*2025/02/26 09:06:36.92 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2019/06/05 13:36:42.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 47D29C9 NUMBER OF CHANNELS : 57 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 158 174 2 Bottle_Number n/a 1 17 3 Bottle:Firing_Sequence n/a 1 17 4 Pressure decibar 1.7 371.2 5 Depth metres 1.7 367.7 6 Temperature:Secondary 'deg C (ITS90)' 8.7513 16.1468 7 Conductivity:Secondary S/m 2.133715 3.516314 8 Transmissivity %/metre 10.8 53.6 9 Fluorescence:URU:Seapoint mg/m^3 0.134 1.741 10 PAR uE/m^2/sec 0 159.9 11 PAR:Reference uE/m^2/sec 317.9 478.2 12 pH:SBE:Nominal n/a 7.913 8.529 13 Salinity:T1:C1 PSS-78 15.7254 31.1509 14 Oxygen:Dissolved:SBE mL/L 3.29 6.86 15 Oxygen:Dissolved:SBE umol/kg 143.3 302.8 16 Number_of_bin_records n/a 241 241 17 Temperature:Draw 'deg C (ITS90)' 9.2 16.8 18 Salinity:Bottle PSS-78 31.1479 31.1479 19 Flag:Salinity:Bottle n/a 20 Chlorophyll:Extracted mg/m^3 1.04 3.1 21 Flag:Chlorophyll:Extracted ' ' 22 Phaeo-Pigment:Extracted mg/m^3 0.38 0.61 23 Oxygen:Dissolved mL/L 3.303 6.833 24 Oxygen:Dissolved umol/kg 144 301.8 25 Flag:Oxygen:Dissolved ' ' 26 Nitrate_plus_Nitrite umol/L 2.05 26.23 27 Flag:Nitrate_plus_Nitrite ' ' 28 Silicate umol/L 22.32 56.43 29 Flag:Silicate ' ' 30 Phosphate umol/L 0.346 2.5 31 Flag:Phosphate ' ' 32 HPLC:Chl-c3 mg/m^3 0.28E-01 0.28E-01 33 HPLC:Chlide-a mg/m^3 0 0 34 HPLC:MgDVP mg/m^3 0.26E-01 0.26E-01 35 HPLC:Chl-c2 mg/m^3 0.265 0.265 36 HPLC:Chl-c1 mg/m^3 0.7E-01 0.7E-01 37 HPLC:Me-chlide mg/m^3 0.1E-01 0.1E-01 38 HPLC:Peri mg/m^3 0.103 0.103 39 HPLC:But-fuco mg/m^3 0.4E-02 0.4E-02 40 HPLC:Fuco mg/m^3 0.706 0.706 41 HPLC:Neo mg/m^3 0.55E-01 0.55E-01 42 HPLC:Pras mg/m^3 0.35E-01 0.35E-01 43 HPLC:Viola mg/m^3 0.93E-01 0.93E-01 44 HPLC:Hex-fuco mg/m^3 0.3E-01 0.3E-01 45 HPLC:Diadino mg/m^3 0.69E-01 0.69E-01 46 HPLC:Allo mg/m^3 0.265 0.265 47 HPLC:Diato mg/m^3 0.7E-02 0.7E-02 48 HPLC:Zea mg/m^3 0.39E-01 0.39E-01 49 HPLC:Lut mg/m^3 0.38E-01 0.38E-01 50 HPLC:Gyr-de mg/m^3 0 0 51 HPLC:Chl-b mg/m^3 0.274 0.274 52 HPLC:c2-MGDG mg/m^3 0.1E-01 0.1E-01 53 HPLC:DVChl-a mg/m^3 0 0 54 HPLC:Chl-a mg/m^3 3.028 3.028 55 HPLC:B-Car mg/m^3 0.72E-01 0.72E-01 56 HPLC:TChl-a mg/m^3 3.038 3.038 57 Flag:HPLC n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 10 F ' ' 6 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 7 F ' ' 1 11 -99 ' ' 7 F ' ' 1 12 -99 ' ' 8 F ' ' 3 13 -99 ' ' 9 F ' ' 4 14 -99 ' ' 7 F ' ' 2 15 -99 ' ' 6 F ' ' 1 16 -99 ' ' 5 I I 0 17 -99 ' ' 6 F R4 1 18 -99 ' ' 9 F R4 4 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 8 F R4 3 24 -99 ' ' 6 F ' ' 1 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 3 NQ C ' ' 30 -99 ' ' 8 F R4 3 31 -99 ' ' 3 NQ C ' ' 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 8 F R4 3 57 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2019-050 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : JdF/SoG Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Juan de Fuca Strait / Strait of Georgia STATION : 39 EVENT NUMBER : 53 LATITUDE : 49 9.88000 N ! (deg min) LONGITUDE : 123 32.97000 W ! (deg min) WATER DEPTH : 374 ALTIMETER (M) : 5.08 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4888 Conductivity ' ' 3531 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 4700 Conductivity:2 ' ' 4513 'Oxygen:SBE 43' ' ' 3791 Fluorometer:Seapoint ' ' 3642 'Transmissometer:WET Labs C-Star' ' ' 953DR Altimeter ' ' 43281 pH ' ' 0691 PAR/Irradiance:Biospherical/Licor ' ' '4565 QSP200L4S' Unavailable ' ' ' ' SPAR:Biospherical/Licor ' ' 20518 $END $REMARKS Software Version Seasave V 7.26.2.13 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2019/12/04 11:18:08 4097 4097 CLEAN 5.2.3 2019/12/04 11:18:41 4097 4097 ADDSAMP 3.6 2019/12/04 11:41:52 4097 4097 