*2022/12/01 11:31:38.83 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2022/08/12 09:48:26.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 19 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : F0E1D08E NUMBER OF CHANNELS : 26 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 19 2 Bottle:Firing_Sequence n/a 1 19 3 Pressure decibar 4.957 1323.228 4 Depth metres 4.915 1307.888 5 Temperature:Secondary 'deg C (ITS90)' 2.8902 14.8462 6 Transmissivity %/metre 43.8 59.4 7 Transmissivity:Green %/metre 63.6 95.8 8 PAR uE/m^2/sec 0 0.433 9 Salinity:T1:C1 PSS-78 31.7779 34.4849 10 Oxygen:Dissolved:SBE mL/L 0.225 6.708 11 Oxygen:Dissolved:SBE umol/kg 9.8 292.3 12 Conductivity:Secondary S/m 3.172491 3.922402 13 Sample_Number n/a 68 86 14 Number_of_bin_records n/a 241 241 15 Temperature:Draw 'deg C (ITS90)' 5.2 15.1 16 Salinity:Bottle PSS-78 31.7869 34.4606 17 Flag:Salinity:Bottle ' ' 18 Oxygen:Dissolved mL/L 0.227 6.626 19 Oxygen:Dissolved umol/kg 9.87053 288.7637 20 Flag:Oxygen:Dissolved ' ' 21 Nitrate_plus_Nitrite umol/L 0 46.14 22 Flag:Nitrate_plus_Nitrite ' ' 23 Silicate umol/L 0.18 153.43 24 Flag:Silicate ' ' 25 Phosphate umol/L 0.8E-01 3.376 26 Flag:Phosphate ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 10 F ' ' 6 13 -99 ' ' 5 I I 0 14 ' ' ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 9 F R4 4 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 8 F R4 3 19 -99 ' ' 6 F ' ' 1 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2022-008 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P4 EVENT NUMBER : 18 LATITUDE : 48 39.03000 N ! (deg min) LONGITUDE : 126 40.01000 W ! (deg min) WATER DEPTH : 1311 ALTIMETER (M) : 9.84 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4700 Conductivity ' ' 3531 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 4888 Conductivity:2 ' ' 4513 'Oxygen:SBE 43' ' ' 3791 Fluorometer:Seapoint ' ' 3982 Altimeter ' ' 76341 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG PAR/Irradiance:Biospherical/Licor ' ' 70613 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.3 2022/11/15 09:27:10 4579 4579 CLEAN 5.3 2022/11/15 09:27:33 4579 4579 ADDSAMP 3.6 2022/11/22 08:35:41 4579 4579 BINAVE 4.2.1 2022/11/22 08:40:03 4579 19 MERGE 3.6 2022/11/22 08:40:15 19 19 CLEAN 5.3 2022/11/23 14:50:52 19 19 CALIB 12.1 2022/11/23 14:52:06 19 19 SORT 3.6 2022/11/23 14:52:47 19 19 REMOVECH 8.2 2022/11/23 16:03:04 19 19 CHGUNITS 3.2 2022/11/23 16:03:24 19 19 CHGUNITS 3.2 2022/11/23 16:03:31 19 19 REORDER 1.3.1 2022/11/23 16:03:37 ? ? HDREDIT2 3.2 2022/12/01 11:31:38 ? ? $END $REMARKS -CLEAN functions: 2022/11/15 09:27:31 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2022-008\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2022/11/22 08:40:15 Merge Channel: Bottle_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, Ammonium, Flag:Ammonium Primary file : D:\Telework\2022-008\Processing\hydro\2022-008-0018.samavg Secondary file: D:\Telework\2022-008\Processing\hydro\2022-008-0018.mrgcln1s 19 secondary records matched to primary records. Comments from secondary file: D:\Telework\2022-008\Processing\hydro\2022-008-0018.mrgcln1s ------------------------------------------------------------ -CLEAN functions: 2022/11/18 15:27:55 20 Reduce header to sections: FIL HIS COM Remarks removed from kept sections. Reset #RECS, MIN & MAX values in header. -SORT parameters: 2022/11/18 15:28:05 