*2022/12/09 08:56:27.84 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2022/08/28 20:12:44.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : F73A061D NUMBER OF CHANNELS : 30 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 17 2 Bottle:Firing_Sequence n/a 1 17 3 Pressure decibar 5.077 157.474 4 Depth metres 5.034 156.083 5 Temperature:Secondary 'deg C (ITS90)' 7.6191 12.7419 6 Transmissivity %/metre 16.3 51.8 7 Transmissivity:Green %/metre 21.9 80.6 8 Fluorescence:URU:Seapoint mg/m^3 0.198 16.715 9 PAR uE/m^2/sec 0 82.727 10 Salinity:T1:C1 PSS-78 31.0716 33.3432 11 Oxygen:Dissolved:SBE mL/L 1.929 6.984 12 Oxygen:Dissolved:SBE umol/kg 84 304.8 13 Conductivity:Secondary S/m 3.438425 3.659506 14 Sample_Number n/a 199 215 15 Number_of_bin_records n/a 42 241 16 Temperature:Draw 'deg C (ITS90)' 8.3 13.1 17 Chlorophyll:Extracted mg/m^3 2.02 25.81 18 Flag:Chlorophyll:Extracted ' ' 19 Phaeo-Pigment:Extracted mg/m^3 2.13 3.14 20 Oxygen:Dissolved mL/L 1.934 7.136 21 Oxygen:Dissolved umol/kg 84.18952 311.4273 22 Flag:Oxygen:Dissolved ' ' 23 Nitrate_plus_Nitrite umol/L 8 32.09 24 Flag:Nitrate_plus_Nitrite ' ' 25 Silicate umol/L 26.7 57.52 26 Flag:Silicate ' ' 27 Phosphate umol/L 1.002 2.682 28 Flag:Phosphate ' ' 29 Ammonium umol/L 0.49 2.57 30 Flag:Ammonium ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 6 14 -99 ' ' 5 I I 0 15 ' ' ' ' 5 I I 0 16 -99 ' ' 6 F R4 1 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 8 F R4 3 21 -99 ' ' 6 F ' ' 1 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 8 F R4 3 28 0 ' ' 3 NQ C ' ' 29 -99 ' ' ' ' F7.2 R4 ' ' 30 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2022-022 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Nelson J. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LC04 EVENT NUMBER : 73 LATITUDE : 48 43.42000 N ! (deg min) LONGITUDE : 125 40.83000 W ! (deg min) WATER DEPTH : 166 ALTIMETER (M) : 10.16 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4700 Conductivity ' ' 3531 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 4888 Conductivity:2 ' ' 4513 'Oxygen:SBE 43' ' ' 3791 Fluorometer:Seapoint ' ' 3641 Altimeter ' ' 76341 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG PAR/Irradiance:Biospherical/Licor ' ' 70613 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2022/10/18 15:58:05 2778 2778 CLEAN 5.3 2022/10/18 15:59:53 2778 2778 ADDSAMP 3.6 2022/10/18 16:44:33 2778 2778 BINAVE 4.2.1 2022/10/18 16:45:02 2778 17 MERGE 3.6 2022/12/08 09:55:49 17 17 CLEAN 5.3 2022/12/08 09:55:54 17 17 CALIB 12.1 2022/12/08 13:45:52 17 17 CALIB 12.1 2022/12/08 13:58:57 17 17 SORT 3.6 2022/12/08 15:28:10 17 17 REMOVECH 8.2 2022/12/09 08:49:46 17 17 CHGUNITS 3.2 2022/12/09 08:51:54 17 17 CHGUNITS 3.2 2022/12/09 08:52:00 17 17 REORDER 1.3.1 2022/12/09 08:52:16 ? ? HDREDIT2 3.2 2022/12/09 08:56:27 ? ? $END $REMARKS -CLEAN functions: 2022/10/18 15:59:46 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2022-022\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2022/12/08 09:55:49 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : D:\Telework\2022-022\Processing\hydro\2022-022-0073.samavg Secondary file: D:\Telework\2022-022\Processing\hydro\2022-022-0073.mrgcln1s 17 secondary records matched to primary records. Comments from secondary file: D:\Telework\2022-022\Processing\hydro\2022-022-0073.mrgcln1s ------------------------------------------------------------ -CLEAN functions: 2022/12/08 09:55:04 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2022/12/08 09:55:08 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2022/12/08 09:55:53 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2022/12/08 13:45:52 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-022\Processing\doc\2022-022-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 -0.6300000E-02 0.1016400E+01 -CALIB parameters: 2022/12/08 13:58:57 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-022\Processing\doc\2022-022-recal2.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 32 Silicate umol/L 120 0.9040000E+00 0.3000000E-02 0.2500000E+02 Salinity:T1:C1 -SORT parameters: 2022/12/08 15:28:10 Sorted in ascending order of channel Pressure -REMOVECH 2022/12/09 08:49:46 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T0:C0 [PSS-78] Status:Pump Descent_Rate [m/s] Altimeter [metres] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary [deg C (ITS90)] Salinity reference channel: Salinity:T1:C1 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2022/12/09 08:56:27 Applied edit header: D:\Telework\2022-022\Processing\doc\HYDRO\2022-022-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Format: F8.3 ==> F6.1 Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 16: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 $END *COMMENTS Comments from secondary file: D:\Telework\2022-022\Processing\hydro\2022-022-0073.mrgcln1s ------------------------------------------------------------ Comments from secondary file: D:\Telework\2022-022\Processing\hydro\2022-022-0073.nut ------------------------------------------------------- Sample_Number 214: NUTS: Sample label 213, however 214 was indicated on the rosette sheet (changed) Comments from secondary file: D:\Telework\2022-022\Processing\hydro\2022-022-0073.NH4 ------------------------------------------------------- Sample_Number 209: NH4: Sample over std curve Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 11 weeks after the cruise on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For details on methodology, see document QF2022-022_CHL*.xlsx Methodology sheet. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2022-022OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 6 - 17 days after collection. For details including a duplicate analysis, see document QF2022-022SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Insitute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2022-022nuts*.xlsx. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a Trilogy Fluorometer in Raw Fluorescence Mode. Standards are made in LNSW collected at P22 400m. For full details including a precision study see file QF2022-022NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminot, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Channel Salinity:T1:C1 was found to be very close to bottle samples. The SBE DO sensor hysteresis setting and calibration appeared to change suddenly between casts #128 and #133. This might be related to problems encountered in the previous cast at the same site as #133. The change was small and principally affected low oxygen values. The later casts were reconverted with different hysteresis parameters. Separate recalibration schemes were applied to the 2 groups of casts. For details on the processing see the report: 2021-022_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.63E-02 1.0164) Silicate umol/L 120 -99 (Salinity:T1:C1) (0.904 0.3E-02 25) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- ---8--- --9--- ---10--- --11-- --12- ----13--- -14- -15- --16- --17-- 18 --19-- ---20-- --21- 22 --23-- 24 --25-- 26 ---27-- 28 --29-- 30 !Bo Bo Pressu Depth Temperat Trans Trans Fluores PAR Salinity Oxygen Oxyge Conductiv Samp Numb Tempe Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Ammoni Fl !tt tt re ure: missi missi cence: :T1:C1 : n: ity: le_ er_o ratur phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag um ag !~u ~u Secondar vity vity: URU: Dissol Disso Secondary Numb ~bin e: Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p ~o !mb en y Green Seapoin ved: lved: er _rec Draw ted ct Extrac lved lv Nitrit ri ca ha ni !er ce t SBE SBE ords ed ted ed e te te te um !-- -- ------ ------ -------- ----- ----- ------- ------ -------- ------ ----- --------- ---- ---- ----- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- ------ -- *END OF HEADER 16 16 5.1 5.0 12.7322 16.3 22.0 15.564 82.7 31.0760 6.97 304.4 3.658680 214 42 -99.0 25.81 0 3.14 -99.000 -99.0 0 8.00 2 26.70 2 1.002 2 0.49 6 15 15 5.1 5.1 12.7363 17.5 21.9 15.793 77.6 31.0716 6.98 304.6 3.658583 213 42 13.1 -99.00 0 -99.00 7.136 311.4 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 17 17 5.2 5.2 12.7419 17.3 23.5 16.715 72.9 31.0757 6.98 304.8 3.659506 215 241 -99.0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 14 14 10.6 10.5 10.8964 45.7 68.0 2.637 10.1 31.4810 4.60 200.6 3.540987 212 241 -99.0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 13 13 10.6 10.6 10.8998 46.0 68.4 2.432 9.4 31.4798 4.60 200.6 3.541152 211 52 11.1 4.14 0 2.13 4.462 194.6 0 18.79 0 35.08 0 1.840 0 2.43 6 11 11 20.2 20.0 10.0064 51.4 80.6 1.085 2.1 31.7725 3.61 157.3 3.493142 209 51 10.3 2.02 0 2.30 3.537 154.2 0 24.17 0 38.83 0 2.161 0 2.57 36 12 12 20.3 20.1 10.0046 51.8 80.3 1.050 2.1 31.7732 3.61 157.2 3.493061 210 241 -99.0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 10 10 30.4 30.1 9.4099 50.8 78.2 1.050 0.6 32.0646 3.12 136.1 3.470282 208 241 9.7 2.09 6 2.42 3.097 135.0 6 25.82 0 44.82 0 2.326 0 -99.00 0 8 8 50.8 50.3 8.7523 47.2 72.1 1.066 0.0 32.5198 2.93 127.8 3.457518 206 69 9.2 2.21 0 2.28 3.069 133.7 0 27.08 6 45.61 6 2.295 6 -99.00 0 9 9 50.8 50.3 8.7502 47.3 72.1 1.232 0.0 32.5213 2.94 128.1 3.457475 207 241 -99.0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 7 7 75.1 74.4 8.1257 48.9 75.3 0.359 0.0 32.9676 2.49 108.6 3.445829 205 241 8.7 -99.00 0 -99.00 2.492 108.5 0 30.21 0 51.71 0 2.477 0 -99.00 0 5 5 100.4 99.6 7.9120 47.4 72.3 0.277 0.0 33.1288 2.56 111.3 3.443140 203 55 8.5 -99.00 0 -99.00 2.565 111.7 0 30.11 0 47.14 0 2.363 0 -99.00 0 6 6 100.5 99.6 7.9139 47.4 72.3 0.337 0.0 33.1300 2.57 111.9 3.443427 204 241 -99.0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 4 4 124.6 123.5 7.8127 48.9 75.4 0.201 0.0 33.2046 2.36 102.7 3.442466 202 241 8.5 -99.00 0 -99.00 2.298 100.0 0 31.28 0 49.58 0 2.475 0 -99.00 0 3 3 149.8 148.5 7.6289 42.2 63.6 0.198 0.0 33.3247 1.98 86.0 3.438425 201 241 -99.0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 2 2 149.9 148.6 7.6283 42.0 63.1 0.199 0.0 33.3253 1.98 86.0 3.438429 200 57 8.3 -99.00 0 -99.00 1.981 86.2 0 32.08 0 56.28 0 2.682 0 -99.00 0 1 1 157.5 156.1 7.6191 41.0 62.0 0.205 0.0 33.3432 1.93 84.0 3.439610 199 241 8.3 -99.00 0 -99.00 1.934 84.2 0 32.09 0 57.52 0 2.647 0 -99.00 0