*2025/02/26 09:18:04.55 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2019/10/05 15:53:34.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 14 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 758609E5 NUMBER OF CHANNELS : 58 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 362 375 2 Bottle_Number n/a 1 14 3 Bottle:Firing_Sequence n/a 1 14 4 Pressure decibar 2.1 214.8 5 Depth metres 2.1 212.8 6 Temperature:Primary 'deg C (ITS90)' 8.1166 13.4478 7 Transmissivity %/metre 17.2 49.4 8 Fluorescence:URU:Seapoint mg/m^3 0.321 7.839 9 PAR uE/m^2/sec 0 111.9 10 Salinity:T0:C0 PSS-78 19.4675 27.6206 11 Oxygen:Dissolved:SBE mL/L 3.05 7.23 12 Oxygen:Dissolved:SBE umol/kg 133.5 318.3 13 Conductivity:Primary S/m 2.403081 3.232666 14 Number_of_bin_records n/a 241 241 15 Temperature:Draw 'deg C (ITS90)' 8.6 13.5 16 Salinity:Bottle PSS-78 27.6225 27.6225 17 Oxygen:Dissolved mL/L 3.071 4.609 18 Oxygen:Dissolved umol/kg 134.3 202 19 Flag:Oxygen:Dissolved ' ' 20 Nitrate_plus_Nitrite umol/L 1.15 32.74 21 Flag:Nitrate_plus_Nitrite ' ' 22 Silicate umol/L 34.14 70.41 23 Flag:Silicate ' ' 24 Phosphate umol/L 0.394 3.992 25 Flag:Phosphate ' ' 26 Chlorophyll:Extracted mg/m^3 0.21 13.14 27 Flag:Chlorophyll:Extracted ' ' 28 Phaeo-Pigment:Extracted mg/m^3 -1.08 0.48 29 Transmissivity:Green %/metre 16 70.7 30 PAR:Reference uE/m^2/sec 190.7 206.6 31 pH:SBE:Nominal n/a 8.203 8.994 32 Flag:Salinity:Bottle ' ' 33 HPLC:Chl-c3 mg/m^3 0.29E-01 0.29E-01 34 HPLC:Chlide-a mg/m^3 0.309 0.309 35 HPLC:MgDVP mg/m^3 0.93E-01 0.93E-01 36 HPLC:Chl-c2 mg/m^3 1.006 1.006 37 HPLC:Chl-c1 mg/m^3 0.37 0.37 38 HPLC:Me-chlide mg/m^3 0.646 0.646 39 HPLC:Peri mg/m^3 0.68E-01 0.68E-01 40 HPLC:But-fuco mg/m^3 0.31E-01 0.31E-01 41 HPLC:Fuco mg/m^3 4.334 4.334 42 HPLC:Neo mg/m^3 0.118 0.118 43 HPLC:Pras mg/m^3 0.5E-01 0.5E-01 44 HPLC:Viola mg/m^3 0.5E-01 0.5E-01 45 HPLC:Hex-fuco mg/m^3 0.25E-01 0.25E-01 46 HPLC:Diadino mg/m^3 0.553 0.553 47 HPLC:Allo mg/m^3 0.93E-01 0.93E-01 48 HPLC:Diato mg/m^3 0.31E-01 0.31E-01 49 HPLC:Zea mg/m^3 0.6E-01 0.6E-01 50 HPLC:Lut mg/m^3 0.21E-01 0.21E-01 51 HPLC:Gyr-de mg/m^3 0 0 52 HPLC:Chl-b mg/m^3 0.335 0.335 53 HPLC:c2-MGDG mg/m^3 0 0 54 HPLC:DVChl-a mg/m^3 0 0 55 HPLC:Chl-a mg/m^3 9.446 9.446 56 HPLC:B-Car mg/m^3 0.125 0.125 57 HPLC:TChl-a mg/m^3 10.402 10.402 58 Flag:HPLC n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 6 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 9 F R4 4 17 -99 ' ' 8 F R4 3 18 -99 ' ' 6 F ' ' 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 3 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 6 F ' ' 1 30 -99 ' ' 7 F ' ' 1 31 -99 ' ' 8 F ' ' 3 32 -99 ' ' 3 NQ C ' ' 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 8 F R4 3 57 -99 ' ' 8 F R4 3 58 -99 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2019-062 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Salish Sea/ Burrard Inlet SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : 'Juan de Fuca Strait/ Strait of Georgia/ Burrard' CONTINUED : ' Inlet' STATION : ind4 EVENT NUMBER : 108 LATITUDE : 49 23.27000 N ! (deg min) LONGITUDE : 122 52.48000 W ! (deg min) WATER DEPTH : 220 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 506 $REMARKS Software Version Seasave V 7.26.2.13 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2020/02/11 08:49:43 3374 3374 CLEAN 5.2.3 2020/02/11 09:26:40 3374 3374 ADDSAMP 3.6 2020/02/11 10:01:07 3374 3374 BINAVE 4.2 2020/02/11 10:03:21 3374 14 MERGE 3.5.1 2020/03/26 11:26:20 14 14 CALIB 12.0.1 2020/04/01 17:06:58 14 14 SORT 3.6 2020/04/03 09:57:08 14 14 REMOVECH 8.2 2020/04/03 09:57:39 14 14 CHGUNITS 3.1.2 2020/04/03 09:58:44 14 14 CHGUNITS 3.1.2 2020/04/03 09:58:51 14 14 REORDER 1.3.1 2020/04/03 10:00:15 ? ? REMOVECH 8.2 2020/04/03 15:27:52 14 14 HDREDIT2 3.2 2020/04/03 15:28:31 ? ? CALIB 12.0.1 2021/01/20 13:18:27 14 14 Silicate_Correction 1.1 2021/12/08 10:52:05 14 14 CLEAN 5.3 2022/05/25 12:22:53 14 14 SORT 3.6 2023/03/12 20:41:44 14 14 REORDER 1.3.1 2023/03/12 20:42:17 ? ? MERGE 3.6 2023/03/12 20:43:00 