*2022/09/12 16:17:33.24 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2022/04/02 01:29:54.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 6B67F685 NUMBER OF CHANNELS : 31 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 14 2 Bottle:Firing_Sequence n/a 1 14 3 Pressure decibar 1.425 173.979 4 Depth metres 1.413 172.436 5 Temperature:Primary 'deg C (ITS90)' 7.7723 10.0458 6 Transmissivity %/metre 1.6 56.5 7 Fluorescence:URU:Seapoint mg/m^3 0.76E-01 2.099 8 PAR uE/m^2/sec 0.348 48.638 9 PAR:Reference uE/m^2/sec 112.03 145.09 10 pH:SBE:Nominal n/a 8.036 9.535 11 Salinity:T0:C0 PSS-78 26.8025 31.3746 12 Oxygen:Dissolved:SBE mL/L 0.82E-01 13.216 13 Oxygen:Dissolved:SBE umol/kg 3.6 578.3 14 Conductivity:Primary S/m 2.997756 3.414054 15 Sample_Number n/a 1 14 16 Number_of_bin_records n/a 119 121 17 Temperature:Draw 'deg C (ITS90)' 9.1 10.7 18 Salinity:Bottle PSS-78 31.3717 31.3717 19 Flag:Salinity:Bottle ' ' 20 Chlorophyll:Extracted mg/m^3 1.35 57.17 21 Flag:Chlorophyll:Extracted ' ' 22 Phaeo-Pigment:Extracted mg/m^3 0.62 8.28 23 Oxygen:Dissolved mL/L 0 12.306 24 Oxygen:Dissolved umol/kg 0 538.572 25 Flag:Oxygen:Dissolved ' ' 26 Nitrate_plus_Nitrite umol/L 0.2E-01 27.6 27 Flag:Nitrate_plus_Nitrite ' ' 28 Silicate umol/L 5.09 103.44 29 Flag:Silicate ' ' 30 Phosphate umol/L 0.282 5.295 31 Flag:Phosphate ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 10 F ' ' 6 15 -99 ' ' 5 I I 0 16 ' ' ' ' 5 I I 0 17 -99 ' ' 6 F R4 1 18 -99 ' ' 9 F R4 4 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 8 F R4 3 24 -99 ' ' 6 F ' ' 1 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 0 ' ' 3 NQ C ' ' 30 -99 ' ' 8 F R4 3 31 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2022-013 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Salish Sea Biophysical Survey SCIENTIST : O'Neill C. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : SI EVENT NUMBER : 1 LATITUDE : 48 39.08000 N ! (deg min) LONGITUDE : 123 29.94000 W ! (deg min) WATER DEPTH : 182 ALTIMETER (M) : 4.93 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 2663 Conductivity:2 ' ' 2754 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3949 Altimeter ' ' 73171 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'LISST-200X:Sauter Mean Diameter' ' ' 2203 'LISST-200X:Total Volume Conc.' ' ' 2203 pH ' ' 0691 PAR/Irradiance:Biospherical/Licor ' ' 4565 Unavailable ' ' ' ' SPAR:Biospherical/Licor ' ' 20518 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2022/08/22 14:24:27 1694 1694 CLEAN 5.3 2022/08/22 14:27:06 1694 1694 ADDSAMP 3.6 2022/08/22 15:58:43 1694 1694 BINAVE 4.2.1 2022/08/23 15:08:41 1694 14 MERGE 3.6 2022/09/12 16:08:51 14 14 CLEAN 5.3 2022/09/12 16:10:56 14 14 CALIB 12.1 2022/09/12 16:11:12 14 14 SORT 3.6 2022/09/12 16:11:24 14 14 REMOVECH 8.2 2022/09/12 16:12:13 14 14 CHGUNITS 3.2 2022/09/12 16:12:29 14 14 CHGUNITS 3.2 2022/09/12 16:13:00 14 14 REORDER 1.3.1 2022/09/12 16:15:23 ? ? HDREDIT2 3.2 2022/09/12 16:17:33 ? ? $END $REMARKS -CLEAN functions: 2022/08/22 14:27:06 Reset #RECS, MIN & MAX values in header. Insert Pad Values in Channel: Fluorescence:URU:Seapoint [mg/m^3] where channel Fluorescence:URU:Seapoint [mg/m^3] is in the range 14.85 to 15 242 data records in pad range. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2022-013\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2022/09/12 16:08:51 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : D:\Telework\2022-013\Processing\hydro\2022-013-0001.samavg Secondary file: D:\Telework\2022-013\Processing\hydro\2022-013-0001.mrgcln1s 14 secondary records matched to primary records. -SORT parameters: 2022/09/12 16:08:30 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2022/09/12 16:10:56 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2022/09/12 16:11:12 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-013\Processing\doc\2022-013-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Oxygen:Dissolved:SBE mL/L 10 0.4610000E-01 0.1015300E+01 -SORT parameters: 2022/09/12 16:11:24 Sorted in ascending order of channel Pressure -REMOVECH 2022/09/12 16:12:13 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Particle Mean Diameter [u] Particle Volume Conc [ppm] Salinity:T1:C1 [PSS-78] Status:Pump Descent_Rate [m/s] Altimeter [metres] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2022/09/12 16:17:33 Applied edit header: D:\Telework\2022-013\Processing\doc\HYDRO\2022-013-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Channel 14: Conductivity:Primary [S/m] Format: F8.3 ==> F10.6 Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Format: F8.3 ==> F6.1 Channel 17: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 Channel 10: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Format: F10.6 ==> F8.3 $END *COMMENTS Sample_Number 1: OXY: Anoxic sample. Sample_Number 2: OXY: Anoxic samples. Sample_Number 12: OXY: Sample over-titrated. Sample_Number 14: ALL: Niskin 6 misfired. Niskin 14 closed in its placed. Sample_Number 1: SIL, PO4: Data extrapolated, NO3: Very low oxygen - no NO3 data Sample_Number 2: SIL, PO4: Data extrapolated, NO3: Very low oxygen - no NO3 data Sample_Number 3: SIL, PO4: Data extrapolated, NO3: Very low oxygen - no NO3 data Sample_Number 4: PO4: Data extrapolated, NO3: Veru low oxygen - no NO3 data Sample_Number 5: SIL: Chauvenet outlier in duplicate study Sample_Number 8: PO4: Bad data point Sample_Number 12: SIL: Chauvenet outlier in duplicate study Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in scintillation vials in the -80C freezer onboard the Vector, then transferred to -80C storage in the lab until analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner Trilogy7200-000 fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 18 weeks after the cruise. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Chlorophyll values ranged from 0.15 - 57.17 ug/L in 117 samples. 0 samples were below Minimum Limit of Detection (10, and 0 duplicates had a CV%>30. 1 duplicate was rejected (A or B), improving the %CV to 4.64% over 27 duplicate pairs, with 1 samples having a CV%>10 and 0 having a %CV>30. Our average dataset %CV is 3.89 % for 2013 - 2021 using the Turner 10-AU - so the overall quality of this dataset is acceptable For details see worksheet “CV%” in file QF2022-013_CHL*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2022-013OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 21 - 49 days after collection. For details including a duplicate analysis, see document QF2022-013SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. CTD Salinity values were all > 25psu so no silicate data corrections were needed. For details including a duplicate analysis, see document QF2022-013nuts*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint, pH:SBE, PAR and SPAR data are nominal and unedited except that some records were removed in editing temperature and salinity. Channel pH:SBE was removed for events #67-94 because the sensor malfunctioned. While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Fluorescence:URU:Seapoint Fluorescence went off-scale near the surface for event #1; affected values were replaced with pad values. Extracted Chlorophyll values were well above the top of the range for the sensor. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2022-013_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.461E-01 1.0153) $END !1- 2- --3--- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10-- ---11--- --12-- --13- ----14--- -15- -16- --17- ---18--- 19 --20-- 21 --22-- ---23-- --24- 25 --26-- 27 --28-- 29 ---30-- 31 !Bo Bo Pressu Depth Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Conductiv Samp Numb Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: Refere Nominal :T0:C0 : n: ity: le_ er_o ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag !~u ~u Primary vity URU: nce Dissol Disso Primary Numb ~bin e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p !mb en Seapoin ved: lved: er _rec Draw tt ted ct Extrac lved lv Nitrit ri ca ha !er ce t SBE SBE ords le ed ted ed e te te te !-- -- ------ ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- --------- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 13 14 1.4 1.4 10.0458 2.0 -99.000 48.6 121.2 9.535 26.8025 13.22 578.3 2.998000 13 121 10.7 -99.0000 0 35.44 0 7.54 12.306 538.6 0 0.02 0 5.09 0 0.282 0 12 13 5.5 5.5 8.9687 1.6 -99.000 1.9 134.1 9.066 28.4810 8.98 392.3 3.083000 12 121 10.0 -99.0000 0 57.17 0 8.28 8.429 368.4 2 7.64 6 27.88 36 1.209 6 11 12 10.5 10.4 8.3062 43.0 2.099 0.5 143.2 8.613 29.0877 6.16 269.0 3.089000 11 121 9.5 -99.0000 0 5.94 6 0.62 5.864 256.1 0 21.30 0 44.65 0 1.917 0 10 11 20.5 20.3 8.0188 49.5 0.601 0.4 145.1 8.489 29.3558 5.26 229.6 3.092000 10 121 9.3 -99.0000 0 1.35 0 0.69 5.187 226.5 0 24.82 0 50.23 0 2.119 0 9 10 30.5 30.3 7.8738 50.2 0.338 0.4 136.9 8.441 29.4662 4.90 213.9 3.092000 9 121 9.2 -99.0000 0 -99.00 0 -99.00 4.987 217.8 0 26.09 0 51.86 0 2.135 0 8 9 40.5 40.2 7.8080 50.6 0.212 0.3 126.7 8.455 29.5296 4.97 216.8 3.093000 8 121 9.1 -99.0000 0 -99.00 0 -99.00 4.929 215.2 0 26.73 0 52.30 0 -99.000 5 14 8 50.5 50.1 7.7723 49.7 0.156 0.3 130.4 8.453 29.6594 4.91 214.4 3.103000 14 121 9.1 -99.0000 0 -99.00 0 -99.00 4.852 211.8 2 27.23 2 52.82 2 2.234 2 7 7 75.5 74.9 7.8183 43.5 0.175 0.3 137.4 8.417 30.2004 4.47 195.0 3.159000 7 121 9.1 -99.0000 0 -99.00 0 -99.00 4.284 187.0 0 27.60 0 53.83 0 2.376 0 5 5 100.5 99.6 8.4281 33.8 0.104 0.3 135.9 8.182 30.7788 2.11 92.1 3.265000 5 121 9.6 -99.0000 0 -99.00 0 -99.00 1.764 77.0 6 20.58 6 74.10 36 3.518 6 4 4 125.5 124.4 9.3837 54.1 0.076 0.3 123.1 8.036 31.2612 0.10 4.2 3.394000 4 121 10.1 -99.0000 0 -99.00 0 -99.00 0.057 2.5 0 -99.00 5 89.61 0 4.566 3 3 3 150.6 149.2 9.4675 54.1 0.079 0.3 115.7 8.045 31.3486 0.08 3.6 3.410000 3 119 10.1 -99.0000 0 -99.00 0 -99.00 0.022 1.0 0 -99.00 5 96.81 3 4.932 3 2 2 173.8 172.2 9.4698 56.4 0.085 0.3 112.3 8.051 31.3746 0.10 4.2 3.414000 2 120 10.2 31.3717 0 -99.00 0 -99.00 0.000 0.0 26 -99.00 5 102.57 3 5.243 3 1 1 174.0 172.4 9.4698 56.5 0.084 0.3 112.0 8.050 31.3746 0.10 4.4 3.414000 1 119 10.3 -99.0000 0 -99.00 0 -99.00 0.000 0.0 2 -99.00 5 103.44 3 5.295 3