*2023/07/04 15:49:41.55 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2022/10/07 13:45:41.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 10 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : B713619B NUMBER OF CHANNELS : 30 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle:Position n/a 1 10 2 Bottle_Number n/a 1 10 3 Pressure decibar 2.167 123.538 4 Depth metres 2.149 122.462 5 Temperature:Primary 'deg C (ITS90)' 8.2832 10.7716 6 Transmissivity %/metre 39 48.4 7 Fluorescence:URU:Seapoint mg/m^3 0.278 1.023 8 PAR uE/m^2/sec 0 6.98 9 pH:SBE:Nominal n/a 8.667 8.846 10 Salinity:T0:C0 PSS-78 31.0198 33.1476 11 Oxygen:Dissolved:SBE mL/L 1.894 3.832 12 Oxygen:Dissolved:SBE umol/kg 82.5 167.2 13 Conductivity:Primary S/m 3.478545 3.495068 14 Number_of_bin_records n/a 241 241 15 Sample_Number n/a 84 93 16 Temperature:Draw 'deg C (ITS90)' 8.8 10.9 17 Salinity:Bottle PSS-78 32.7019 32.7019 18 Flag:Salinity:Bottle ' ' 19 Chlorophyll:Extracted mg/m^3 1.97 3.06 20 Flag:Chlorophyll:Extracted ' ' 21 Phaeo-Pigment:Extracted mg/m^3 0.65 0.68 22 Oxygen:Dissolved mL/L 1.893 3.788 23 Oxygen:Dissolved umol/kg 82.42316 165.2562 24 Flag:Oxygen:Dissolved ' ' 25 Nitrate_plus_Nitrite umol/L 23.01 31.87 26 Flag:Nitrate_plus_Nitrite ' ' 27 Silicate umol/L 45.93 54.2 28 Flag:Silicate ' ' 29 Phosphate umol/L 2.045 2.531 30 Flag:Phosphate ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 5 14 -99 ' ' 5 I I 0 15 -99 ' ' 5 I I 0 16 -99 ' ' 6 F R4 1 17 -99 ' ' 9 F R4 4 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 8 F R4 3 23 -99 ' ' 6 F ' ' 1 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 0 ' ' 3 NQ C ' ' 29 -99 ' ' 8 F R4 3 30 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2022-070 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Salish Sea Biophysical Survey SCIENTIST : Young K. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 65 EVENT NUMBER : 22 LATITUDE : 48 15.91000 N ! (deg min) LONGITUDE : 123 9.78000 W ! (deg min) WATER DEPTH : 125 ALTIMETER (M) : 3.27 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2374 Conductivity ' ' 3184 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 4883 Conductivity:2 ' ' 4395 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3949 Altimeter ' ' 76341 'Transmissometer:WET Labs C-Star' ' ' 983DR 'LISST-200X:Sauter Mean Diameter' ' ' 2203 'LISST-200X:Total Volume Conc.' ' ' 2203 pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' 4565 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2023/02/20 14:16:18 2410 2410 CLEAN 5.3 2023/02/20 14:16:32 2410 2410 ADDSAMP 3.6 2023/02/20 16:02:40 2410 2410 BINAVE 4.2.1 2023/02/20 16:03:17 2410 10 MERGE 3.6 2023/02/20 16:34:05 10 10 CLEAN 5.3 2023/02/27 15:16:07 10 10 CALIB 12.1 2023/02/28 13:43:29 10 10 CALIB 12.1 2023/02/28 13:43:52 10 10 SORT 3.6 2023/02/28 13:45:56 10 10 REMOVECH 8.2 2023/02/28 13:47:08 10 10 CHGUNITS 3.2 2023/02/28 13:51:04 10 10 CHGUNITS 3.2 2023/03/01 15:03:59 10 10 REORDER 1.3.1 2023/07/04 15:37:05 ? ? HDREDIT2 3.2 2023/07/04 15:49:41 ? ? $END $REMARKS -CLEAN functions: 2023/02/20 14:16:30 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2022-070\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2023/02/20 16:34:05 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : D:\Telework\2022-070\Processing\hydro\2022-070-0022.samavg Secondary file: D:\Telework\2022-070\Processing\hydro\2022-070-0022.mrgcln1s 10 secondary records matched to primary records. Comments from secondary file: D:\Telework\2022-070\Processing\hydro\2022-070-0022.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2023/02/20 16:32:54 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2023/02/27 15:16:06 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2023/02/28 13:43:29 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-070\Processing\doc\2022-070-recal-SIL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 34 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T0:C0 -CALIB parameters: 2023/02/28 13:43:52 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-070\Processing\doc\2022-070-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1028300E+01 -SORT parameters: 2023/02/28 13:45:56 Sorted in ascending order of channel Pressure -REMOVECH 