*2023/03/31 13:34:49.52 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2020/02/11 09:36:17.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 1 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : FE7F2B04 NUMBER OF CHANNELS : 52 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 172 172 2 Bottle_Number n/a 1 1 3 Bottle:Firing_Sequence n/a 1 1 4 Pressure decibar 5.5 5.5 5 Depth metres 5.4 5.4 6 Temperature:Primary 'deg C (ITS90)' 8.6614 8.6614 7 Conductivity:Primary S/m 3.421631 3.421631 8 Transmissivity %/metre 53.6 53.6 9 Transmissivity:Green %/metre 88.8 88.8 10 Fluorescence:URU:Seapoint mg/m^3 0.848 0.848 11 PAR uE/m^2/sec 0 0 12 Salinity:T0:C0 PSS-78 32.2448 32.2448 13 Oxygen:Dissolved:SBE mL/L 6.63 6.63 14 Oxygen:Dissolved:SBE umol/kg 288.8 288.8 15 Number_of_bin_records n/a 241 241 16 Salinity:Bottle PSS-78 32.2461 32.2461 17 Flag:Salinity:Bottle ' ' 18 Chlorophyll:Extracted mg/m^3 0.32 0.32 19 Flag:Chlorophyll:Extracted ' ' 20 Phaeo-Pigment:Extracted mg/m^3 0.13 0.13 21 Nitrate_plus_Nitrite umol/L 6.29 6.29 22 Flag:Nitrate_plus_Nitrite ' ' 23 Silicate umol/L 5.31 5.31 24 Flag:Silicate ' ' 25 Phosphate umol/L 0.842 0.842 26 Flag:Phosphate ' ' 27 HPLC:Chl-c3 mg/m^3 0.4E-01 0.4E-01 28 HPLC:Chlide-a mg/m^3 0 0 29 HPLC:MgDVP mg/m^3 0.3E-02 0.3E-02 30 HPLC:Chl-c2 mg/m^3 0.37E-01 0.37E-01 31 HPLC:Chl-c1 mg/m^3 0 0 32 HPLC:Me-chlide mg/m^3 0 0 33 HPLC:Peri mg/m^3 0.6E-02 0.6E-02 34 HPLC:But-fuco mg/m^3 0.39E-01 0.39E-01 35 HPLC:Fuco mg/m^3 0.28E-01 0.28E-01 36 HPLC:Neo mg/m^3 0.7E-02 0.7E-02 37 HPLC:Pras mg/m^3 0.4E-02 0.4E-02 38 HPLC:Viola mg/m^3 0.2E-02 0.2E-02 39 HPLC:Hex-fuco mg/m^3 0.113 0.113 40 HPLC:Diadino mg/m^3 0.17E-01 0.17E-01 41 HPLC:Allo mg/m^3 0.1E-02 0.1E-02 42 HPLC:Diato mg/m^3 0.3E-02 0.3E-02 43 HPLC:Zea mg/m^3 0.6E-02 0.6E-02 44 HPLC:Lut mg/m^3 0.4E-02 0.4E-02 45 HPLC:Gyr-de mg/m^3 0.3E-02 0.3E-02 46 HPLC:Chl-b mg/m^3 0.44E-01 0.44E-01 47 HPLC:c2-MGDG mg/m^3 0.8E-02 0.8E-02 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 0.295 0.295 50 HPLC:B-Car mg/m^3 0.4E-02 0.4E-02 51 HPLC:TChl-a mg/m^3 0.295 0.295 52 Flag:HPLC n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 10 F ' ' 6 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 7 F ' ' 1 12 -99 ' ' 9 F ' ' 4 13 -99 ' ' 7 F ' ' 2 14 -99 ' ' 6 F ' ' 1 15 -99 ' ' 5 I I 0 16 -99 ' ' 9 F R4 4 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2020-001 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P9 EVENT NUMBER : 31 LATITUDE : 48 51.40000 N ! (deg min) LONGITUDE : 129 9.99000 W ! (deg min) WATER DEPTH : 2373 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4700 Conductivity ' ' 3531 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 4888 Conductivity:2 ' ' 4513 'Oxygen:SBE 43' ' ' 3791 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 62355 $END $REMARKS Software Version Seasave V 7.26.7.121 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.3 2020/06/03 11:26:19 241 241 CLEAN 5.2.4 2020/06/03 11:27:20 241 241 ADDSAMP 3.6 2020/06/03 13:21:45 241 241 BINAVE 4.2.1 2020/06/08 16:41:00 241 1 MERGE 3.5.1 2020/06/08 16:41:20 1 1 CLEAN 5.2.4 2020/06/08 16:41:28 1 1 CALIB 12.0.1 2020/06/15 13:57:22 1 1 SORT 3.6 2020/06/15 16:57:28 1 1 REMOVECH 8.2 2020/06/15 16:58:34 1 1 CHGUNITS 3.1.2 2020/06/15 17:01:30 1 1 CHGUNITS 3.1.2 2020/06/15 17:01:40 1 1 REORDER 1.3.1 2020/06/15 17:01:57 ? ? HDREDIT2 3.2 2020/09/29 10:53:05 ? ? CALIB 12.0.1 2021/01/20 13:43:18 1 1 SORT 3.6 2023/03/23 13:10:32 1 1 MERGE 3.6 2023/03/27 16:39:25 1 1 SORT 3.6 2023/03/27 16:39:47 1 1 CLEAN 5.3 2023/03/27 16:39:56 1 1 HDREDIT2 3.2 2023/03/27 16:40:39 ? ? HDREDIT2 3.2 2023/03/27 16:41:00 ? ? CLEAN 5.3 2023/03/31 13:34:49 1 1 $END $REMARKS -CLEAN functions: 2020/06/03 11:27:16 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\Telework\2020-001\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2020/06/08 16:41:20 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Temperature:Draw, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : D:\Telework\2020-001\Processing\hydro\2020-001-0031.samavg Secondary file: D:\Telework\2020-001\Processing\hydro\2020-001-0031.mrgcln1s Comments from secondary file: D:\Telework\2020-001\Processing\hydro\2020-001-0031.mrgcln1s ------------------------------------------------------------ -SORT parameters: 2020/06/08 14:02:49 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2020/06/08 16:41:28 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -CALIB parameters: 2020/06/15 13:57:22 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2020-001\Processing\doc\2020-001-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Salinity:T0:C0 