*2023/03/28 10:37:17.76 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2019/09/03 08:09:08.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 18 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : CCE461A NUMBER OF CHANNELS : 58 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 351 368 2 Bottle_Number n/a 1 18 3 Bottle:Firing_Sequence n/a 1 18 4 Pressure decibar 4.8 1040.4 5 Depth metres 4.8 1029 6 Temperature:Primary 'deg C (ITS90)' 3.4183 16.7782 7 Conductivity:Primary S/m 3.199108 4.14197 8 Transmissivity %/metre 45.2 57.3 9 Transmissivity:Green %/metre 64.1 88.1 10 Fluorescence:URU:Seapoint mg/m^3 0.135 2.493 11 PAR uE/m^2/sec 0 0.6 12 Salinity:T0:C0 PSS-78 32.1661 34.4007 13 Oxygen:Dissolved:SBE mL/L 0.25 7.02 14 Oxygen:Dissolved:SBE umol/kg 11 306 15 Number_of_bin_records n/a 57 241 16 Temperature:Draw 'deg C (ITS90)' 5.9 18 17 Salinity:Bottle PSS-78 32.1654 34.2544 18 Flag:Salinity:Bottle ' ' 19 Chlorophyll:Extracted mg/m^3 0.31 0.97 20 Flag:Chlorophyll:Extracted ' ' 21 Phaeo-Pigment:Extracted mg/m^3 0.2E-01 0.27 22 Oxygen:Dissolved mL/L 0.26 6.894 23 Oxygen:Dissolved umol/kg 11.3 300.4 24 Flag:Oxygen:Dissolved ' ' 25 Nitrate_plus_Nitrite umol/L 0 28.07 26 Flag:Nitrate_plus_Nitrite ' ' 27 Silicate umol/L 0.42 136.85 28 Flag:Silicate ' ' 29 Phosphate umol/L 0.316 2.204 30 Flag:Phosphate ' ' 31 Ammonium umol/L 0.2E-01 0.3E-01 32 Flag:Ammonium ' ' 33 HPLC:Chl-c3 mg/m^3 0.2E-01 0.2E-01 34 HPLC:Chlide-a mg/m^3 0 0 35 HPLC:MgDVP mg/m^3 0.2E-02 0.2E-02 36 HPLC:Chl-c2 mg/m^3 0.36E-01 0.36E-01 37 HPLC:Chl-c1 mg/m^3 0 0 38 HPLC:Me-chlide mg/m^3 0.2E-02 0.2E-02 39 HPLC:Peri mg/m^3 0.19E-01 0.19E-01 40 HPLC:But-fuco mg/m^3 0.32E-01 0.32E-01 41 HPLC:Fuco mg/m^3 0.64E-01 0.64E-01 42 HPLC:Neo mg/m^3 0.3E-02 0.3E-02 43 HPLC:Pras mg/m^3 0.5E-02 0.5E-02 44 HPLC:Viola mg/m^3 0.4E-02 0.4E-02 45 HPLC:Hex-fuco mg/m^3 0.32E-01 0.32E-01 46 HPLC:Diadino mg/m^3 0.34E-01 0.34E-01 47 HPLC:Allo mg/m^3 0.2E-02 0.2E-02 48 HPLC:Diato mg/m^3 0.1E-02 0.1E-02 49 HPLC:Zea mg/m^3 0.16E-01 0.16E-01 50 HPLC:Lut mg/m^3 0.1E-02 0.1E-02 51 HPLC:Gyr-de mg/m^3 0 0 52 HPLC:Chl-b mg/m^3 0.26E-01 0.26E-01 53 HPLC:c2-MGDG mg/m^3 0 0 54 HPLC:DVChl-a mg/m^3 0 0 55 HPLC:Chl-a mg/m^3 0.249 0.249 56 HPLC:B-Car mg/m^3 0.6E-02 0.6E-02 57 HPLC:TChl-a mg/m^3 0.251 0.251 58 Flag:HPLC n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 10 F ' ' 6 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 7 F ' ' 1 12 -99 ' ' 9 F ' ' 4 13 -99 ' ' 7 F ' ' 2 14 -99 ' ' 6 F ' ' 1 15 -99 ' ' 5 I I 0 16 -99 ' ' 6 F R4 1 17 -99 ' ' 9 F R4 4 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 8 F R4 3 23 -99 ' ' 6 F ' ' 1 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 8 F R4 3 30 -99 ' ' 3 NQ C ' ' 31 -99 ' ' 7 F R4 2 32 -99 ' ' 3 NQ C ' ' 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 8 F R4 3 57 -99 ' ' 8 F R4 3 58 -99 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2019-023 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Sastri A. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LJ06 EVENT NUMBER : 94 LATITUDE : 49 27.83000 N ! (deg min) LONGITUDE : 127 28.59000 W ! (deg min) WATER DEPTH : 1088 ALTIMETER (M) : 7.96 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 $REMARKS Software Version Seasave V 7.26.7.107 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2020/01/28 09:29:09 4154 4154 CLEAN 5.2.3 2020/01/28 09:29:40 4154 4154 ADDSAMP 3.6 2020/01/30 14:22:46 4154 4154 BINAVE 4.2.1 2020/03/13 14:27:46 4154 18 MERGE 3.5.1 2020/03/18 11:17:51 18 18 CLEAN 5.2.4 2020/03/18 11:19:14 18 18 CALIB 12.0.1 2020/03/18 11:28:03 18 18 SORT 3.6 2020/03/18 11:28:16 18 18 REMOVECH 8.2 2020/03/18 11:28:41 18 18 CHGUNITS 3.1.2 2020/03/18 11:28:52 18 18 CHGUNITS 3.1.2 2020/03/18 11:35:34 18 18 REORDER 1.3.1 2020/03/18 11:35:45 ? ? HDREDIT2 3.2 2020/03/18 11:52:50 ? ? CALIB 12.0.1 2021/01/20 13:09:08 18 18 HDREDIT2 3.2 2021/01/20 16:10:32 ? ? HDREDIT2 3.2 2021/01/20 16:13:25 ? ? SORT 3.6 2023/03/23 12:18:24 18 18 MERGE 3.6 2023/03/26 15:39:02 18 18 SORT 3.6 2023/03/26 15:39:23 18 18 CLEAN 5.3 2023/03/26 15:39:34 18 18 HDREDIT2 3.2 2023/03/26 15:40:15 ? ? HDREDIT2 3.2 2023/03/26 