14 14 SORT 3.6 2023/03/12 20:43:42 14 14 CLEAN 5.3 2023/03/12 20:44:08 14 14 HDREDIT2 3.2 2023/03/19 16:13:30 ? ? REMOVECH 8.2 2023/03/19 16:13:43 14 14 HDREDIT2 3.2 2023/03/19 16:14:08 ? ? CLEAN 5.3 2023/03/28 10:49:33 14 14 REMOVECH 8.2 2025/02/26 09:16:08 14 14 REORDER 1.3.1 2025/02/26 09:18:04 ? ? $END $REMARKS -CLEAN functions: 2020/02/11 09:26:15 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\OSD_DataProcessing\Cruise_Data\2019-062\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2020/03/26 11:26:20 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Temperature:Draw, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Gyr-de, HPLC:Chl-b, HPLC:c2-MGDG, HPLC:DVChl-a, HPLC:Chl-a, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC Primary file : D:\Telework\2019-062\processing\hydro\2019-062-0108.samavg Secondary file: D:\Telework\2019-062\processing\hydro\2019-062-0108.mrgcln1s Comments from secondary file: D:\Telework\2019-062\processing\hydro\2019-062-0108.mrgcln1s ------------------------------------------------------------ -CLEAN functions: 2020/03/26 11:17:57 20 Reduce header to sections: FIL HIS COM Remarks removed from kept sections. Remove remark heading: "Comments from secondary" -SORT parameters: 2020/03/26 11:18:09 Sorted in ascending order of channel Bottle_Number -CALIB parameters: 2020/04/01 17:06:58 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2019-062\Processing\doc\2019-062-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Salinity:T0:C0 PSS-78 10 0.8600000E-02 0.1000000E+01 22 Oxygen:Dissolved:SBE mL/L 10 0.1670000E-01 0.1038400E+01 -SORT parameters: 2020/04/03 09:57:08 Sorted in ascending order of channel Press* -REMOVECH 2020/04/03 09:57:39 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -REMOVECH 2020/04/03 15:27:52 The following CHANNEL(S) were removed: HPLC:Chl-c3 [mg/m^3] HPLC:Chlide-a [mg/m^3] HPLC:MgDVP [mg/m^3] HPLC:Chl-c2 [mg/m^3] HPLC:Chl-c1 [mg/m^3] HPLC:Me-chlide [mg/m^3] HPLC:Peri [mg/m^3] HPLC:But-fuco [mg/m^3] HPLC:Fuco [mg/m^3] HPLC:Neo [mg/m^3] HPLC:Pras [mg/m^3] HPLC:Viola [mg/m^3] HPLC:Hex-fuco [mg/m^3] HPLC:Diadino [mg/m^3] HPLC:Allo [mg/m^3] HPLC:Diato [mg/m^3] HPLC:Zea [mg/m^3] HPLC:Lut [mg/m^3] HPLC:Gyr-de [mg/m^3] HPLC:Chl-b [mg/m^3] HPLC:c2-MGDG [mg/m^3] HPLC:DVChl-a [mg/m^3] HPLC:Chl-a [mg/m^3] HPLC:B-Car [mg/m^3] HPLC:TChl-a [mg/m^3] Flag:HPLC -HEADER EDITS: 2020/04/03 15:28:31 Applied edit header: D:\Telework\2019-062\Processing\doc\HYDRO\2019-062-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 Channel 8: Transmissivity:Green [%/metre] Name: Transmissivity2 ==> Transmissivity:Green Channel 10: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 14: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 18: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 21: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 23: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 24: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 27: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 29: Silicate [umol/L] Units: ==> umol/L Channel 31: Phosphate [umol/L] Units: ==> umol/L Channel 19: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 12: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Channel 11: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 -CALIB parameters: 2021/01/20 13:18:27 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = 2019-062-transcor.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Transmissivity:Green %/metre 10 -0.2000000E-01 0.1439800E+01 -CLEAN functions: 2022/05/25 12:22:11 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* Insert Pad Values in Channel: Temperature:Primary [deg C (ITS90)] where channel Temperature:Primary [deg C (ITS90)] is in the range -10000 to - 0 data records in pad range. -SORT parameters: 2023/03/12 20:41:44 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2023/03/12 20:43:00 