*2021/01/20 13:29:49.40 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2019/08/07 05:09:11.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 12 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 372EA2A0 NUMBER OF CHANNELS : 31 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 12 2 Bottle:Firing_Sequence n/a 1 12 3 Pressure decibar 2.7 117.1 4 Depth metres 2.7 116 5 Temperature:Primary 'deg C (ITS90)' 6.8222 13.2972 6 Conductivity:Primary S/m 3.358499 3.786372 7 Transmissivity %/metre 18.4 37.6 8 Transmissivity:Green %/metre 26.90426 60.88354 9 Fluorescence:URU:Seapoint mg/m^3 0.593 19.558 10 Salinity:T0:C0 PSS-78 31.5476 33.2526 11 Oxygen:Dissolved:SBE mL/L 2.45 7.09 12 Oxygen:Dissolved:SBE umol/kg 106.5 309.1 13 Sample_Number n/a 252 263 14 Number_of_bin_records n/a 42 241 15 Temperature:Draw 'deg C (ITS90)' 8.7 14.8 16 Salinity:Bottle PSS-78 31.5747 33.2426 17 Flag:Salinity:Bottle n/a 18 Chlorophyll:Extracted mg/m^3 2.33 8.92 19 Flag:Chlorophyll:Extracted ' ' 20 Phaeo-Pigment:Extracted mg/m^3 0.55 0.66 21 Oxygen:Dissolved mL/L 2.455 7.079 22 Oxygen:Dissolved umol/kg 106.8 308.8 23 Flag:Oxygen:Dissolved ' ' 24 Nitrate_plus_Nitrite umol/L 0.32 29.16 25 Flag:Nitrate_plus_Nitrite ' ' 26 Silicate umol/L 12.84 60.44 27 Flag:Silicate ' ' 28 Phosphate umol/L 0.438 2.37 29 Flag:Phosphate ' ' 30 Ammonium umol/L 0 0.69 31 Flag:Ammonium ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 10 F ' ' 6 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 5 I I 0 14 ' ' ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 9 F R4 4 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 8 F R4 3 22 -99 ' ' 6 F ' ' 1 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 8 F R4 3 29 0 ' ' 3 NQ C ' ' 30 -99 ' ' 7 F R4 2 31 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2019-069 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Moorings and Chatham Sound SCIENTIST : Spear D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : BC Coast STATION : HECS7 EVENT NUMBER : 92 LATITUDE : 54 13.63000 N ! (deg min) LONGITUDE : 131 1.97000 W ! (deg min) WATER DEPTH : 120 ALTIMETER (M) : 5.37 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 1763 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 5013 Conductivity:2 ' ' 3394 'Oxygen:SBE 43' ' ' 3234 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1883DG 'Transmissometer:WET Labs C-Star:2' ' ' 1185DR Altimeter ' ' 62355 $END $REMARKS Software Version Seasave V 7.26.7.107 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2020/01/13 11:18:28 2110 2110 CLEAN 5.2.3 2020/01/13 11:20:01 2110 2110 ADDSAMP 3.6 2020/01/13 12:13:43 2110 2110 BINAVE 4.2 2020/01/13 14:10:29 2110 12 MERGE 3.5 2020/01/16 10:28:21 12 12 CLEAN 5.2.3 2020/01/16 10:28:29 12 12 CALIB 12.0 2020/01/20 14:36:08 12 12 SORT 3.6 2020/01/21 09:47:39 12 12 REMOVECH 8.2 2020/01/21 09:49:19 12 12 CHGUNITS 3.1.1 2020/01/21 09:50:10 12 12 CHGUNITS 3.1.1 2020/01/21 09:50:46 12 12 REORDER 1.3.1 2020/01/21 09:51:42 ? ? HDREDIT2 3.1.1 2020/01/21 10:06:07 ? ? REORDER 1.3.1 2020/07/09 16:05:22 ? ? HDREDIT2 3.2 2020/07/09 16:15:45 ? ? CALIB 12.0.1 2021/01/20 13:29:49 12 12 $END $REMARKS -CLEAN functions: 2020/01/13 11:19:53 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\OSD_DataProcessing\Cruise_Data\2019-069\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2020/01/16 10:28:21 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Temperature:Draw, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\2019-069\Processing\hydro\2019-069-0092.samavg Secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-069\Processing\hydro\2019-069-0092.mrgcln1s Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-069\Processing\hydro\2019-069-0092.mrgcln1s --------------------------------------------------------------------------- -CLEAN functions: 2020/01/16 10:27:51 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2020/01/16 10:27:59 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2020/01/16 10:28:28 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2020/01/20 14:36:08 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\OSD_DataProcessing\Cruise_Data\2019-069\Processing\doc\2019-069-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T0:C0 PSS-78 10 0.5100000E-02 0.1000000E+01 18 Salinity:T1:C1 PSS-78 10 -0.7000000E-03 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 10 0.9000000E-02 0.1035700E+01 -SORT parameters: 2020/01/21 09:47:39 Sorted in ascending order of channel Press* -REMOVECH 2020/01/21 09:49:19 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2020/01/21 10:06:07 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\2019-069\Processing\doc\HYDRO\2019-069-bot- hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 16: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 17: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 18: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 20: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 21: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 24: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 26: Silicate [umol/L] Units: ==> umol/L Channel 28: Phosphate [umol/L] Units: ==> umol/L Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 -HEADER EDITS: 2020/07/09 16:15:45 Applied edit header: D:\Telework\2019-069\DOC\2019-069-HDR2.TXT -CALIB parameters: 2021/01/20 13:29:49 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = 2019-069-transcor.