15:40:38 ? ? CLEAN 5.3 2023/03/28 10:37:17 18 18 $END $REMARKS -CLEAN functions: 2020/01/28 09:29:27 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\OSD_DataProcessing\Cruise_Data\2019-023\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number [n/a] Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2020/03/18 11:17:51 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Temperature:Draw, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium Primary file : D:\Telework\2019-023\Processing\hydro\2019-023-0094.samavg Secondary file: D:\Telework\2019-023\Processing\hydro\2019-023-0094.mrgcln1s Comments from secondary file: D:\Telework\2019-023\Processing\hydro\2019-023-0094.mrgcln1s ------------------------------------------------------------ -CLEAN functions: 2020/01/30 14:43:57 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2020/01/30 14:44:02 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2020/03/18 11:19:13 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -CALIB parameters: 2020/03/18 11:28:03 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\Telework\2019-023\Processing\doc\2019-023-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Salinity:T0:C0 PSS-78 10 0.8200000E-02 0.1000000E+01 19 Salinity:T1:C1 PSS-78 10 -0.8000000E-03 0.1000000E+01 20 Oxygen:Dissolved:SBE mL/L 10 0.1670000E-01 0.1038400E+01 -SORT parameters: 2020/03/18 11:28:16 Sorted in ascending order of channel Press* -REMOVECH 2020/03/18 11:28:41 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2020/03/18 11:52:50 Applied edit header: D:\Telework\2019-023\Processing\doc\HYDRO\2019-023-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 Channel 8: Transmissivity:Green [%/metre] Name: Transmissivity2 ==> Transmissivity:Green Channel 10: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 16: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 19: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 21: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 22: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 25: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 27: Silicate [umol/L] Units: ==> umol/L Channel 29: Phosphate [umol/L] Units: ==> umol/L Channel 17: Salinity:Bottle [PSS-78] Units: ==> PSS-78 -CALIB parameters: 2021/01/20 13:09:08 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = 2019-023-transcor.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Transmissivity:Green %/metre 10 -0.2000000E-01 0.1439800E+01 -HEADER EDITS: 2021/01/20 16:10:32 Channel 1: Bottle_Number [n/a] Format: I3 ==> I5 Channel 2: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 -HEADER EDITS: 2021/01/20 16:13:25 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2019\2019-023-transmissivity\ 2019-023-trms-hdr1.txt -SORT parameters: 2023/03/23 12:18:24 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2023/03/26 15:39:02 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:Pheide-a, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Gyr-de, HPLC:Chl-b, HPLC:c2-MGDG, HPLC:DVChl-a, HPLC:Phe, HPLC:Chl-a, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC Primary file : C:\HPLC\2019-023\Processing\IOS\2019-023-0094.che1 Secondary file: C:\HPLC\2019-023\Processing\IOS\2019-023-0094.hplc 1 secondary records matched to primary records. -SORT parameters: 2023/03/26 15:39:23 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2023/03/26 15:39:33 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2023/03/26 15:40:15 Applied edit header: C:\HPLC\2019-023\2019-023-bot-hdr1.txt -HEADER EDITS: 2023/03/26 15:40:38 Applied edit header: C:\HPLC\2019-023\2019-023-bot-hdr2.txt Channel 2: Bottle_Number [n/a] Format: I5 ==> I3 Channel 3: Bottle:Firing_Sequence [n/a] Format: I5 ==> I3 Channel 33: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 57: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:c2-MGDG [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Gyr-de [mg/m^3] Units: ==> mg/m^3 -CLEAN functions: 2023/03/28 10:37:16 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2019-023\2019-023-0094.hex Software Version Seasave V 7.26.7.107 