BINAVE 4.2 2019/12/04 11:42:21 4097 17 MERGE 3.5 2019/12/06 16:17:29 17 17 CLEAN 5.2.3 2019/12/06 16:17:37 17 17 CALIB 12.0 2019/12/16 10:21:22 17 17 SORT 3.6 2019/12/16 13:52:52 17 17 REMOVECH 8.2 2019/12/16 13:53:21 17 17 CHGUNITS 3.1.1 2019/12/16 13:53:57 17 17 CHGUNITS 3.1.1 2019/12/16 13:54:31 17 17 REORDER 1.3.1 2019/12/16 13:55:13 ? ? HDREDIT2 3.1.1 2019/12/16 13:56:38 ? ? Silicate_Correction 1.1 2021/12/08 10:52:04 17 17 SORT 3.6 2023/03/23 12:52:46 17 17 MERGE 3.6 2023/03/26 16:19:17 17 17 SORT 3.6 2023/03/26 16:20:05 17 17 CLEAN 5.3 2023/03/26 16:20:30 17 17 HDREDIT2 3.2 2023/03/26 16:21:38 ? ? HDREDIT2 3.2 2023/03/26 16:22:00 ? ? CLEAN 5.3 2023/03/28 10:46:18 17 17 REMOVECH 8.2 2025/02/26 09:02:07 17 17 REORDER 1.3.1 2025/02/26 09:06:36 ? ? $END $REMARKS -CLEAN functions: 2019/12/04 11:18:33 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\OSD_DataProcessing\Cruise_Data\2019-050\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2019/12/06 16:17:29 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Temperature:Draw, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\2019-050\Processing\hydro\2019-050-0053.samavg Secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-050\Processing\hydro\2019-050-0053.mrgcln1s Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-050\Processing\hydro\2019-050-0053.mrgcln1s --------------------------------------------------------------------------- -SORT parameters: 2019/12/04 12:09:50 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2019/12/06 16:17:36 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2019/12/16 10:21:22 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\OSD_DataProcessing\Cruise_Data\2019-050\Processing\doc\2019-050-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Salinity:T1:C1 PSS-78 10 0.1200000E-02 0.1000000E+01 21 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1035200E+01 -SORT parameters: 2019/12/16 13:52:52 Sorted in ascending order of channel Press* -REMOVECH 2019/12/16 13:53:21 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary [deg C (ITS90)] Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2019/12/16 13:56:38 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\2019-050\Processing\doc\HYDRO\2019-050-bot- hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 9: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 13: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 17: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 18: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 19: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 20: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 22: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 23: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 26: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 28: Silicate [umol/L] Units: ==> umol/L Channel 30: Phosphate [umol/L] Units: ==> umol/L Channel 10: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Channel 12: Salinity:T1:C1 [PSS-78] Format: F11.4 ==> F9.4 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 10: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 6: Conductivity:Secondary [S/m] Format: F11.6 ==> F10.6 -SORT parameters: 2023/03/23 12:52:46 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2023/03/26 16:19:17 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:Pheide-a, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Gyr-de, HPLC:Chl-b, HPLC:c2-MGDG, HPLC:DVChl-a, HPLC:Phe, HPLC:Chl-a, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC Primary file : C:\HPLC\2019-050\Processing\IOS\2019-050-0053.che1 Secondary file: C:\HPLC\2019-050\Processing\IOS\2019-050-0053.hplc 1 secondary records matched to primary records. -SORT parameters: 2023/03/26 