*2023/11/03 13:18:31.16 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2023/05/05 08:18:23.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 5F606F0C NUMBER OF CHANNELS : 25 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 24 2 Bottle:Firing_Sequence n/a 1 24 3 Pressure decibar 4.77 3361.48 4 Depth metres 4.738 3306.633 5 Temperature:Primary 'deg C (ITS90)' 1.6115 7.9153 6 Transmissivity %/metre 66.2 71.5 7 Transmissivity:Green %/metre 91.1 100.1 8 Fluorescence:URU:Seapoint mg/m^3 0.79E-01 0.667 9 Salinity:T0:C0 PSS-78 32.3114 34.6561 10 Oxygen:Dissolved:SBE mL/L 0.277 6.937 11 Oxygen:Dissolved:SBE umol/kg 12 302.2 12 Conductivity:Primary S/m 3.124426 3.363015 13 Number_of_bin_records n/a 72 241 14 Sample_Number n/a 249 272 15 Salinity:Bottle PSS-78 34.3794 34.6559 16 Flag:Salinity:Bottle n/a 17 Chlorophyll:Extracted mg/m^3 0.22 0.22 18 Flag:Chlorophyll:Extracted n/a 19 Phaeo-Pigment:Extracted mg/m^3 0.7E-01 0.7E-01 20 Nitrate_plus_Nitrite umol/L 9.42 9.42 21 Flag:Nitrate_plus_Nitrite n/a 22 Silicate umol/L 13.47 13.47 23 Flag:Silicate n/a 24 Phosphate umol/L 1.004 1.004 25 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 10 F ' ' 5 13 -99 ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 9 F R4 4 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 7 F R4 2 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 3 25 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2023-066 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P14 EVENT NUMBER : 46 LATITUDE : 49 7.34000 N ! (deg min) LONGITUDE : 132 39.93000 W ! (deg min) WATER DEPTH : 3312 ALTIMETER (M) : 10.18 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 1515 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 6754 Conductivity ' ' 6141 'Pressure:Digiquartz with TC' ' ' 1515 Temperature:2 ' ' 6736 Conductivity:2 ' ' 6146 Fluorometer:Seapoint ' ' 3640 'Oxygen:SBE 43' ' ' 1119 PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' ' ' 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2023/08/25 15:50:32 5615 5615 CLEAN 5.3 2023/08/25 17:36:32 5615 5615 ADDSAMP 3.6 2023/08/28 10:58:51 5615 5615 BINAVE 4.2.1 2023/08/28 14:38:59 5615 24 MERGE 3.6 2023/11/03 10:02:41 24 24 CLEAN 5.3 2023/11/03 10:02:47 24 24 CALIB 12.1 2023/11/03 10:03:56 24 24 CALIB 12.1 2023/11/03 10:04:10 24 24 SORT 3.6 2023/11/03 10:04:21 24 24 REMOVECH 8.2 2023/11/03 10:04:34 24 24 CHGUNITS 3.2 2023/11/03 10:04:44 24 24 CHGUNITS 3.2 2023/11/03 10:04:56 24 24 REORDER 1.3.1 2023/11/03 10:05:13 ? ? HDREDIT2 3.2 2023/11/03 13:18:31 ? ? $END $REMARKS -CLEAN functions: 2023/08/25 17:36:31 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2023-066\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2023/11/03 10:02:41 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Sample_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : E:\Telework\2023-066\Processing\hydro\2023-066-0046.samavg Secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0046.mrgcln1s 24 secondary records matched to primary records. Comments from secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0046.mrgcln1s ------------------------------------------------------------ -CLEAN functions: 2023/11/03 10:01:56 20 Reduce header to sections: FIL HIS COM Remarks removed from kept sections. Reset #RECS, MIN & MAX values in header. -SORT parameters: 2023/11/03 10:02:10 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2023/11/03 10:02:46 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. -CALIB parameters: 2023/11/03 10:03:56 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-066\Processing\doc\2023-066-recal-SIL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 31 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2023/11/03 10:04:10 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-066\Processing\doc\2023-066-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Pressure decibar 10 0.5000000E+00 0.1000000E+01 5 Depth:Salt_Water metres 10 0.5000000E+00 0.1000000E+01 20 Oxygen:Dissolved:SBE mL/L 10 0.1130000E-01 0.1022700E+01 -SORT parameters: 2023/11/03 10:04:21 Sorted in ascending order of channel Pressure [decibar] -REMOVECH 2023/11/03 10:04:34 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary [deg C (ITS90)] Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2023/11/03 13:18:31 Applied edit header: E:\Telework\2023-066\Processing\doc\HYDRO\2023-066-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 16: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 18: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 21: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 23: Flag:Silicate [n/a] Units: ==> n/a Channel 25: Flag:Phosphate [n/a] Units: ==> n/a Channel 12: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 $END *COMMENTS Comments from secondary file: E:\Telework\2023-066\Processing\hydro\2023-066-0046.mrgcln1s ------------------------------------------------------------ Comments from secondary file: D:\Telework\2023-066\Processing\hydro\2023-066-0046.sal ------------------------------------------------------- Sample_Number 252: SAL: Communication errors with the computer occurred during the analysis of this sample. Readings were jumpy after re-establishing communication. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 2.5 weeks after the cruise on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For details see worksheet “CV%” in file QF2023-066_CHL*.xlsx. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2023-066OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 18 - 34 days after collection. For details including a duplicate analysis, see document QF2023-066SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2023-066nuts*.xlsx. The minimum detectable level for DMS is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more details including method, raw data and duplicates, see document "DMS Summary (2023-066).xls”. Detailed notes on analysis are in file 2023-066 DMS report*.doc. 7890 DMS System was used for all stations except P26 for which the new 8890 System was used. The minimum detectable level for DMSP is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more details including method, raw data and duplicates, see document "DMSP 2023-066 Summary*.xls”. Detailed notes on analysis are in file 2023-066 DMS report*.doc. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. Two CTDs were used for this cruise (Events #1-58 and #60-153). The CTD data were affected by frequent pressure spikes that were not resolved by replacing the CTD with a new one. Most large spikes were below 1000db and were removed in processing. None were noted during stops for bottles. For Events #1-39 the configuration file was set as follows: Number of Scans Averaged by the Deck Unit = 24 Normally each scan is recorded individually and averaging is not done until after fine-tuning of settings for alignment and removal of bad records. The quality of CTD data from casts #1-39 is considered lower than usual. Fluorescence data were removed from Events #26-39 due to fluorometer malfunction. A new fluorometer was installed for Events #41-153. NOTE: While the SBE fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. For details on the processing see the report: 2023-066_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Pressure decibar 10 -99 () (0.5 1) Depth:Salt_Water metres 10 -99 () (0.5 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.113E-01 1.0227) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- ---8--- ---9---- --10-- --11- ----12--- -13- -14- ---15--- 16 --17-- 18 --19-- --20-- 21 --22-- 23 ---24-- 25 !Bo Bo Pressu Depth Temperat Trans Trans Fluores Salinity Oxygen Oxyge Conductiv Numb Samp Salinity Fl Chloro Fl Phaeo- Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi cence: :T0:C0 : n: ity: er_o le_ :Bottle ag phyll: ag Pigmen e_ ag te ag te ag !~u ~u Primary vity vity: URU: Dissol Disso Primary ~bin Numb ~o Extrac ~a t: plus_ ~t ~i ~p !mb en Green Seapoin ved: lved: _rec er tt ted ct Extrac Nitrit ri ca ha !er ce t SBE SBE ords le ed ted e te te te !-- -- ------ ------ -------- ----- ----- ------- -------- ------ ----- --------- ---- ---- -------- -- ------ -- ------ ------ -- ------ -- ------- -- *END OF HEADER 23 23 4.8 4.7 7.9114 66.2 91.1 0.628 32.3124 6.94 302.2 3.36241 72 271 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 24 24 5.1 5.1 7.9119 66.4 91.2 0.641 32.3123 6.93 302.1 3.36246 241 272 -99.0000 0 0.22 0 0.07 9.42 0 13.47 0 1.004 0 22 22 11.3 11.2 7.9153 66.4 91.4 0.667 32.3122 6.93 302.1 3.36301 241 270 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 21 21 25.3 25.1 7.9037 66.4 91.3 0.654 32.3114 6.93 302.1 3.36254 241 269 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 20 20 51.2 50.7 7.2147 69.4 96.0 0.474 32.3365 6.91 300.9 3.30636 241 268 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 19 19 75.9 75.3 7.1326 69.0 96.1 0.485 32.3424 6.85 298.3 3.30090 241 267 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 18 18 100.8 100.0 6.8621 70.3 98.2 0.201 32.5737 6.19 269.4 3.29981 241 266 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 17 17 126.2 125.1 6.2575 70.6 98.6 0.110 33.2234 4.68 203.9 3.30709 241 265 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 16 16 151.2 149.8 5.9204 70.0 97.4 0.096 33.6447 3.57 155.4 3.31616 241 264 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 15 15 175.8 174.3 5.4240 69.7 97.3 0.095 33.7205 3.17 137.9 3.28017 241 263 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 14 14 201.4 199.6 5.0755 70.1 97.3 0.102 33.7714 2.64 114.8 3.25511 241 262 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 13 13 251.2 249.0 4.7220 70.0 97.3 0.090 33.8133 2.12 92.0 3.22991 241 261 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 12 12 300.8 298.0 4.3937 70.6 98.3 0.090 33.8799 1.55 67.6 3.20906 241 260 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 11 11 400.9 397.1 4.3510 70.9 98.7 0.088 33.9948 1.02 44.2 3.21956 241 259 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 10 10 599.8 593.9 3.9477 71.3 99.3 0.092 34.1959 0.39 17.0 3.20999 241 258 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 9 9 800.7 792.3 3.4699 71.3 99.3 0.090 34.3055 0.28 12.0 3.18602 241 257 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 8 8 1000.1 989.3 3.1126 71.3 99.3 0.089 34.3774 0.28 12.1 3.16932 241 256 34.3794 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 7 7 1251.2 1236.9 2.6821 71.3 99.4 0.088 34.4445 0.37 16.0 3.14793 241 255 34.4466 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 6 6 1500.8 1482.7 2.3311 71.4 99.6 0.086 34.5074 0.60 26.2 3.13295 241 254 34.5088 6 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 5 5 1749.7 1727.6 2.1027 71.4 99.7 0.084 34.5519 0.95 41.2 3.12695 241 253 34.5525 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 4 4 2000.5 1974.0 1.9233 71.5 99.9 0.083 34.5877 1.33 58.0 3.12443 241 252 34.5882 3 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 3 3 2500.3 2464.4 1.7344 71.5 100.1 0.081 34.6260 1.91 83.2 3.13085 241 251 34.6267 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 2 2 3001.2 2954.7 1.6172 71.4 99.9 0.079 34.6500 2.38 103.3 3.14168 241 250 34.6559 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0 1 1 3361.5 3306.6 1.6115 70.9 99.1 0.080 34.6561 2.49 108.3 3.15493 241 249 -99.0000 0 -99.00 0 -99.00 -99.00 0 -99.00 0 -99.000 0