Temperature SN = 2023 Conductivity SN = 1763 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Sep 03 2019 08:12:05 NMEA Latitude = 49 27.83 N NMEA Longitude = 127 28.59 W NMEA UTC (Time) = Sep 03 2019 08:09:08 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Tully: 2019-023 Station: LJ06 Depth: 1088 System UTC = Sep 03 2019 08:12:05 # nquan = 21 # nvalues = 4154 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = CStarTr1: Beam Transmission, WET Labs C-Star, 2 [%] # name 11 = flSP: Fluorescence, Seapoint # name 12 = sbeox0V: Oxygen raw, SBE 43 [V] # name 13 = par: PAR/Irradiance, Biospherical/Licor # name 14 = altM: Altimeter [m] # name 15 = dz/dtM: Descent Rate [m/s] # name 16 = pumps: Pump Status # name 17 = sal00: Salinity, Practical [PSU] # name 18 = sal11: Salinity, Practical, 2 [PSU] # name 19 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 20 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Sep 03 2019 08:09:08 [NMEA time, header] # bad_flag = -9.990e-29 # datcnv_date = Jan 27 2020 16:25:55, 7.26.7.129 # datcnv_in = P:\Cruise_Data_Raw\2019\2019-023\CTD Data\2019-023-0094.hex Q:\OSD _DataProcessing\Cruise_Data\2019-023\Processing\doc\2019-023-ctd.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: D:\Telework\2019-023\Processing\hydro\2019-023-0094.mrgcln1s ------------------------------------------------------------ Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-023\Processing\hydro\2019-023-0094.oxy --------------------------------------------------------------------------- Sample_Number 357: OXY-2: Endpoint was late. Sample over-titrated. Sample_Number 362: OXY: Endpoint was late. Sample over-titrated. Sample_Number 365: OXY-2: Unstoppered OXY-2 before OXY-1 but no measurable change regardless of the sample being exposed to the atmosphere for a few minutes. Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-023\Processing\hydro\2019-023-0094.nut --------------------------------------------------------------------------- Sample_Number 353: NUTS: Sample intended as a duplicate, one sample clearly out of line Sample_Number 354: NUTS: values clearly bad Sample_Number 363: NUTS: Sample intended as a duplicate, one sample clearly out of line Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~7 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.05-17.56ug/l in 302 samples. Average %CV for this cruise was 3.27% with 2 out of 61 duplicate pairs having a CV>10% and 0 duplicate pairs having a CV>30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is very good. For details see worksheet “CV%” in file QF2019-023CHL*.xlsx. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2019-023HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a precision analysis, see document QF2019-023OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 8 - 19 days after collection. For details including a duplicate analysis, see document QF2019-023SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2019-023nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. Standards are made in LNSW collected at 250m at station LB14. For full details including a precision study see file 2019-023NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on the processing see the report: 2019-023_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.82E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (-0.8E-03 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.167E-01 1.0384) Transmissivity:Green %/metre 10 -99 () (-0.2E-01 1.4398) $END !-1-- 2- 3- --4--- --5--- ---6---- ----7---- --8-- --9-- ---10-- --11-- ---12--- --13-- --14- -15- --16- ---17--- 18 --19-- 20 --21-- ---22-- --23- 24 --25-- 26 --27-- 28 ---29-- 30 --31-- 32 ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- ---56-- ---57-- 58 !Samp Bo Bo Pressu Depth Temperat Conductiv Trans Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Ammoni Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ tt tt re ure: ity: missi missi cence: :T0:C0 : n: er_o ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te ag um ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Gyr-de Chl-b c2-MGDG DVChl-a Chl-a Car TChl-a ag !Numb ~u ~u Primary Primary vity vity: URU: Dissol Disso ~bin e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~i ~p ~o a chlide fuco fuco : !er mb en Green Seapoin ved: lved: _rec Draw tt ted ct Extrac lved lv Nitrit ri ca ha ni HP ! er ce t SBE SBE ords le ed ted ed e te te te um LC !