*2024/08/14 09:56:49.37 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2019/08/23 21:45:40.000 END TIME : UTC 2019/08/23 21:45:40.125 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 4 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 85575ED0 NUMBER OF CHANNELS : 20 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 766 784 2 Bottle_Number n/a 1 19 3 Bottle:Firing_Sequence n/a 1 19 4 Pressure decibar 201.1 499.9 5 Depth metres 199.3 495 6 Temperature:Primary 'deg C (ITS90)' 3.9034 4.766 7 Conductivity:Primary S/m 3.1756 3.2202 8 Transmissivity %/metre 56.1 57.4 9 Transmissivity:Green %/metre 85.6 88.1 10 Fluorescence:URU:Seapoint mg/m^3 0.122 0.144 11 PAR uE/m^2/sec 0 0 12 Salinity:T0:C0 PSS-78 33.6899 34.0561 13 Oxygen:Dissolved:SBE mL/L 0.92 3.48 14 Oxygen:Dissolved:SBE umol/kg 40.1 151 15 Number_of_bin_records n/a 182 241 16 Cesium-134 Bq/m3 0 0 17 Cesium-134:Uncertainty Bq/m3 -99 -99 18 Cesium-137 Bq/m3 0.64 1.71 19 Cesium-137:Uncertainty Bq/m3 0.1 0.15 20 Flag:Cs n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 10 F ' ' 4 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 7 F ' ' 1 12 -99 ' ' 9 F ' ' 4 13 -99 ' ' 7 F ' ' 2 14 -99 ' ' 6 F ' ' 1 15 ' ' ' ' 5 I I 0 16 -99 ' ' 7 F R4 2 17 -99 ' ' 7 F R4 2 18 -99 ' ' 7 F R4 2 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2019-008 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P26 EVENT NUMBER : 95 LATITUDE : 49 59.99000 N ! (deg min) LONGITUDE : 144 59.98000 W ! (deg min) WATER DEPTH : 4227 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 1763 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 5013 Conductivity:2 ' ' 3394 'Oxygen:SBE 43' ' ' 3234 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 62355 $END $REMARKS Software Version Seasave V 7.26.7.107 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2020/01/24 08:25:25 5171 5171 CLEAN 5.2.3 2020/01/24 08:37:10 5171 5171 ADDSAMP 3.6 2020/01/24 11:28:02 5171 5171 BINAVE 4.2 2020/01/24 11:30:04 5171 24 MERGE 3.5.1 2020/02/13 14:04:47 24 24 CLEAN 5.2.4 2020/02/24 15:59:44 24 24 CALIB 12.0.1 2020/02/24 16:00:05 24 24 SORT 3.6 2020/02/24 16:00:10 24 24 REMOVECH 8.2 2020/02/24 16:00:47 24 24 CHGUNITS 3.1.2 2020/02/24 16:03:54 24 24 CHGUNITS 3.1.2 2020/02/24 16:04:18 24 24 REORDER 1.3.1 2020/03/17 12:59:09 ? ? SORT 3.6 2020/03/18 10:54:56 24 24 HDREDIT2 3.2 2020/03/18 10:55:31 ? ? CALIB 12.0.1 2021/01/20 12:16:01 24 24 SORT 3.6 2024/07/26 15:16:25 24 24 MERGE 3.6 2024/07/26 15:24:29 24 24 SORT 3.6 2024/07/26 15:24:47 24 24 CLEAN 5.3 2024/08/12 14:46:16 4 4 HDREDIT2 3.2 2024/08/14 09:56:49 ? ? $END $REMARKS -CLEAN functions: 2020/01/24 08:36:48 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2020/02/13 14:04:47 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Gyr-de, HPLC:Chl-b, HPLC:c2-MGDG, HPLC:DVChl-a, HPLC:Chl-a, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC, Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw Primary file : Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0095.samavg Secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0095.mrgcln1s Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0095.mrgcln1s --------------------------------------------------------------------------- -SORT parameters: 2020/02/13 14:01:41 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2020/02/24 15:59:42 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. -CALIB parameters: 2020/02/24 16:00:05 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\doc\2019-008-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Salinity:T0:C0 PSS-78 10 0.8300000E-02 0.1000000E+01 20 Salinity:T1:C1 PSS-78 10 0.4000000E-03 0.1000000E+01 21 Oxygen:Dissolved:SBE mL/L 10 0.1820000E-01 0.1034800E+01 -SORT parameters: 2020/02/24 16:00:10 Sorted in ascending order of channel Press* -REMOVECH 2020/02/24 16:00:47 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -SORT parameters: 2020/03/18 10:54:56 Sorted in ascending order of channel Press* -HEADER EDITS: 2020/03/18 10:55:31 Applied edit header: D:\Telework\2019-008\Processing\doc\HYDRO\2019-008-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 Channel 8: Transmissivity:Green [%/metre] Name: Transmissivity2 ==> Transmissivity:Green Channel 10: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 -CALIB parameters: 2021/01/20 12:16:01 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = 2019-008-transcor.