*2023/07/04 15:49:41.73 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2022/10/08 05:49:20.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 15 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 1CFA9114 NUMBER OF CHANNELS : 30 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle:Position n/a 1 15 2 Bottle_Number n/a 1 15 3 Pressure decibar 2.352 226.953 4 Depth metres 2.332 224.912 5 Temperature:Primary 'deg C (ITS90)' 9.4041 11.1426 6 Transmissivity %/metre 34.6 44.9 7 Fluorescence:URU:Seapoint mg/m^3 0.371 3.07 8 PAR uE/m^2/sec 0 5.506 9 pH:SBE:Nominal n/a 8.759 8.931 10 Salinity:T0:C0 PSS-78 29.9692 32.0292 11 Oxygen:Dissolved:SBE mL/L 2.693 4.235 12 Oxygen:Dissolved:SBE umol/kg 117.4 184.9 13 Conductivity:Primary S/m 3.407547 3.474815 14 Number_of_bin_records n/a 90 241 15 Sample_Number n/a 124 138 16 Temperature:Draw 'deg C (ITS90)' 9.7 11.5 17 Salinity:Bottle PSS-78 32.0291 32.0291 18 Flag:Salinity:Bottle ' ' 19 Chlorophyll:Extracted mg/m^3 2.79 7.13 20 Flag:Chlorophyll:Extracted ' ' 21 Phaeo-Pigment:Extracted mg/m^3 0.75 1.1 22 Oxygen:Dissolved mL/L 2.683 4.192 23 Oxygen:Dissolved umol/kg 116.9365 183.0455 24 Flag:Oxygen:Dissolved ' ' 25 Nitrate_plus_Nitrite umol/L 20.9 27.91 26 Flag:Nitrate_plus_Nitrite ' ' 27 Silicate umol/L 45.14 50.35 28 Flag:Silicate ' ' 29 Phosphate umol/L 1.952 2.346 30 Flag:Phosphate ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 5 14 -99 ' ' 5 I I 0 15 -99 ' ' 5 I I 0 16 -99 ' ' 6 F R4 1 17 -99 ' ' 9 F R4 4 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 8 F R4 3 23 -99 ' ' 6 F ' ' 1 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 0 ' ' 3 NQ C ' ' 29 -99 ' ' 8 F R4 3 30 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2022-070 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Salish Sea Biophysical Survey SCIENTIST : Young K. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 59 EVENT NUMBER : 36 LATITUDE : 48 37.81000 N ! (deg min) LONGITUDE : 123 14.64000 W ! (deg min) WATER DEPTH : 228 ALTIMETER (M) : 3.69 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2374 Conductivity ' ' 3184 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 4883 Conductivity:2 ' ' 4395 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3949 Altimeter ' ' 76341 'Transmissometer:WET Labs C-Star' ' ' 983DR 'LISST-200X:Sauter Mean Diameter' ' ' 2203 'LISST-200X:Total Volume Conc.' ' ' 2203 pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' 4565 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2023/02/20 14:16:20 3464 3464 CLEAN 5.3 2023/02/20 14:16:33 3464 3464 ADDSAMP 3.6 2023/02/20 16:02:41 3464 3464 BINAVE 4.2.1 2023/02/20 16:03:17 3464 15 MERGE 3.6 2023/02/20 16:34:06 15 15 CLEAN 5.3 2023/02/27 15:16:07 15 15 CALIB 12.1 2023/02/28 13:43:30 15 15 CALIB 12.1 2023/02/28 13:43:52 15 15 SORT 3.6 2023/02/28 13:45:56 15 15 REMOVECH 8.2 2023/02/28 13:47:08 15 15 CHGUNITS 3.2 2023/02/28 13:51:04 15 15 CHGUNITS 3.2 2023/03/01 15:03:59 15 15 REORDER 1.3.1 2023/07/04 15:37:05 ? ? HDREDIT2 3.2 2023/07/04 15:49:41 ? ? $END $REMARKS -CLEAN functions: 2023/02/20 14:16:30 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2022-070\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2023/02/20 16:34:06 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : D:\Telework\2022-070\Processing\hydro\2022-070-0036.samavg Secondary file: D:\Telework\2022-070\Processing\hydro\2022-070-0036.mrgcln1s 15 secondary records matched to primary records. Comments from secondary file: D:\Telework\2022-070\Processing\hydro\2022-070-0036.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2023/02/20 16:32:54 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2023/02/27 15:16:06 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2023/02/28 13:43:30 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-070\Processing\doc\2022-070-recal-SIL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 34 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2023/02/28 13:43:52 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-070\Processing\doc\2022-070-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1028300E+01 -SORT parameters: 2023/02/28 13:45:56 Sorted in ascending order of channel Pressure -REMOVECH 2023/02/28 13:47:08 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T1:C1 [PSS-78] Status:Pump Descent_Rate [m/s] Altimeter [metres] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2023/07/04 15:49:41 Applied edit header: D:\Telework\1a-IOS_Tasks\corrections\2022-070\2022-070-bot-hdr.txt Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 Channel 14: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 16: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Channel 