---- -- -- ------ ------ -------- --------- ----- ----- ------- ------ -------- ------ ----- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 367 17 17 4.8 4.8 16.7782 4.141970 48.2 70.2 0.684 0.6 32.1661 5.72 249.3 57 18.0 32.1654 0 0.32 0 0.02 5.743 250.6 0 0.16 0 3.75 0 0.385 0 0.03 6 0.020 0.000 0.002 0.036 0.000 0.002 0.019 0.032 0.064 0.003 0.005 0.004 0.032 0.034 0.002 0.001 0.016 0.001 0.000 0.026 0.000 0.000 0.249 0.006 0.251 6 368 18 18 4.9 4.9 16.7773 4.141884 48.1 70.4 0.689 0.6 32.1661 5.72 249.3 241 -99.0 -99.0000 0 -99.00 0 -99.00 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 366 16 16 10.0 9.9 16.7732 4.141790 48.0 70.2 0.679 0.2 32.1667 5.71 249.1 241 17.9 -99.0000 0 0.31 6 0.04 5.748 250.8 0 0.00 0 0.42 0 0.316 0 0.02 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 365 15 15 20.0 19.9 16.2804 4.100640 48.0 69.7 0.972 0.0 32.2011 5.83 254.3 241 15.9 -99.0000 0 0.68 0 0.17 6.255 272.8 26 0.00 0 1.14 0 0.327 0 0.03 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 364 14 14 30.1 29.8 12.3888 3.759421 45.2 64.1 2.493 0.0 32.3207 7.02 306.0 241 12.7 -99.0000 0 0.97 0 0.27 6.894 300.4 0 0.42 0 1.15 0 0.399 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 363 13 13 50.0 49.6 9.2069 3.486704 54.1 81.9 0.640 0.0 32.4163 6.04 263.0 241 10.0 -99.0000 0 0.42 0 0.23 6.039 263.0 0 5.13 2 5.92 2 0.672 2 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 362 12 12 75.0 74.4 8.0999 3.419634 56.6 86.9 0.221 0.0 32.7217 5.10 222.1 241 8.9 -99.0000 0 -99.00 0 -99.00 4.946 215.3 2 11.09 0 14.71 0 1.027 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 361 11 11 99.9 99.0 7.6419 3.425492 56.7 87.4 0.173 0.0 33.2047 4.31 187.4 241 8.7 -99.0000 0 -99.00 0 -99.00 4.291 186.8 0 12.79 0 15.87 0 1.117 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 360 10 10 125.0 123.9 7.4108 3.443547 56.8 87.5 0.161 0.0 33.6101 3.80 165.2 241 8.4 -99.0000 0 -99.00 0 -99.00 3.776 164.3 0 14.17 0 18.03 0 1.157 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 359 9 9 150.0 148.6 7.3129 3.455684 56.8 87.5 0.161 0.0 33.8250 3.40 148.0 241 8.4 -99.0000 0 -99.00 0 -99.00 3.335 145.1 0 16.34 0 20.96 0 1.257 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 358 8 8 175.2 173.6 7.2424 3.459009 56.4 86.4 0.159 0.0 33.9180 2.76 119.9 241 8.3 -99.0000 0 -99.00 0 -99.00 2.751 119.7 0 15.42 0 21.63 0 1.259 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 357 7 7 200.0 198.2 6.9743 3.436527 56.6 86.8 0.158 0.0 33.9236 2.64 114.9 241 8.2 -99.0000 0 -99.00 0 -99.00 2.643 115.0 26 15.83 0 22.96 0 1.342 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 356 6 6 250.1 247.8 6.4845 3.396400 56.9 87.5 0.151 0.0 33.9405 2.21 95.9 241 7.8 -99.0000 0 -99.00 0 -99.00 2.210 96.1 0 18.00 0 32.26 0 1.420 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 355 5 5 300.2 297.4 5.9735 3.354518 56.9 87.7 0.147 0.0 33.9570 1.77 77.1 241 7.5 -99.0000 0 -99.00 0 -99.00 1.778 77.3 0 18.83 0 39.55 0 1.568 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 354 4 4 400.5 396.7 5.4300 3.315096 57.2 88.1 0.147 0.0 34.0072 1.24 53.9 241 7.1 -99.0000 0 -99.00 0 -99.00 1.241 54.0 0 -99.00 5 -99.00 5 -99.000 5 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 353 3 3 500.0 495.1 4.8981 3.278153 57.3 88.1 0.146 0.0 34.0732 0.78 34.1 241 6.8 -99.0000 0 -99.00 0 -99.00 0.826 35.9 0 20.02 2 86.88 2 1.708 2 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 352 2 2 749.9 742.2 4.0920 3.233223 57.2 88.1 0.135 0.0 34.2512 0.27 11.6 241 6.3 34.2544 0 -99.00 0 -99.00 0.276 12.0 0 27.66 0 114.29 0 2.204 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 351 1 1 1040.4 1029.0 3.4183 3.199108 55.7 85.1 0.142 0.0 34.4007 0.25 11.0 241 5.9 -99.0000 0 -99.00 0 -99.00 0.260 11.3 0 28.07 0 136.85 0 2.192 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0