*2023/12/06 11:12:07.95 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2023/05/25 13:04:22.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 9 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : A0303E49 NUMBER OF CHANNELS : 25 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 9 2 Bottle:Firing_Sequence n/a 1 9 3 Pressure decibar 2.12 351.43 4 Depth metres 2.104 348.156 5 Temperature:Primary 'deg C (ITS90)' 8.065 16.6986 6 Transmissivity %/metre 34 64.2 7 Transmissivity:Green %/metre 40.3 85.5 8 PAR uE/m^2/sec 0 169.257 9 Salinity:T0:C0 PSS-78 22.2148 30.9275 10 Oxygen:Dissolved:SBE mL/L 3.583 7.616 11 Oxygen:Dissolved:SBE umol/kg 156.3 333.1 12 Conductivity:Primary S/m 2.961308 3.391059 13 Number_of_bin_records n/a 241 241 14 Sample_Number n/a 535 543 15 Salinity:Bottle PSS-78 27.9916 30.9265 16 Flag:Salinity:Bottle n/a 17 Chlorophyll:Extracted mg/m^3 0.69 3.17 18 Flag:Chlorophyll:Extracted n/a 19 Phaeo-Pigment:Extracted mg/m^3 0.44 0.75 20 Nitrate_plus_Nitrite umol/L 0.6E-01 29.72 21 Flag:Nitrate_plus_Nitrite n/a 22 Silicate umol/L 11.2 65.69 23 Flag:Silicate n/a 24 Phosphate umol/L 0.102 2.701 25 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 10 F ' ' 6 13 -99 ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 9 F R4 4 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 7 F R4 2 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 3 25 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2023-019 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Nelson J. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : GEO1 EVENT NUMBER : 153 LATITUDE : 49 15.00000 N ! (deg min) LONGITUDE : 123 44.90000 W ! (deg min) WATER DEPTH : 403 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2663 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 2106 Conductivity:2 ' ' 2754 Fluorometer:Seapoint ' ' 4108 'Oxygen:SBE 43' ' ' 3791 PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' ' ' 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2023/11/15 15:19:17 2169 2169 CLEAN 5.3 2023/11/15 15:19:36 2169 2169 ADDSAMP 3.6 2023/11/16 09:35:47 2169 2169 BINAVE 4.2.1 2023/11/21 14:11:43 2169 9 MERGE 3.6 2023/11/23 09:38:57 9 9 CLEAN 5.3 2023/11/23 09:39:01 9 9 CALIB 12.1 2023/12/04 10:07:42 9 9 CALIB 12.1 2023/12/06 10:21:26 9 9 SORT 3.6 2023/12/06 10:23:45 9 9 CLEAN 5.3 2023/12/06 10:25:28 9 9 REMOVECH 8.2 2023/12/06 10:28:36 9 9 CHGUNITS 3.2 2023/12/06 10:41:39 9 9 CHGUNITS 3.2 2023/12/06 10:42:00 9 9 REORDER 1.3.1 2023/12/06 10:44:29 ? ? HDREDIT2 3.2 2023/12/06 11:12:07 ? ? $END $REMARKS -CLEAN functions: 2023/11/15 15:19:24 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: E:\Telework\2023-019\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2023/11/23 09:38:57 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Sample_Number, Bottle:Position, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : E:\Telework\2023-019\Processing\hydro\2023-019-0153.samavg Secondary file: E:\Telework\2023-019\Processing\hydro\2023-019-0153.mrgcln1s 9 secondary records matched to primary records. Comments from secondary file: E:\Telework\2023-019\Processing\hydro\2023-019-0153.mrgcln1s ------------------------------------------------------------ -CLEAN functions: 2023/11/23 09:37:49 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2023/11/23 09:38:01 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2023/11/23 09:38:59 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. -CALIB parameters: 2023/12/04 10:07:42 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-019\Processing\doc\2023-019-recal-SIL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 31 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2023/12/06 10:21:26 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = E:\Telework\2023-019\Processing\doc\2023-019-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Pressure decibar 10 0.8000000E+00 0.1000000E+01 5 Depth:Salt_Water metres 10 0.8000000E+00 0.1000000E+01 18 Salinity:T0:C0 PSS-78 10 -0.2000000E-02 0.1000000E+01 20 Oxygen:Dissolved:SBE mL/L 10 0.1430000E-01 0.1024500E+01 -SORT parameters: 2023/12/06 10:23:45 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2023/12/06 10:25:26 20 Reset #RECS, MIN & MAX values in header. Insert Pad Values in Channel: Fluorescence:URU:Seapoint [mg/m^3] where channel Pressure [decibar] is in the range 80 to 5000 4 data records in pad range. -REMOVECH 2023/12/06 10:28:36 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Fluorescence:URU:Seapoint [mg/m^3] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Status:Pump Altimeter [metres] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary [deg C (ITS90)] Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2023/12/06 