*2023/04/11 13:28:40.95 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2022/05/09 06:23:35.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 7 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 17B78F8A NUMBER OF CHANNELS : 25 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 7 2 Bottle:Firing_Sequence n/a 1 7 3 Pressure decibar 5.196 103.132 4 Depth metres 5.151 102.236 5 Temperature:Secondary 'deg C (ITS90)' 7.1539 10.2689 6 Transmissivity %/metre 31.2 55.4 7 Salinity:T1:C1 PSS-78 29.6172 33.6741 8 Oxygen:Dissolved:SBE mL/L 2.121 7.341 9 Oxygen:Dissolved:SBE umol/kg 92.3 320.6 10 Conductivity:Secondary S/m 3.299614 3.426495 11 Number_of_bin_records n/a 241 241 12 Sample_Number n/a 148 154 13 Temperature:Draw 'deg C (ITS90)' 7.2 10.3 14 Chlorophyll:Extracted mg/m^3 0.44 6.54 15 Flag:Chlorophyll:Extracted ' ' 16 Phaeo-Pigment:Extracted mg/m^3 0.62 1.47 17 Oxygen:Dissolved mL/L 2.13 7.341 18 Oxygen:Dissolved umol/kg 92.68385 320.5707 19 Flag:Oxygen:Dissolved ' ' 20 Nitrate_plus_Nitrite umol/L 2.92 33.08 21 Flag:Nitrate_plus_Nitrite ' ' 22 Silicate umol/L 6.25 51.53 23 Flag:Silicate ' ' 24 Phosphate umol/L 0.383 2.4 25 Flag:Phosphate ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 10 F ' ' 6 11 -99 ' ' 5 I I 0 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 7 F R4 2 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 -99 ' ' 8 F R4 3 18 -99 ' ' 6 F ' ' 1 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 3 25 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2022-015 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Nelson J. PLATFORM : Sir John Franklin *LOCATION GEOGRAPHIC AREA : WCVI STATION : LB04 EVENT NUMBER : 62 LATITUDE : 48 35.69000 N ! (deg min) LONGITUDE : 125 8.61000 W ! (deg min) WATER DEPTH : 108 ALTIMETER (M) : 8.525 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! --------------------------------- -------------- ---------- Temperature ' ' 2449 Conductivity ' ' 1764 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 4484 Conductivity:2 ' ' 2128 'Oxygen:SBE 43' ' ' 1176 Fluorometer:Seapoint ' ' 2225 Altimeter ' ' 75321 'Transmissometer:WET Labs C-Star' ' ' 1201DR $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2022/11/08 12:01:21 1687 1687 CLEAN 5.3 2022/11/08 12:01:32 1687 1687 ADDSAMP 3.6 2022/11/08 13:08:54 1687 1687 BINAVE 4.2.1 2022/11/08 13:12:08 1687 7 MERGE 3.6 2022/12/02 10:23:49 7 7 CLEAN 5.3 2022/12/09 12:01:14 7 7 CALIB 12.1 2022/12/16 14:14:03 7 7 SORT 3.6 2022/12/16 14:14:14 7 7 REMOVECH 8.2 2022/12/16 14:23:17 7 7 CHGUNITS 3.2 2022/12/16 14:23:26 7 7 CHGUNITS 3.2 2022/12/16 14:23:40 7 7 REORDER 1.3.1 2022/12/16 14:25:00 ? ? HDREDIT2 3.2 2022/12/16 14:25:05 ? ? REMOVECH 8.2 2023/04/11 13:23:37 7 7 HDREDIT2 3.2 2023/04/11 13:28:40 ? ? $END $REMARKS -CLEAN functions: 2022/11/08 12:01:27 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2022-015\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2022/12/02 10:23:49 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : D:\Telework\2022-015\Processing\hydro\2022-015-0062.samavg Secondary file: D:\Telework\2022-015\Processing\hydro\2022-015-0062.mrgcln1s 7 secondary records matched to primary records. Comments from secondary file: D:\Telework\2022-015\Processing\hydro\2022-015-0062.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2022/12/02 10:19:31 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2022/12/09 12:01:13 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2022/12/16 14:14:03 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-015\Processing\doc\2022-015-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Fluorescence:URU:Seapoint mg/m^3 10 0.0000000E+00 0.1000000E+02 15 Oxygen:Dissolved:SBE mL/L 10 0.4490000E-01 0.1072600E+01 -SORT parameters: 2022/12/16 14:14:14 Sorted in ascending order of channel Pressure -REMOVECH 2022/12/16 14:23:17 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T0:C0 [PSS-78] Status:Pump Descent_Rate [m/s] Altimeter [metres] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2022/12/16 14:25:05 Applied edit header: D:\Telework\2022-015\Processing\doc\HYDRO\2022-015-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Format: F8.3 ==> F6.1 Channel 14: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 -REMOVECH 2023/04/11 13:23:37 The following CHANNEL(S) were removed: Fluorescence:URU:Seapoint [mg/m^3] -HEADER EDITS: 2023/04/11 13:28:40 Applied edit header: D:\Telework\2022-015\Processing\Files_with_Fluor\2022-015-bot-hdr2.txt Channel 11: Number_of_bin_records [n/a] Pad: ' ' ==> -99 $END *COMMENTS Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters after collection, and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 15.5 weeks after the cruise on a Turner Trilogy7200-000 fluorometer, using methods described in Holm-Hansen et al. (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For further details on methodolgy, see document QF 2022-015_CHL_*.xlsx Methodology sheet. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values Oxygen samples were analyzed in the laboratory at the Institute of Ocean Sciences using an automated Winkler titration system (Metrohm Dosimat model 876, (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2022-015OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 35 - 43 days after collection. For details including a duplicate analysis, see document QF2022-015SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Insitute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2022-015nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminot, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. Seapoint Fluorescence values were unbelievably low, likely due to an error in the gain entered in the configuration file. All values were multiplied by 10. After recalibration, the comparison between Seapoint fluorescence and extracted chlorophyll samples exhibited the usual pattern or fluorescence reading higher than extracted chlorophyl when CHL was <2.5ug/L and lower when CHL was >2.5ug/L. While the CTD fluorescence data are expressed in concentration units, it is recommended that users check extracted chlorophyll values where available. Dissolved oxygen data were recalibrated in two sections as a large change was found in comparison with titrated samples between casts #39 and #51. While calibration drift may be a factor in the change, there was a notable change in oceanic conditions between 180m and 450m that likely affected the response of the oxygen sensor. Channel Salinity:T1:C1 was found to be lower than bottles by approximately 0.002psu, but bottle values are likely a little high due to incomplete flushing of Niskin bottles and evaporation or desorption of glass particles into samples. CTD salinity is likely within +/- 0.002psu. No recalibration was applied to salinity. For details on the processing see the report: 2022-015_Processing_Report.doc. --------------------------------------------------------------------------------- Channel Fluorescence was removed because the values found were extremely low and compared very badly with extracted chlorophyll samples. Files that include fluorescence may be obtained by sending a request to: PAC SCI IOS Data / DonnĂ©es ISO SCI PAC (DFO/MPO) *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! --------------------------- -------- ---- ------ ------------ Fluorescence:URU:Seapoint mg/m^3 10 -99 () (0 10) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.449E-01 1.0726) $END !1- 2- --3--- --4--- ---5---- --6-- ---7---- --8--- --9-- ----10--- -11- -12- --13- --14-- 15 --16-- ---17-- --18- 19 --20-- 21 --22-- 23 ---24-- 25 !Bo Bo Pressu Depth Temperat Trans Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi :T1:C1 : n: ity: er_o le_ ratur phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~u ~u Secondar vity Dissol Disso Secondary ~bin Numb e: Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !mb en y ved: lved: _rec er Draw ted ct Extrac lved lv Nitrit ri ca ha !er ce SBE SBE ords ed ted ed e te te te !-- -- ------ ------ -------- ----- -------- ------ ----- --------- ---- ---- ----- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 7 7 5.2 5.2 10.2689 31.2 29.6172 7.34 320.6 3.299614 241 154 10.3 5.07 0 0.62 7.341 320.6 0 2.92 0 6.25 0 0.383 0 6 6 10.2 10.2 10.0185 33.5 30.0034 7.14 311.6 3.317882 241 153 10.1 6.54 6 0.96 7.179 313.4 0 4.66 0 7.76 0 0.532 0 5 5 20.0 19.8 8.9600 51.2 31.3124 5.55 241.8 3.358002 241 152 9.1 1.67 0 1.47 5.461 238.1 0 17.82 0 27.89 0 1.528 0 4 4 30.4 30.1 8.4916 54.0 31.8698 4.71 205.4 3.371841 241 151 8.8 0.89 0 1.08 4.727 206.0 0 20.19 0 30.69 0 1.671 0 3 3 49.7 49.3 8.1824 55.4 32.3657 4.36 190.0 3.392959 241 150 8.4 0.44 0 0.86 4.346 189.3 0 22.33 6 31.72 6 1.786 6 2 2 75.7 75.1 7.3594 47.4 33.4903 2.51 109.4 3.426495 241 149 7.8 -99.00 0 -99.00 2.510 109.2 6 31.46 0 47.12 0 2.313 0 1 1 103.1 102.2 7.1539 42.3 33.6741 2.12 92.3 3.426264 241 148 7.2 -99.00 0 -99.00 2.130 92.7 0 33.08 0 51.53 0 2.400 0