*2023/01/05 15:59:59.51 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2022/06/26 04:26:24.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 12 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 5A1A8962 NUMBER OF CHANNELS : 29 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 12 2 Bottle:Firing_Sequence n/a 1 12 3 Pressure decibar 1.279 175.617 4 Depth metres 1.269 174.053 5 Temperature:Primary 'deg C (ITS90)' 6.8218 11.6326 6 Transmissivity %/metre 40.8 50.7 7 Fluorescence:URU:Seapoint mg/m^3 0.228 1.944 8 PAR uE/m^2/sec 0.784 7.539 9 Salinity:T0:C0 PSS-78 30.1 33.8475 10 Oxygen:Dissolved:SBE mL/L 1.904 5.572 11 Oxygen:Dissolved:SBE umol/kg 82.8 243.3 12 Conductivity:Primary S/m 3.360782 3.462224 13 Number_of_bin_records n/a 241 241 14 Sample_Number n/a 69 80 15 Temperature:Draw 'deg C (ITS90)' 7.5 11.8 16 Salinity:Bottle PSS-78 33.8455 33.8455 17 Flag:Salinity:Bottle ' ' 18 Chlorophyll:Extracted mg/m^3 0.64 3.59 19 Flag:Chlorophyll:Extracted ' ' 20 Phaeo-Pigment:Extracted mg/m^3 0.48 0.57 21 Oxygen:Dissolved mL/L 1.895 5.554 22 Oxygen:Dissolved umol/kg 82.45081 242.5066 23 Flag:Oxygen:Dissolved ' ' 24 Nitrate_plus_Nitrite umol/L 18.8 34.73 25 Flag:Nitrate_plus_Nitrite ' ' 26 Silicate umol/L 37.22 53.75 27 Flag:Silicate ' ' 28 Phosphate umol/L 1.638 2.57 29 Flag:Phosphate ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 10 F ' ' 6 13 ' ' ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 9 F R4 4 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 8 F R4 3 22 -99 ' ' 6 F ' ' 1 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 8 F R4 3 29 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2022-040 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Salish Sea Biophysical Survey SCIENTIST : O'Neill C. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 69 EVENT NUMBER : 24 LATITUDE : 48 15.61000 N ! (deg min) LONGITUDE : 123 43.24300 W ! (deg min) WATER DEPTH : 179 ALTIMETER (M) : 3.96 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 1222 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 5013 Conductivity ' ' 4434 'Pressure:Digiquartz with TC' ' ' 1222 Temperature:2 ' ' 5725 Conductivity:2 ' ' 4448 'Oxygen:SBE 43' ' ' 1438 Fluorometer:Seapoint ' ' 3685 Altimeter ' ' 73171 'LISST-200X:Sauter Mean Diameter' ' ' 2203 'Transmissometer:WET Labs C-Star' ' ' 983DR pH ' ' 0691 PAR/Irradiance:Biospherical/Licor ' ' 4565 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2022/12/19 14:43:43 2892 2892 CLEAN 5.3 2022/12/19 14:49:09 2892 2892 MERGEHDR 1.3 2022/12/23 09:37:34 2892 2892 ADDSAMP 3.6 2022/12/23 09:38:19 2892 2892 BINAVE 4.2.1 2022/12/23 09:38:35 2892 12 MERGE 3.6 2022/12/23 09:39:03 12 12 CLEAN 5.3 2022/12/23 09:39:10 12 12 CALIB 12.1 2023/01/05 10:01:20 12 12 CALIB 12.1 2023/01/05 10:06:44 12 12 SORT 3.6 2023/01/05 10:45:26 12 12 REMOVECH 8.2 2023/01/05 10:46:10 12 12 CHGUNITS 3.2 2023/01/05 10:48:05 12 12 CHGUNITS 3.2 2023/01/05 11:02:51 12 12 REORDER 1.3.1 2023/01/05 15:59:12 ? ? HDREDIT2 3.2 2023/01/05 15:59:59 ? ? $END $REMARKS -CLEAN functions: 2022/12/19 14:49:07 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2022-040\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2022/12/23 09:39:03 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : D:\Telework\2022-040\Processing\hydro\2022-040-0024.samavg Secondary file: D:\Telework\2022-040\Processing\hydro\2022-040-0024.mrgcln1s 12 secondary records matched to primary records. Comments from secondary file: D:\Telework\2022-040\Processing\hydro\2022-040-0024.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2022/12/20 14:48:14 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2022/12/23 09:39:09 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2023/01/05 10:01:20 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-040\Processing\doc\2022-040-recal-SIL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 34 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Silicate -CALIB parameters: 2023/01/05 10:06:44 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-040\Processing\doc\2022-040-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1047500E+01 -SORT parameters: 2023/01/05 10:45:26 Sorted in ascending order of channel Pressure -REMOVECH 2023/01/05 10:46:10 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] pH:SBE [pH Units] Salinity:T1:C1 [PSS-78] Status:Pump Descent_Rate [m/s] Altimeter [metres] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2023/01/05 15:59:59 Applied edit header: D:\Telework\2022-040\Processing\doc\HYDRO\2022-040-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Channel 12: Conductivity:Primary [S/m] Format: F8.3 ==> F10.6 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Format: F8.3 ==> F6.1 Channel 