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Transmissivity:Green %/metre 10 -0.2000000E-01 0.1439800E+01 $END *COMMENTS Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~1 week after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.17-11.73ug/l in 102 samples. Average %CV for this cruise was 6.50 with 7 out of 33 duplicate pairs having a CV>10% and 1 duplicate pair having a CV>30% . Our average dataset %CV is 3.80 % for 2013 - 2018 so the overall quality of this dataset is acceptable. For details see worksheet “CV%” in file QF2019-069-CHL*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2019-069-OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 38 - 45 days after collection. For details including a duplicate analysis, see document QF2019-069-SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All samples were performed on frozen samples. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2019-069-NUTS*.xlsx. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. Standards are made in LNSW collected at 250m at station A1-58. For full details including a precision study see file QF2019-069-NH4*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity and Fluorescence:URU:Seapoint data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on the processing see the report: 2019-069_Processing_Report.doc. --------------------------------------------------------------------------------- There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissivity refers to sensor #1185DR (650nm - red) Channel Transmissivity:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. -------------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.51E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (-0.7E-03 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.9E-02 1.0357) Transmissivity:Green %/metre 10 -99 () (-0.2E-01 1.4398) $END !1- 2- --3--- --4--- ---5---- ----6---- --7-- --8-- ---9--- ---10--- --11-- --12- -13- -14- --15- ---16--- 17 --18-- 19 --20-- ---21-- --22- 23 --24-- 25 --26-- 27 ---28-- 29 --30-- 31 !Bo Bo Pressu Depth Temperat Conductiv Trans Trans Fluores Salinity Oxygen Oxyge Samp Numb Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Ammoni Fl !tt tt re ure: ity: missi missi cence: :T0:C0 : n: le_ er_o ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag um ag !~u ~u Primary Primary vity vity: URU: Dissol Disso Numb ~bin e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p ~o !mb en Green Seapoin ved: lved: er _rec Draw tt ted ct Extrac lved lv Nitrit ri ca ha ni !er ce t SBE SBE ords le ed ted ed e te te te um !-- -- ------ ------ -------- --------- ----- ----- ------- -------- ------ ----- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- ------ -- *END OF HEADER 10 10 2.7 2.7 13.2943 3.761306 21.8 35.1 19.170 31.5810 7.02 306.3 261 47 14.8 -99.0000 0 8.92 0 0.62 7.063 308.1 0 0.36 0 12.96 0 0.438 0 0.09 6 12 12 2.7 2.7 13.2972 3.762674 22.5 35.8 18.713 31.5914 7.03 306.4 263 241 -99.0 -99.0000 0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 11 11 2.7 2.7 13.2940 3.761163 22.0 35.4 18.658 31.5800 7.04 307.0 262 42 -99.0 31.5747 0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 9 9 5.0 4.9 13.2801 3.756556 21.5 34.7 19.558 31.5476 7.09 309.1 260 241 14.7 -99.0000 0 -99.00 0 -99.00 7.079 308.8 0 0.32 0 13.03 0 0.450 0 0.03 6 8 8 10.2 10.2 13.2942 3.786372 25.2 40.6 13.577 31.8125 6.61 288.3 259 241 14.7 -99.0000 0 7.46 6 0.66 6.847 298.6 0 0.84 6 12.84 6 0.459 6 0.00 6 7 7 20.1 20.0 11.9701 3.700643 34.7 55.8 5.507 32.1174 5.46 238.1 258 241 13.4 -99.0000 0 2.33 0 0.55 5.489 239.3 0 6.97 0 18.75 0 0.832 0 0.01 6 6 6 30.3 30.1 11.3976 3.659096 36.5 59.2 4.159 32.2054 5.15 224.5 257 241 12.7 -99.0000 0 -99.00 0 -99.00 5.172 225.4 6 9.35 0 22.02 0 1.014 0 0.45 6 4 4 49.7 49.3 11.0326 3.632330 37.6 60.9 3.704 32.2534 4.98 217.1 255 46 12.3 -99.0000 0 -99.00 0 -99.00 4.975 216.8 0 10.88 0 24.31 0 1.123 0 0.69 6 5 5 49.8 49.3 11.0361 3.632591 37.6 60.9 3.332 32.2529 4.99 217.2 256 241 -99.0 32.2592 0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 3 3 75.9 75.2 7.6633 3.405921 31.6 50.2 0.632 32.9822 3.01 130.9 254 241 9.3 -99.0000 0 -99.00 0 -99.00 3.110 135.4 0 24.89 6 49.49 6 2.102 6 0.01 6 2 2 117.0 116.0 6.8306 3.358850 18.7 27.9 0.746 33.2484 2.45 106.5 253 241 8.7 -99.0000 0 -99.00 0 -99.00 2.455 106.8 6 29.16 0 60.44 0 2.370 0 0.12 6 1 1 117.1 116.0 6.8222 3.358499 18.4 26.9 0.593 33.2526 2.45 106.5 252 47 -99.0 33.2426 0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0