 -99.00 3.662 159.8 0 31.58 6 62.56 6 2.725 6 7 7 126.4 125.3 8.3488 64.9 86.7 0.116 0.0 30.6166 3.84 167.6 3.24404 241 695 9.5 -99.0000 0 -99.00 0 -99.00 3.805 166.0 0 30.97 0 62.24 0 2.681 0 6 6 151.1 149.7 8.3002 65.6 87.6 0.113 0.0 30.6477 3.99 174.1 3.24399 241 694 9.1 -99.0000 0 -99.00 0 -99.00 3.983 173.8 0 30.46 0 61.37 0 2.634 0 5 5 175.9 174.3 8.2659 64.8 86.5 0.115 0.0 30.6565 4.06 177.3 3.24300 241 693 9.2 -99.0000 0 -99.00 0 -99.00 4.072 177.6 0 30.14 0 61.03 0 2.609 0 4 4 200.9 199.1 8.3095 63.3 84.2 0.112 0.0 30.6871 3.99 174.2 3.25058 241 692 9.2 -99.0000 0 -99.00 0 -99.00 3.999 174.5 0 30.46 0 61.96 0 2.628 0 3 3 251.3 249.0 8.2871 62.9 83.4 0.104 0.0 30.7199 4.05 176.6 3.25391 241 691 9.2 -99.0000 0 -99.00 0 -99.00 4.054 176.9 0 30.21 0 61.58 0 2.611 0 2 2 301.4 298.6 8.3686 60.8 80.2 0.109 0.0 30.7437 3.90 170.0 3.26502 241 690 9.2 30.7430 0 -99.00 0 -99.00 3.886 169.5 6 30.00 0 63.16 0 2.644 0 1 1 310.5 307.6 8.3818 59.9 79.0 0.105 0.0 30.7489 3.87 169.0 3.26699 241 689 9.2 -99.0000 0 -99.00 0 -99.00 3.877 169.1 0 30.02 0 63.33 0 2.647 0