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2022/11/23 14:50:51 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2022/11/23 14:52:06 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2022-008\Processing\doc\2022-008-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1016300E+01 -SORT parameters: 2022/11/23 14:52:47 Sorted in ascending order of channel Pressure -REMOVECH 2022/11/23 16:03:04 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Fluorescence:URU:Seapoint [mg/m^3] Oxygen:Voltage:SBE [volts] Salinity:T0:C0 [PSS-78] Status:Pump Descent_Rate [m/s] Altimeter [metres] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2022/12/01 11:31:38 Applied edit header: D:\Telework\2022-008\Processing\doc\HYDRO\2022-008-bot-hdr-1_27.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Channel 6: Transmissivity [%/metre] Name: Transmissivity:1 ==> Transmissivity Format: F8.3 ==> F6.1 Channel 7: Transmissivity:Green [%/metre] Name: Transmissivity:2 ==> Transmissivity:Green Channel 15: Temperature:Draw [deg C (ITS90)] Format: F7.2 ==> F6.1 $END *COMMENTS Comments from secondary file: D:\Telework\2022-008\Processing\hydro\2022-008-0018.mrgcln1s ------------------------------------------------------------ Comments from secondary file: D:\Telework\2022-008\Processing\hydro\2022-008-0018.oxy ------------------------------------------------------- Sample_Number 75: OXY: Analyst mistakenly forgot to add acid prior to titration. No titration occurred. Comments from secondary file: D:\Telework\2022-008\Processing\hydro\2022-008-0018.nut ------------------------------------------------------- Sample_Number 72: SIL: Chauvenet outlier in duplicate study Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and immediately frozen and stored in a -80C freezer until analysis. All samples were returned to the Institute of Ocean Sciences and analyzed 2 weeks after the cruise on a Turner Trilogy 7200-000 fluorometer, using methods described in Holm-Hansen et al (1965). Fluorescence readings taken before and after sample acidification were used to calculate chlorophyll and phaeopigment concentrations. For details see worksheet “CV%” in file QF2022-008_CHL*.xlsx. NOTE: Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeo-Pigment values. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2022-008OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 8 - 21 days after collection. For details including a duplicate analysis, see document QF2022-008SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. For samples 400m and deeper a second set of samples are collected and stored cool for silicate analysis. All samples were returned to the Institute of Ocean Sciences and they were analyzed using an Astoria-Pacific Analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2022-008nuts*.xlsx. The minimum detectable level for DMS is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more details including method, raw data and duplicates, see document "DMS 2022-08 Summary*.xls”. Detailed notes on analysis are in file 2022-008 DMS report*.doc. The minimum detectable level for DMSP is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more details including method, raw data and duplicates, see document "DMSP 2022-08 Summary*.xls Detailed notes on analysis are in file 2022-008 DMS report*.doc. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For casts #16 to 27 channel Fluorescence:URU:Seapoint was removed because the sensor malfunctioned. The sensor was changed after cast #27. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on the processing see the report: 2022-008_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0163) $END !1- 2- --3--- --4--- ---5---- --6-- --7-- --8--- ---9---- --10-- --11- ----12--- -13- -14- --15- ---16--- 17 ---18-- --19- 20 --21-- 22 --23-- 24 ---25-- 26 !Bo Bo Pressu Depth Temperat Trans Trans PAR Salinity Oxygen Oxyge Conductiv Samp Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi missi :T1:C1 : n: ity: le_ er_o ratur :Bottle ag Dissolv n: ag e_ ag te ag te ag !~u ~u Secondar vity vity: Dissol Disso Secondary Numb ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p !mb en y Green ved: lved: er _rec Draw tt lved lv Nitrit ri ca ha !er ce SBE SBE ords le ed e te te te !-- -- ------ ------ -------- ----- ----- ------ -------- ------ ----- --------- ---- ---- ----- -------- -- ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 19 19 5.0 4.9 14.8462 45.4 65.9 0.4 31.7779 6.46 281.9 3.922402 86 241 15.1 31.7869 0 6.315 275.6 0 0.00 0 0.18 0 0.080 0 18 18 10.2 10.1 11.8504 43.8 63.6 0.1 32.0051 6.59 287.1 3.678465 85 241 12.3 -99.0000 0 6.423 280.1 6 2.26 0 3.05 0 0.608 0 17 17 24.8 24.6 9.3578 54.0 84.8 0.0 32.1866 6.71 292.3 3.477369 84 241 9.9 -99.0000 0 6.626 288.8 0 7.07 0 8.40 0 0.918 0 16 16 50.0 49.5 8.0804 56.8 90.9 0.0 32.3206 6.31 275.0 3.379829 83 241 8.9 -99.0000 0 6.067 264.3 0 12.28 0 11.47 0 1.183 0 15 15 75.4 74.7 7.9345 59.1 95.1 0.0 33.0199 4.59 199.9 3.433845 82 241 8.8 -99.0000 0 4.467 194.5 0 21.82 6 22.22 6 1.709 6 14 14 100.1 99.3 7.6339 59.3 95.8 0.0 33.4620 3.91 170.0 3.449433 81 241 8.5 -99.0000 0 3.815 166.1 0 25.61 0 29.79 0 1.872 0 13 13 124.8 123.7 7.6261 58.7 94.3 0.0 33.7192 3.07 133.5 3.473678 80 241 8.6 -99.0000 0 3.096 134.7 6 29.10 0 36.11 0 2.072 0 12 12 149.9 148.6 7.3834 59.1 95.2 0.0 33.8345 3.07 133.5 3.463642 79 241 8.3 -99.0000 0 3.035 132.1 0 29.62 0 39.20 0 2.107 0 11 11 174.9 173.4 7.3714 58.9 94.9 0.0 33.9038 2.37 103.3 3.470055 78 241 8.2 -99.0000 0 2.324 101.1 0 32.72 0 44.91 0 2.308 0 10 10 200.0 198.2 7.0725 58.7 94.2 0.0 33.9465 1.94 84.5 3.448187 77 241 8.0 -99.0000 0 1.942 84.5 0 34.93 0 50.58 0 2.460 0 9 9 249.7 247.5 6.7787 59.3 95.5 0.0 33.9944 1.75 76.3 3.428358 76 241 7.8 -99.0000 0 1.730 75.3 0 36.00 0 55.14 0 2.557 0 8 8 300.1 297.4 6.3093 58.8 94.5 0.0 34.0219 1.39 60.4 3.391006 75 241 7.4 -99.0000 0 -99.000 -99.0 5 38.79 0 63.15 0 2.778 0 7 7 400.2 396.5 5.7013 59.3 95.5 0.0 34.0636 1.02 44.4 3.344882 74 241 7.1 -99.0000 0 1.014 44.1 0 40.77 0 75.80 0 2.936 0 6 6 600.0 594.1 4.8492 58.8 94.3 0.0 34.1612 0.49 21.3 3.286538 73 241 6.5 -99.0000 0 0.491 21.4 6 43.50 0 97.51 0 3.166 0 5 5 800.3 792.0 4.2312 59.1 94.9 0.0 34.2699 0.25 10.9 3.249961 72 241 6.2 34.2732 0 0.265 11.5 0 45.84 6 115.70 36 3.376 6 4 4 1000.4 989.5 3.7219 59.4 95.8 0.0 34.3693 0.22 9.8 3.222121 71 241 5.8 34.3733 6 0.227 9.9 0 46.14 0 134.11 0 3.356 0 3 3 1249.4 1235.2 3.0921 59.2 95.5 0.0 34.4595 0.42 18.1 3.184955 70 241 5.4 34.4606 0 0.416 18.1 0 46.14 0 153.43 0 3.293 0 2 2 1249.4 1235.2 3.0921 59.3 95.2 0.0 34.4595 0.42 18.1 3.184953 69 241 5.4 34.4606 0 0.429 18.7 0 46.13 0 147.01 0 3.289 0 1 1 1323.2 1307.9 2.8902 58.3 93.8 0.0 34.4849 0.52 22.4 3.172491 68 241 5.2 -99.0000 0 0.512 22.3 6 45.95 0 152.94 0 3.156 0