*2022/09/12 16:17:33.67 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2022/04/03 15:37:45.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 11 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : FD049938 NUMBER OF CHANNELS : 31 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 11 2 Bottle:Firing_Sequence n/a 1 11 3 Pressure decibar 2.263 144.167 4 Depth metres 2.244 142.903 5 Temperature:Primary 'deg C (ITS90)' 7.6486 8.0729 6 Transmissivity %/metre 22.3 42.4 7 Fluorescence:URU:Seapoint mg/m^3 0.312 0.727 8 PAR uE/m^2/sec 0.348 428.029 9 PAR:Reference uE/m^2/sec 350.055 1382.546 10 pH:SBE:Nominal n/a 8.48 8.569 11 Salinity:T0:C0 PSS-78 30.4326 32.363 12 Oxygen:Dissolved:SBE mL/L 3.633 5.429 13 Oxygen:Dissolved:SBE umol/kg 158.3 236.8 14 Conductivity:Primary S/m 3.198576 3.350383 15 Sample_Number n/a 109 119 16 Number_of_bin_records n/a 121 121 17 Temperature:Draw 'deg C (ITS90)' 7.9 8.3 18 Salinity:Bottle PSS-78 32.1213 32.1213 19 Flag:Salinity:Bottle ' ' 20 Chlorophyll:Extracted mg/m^3 0.64 0.89 21 Flag:Chlorophyll:Extracted ' ' 22 Phaeo-Pigment:Extracted mg/m^3 0.54 0.62 23 Oxygen:Dissolved mL/L 3.861 5.417 24 Oxygen:Dissolved umol/kg 168.2245 236.3333 25 Flag:Oxygen:Dissolved ' ' 26 Nitrate_plus_Nitrite umol/L 26.9 29.53 27 Flag:Nitrate_plus_Nitrite ' ' 28 Silicate umol/L 48.16 48.81 29 Flag:Silicate ' ' 30 Phosphate umol/L 2.096 2.296 31 Flag:Phosphate ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 10 F ' ' 6 15 -99 ' ' 5 I I 0 16 ' ' ' ' 5 I I 0 17 -99 ' ' 6 F R4 1 18 -99 ' ' 9 F R4 4 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 8 F R4 3 24 -99 ' ' 6 F ' ' 1 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 0 ' ' 3 NQ C ' ' 30 -99 ' ' 8 F R4 3 31 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2022-013 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Salish Sea Biophysical Survey SCIENTIST : O'Neill C. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 62 EVENT NUMBER : 26 LATITUDE : 48 22.82000 N ! (deg min) LONGITUDE : 123 2.66000 W ! (deg min) WATER DEPTH : 149 ALTIMETER (M) : 5.67 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 2663 Conductivity:2 ' ' 2754 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3949 Altimeter ' ' 73171 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'LISST-200X:Sauter Mean Diameter' ' ' 2203 'LISST-200X:Total Volume Conc.' ' ' 2203 pH ' ' 0691 PAR/Irradiance:Biospherical/Licor ' ' 4565 Unavailable ' ' ' ' SPAR:Biospherical/Licor ' ' 20518 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2022/08/22 14:24:30 1331 1331 CLEAN 5.3 2022/08/22 14:27:08 1331 1331 ADDSAMP 3.6 2022/08/22 15:58:45 1331 1331 BINAVE 4.2.1 2022/08/23 15:08:42 1331 11 MERGE 3.6 2022/09/12 16:08:51 11 11 CLEAN 5.3 2022/09/12 16:10:56 11 11 CALIB 12.1 2022/09/12 16:11:13 11 11 SORT 3.6 2022/09/12 16:11:25 11 11 REMOVECH 8.2 2022/09/12 16:12:14 11 11 CHGUNITS 3.2 2022/09/12 16:12:30 11 11 CHGUNITS 3.2 2022/09/12 16:13:01 11 11 REORDER 1.3.1 2022/09/12 16:15:24 ? ? HDREDIT2 3.2 2022/09/12 16:17:33 ? ? $END $REMARKS -CLEAN functions: 2022/08/22 14:27:06 20 Reset #RECS, MIN & MAX values in header. Insert Pad Values in Channel: Fluorescence:URU:Seapoint [mg/m^3] where channel Fluorescence:URU:Seapoint [mg/m^3] is in the range 14.85 to 15 0 data records in pad range. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2022-013\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2022/09/12 16:08:51 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : D:\Telework\2022-013\Processing\hydro\2022-013-0026.samavg Secondary file: D:\Telework\2022-013\Processing\hydro\2022-013-0026.mrgcln1s 11 secondary records matched to primary records. -SORT parameters: 2022/09/12 16:08:30 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2022/09/12 16:10:56 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2022/09/12 16:11:13 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-013\Processing\doc\2022-013-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Oxygen:Dissolved:SBE mL/L 10 0.4610000E-01 0.1015300E+01 -SORT parameters: 2022/09/12 16:11:25 Sorted in ascending order of channel Pressure -REMOVECH 2022/09/12 16:12:14 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Particle Mean Diameter [u] Particle Volume Conc [ppm] Salinity:T1:C1 [PSS-78] Status:Pump Descent_Rate [m/s] Altimeter [metres] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2022/09/12 16:17:33 Applied edit header: D:\Telework\2022-013\Processing\doc\HYDRO\2022-013-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Channel 14: Conductivity:Primary [S/m] Format: F8.3 ==> F10.6 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Format: F8.3 ==> F6.1 Channel 17: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 10: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Format: F10.6 ==> F8.3 $END *COMMENTS Sample_Number 110: SAL: Bottle chipped, unreliable seal formed, use with caution. Sample_Number 109: OXY: Dose tip was found to be partially blocked. Replaced for subsequent samples. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in scintillation vials in the -80C freezer onboard the Vector, then transferred to -80C storage in the lab until analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner Trilogy7200-000 fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 18 weeks after the cruise. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Chlorophyll values ranged from 0.15 - 57.17 ug/L in 117 samples. 0 samples were below Minimum Limit of Detection (10, and 0 duplicates had a CV%>30. 1 duplicate was rejected (A or B), improving the %CV to 4.64% over 27 duplicate pairs, with 1 samples having a CV%>10 and 0 having a %CV>30. Our average dataset %CV is 3.89 % for 2013 - 2021 using the Turner 10-AU - so the overall quality of this dataset is acceptable For details see worksheet “CV%” in file QF2022-013_CHL*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2022-013OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 21 - 49 days after collection. For details including a duplicate analysis, see document QF2022-013SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. CTD Salinity values were all > 25psu so no silicate data corrections were needed. For details including a duplicate analysis, see document QF2022-013nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint, pH:SBE, PAR and SPAR data are nominal and unedited except that some records were removed in editing temperature and salinity. Channel pH:SBE was removed for events #67-94 because the sensor malfunctioned. While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2022-013_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.461E-01 1.0153) $END !1- 2- --3--- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10-- ---11--- --12-- --13- ----14--- -15- -16- --17- ---18--- 19 --20-- 21 --22-- ---23-- --24- 25 --26-- 27 --28-- 29 ---30-- 31 !Bo Bo Pressu Depth Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Conductiv Samp Numb Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: Refere Nominal :T0:C0 : n: ity: le_ er_o ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~u ~u Primary vity URU: nce Dissol Disso Primary Numb ~bin e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !mb en Seapoin ved: lved: er _rec Draw tt ted ct Extrac lved lv Nitrit ri ca ha !er ce t SBE SBE ords le ed ted ed e te te te !-- -- ------ ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- --------- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 11 11 2.3 2.2 8.0729 39.7 0.591 428.0 1243.1 8.569 30.4326 5.42 236.6 3.199000 119 121 8.3 -99.0000 0 0.85 0 0.57 5.409 236.0 6 27.06 0 48.81 0 2.166 0 10 10 5.6 5.5 8.0695 40.4 0.727 118.4 1382.5 8.567 30.4399 5.43 236.8 3.199000 118 121 8.3 -99.0000 0 0.86 0 0.57 5.417 236.3 0 26.90 6 48.78 6 2.096 6 9 9 10.9 10.8 8.0531 41.1 0.706 36.7 1301.5 8.560 30.4960 5.36 234.0 3.203000 117 121 8.3 -99.0000 0 0.89 0 0.54 5.361 233.9 0 27.19 0 48.59 0 2.169 0 8 8 21.3 21.1 8.0258 42.1 0.587 2.4 412.9 8.549 30.6342 5.18 226.0 3.215000 116 121 8.3 -99.0000 0 0.64 6 0.62 5.211 227.3 0 27.46 0 48.50 0 2.172 0 7 7 31.0 30.8 7.9819 41.5 0.513 0.8 586.7 8.545 30.7541 5.07 221.1 3.223000 115 121 8.2 -99.0000 0 -99.00 0 -99.00 5.053 220.4 0 27.60 0 48.25 0 2.193 0 6 6 39.9 39.6 7.9667 42.1 0.490 0.4 358.5 8.540 30.8008 5.03 219.3 3.226000 114 121 8.2 -99.0000 0 -99.00 0 -99.00 5.004 218.3 0 27.96 0 48.42 0 2.153 0 5 5 50.4 50.0 7.9380 42.4 0.456 0.4 350.1 8.536 30.9126 4.91 213.9 3.235000 113 121 8.2 -99.0000 0 -99.00 0 -99.00 4.902 213.8 0 28.01 0 48.42 0 2.206 0 4 4 76.0 75.3 7.8780 40.7 0.397 0.3 394.6 8.522 31.2018 4.65 202.9 3.258000 112 121 8.1 -99.0000 0 -99.00 0 -99.00 4.649 202.7 6 28.49 0 48.20 0 2.221 0 3 3 101.1 100.2 7.7107 27.9 0.333 0.3 366.6 8.489 32.0465 3.94 171.5 3.324000 111 121 8.0 -99.0000 0 -99.00 0 -99.00 3.924 171.0 0 29.24 0 48.16 0 2.196 0 2 2 126.1 125.0 7.6969 26.7 0.324 0.3 364.0 8.489 32.1197 3.88 168.9 3.331000 110 121 8.0 32.1213 4 -99.00 0 -99.00 3.861 168.2 0 29.30 0 48.22 0 2.296 0 1 1 144.2 142.9 7.6486 22.3 0.312 0.3 389.1 8.480 32.3630 3.63 158.3 3.350000 109 121 7.9 -99.0000 0 -99.00 0 -99.00 4.253 185.3 4 29.53 6 48.42 6 2.218 6