16:20:05 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2023/03/26 16:20:30 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2023/03/26 16:21:38 Applied edit header: C:\HPLC\2019-050\2019-050-bot-hdr1.txt -HEADER EDITS: 2023/03/26 16:22:00 Applied edit header: C:\HPLC\2019-050\2019-050-bot-hdr2.txt Channel 34: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 57: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 58: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:c2-MGDG [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Gyr-de [mg/m^3] Units: ==> mg/m^3 -CLEAN functions: 2023/03/28 10:46:17 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -REMOVECH 2025/02/26 09:02:07 The following CHANNEL(S) were removed: Silicate [umol/L] Flag:Silicate $END *COMMENTS ===================================================================================== NOTE: New Silicate:Correction channel, 2021/12/ 8 ----------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: 39, Sample Number: 174, Silicate corrected using CTD salinity. At Station: 39, Sample Number: 173, Silicate corrected using CTD salinity. February 2025: The uncorrected channels were removed and Silicate:Corrected was renamed Silicate and Flag:Silicate:Corrected was renamed Flag:Silicate. ===================================================================================== Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-050\Processing\hydro\2019-050-0053.mrgcln1s --------------------------------------------------------------------------- Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-050\Processing\hydro\2019-050-0053.oxy --------------------------------------------------------------------------- Sample_Number 169: ALL: Niskin bottle did not close due to a sticky latch. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~3 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.29 - 6.18 ug/l in 116 samples. Average %CV for this cruise was 2.35 with 1 out of 29 duplicate pairs having a CV>10% and 0 duplicate pairs having a CV>30% . Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is excellent. For details see worksheet CV% in file QF2019-060CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 weeks after collection The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2019-050HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2019-060OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 48-53 days after collection. There were no duplicates. For details see document QF2019-060SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2019-060NUTS*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Pe a, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint, pH:SBE, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data are available. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see document: 2019-060_Processing_Report.doc. -------------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (0.12E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0352) $END !-1-- 2- 3- --4--- --5--- ---6---- ----7---- --8-- ---9--- --10-- --11-- ---12-- ---13--- --14-- --15- -16- --17- ---18--- 19 --20-- 21 --22-- ---23-- --24- 25 --26-- 27 --28-- 29 ---30-- 31 ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- ---56-- 57 !Samp Bo Bo Pressu Depth Temperat Conductiv Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ tt tt re ure: ity: missi cence: Refere Nominal :T1:C1 : n: er_o ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Gyr-de Chl-b c2-MGDG DVChl-a Chl-a Car TChl-a ag !Numb ~u ~u Secondar Secondary vity URU: nce Dissol Disso ~bin e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p a chlide fuco fuco : !er mb en y Seapoin ved: lved: _rec Draw tt ted ct Extrac lved lv Nitrit ri ca ha HP ! er ce t SBE SBE ords le ed ted ed e te te te LC !