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:Pheide-a, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Gyr-de, HPLC:Chl-b, HPLC:c2-MGDG, HPLC:DVChl-a, HPLC:Phe, HPLC:Chl-a, HPLC:B-Car, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC Primary file : C:\Users\jared\OneDrive\Documents\DFO\HPLC\2019-062\Processing\IOS\2019-062-0108. che2 Secondary file: C:\Users\jared\OneDrive\Documents\DFO\HPLC\2019-062\Processing\IOS\2019-062-0108. hplc 1 secondary records matched to primary records. -SORT parameters: 2023/03/12 20:43:42 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2023/03/12 20:44:07 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2023/03/19 16:13:30 - none. -REMOVECH 2023/03/19 16:13:43 The following CHANNEL(S) were removed: HPLC:B-Car -HEADER EDITS: 2023/03/19 16:14:08 Channel 35: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 57: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 58: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 59: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:c2-MGDG [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:Gyr-de [mg/m^3] Units: ==> mg/m^3 -CLEAN functions: 2023/03/28 10:49:31 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -REMOVECH 2025/02/26 09:16:08 The following CHANNEL(S) were removed: Silicate [umol/L] Flag:Silicate $END *COMMENTS ===================================================================================== NOTE: New Silicate:Correction channel, 2021/12/ 8 ----------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: ind4, Sample Number: 375, Silicate corrected using CTD salinity. February 2025: The uncorrected channels were removed and Silicate:Corrected was renamed Silicate and Flag:Silicate:Corrected was renamed Flag:Silicate. ===================================================================================== SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2019-62\2019-062-0108.hex Software Version Seasave V 7.26.2.13 Temperature SN = 2023 Conductivity SN = 1763 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Oct 05 2019 15:55:33 NMEA Latitude = 49 23.27 N NMEA Longitude = 122 52.48 W NMEA UTC (Time) = Oct 05 2019 15:53:34 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 0 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> VECTOR: 2019-062 Station: ind4 Depth: 220 System UTC = Oct 05 2019 15:55:33 # nquan = 23 # nvalues = 3374 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = CStarTr1: Beam Transmission, WET Labs C-Star, 2 [%] # name 11 = flSP: Fluorescence, Seapoint # name 12 = sbeox0V: Oxygen raw, SBE 43 [V] # name 13 = ph: pH # name 14 = par: PAR/Irradiance, Biospherical/Licor # name 15 = spar: SPAR, Biospherical/Licor # name 16 = altM: Altimeter [m] # name 17 = dz/dtM: Descent Rate [m/s] # name 18 = pumps: Pump Status # name 19 = sal00: Salinity, Practical [PSU] # name 20 = sal11: Salinity, Practical, 2 [PSU] # name 21 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 22 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Oct 05 2019 15:53:34 [NMEA time, header] # bad_flag = -9.990e-29 # datcnv_date = Jan 31 2020 13:46:58, 7.26.7.129 # datcnv_in = Q:\OSD_DataProcessing\Cruise_Data\2019-062\Unprocessed\CTD\2019-06 2-0108.hex Q:\OSD_DataProcessing\Cruise_Data\2019-062\Processing\doc\2019-062-ctd.XMLCON # datcnv_ox_hysteresis_correction = no # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: D:\Telework\2019-062\processing\hydro\2019-062-0108.mrgcln1s ------------------------------------------------------------ Sample_Number 375: OXY: Flask did not have a calibrated volume. Sample lost. Sample_Number 375: HPLC:problem with replicate collection, discarded Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~7 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.21-18.71ug/l in 192 samples. Average %CV for this cruise was 3.80% with 2 out of 36 duplicate pairs having a CV>10% and 0 duplicate pairs having a CV>30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is good. For details see worksheet CV% in file QF2019-062CHL*.xlsx. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 weeks after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF2019-062_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2019-062OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 29-35 days after collection. There was no duplicate sampling. For details see document QF2019-062SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2019-062nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Pe a, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint; pH:SBE, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was recalibrated using the results of cruise 2019-023 and Salinity:T0:C0 was recalibrated based on a post-cruise calibration. For details on the processing see the report: 2019-062_Processing_Report.doc. --------------------------------------------------------------------------------- HPLC data will be available in March 2022. Comments from secondary file: C:\Users\jared\OneDrive\Documents\DFO\HPLC\2019-062\Processing\IOS\2019-062-0108.hplc --------------------------------------------------------------------------- Sample_Number 375: HPLC:problem with replicate collection, discarded *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.86E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.167E-01 1.0384) Transmissivity:Green %/metre 10 -99 () (-0.2E-01 1.4398) $END !-1-- 2- 3- --4--- --5--- ---6---- --7-- ---8--- --9--- ---10--- --11-- --12- ----13--- -14- --15- ---16--- ---17-- --18- 19 --20-- 21 --22-- 23 ---24-- 25 --26-- 27 --28-- --29- --30-- ---31-- 32 ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- ---56-- ---57-- 58 !Samp Bo Bo Pressu Depth Temperat Trans Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Tempe Salinity Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Chloro Fl Phaeo- Trans PAR: pH:SBE: Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ tt tt re ure: missi cence: :T0:C0 : n: ity: er_o ratur :Bottle Dissolv n: ag e_ ag te ag te ag phyll: ag Pigmen missi Refere Nominal ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Gyr-de Chl-b c2-MGDG DVChl-a Chl-a Car TChl-a ag !Numb ~u ~u Primary vity URU: Dissol Disso Primary ~bin e: ed Disso ~o plus_ ~t ~i ~p Extrac ~a t: vity: nce ~o a chlide fuco fuco : !er mb en Seapoin ved: lved: _rec Draw lved lv Nitrit ri ca ha ted ct Extrac Green tt HP ! er ce t SBE SBE ords ed e te te te ed ted le LC !---- -- -- ------ ------ -------- ----- ------- ------ -------- ------ ----- --------- ---- ----- -------- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ ----- ------ ------- -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 375 14 14 2.1 2.1 12.9064 17.2 7.839 111.9 19.4675 7.23 318.3 2.403081 241 13.4 -99.0000 -99.000 -99.0 5 1.15 6 34.14 6 0.394 6 13.14 0 -1.08 16.0 200.7 8.994 0 0.029 0.309 0.093 1.006 0.370 0.646 0.068 0.031 4.334 0.118 0.050 0.050 0.025 0.553 0.093 0.031 0.060 0.021 0.000 0.335 0.000 0.000 9.446 0.125 10.402 2 374 13 13 5.0 5.0 13.4478 39.3 2.381 26.5 25.1296 4.33 189.5 3.070983 241 13.5 -99.0000 4.609 202.0 0 15.89 0 40.45 0 1.552 0 3.29 0 0.48 48.6 204.6 8.537 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 373 12 12 10.1 10.0 13.1629 45.5 0.769 6.0 26.3985 3.59 157.1 3.189667 241 13.4 -99.0000 3.553 155.6 0 21.06 0 42.91 0 2.074 0 0.52 6 0.42 62.0 206.6 8.464 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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-99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 369 8 8 50.1 49.6 12.7837 48.8 0.336 0.0 26.8901 3.43 150.2 3.215673 241 12.7 -99.0000 3.372 147.6 0 22.87 0 45.47 0 2.340 0 -99.00 0 -99.00 69.4 202.6 8.418 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 368 7 7 75.1 74.4 9.0085 43.8 0.330 0.0 27.3388 3.05 133.5 2.975165 241 9.3 -99.0000 3.071 134.3 0 31.04 0 55.79 0 3.161 0 -99.00 0 -99.00 59.9 203.1 8.223 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 367 6 6 100.0 99.2 8.4128 45.6 0.321 0.0 27.4924 3.22 140.9 2.946102 241 8.9 -99.0000 3.213 140.5 0 31.76 0 58.34 0 3.248 0 -99.00 0 -99.00 64.1 197.0 8.223 0 -99.000 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