15: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 $END *COMMENTS Comments from secondary file: D:\Telework\2022-040\Processing\hydro\2022-040-0024.mrgcln1s ------------------------------------------------------------ Comments from secondary file: D:\Telework\2022-040\Processing\hydro\2022-040-0024.oxy ------------------------------------------------------- Sample_Number 80: OXY-1: Endpoint was late. It was adjusted manually and the value was recalculated as a result. Comments from secondary file: D:\Telework\2022-040\Processing\hydro\2022-040-0024.nut ------------------------------------------------------- Sample_Number 76: NUTS: Sample intended as duplicate, however, only one sample processed Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 8 weeks after the cruise on a Turner Trilogy7200-000 fluorometer, using methods described in Holm-Hansen et al. (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For further details on methodolgy, see document QF 2022-040_CHL_*.xlsx. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876, a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2022-040_OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 14 - 20 days after collection. For details including a duplicate analysis, see document QF2022-040SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Insitute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2022-040nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminot, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Two CTDs were used during this cruise. CTD #0550 was used for Event #1 only. CTD #1222 was used for Events 4-91. Conductivity, Transmissivity, Fluorescence and PAR are nominal and unedited except that some records were removed in editing temperature and salinity. Recalibration of dissolved oxygen was based on a comparison with titrated samples for Events 4-91. For Event #1 recalibration was based on the performance of the oxygen sensor during previous cruises. Salinity required no recalibration. Pressure was recalibrated for Event #1. For all other events the pressure offset in the configuration file was adjusted based on results of previous cruises. For details on the processing see the report: 2022-040_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Silicate umol/L 120 -99 (Silicate) (0.904 0.3E-02 25) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0475) $END !1- 2- --3--- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- ----12--- -13- -14- --15- ---16--- 17 --18-- 19 --20-- ---21-- --22- 23 --24-- 25 --26-- 27 ---28-- 29 !Bo Bo Pressu Depth Temperat Trans Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: :T0:C0 : n: ity: er_o le_ ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~u ~u Primary vity URU: Dissol Disso Primary ~bin Numb e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !mb en Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitrit ri ca ha !er ce t SBE SBE ords le ed ted ed e te te te !-- -- ------ ------ -------- ----- ------- ------ -------- ------ ----- --------- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 12 12 1.3 1.3 11.6326 40.8 1.923 7.5 30.1017 5.57 243.2 3.462000 241 80 11.8 -99.0000 0 3.59 0 0.51 5.554 242.5 26 18.80 0 37.22 0 1.638 0 11 11 5.0 5.0 11.6173 40.8 1.944 2.5 30.1000 5.57 243.3 3.461000 241 79 11.3 -99.0000 0 2.78 6 0.48 5.478 239.2 0 20.17 6 41.30 6 1.836 6 10 10 10.4 10.3 10.3171 47.7 1.018 1.1 30.3827 5.01 218.7 3.381000 241 78 11.3 -99.0000 0 0.92 0 0.57 4.904 214.1 0 20.32 0 38.38 0 1.723 0 9 9 20.4 20.2 9.6079 49.5 0.767 0.8 30.7780 4.40 192.1 3.361000 241 77 9.7 -99.0000 0 0.64 0 0.50 4.360 190.2 0 22.68 0 40.87 0 1.909 0 8 8 30.2 29.9 9.4602 49.5 0.676 0.8 31.0010 4.28 186.8 3.371000 241 76 9.7 -99.0000 0 -99.00 0 -99.00 4.284 186.9 0 23.30 2 41.60 2 1.966 2 7 7 40.1 39.8 9.0436 50.2 0.522 0.8 31.5210 3.92 170.8 3.386000 241 75 9.3 -99.0000 0 -99.00 0 -99.00 3.966 172.9 0 24.43 0 42.45 0 2.036 0 6 6 50.5 50.0 8.5624 50.7 0.530 0.8 32.1966 3.41 148.5 3.410000 241 74 8.9 -99.0000 0 -99.00 0 -99.00 3.425 149.2 0 26.86 0 43.56 0 2.131 0 5 5 75.2 74.6 7.6967 48.1 0.346 0.8 32.9660 2.64 114.8 3.408000 241 73 8.2 -99.0000 0 -99.00 0 -99.00 2.608 113.6 6 29.87 0 47.12 0 2.261 0 4 4 100.5 99.6 7.0299 44.3 0.311 0.8 33.6037 1.95 84.8 3.409000 241 72 7.7 -99.0000 0 -99.00 0 -99.00 1.948 84.8 0 32.36 0 50.81 0 2.383 0 3 3 126.0 124.9 6.8249 46.3 0.228 0.8 33.8441 1.90 82.9 3.413000 241 71 7.5 -99.0000 0 -99.00 0 -99.00 1.895 82.5 0 32.18 0 50.30 0 2.364 0 2 2 149.9 148.5 6.8218 45.5 0.267 0.8 33.8474 1.90 82.8 3.414000 241 70 7.5 33.8455 0 -99.00 0 -99.00 1.898 82.6 0 34.73 0 53.75 0 2.570 0 1 1 175.6 174.1 6.8243 45.3 0.235 0.8 33.8475 1.91 83.0 3.416000 241 69 7.6 -99.0000 0 -99.00 0 -99.00 1.898 82.6 0 32.30 0 50.38 0 2.339 0