PSS-78 10 -0.3500000E-02 0.1000000E+01 19 Salinity:T1:C1 PSS-78 10 -0.1120000E-01 0.1000000E+01 20 Oxygen:Dissolved:SBE mL/L 10 -0.2200000E-02 0.1024200E+01 -SORT parameters: 2020/06/15 16:57:28 Sorted in ascending order of channel Press* -REMOVECH 2020/06/15 16:58:34 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2020/09/29 10:53:05 Applied edit header: D:\Telework\2020-001\Processing\doc\HYDRO\2020-001-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 Channel 10: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Number_of_bin_records [n/a] Pad: ' ' ==> -99 Channel 18: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 20: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 21: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 23: Silicate [umol/L] Units: ==> umol/L Channel 25: Phosphate [umol/L] Units: ==> umol/L Channel 16: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 8: Transmissivity:Green [%/metre] Name: Transmissivity2 ==> Transmissivity:Green -CALIB parameters: 2021/01/20 13:43:18 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = 2000-001-transcor.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Transmissivity:Green %/metre 10 -0.2000000E-01 0.1439800E+01 -SORT parameters: 2023/03/23 13:10:32 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2023/03/27 16:39:25 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:Pheide-a, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Gyr-de, HPLC:Chl-b, HPLC:c2-MGDG, HPLC:DVChl-a, HPLC:Phe, HPLC:Chl-a, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC Primary file : C:\HPLC\2020-001\Processing\IOS\2020-001-0031.che1 Secondary file: C:\HPLC\2020-001\Processing\IOS\2020-001-0031.hplc 1 secondary records matched to primary records. -SORT parameters: 2023/03/27 16:39:47 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2023/03/27 16:39:56 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2023/03/27 16:40:39 Applied edit header: C:\HPLC\2020-001\2020-001-hdr1.txt -HEADER EDITS: 2023/03/27 16:41:00 Applied edit header: C:\HPLC\2020-001\2020-001-hdr2.txt Channel 27: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:c2-MGDG [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Gyr-de [mg/m^3] Units: ==> mg/m^3 -CLEAN functions: 2023/03/31 13:34:49 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD data\2020-001-0031.hex Software Version Seasave V 7.26.7.121 Temperature SN = 4700 Conductivity SN = 3531 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Feb 11 2020 01:41:10 NMEA Latitude = 48 51.40 N NMEA Longitude = 129 09.99 W NMEA UTC (Time) = Feb 11 2020 09:36:17 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Tully: 2020-001 Station: P9 Depth: 2373 System UTC = Feb 11 2020 09:41:10 # nquan = 21 # nvalues = 241 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = CStarTr1: Beam Transmission, WET Labs C-Star, 2 [%] # name 11 = flSP: Fluorescence, Seapoint # name 12 = sbeox0V: Oxygen raw, SBE 43 [V] # name 13 = par: PAR/Irradiance, Biospherical/Licor # name 14 = altM: Altimeter [m] # name 15 = dz/dtM: Descent Rate [m/s] # name 16 = pumps: Pump Status # name 17 = sal00: Salinity, Practical [PSU] # name 18 = sal11: Salinity, Practical, 2 [PSU] # name 19 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 20 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Feb 11 2020 09:36:17 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4700 # 11-Dec-19 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.34737905e-003 # 6.38078009e-004 # 2.09621423e-005 # 1.75443016e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 12-Dec-19 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.00964049e+001 # 1.54614863e+000 # -2.86093808e-003 # 3.17937269e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0443 # 09-Jan-20 # -4.435292e+004 # -1.635794e-001 # 1.192740e-002 # 3.979900e-002 # 0.000000e+000 # 2.993627e+001 # -3.271008e-004 # 3.759160e-006 # 1.565300e-009 # 0.99985102 # -2.60896 # 0.000000e+000 # 1.282462e-002 # -8.599824e+000 # # # # # # 4888 # 11-Dec-19 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.32601814e-003 # 6.34316040e-004 # 2.17780633e-005 # 2.00921895e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 4513 # 28-Jan-20 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.00663472e+001 # 1.38017090e+000 # -1.01844528e-003 # 1.34567928e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 3791 # 07-Dec-19 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.6050e-001 # -0.4969 # -3.5626e-003 # 1.3466e-004 # -2.2613e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.2600 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3640 # # # 1 # 0.000 # # # # # # 1185DR # 16Dec2018 # 19.3230 # -1.1207 # 0.250 # # # # # # 1883DG # Nov2018 # 18.9935 # -0.0950 # 0.250 # # # # # # 70613 # 03/21/16 # 1.00000000 # 0.00000000 # 11876484560.57000000 # 1.00000000 # -0.08460000 # # # # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # datcnv_date = Jun 03 2020 09:33:51, 7.23.2 # datcnv_in = D:\Telework\2020-001\Unprocesssed\CTD\2020-001-0031.hex D:\Telewor k\2020-001\Processing\doc\2020-001-ctd.xmlcon # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~1 to 7 weeks after the cruise, during the COVID-19 pandemic restriction. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.02-1.11ug/l in 171 samples. Average %CV for this cruise was 2.24% with 0 out of 52 duplicate pairs having a CV>10% and 0 duplicate pairs having a CV>30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is excellent. For details see worksheet “CV%” in file QF2020-001_CHL*.xlsx. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 months after collection The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2020-001HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2020-001OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 17 - 32 days after collection. For details including a duplicate analysis, see document QF2020-001SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2020-001nuts*.xlsx. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed into a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100 deg C (with a dewar containing boiling water) onto a Chromosil 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. Many samples were run but had bad calibration and data were not logical. Many other samples were planned to be collected but were not due to the instrument problems. The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.1nmol/L. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more detail see files "2020-001 DMS report*.doc" and "QF2020-001_DMS_summary*.xlsx." DMSP-D: Approximately 50-75mL of seawater was allowed to flow directly from the niskin into a filtration funnel containing a 0.7um GF/F filter. The first 3.5mL was collected in a polypropylene tube (15mL) containing 50uL of a 50% sulphuric acid solution. DMPS-T: 3.5mL of seawater was collected directly from the niskin into a polypropylene tube (15mL) containing 50uL of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. There were some detectable concentrations for DMSP-D & DMSP-T at 200m for this cruise. It is uncertain as to the validity of these "hits' because there is not enough historical data to support it, nor is there DMS data for this cruise due to instrument problems. For details on analysis and raw data, see document "QF2020-001_DMSP*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on the processing see the report: 2020-001_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (-0.35E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (-0.112E-01 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.22E-02 1.0242) Transmissivity:Green %/metre 10 -99 () (-0.2E-01 1.4398) $END !-1-- 2- 3- --4--- --5--- ---6---- ----7---- --8-- --9-- ---10-- --11-- ---12--- --13-- --14- -15- ---16--- 17 --18-- 19 --20-- --21-- 22 --23-- 24 ---25-- 26 ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- 52 !Samp Bo Bo Pressu Depth Temperat Conductiv Trans Trans Fluores PAR Salinity Oxygen Oxyge Numb Salinity Fl Chloro Fl Phaeo- Nitrat Fl Silica Fl Phospha Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ tt tt re ure: ity: missi missi cence: :T0:C0 : n: er_o :Bottle ag phyll: ag Pigmen e_ ag te ag te ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Gyr-de Chl-b c2-MGDG DVChl-a Chl-a Car TChl-a ag !Numb ~u ~u Primary Primary vity vity: URU: Dissol Disso ~bin ~o Extrac ~a t: plus_ ~t ~i ~p a chlide fuco fuco : !er mb en Green Seapoin ved: lved: _rec tt ted ct Extrac Nitrit ri ca ha HP ! er ce t SBE SBE ords le ed ted e te te te LC !---- -- -- ------ ------ -------- --------- ----- ----- ------- ------ -------- ------ ----- ---- -------- -- ------ -- ------ ------ -- ------ -- ------- -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 172 1 1 5.5 5.4 8.6614 3.421631 53.6 88.8 0.848 0.0 32.2448 6.63 288.8 241 32.2461 0 0.32 0 0.13 6.29 0 5.31 0 0.842 0 0.040 0.000 0.003 0.037 0.000 0.000 0.006 0.039 0.028 0.007 0.004 0.002 0.113 0.017 0.001 0.003 0.006 0.004 0.003 0.044 0.008 0.000 0.295 0.004 0.295 6