2023/02/28 13:47:08 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T1:C1 [PSS-78] Status:Pump Descent_Rate [m/s] Altimeter [metres] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2023/07/04 15:49:41 Applied edit header: D:\Telework\1a-IOS_Tasks\corrections\2022-070\2022-070-bot-hdr.txt Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 Channel 14: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 16: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Channel 13: Conductivity:Primary [S/m] Format: F11.6 ==> F10.5 $END *COMMENTS Comments from secondary file: D:\Telework\2022-070\Processing\hydro\2022-070-0022.mrgcln1s ------------------------------------------------------------ Comments from secondary file: D:\Telework\2022-070\Processing\hydro\2022-070-0022.oxy ------------------------------------------------------- Sample_Number 88: OXY: Runaway titration caused a late endpoint. Sample over-titrated. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 9 weeks after the cruise on a Turner Trilogy7200-000 fluorometer, using methods described in Holm-Hansen et al. (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For further details on methodology, see document QF 2022-070_CHL_*.xlsx Methodology sheet. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values For details see file QF2022-070_CHL*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2022-035OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 30 - 34 days after collection. For details see document QF2022-070SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2022-070nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity and Fluorescence:URU:Seapoint data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Channel pH:SBE was removed from some casts because the pH buffer vial had not been removed. For details on the processing see the report: 2022-070_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Silicate umol/L 120 -99 (Salinity:T0:C0) (0.904 0.3E-02 25) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0283) $END !1- 2- --3--- --4--- ---5---- --6-- ---7--- --8--- ---9--- ---10--- --11-- --12- ----13--- -14- -15- --16- ---17--- 18 --19-- 20 --21-- ---22-- --23- 24 --25-- 26 --27-- 28 ---29-- 30 !Bo Bo Pressu Depth Temperat Trans Fluores PAR pH:SBE: Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: Nominal :T0:C0 : n: ity: er_o le_ ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~i ~u Primary vity URU: Dissol Disso Primary ~bin Numb e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !ti mb Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitrit ri ca ha !on er t SBE SBE ords le ed ted ed e te te te !-- -- ------ ------ -------- ----- ------- ------ ------- -------- ------ ----- --------- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 10 10 2.2 2.1 10.7716 46.4 1.023 7.0 8.846 31.0198 3.83 167.2 3.48316 241 93 10.9 -99.0000 0 2.39 6 0.66 3.788 165.3 0 23.01 0 45.93 0 2.114 0 9 9 5.4 5.4 10.7366 46.2 0.880 2.2 8.840 31.0337 3.78 164.9 3.48169 241 92 10.9 -99.0000 0 2.68 0 0.65 3.759 164.0 0 23.13 0 46.10 0 2.113 0 8 8 10.5 10.4 10.7295 46.0 0.860 0.5 8.838 31.0502 3.76 164.0 3.48297 241 91 10.8 -99.0000 0 3.06 0 0.68 3.734 162.9 0 23.28 6 46.04 6 2.045 6 7 7 20.6 20.4 10.3319 46.6 0.613 0.0 8.800 31.4340 3.37 146.9 3.48772 241 90 10.5 -99.0000 0 1.97 0 0.65 3.347 146.0 0 24.72 0 47.23 0 2.311 0 6 6 30.5 30.3 10.0142 47.3 0.534 0.0 8.781 31.7773 3.17 138.3 3.49473 241 89 10.2 -99.0000 0 -99.00 0 -99.00 3.152 137.4 0 25.62 0 47.76 0 2.224 0 5 5 40.8 40.4 9.9573 47.4 0.610 0.0 8.779 31.8263 3.16 137.8 3.49507 241 88 10.1 -99.0000 0 -99.00 0 -99.00 3.133 136.6 2 25.94 0 47.85 0 2.242 0 4 4 50.9 50.5 9.8062 47.9 0.482 0.0 8.766 31.9286 3.05 133.0 3.49242 241 87 10.0 -99.0000 0 -99.00 0 -99.00 3.029 132.0 0 26.46 0 48.27 0 2.293 0 3 3 75.7 75.1 9.5150 48.4 0.421 0.0 8.746 32.1498 2.84 123.9 3.48972 241 86 9.7 -99.0000 0 -99.00 0 -99.00 2.762 120.4 0 27.68 0 49.39 0 2.327 0 2 2 100.8 100.0 8.7618 44.5 0.315 0.0 8.693 32.7080 2.26 98.6 3.47854 241 85 9.2 32.7019 0 -99.00 0 -99.00 2.259 98.4 6 30.34 0 52.18 0 2.434 0 1 1 123.5 122.5 8.2832 39.0 0.278 0.0 8.667 33.1476 1.89 82.5 3.47889 241 84 8.8 -99.0000 0 -99.00 0 -99.00 1.893 82.4 0 31.87 0 54.20 0 2.531 0