---- -- -- ------ ------ -------- --------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 174 17 17 1.7 1.7 16.1468 2.133715 10.8 1.741 159.9 340.2 8.529 15.7254 6.86 302.8 241 16.8 -99.0000 0 3.10 6 0.42 6.833 301.8 0 3.01 0 48.67 0 0.346 0 0.028 0.000 0.026 0.265 0.070 0.010 0.103 0.004 0.706 0.055 0.035 0.093 0.030 0.069 0.265 0.007 0.039 0.038 0.000 0.274 0.010 0.000 3.028 0.072 3.038 6 173 16 16 5.1 5.0 15.6239 3.077371 30.4 1.160 27.6 335.7 8.513 23.8115 6.74 296.0 241 15.9 -99.0000 0 1.18 0 0.38 6.710 294.5 0 2.05 0 32.47 0 0.502 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 172 15 15 10.0 9.9 13.9542 3.516314 42.0 1.488 4.4 331.9 8.451 28.7978 6.72 293.9 241 13.4 -99.0000 0 1.29 0 0.61 6.415 280.4 0 5.36 0 22.32 0 0.962 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 171 14 14 20.0 19.9 11.3368 3.363750 46.8 1.048 0.4 326.0 8.251 29.3819 5.74 250.5 241 11.4 -99.0000 0 1.04 0 0.55 5.633 246.0 0 12.56 0 28.26 0 1.525 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 170 13 13 30.1 29.8 10.3059 3.316063 49.1 0.682 0.1 319.9 8.129 29.7417 5.15 224.7 241 10.5 -99.0000 0 -99.00 0 -99.00 5.127 223.8 0 17.23 0 33.88 0 1.895 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 169 12 12 40.1 39.8 9.0443 3.234433 52.2 0.185 0.0 317.9 7.959 29.9602 4.27 186.5 241 -99.0 -99.0000 0 -99.00 0 -99.00 -99.000 -99.0 9 -99.00 9 -99.00 9 -99.000 9 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 168 11 11 50.1 49.7 9.1500 3.259588 50.4 0.157 0.0 323.8 7.995 30.1246 4.38 191.2 241 9.4 -99.0000 0 -99.00 0 -99.00 4.362 190.3 0 25.61 0 43.25 0 2.197 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 167 10 10 75.1 74.4 9.0738 3.267320 50.4 0.143 0.0 330.4 8.005 30.2579 4.43 193.2 241 9.3 -99.0000 0 -99.00 0 -99.00 4.399 191.9 0 25.52 6 43.62 6 2.181 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 166 9 9 100.0 99.1 8.7513 3.254818 53.6 0.134 0.0 329.8 7.998 30.3936 4.53 197.4 241 9.2 -99.0000 0 -99.00 0 -99.00 4.510 196.7 6 25.49 0 43.92 0 2.172 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 165 8 8 125.0 123.9 8.9097 3.285989 51.1 0.134 0.0 327.8 8.011 30.5690 4.43 193.2 241 9.2 -99.0000 0 -99.00 0 -99.00 4.422 192.9 0 25.09 0 44.17 0 2.155 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 164 7 7 150.2 148.8 9.0061 3.306852 47.4 0.134 0.0 344.4 8.001 30.6902 4.24 185.0 241 9.3 -99.0000 0 -99.00 0 -99.00 4.239 184.9 0 25.03 0 45.92 0 2.251 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 163 6 6 175.1 173.6 8.9977 3.311952 47.4 0.134 0.0 394.6 8.000 30.7394 4.22 184.1 241 9.3 -99.0000 0 -99.00 0 -99.00 4.220 184.0 0 25.06 0 46.42 0 2.189 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 162 5 5 200.3 198.5 9.0832 3.328341 45.6 0.136 0.0 399.4 7.983 30.8235 4.05 176.7 241 9.5 -99.0000 0 -99.00 0 -99.00 4.025 175.5 0 25.41 0 48.34 0 2.251 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 161 4 4 251.0 248.8 9.3324 3.371397 39.4 0.155 0.0 478.2 7.967 31.0276 3.73 162.6 241 9.7 -99.0000 0 -99.00 0 -99.00 3.761 164.0 0 25.44 0 49.41 0 2.301 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 160 3 3 300.9 298.1 9.4121 3.390554 35.9 0.154 0.0 385.4 7.913 31.1331 3.29 143.3 241 9.8 -99.0000 0 -99.00 0 -99.00 3.303 144.0 6 26.23 0 56.43 0 2.500 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 159 2 2 350.1 346.9 9.3625 3.389914 30.9 0.159 0.0 397.2 7.935 31.1489 3.47 151.1 241 9.7 31.1479 0 -99.00 0 -99.00 3.470 151.3 0 25.67 0 54.44 0 2.453 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 158 1 1 371.2 367.7 9.3503 3.389930 27.7 0.161 0.0 407.3 7.935 31.1509 3.49 152.3 241 9.8 -99.0000 0 -99.00 0 -99.00 3.503 152.7 0 25.62 0 54.18 0 2.438 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0