13: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 $END *COMMENTS Comments from secondary file: D:\Telework\2022-070\Processing\hydro\2022-070-0036.mrgcln1s ------------------------------------------------------------ Comments from secondary file: D:\Telework\2022-070\Processing\hydro\2022-070-0036.oxy ------------------------------------------------------- Sample_Number 130: OXY-2: Fluffy precipitate likely as a result of a bottle-top dispenser problem. Did not settle as expected. Value low in comparison to replicate sample. Value discarded. Only OXY-1 reported. Sample_Number 132: OXY: Fluffy precipitate likely as a result of a bottle-top dispenser problem. Did not settle as expected. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 9 weeks after the cruise on a Turner Trilogy7200-000 fluorometer, using methods described in Holm-Hansen et al. (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For further details on methodology, see document QF 2022-070_CHL_*.xlsx Methodology sheet. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values For details see file QF2022-070_CHL*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2022-035OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 30 - 34 days after collection. For details see document QF2022-070SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2022-070nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity and Fluorescence:URU:Seapoint data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Channel pH:SBE was removed from some casts because the pH buffer vial had not been removed. For details on the processing see the report: 2022-070_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0283) $END !1- 2- --3--- --4--- ---5---- --6-- ---7--- --8--- ---9--- ---10--- --11-- --12- ----13--- -14- -15- --16- ---17--- 18 --19-- 20 --21-- ---22-- --23- 24 --25-- 26 --27-- 28 ---29-- 30 !Bo Bo Pressu Depth Temperat Trans Fluores PAR pH:SBE: Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: Nominal :T0:C0 : n: ity: er_o le_ ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~i ~u Primary vity URU: Dissol Disso Primary ~bin Numb e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !ti mb Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitrit ri ca ha !on er t SBE SBE ords le ed ted ed e te te te !-- -- ------ ------ -------- ----- ------- ------ ------- -------- ------ ----- --------- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 14 14 2.4 2.3 11.1415 34.7 3.070 5.5 8.931 29.9716 4.22 184.4 3.40770 90 137 11.5 -99.0000 0 -99.00 0 -99.00 4.192 183.0 0 -99.00 0 -99.00 0 -99.000 0 15 15 2.4 2.4 11.1426 34.7 2.948 5.5 8.931 29.9692 4.24 184.9 3.40755 241 138 -99.0 -99.0000 0 6.74 6 0.86 -99.000 -99.0 0 20.90 6 45.14 6 1.952 6 13 13 5.1 5.1 11.1107 35.0 3.052 1.7 8.926 30.0085 4.18 182.3 3.40902 241 136 11.3 -99.0000 0 7.13 0 1.10 4.076 178.0 0 21.12 0 45.71 0 2.003 0 12 12 10.6 10.5 10.9708 36.8 2.481 0.2 8.906 30.1500 4.03 175.8 3.41201 241 135 11.2 -99.0000 0 6.83 0 1.01 3.979 173.7 0 21.76 6 45.88 6 1.982 6 11 11 20.8 20.6 10.5236 42.0 1.350 0.0 8.848 30.5821 3.59 156.8 3.41861 241 134 10.7 -99.0000 0 2.79 0 0.75 3.478 151.8 0 24.29 0 48.30 0 2.162 0 10 10 30.8 30.6 10.3603 43.8 0.952 0.0 8.828 30.7603 3.42 149.1 3.42312 241 133 10.6 -99.0000 0 -99.00 0 -99.00 3.398 148.3 0 24.76 0 48.57 0 2.181 0 9 9 40.9 40.5 10.3285 44.3 0.929 0.0 8.824 30.8004 3.39 148.0 3.42486 241 132 10.5 -99.0000 0 -99.00 0 -99.00 3.376 147.3 4 24.80 0 48.67 0 2.182 0 8 8 51.0 50.6 10.3205 44.3 0.930 0.0 8.824 30.8157 3.39 147.8 3.42613 241 131 10.5 -99.0000 0 -99.00 0 -99.00 3.356 146.4 0 25.03 0 48.66 0 2.189 0 7 7 75.7 75.1 10.2226 44.9 0.874 0.0 8.817 30.9947 3.32 144.7 3.43673 241 130 10.4 -99.0000 0 -99.00 0 -99.00 3.284 143.3 2 25.27 0 48.55 0 2.204 0 6 6 100.7 99.8 9.9479 42.8 0.701 0.0 8.798 31.3087 3.10 135.1 3.44551 241 129 10.2 -99.0000 0 -99.00 0 -99.00 3.095 135.0 0 26.06 0 49.24 0 2.239 0 5 5 124.8 123.7 9.8394 41.7 0.625 0.0 8.789 31.4557 3.02 131.7 3.45174 241 128 10.1 -99.0000 0 -99.00 0 -99.00 3.021 131.7 6 26.28 0 49.43 0 2.269 0 4 4 152.3 150.9 9.6257 40.7 0.489 0.0 8.773 31.7355 2.87 124.9 3.46199 241 127 9.9 -99.0000 0 -99.00 0 -99.00 2.846 124.1 0 26.98 0 49.88 0 2.329 0 3 3 177.9 176.3 9.4326 36.6 0.374 0.0 8.761 31.9889 2.72 118.5 3.47113 241 126 9.7 -99.0000 0 -99.00 0 -99.00 2.718 118.5 0 27.41 0 50.24 0 2.346 0 2 2 200.8 199.0 9.4041 34.9 0.375 0.0 8.759 32.0292 2.69 117.4 3.47355 241 125 9.7 32.0291 0 -99.00 0 -99.00 2.683 116.9 0 27.73 0 50.26 0 2.342 0 1 1 227.0 224.9 9.4084 34.6 0.371 0.0 8.759 32.0271 2.70 117.7 3.47481 241 124 9.7 -99.0000 0 -99.00 0 -99.00 2.689 117.2 0 27.91 0 50.35 0 2.312 0