11:12:07 Applied edit header: E:\Telework\2023-019\Processing\doc\HYDRO\2023-019-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 16: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 18: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 21: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 23: Flag:Silicate [n/a] Units: ==> n/a Channel 25: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 12: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 $END *COMMENTS Comments from secondary file: E:\Telework\2023-019\Processing\hydro\2023-019-0153.mrgcln1s ------------------------------------------------------------ Comments from secondary file: E:\Telework\2023-019\Processing\hydro\2023-019-0153.chl ------------------------------------------------------- Sample_Number 540: CHL: sample 540A run 3 hours after pull, but replicate agrees well (CV%>10). Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 11 weeks after the cruise on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For details on methodology, see document QF2023-019_CHL*.xlsx Methodology sheet. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2023-019OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 11 - 20 days after collection. For details including a duplicate analysis, see document QF2023-019SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Insitute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in "IOS Nutrient Methods (1996) Barwell-Clarke and Whitney". For details including a duplicate analysis, see document QF2023-019nuts*.xlsx. The ammonium method used at IOS is a modification of the fluorometric technique of Holmes et al, 1999. For methodology details, please see the Methodology tab of file QF2022-019NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminot, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were significant problems with fluorescence data during bottle stops below 80db so those data were padded. For events #120 and #135-153 all data were removed from channel Fluorescence:URU:Seapoint, since values were very low during upcasts and compared very poorly with extracted chlorophyll samples. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. The primary temperature and secondary channels were selected for most casts due to some problems in the secondary system, but the secondary channels were used for casts #46 and #50 due to problems with the primary system. Salinity:T0:C0 data were recalibrated to bring them into correspondence with Salinity:T1:C1. Salinity:T1:C1 compared well with salinity samples from Niskin bottles. For details on the processing see the report: 2023-019_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Pressure decibar 10 -99 () (0.8 1) Depth:Salt_Water metres 10 -99 () (0.8 1) Salinity:T0:C0 PSS-78 10 -99 () (-0.2E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.143E-01 1.0245) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- --8--- ---9---- --10-- --11- ----12--- -13- -14- ---15--- 16 --17-- 18 --19-- --20-- 21 --22-- 23 ---24-- 25 !Bo Bo Pressu Depth Temperat Trans Trans PAR Salinity Oxygen Oxyge Conductiv Numb Samp Salinity Fl Chloro Fl Phaeo- Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi :T0:C0 : n: ity: er_o le_ :Bottle ag phyll: ag Pigmen e_ ag te ag te ag !~u ~u Primary vity vity: Dissol Disso Primary ~bin Numb ~o Extrac ~a t: plus_ ~t ~i ~p !mb en Green ved: lved: _rec er tt ted ct Extrac Nitrit ri ca ha !er ce SBE SBE ords le ed ted e te te te !-- -- ------ ------ -------- ----- ----- ------ -------- ------ ----- --------- ---- ---- -------- -- ------ -- ------ ------ -- ------ -- ------- -- *END OF HEADER 9 9 2.1 2.1 16.6986 43.1 48.9 169.3 22.2148 7.18 315.8 2.961308 241 543 -99.0000 0 2.36 0 0.44 0.06 0 18.37 0 0.102 0 8 8 5.8 5.8 15.1049 34.0 40.3 34.4 26.8549 7.51 329.0 3.391059 241 542 -99.0000 0 3.17 0 0.52 1.25 6 11.20 6 0.430 6 7 7 10.9 10.8 12.7265 49.6 59.6 4.7 27.9286 7.62 333.1 3.322826 241 541 27.9916 0 1.64 0 0.70 5.60 0 19.19 0 0.965 0 6 6 21.1 20.9 9.7175 60.6 78.8 0.5 29.3209 6.31 275.8 3.225865 241 540 -99.0000 0 0.69 26 0.75 15.99 0 36.40 0 1.948 0 5 5 51.4 50.9 8.3595 64.2 85.5 0.0 29.9936 5.05 220.2 3.182373 241 539 -99.0000 0 -99.00 0 -99.00 26.79 0 50.36 0 2.372 0 4 4 101.0 100.1 8.3122 59.4 78.8 0.0 30.4545 5.07 221.3 3.224642 241 538 -99.0000 0 -99.00 0 -99.00 26.76 0 48.51 0 2.275 0 3 3 150.8 149.5 8.0650 63.4 85.2 0.0 30.5209 5.46 238.4 3.212590 241 537 -99.0000 0 -99.00 0 -99.00 26.47 0 46.93 0 2.184 0 2 2 251.7 249.4 8.3837 63.6 85.3 0.0 30.8476 3.88 169.3 3.274395 241 536 -99.0000 0 -99.00 0 -99.00 29.53 0 62.57 0 2.574 0 1 1 351.4 348.2 8.5347 62.0 82.7 0.0 30.9275 3.58 156.3 3.298802 241 535 30.9265 0 -99.00 0 -99.00 29.72 0 65.69 0 2.701 0