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Transmissivity:Green %/metre 10 -0.2000000E-01 0.1439800E+01 -SORT parameters: 2024/07/26 15:16:25 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2024/07/26 15:24:29 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Cesium-134, Cesium-134:Uncertainty, Cesium-137, Cesium-137:Uncertainty, Flag:Cs Primary file : C:\Users\huntingtons\Desktop\Cesium_additions\2019-008\Processing\IOS\2019-008- 0095.chesort Secondary file: C:\Users\huntingtons\Desktop\Cesium_additions\2019-008\Processing\IOS\2019-008- 0095.csm 4 secondary records matched to primary records. -SORT parameters: 2024/07/26 15:24:47 Sorted in ascending order of channel Pressure -CLEAN functions: 2024/08/12 14:46:15 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag* Set header Start and End times from the data. -HEADER EDITS: 2024/08/14 09:56:49 Applied edit header: C:\Users\huntingtons\Desktop\Additions\Cesium_additions\2019-008\Processing\ DOC\2019-009-hdr.txt Channel 20: Flag:Cs [n/a] Units: ==> n/a Pad: 0 ==> -99 Channel 7: Conductivity:Primary [S/m] Format: F10.6 ==> F10.4 $END *COMMENTS Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~2 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.03-10.66ug/l in 115 samples. Average %CV for this cruise was 2.80% with 0 out of 35 duplicate pairs having a CV>10% and 0 duplicate pairs having a CV>30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is excellent. For details see worksheet “CV%” in file QF2019-008CHL*.xlsx. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF2019-008_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2019-008OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 13 - 25 days after collection. For details including a duplicate analysis, see document QF2019-008SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2019-008nuts*.xlsx. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed into a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100 deg C (with a dewar containing boiling water) onto a Chromosil 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.1nmol/L. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more detail see file "2019-008 DMS report.doc" and for data and duplicate analysis see "QF2019-008_DMS*.xlsx." DMSP-D: Approximately 20-75mL of seawater was allowed to flow directly from the niskin into a magnetic filtration funnel containing a 0.7um GF/F filter. The first 3.5mL was collected in a polypropylene tube (15mL) containing 50uL of a 50% sulphuric acid solution. A new funnel and filter are used for each sample. Samples are hydrolized and run at IOS when time permits. DMPS-T: 3.5mL of seawater was collected directly from the niskin into a polypropylene tube (15mL) containing 50uL of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For details on analysis and raw data, see document "QF2019-008 dmsp*.xlsx. Cesium Analysis: Large volume (~60 L) water samples were collected and then passed through potassium cobalt ferrocyanide (KCFC) resin columns to selectively extract Cs isotopes from seawater. Column extraction efficiencies are generally greater than 96% as determined using spiked yield tracers with resin columns arranged in series. The isotopes 137Cs and 134Cs were subsequently measured on the oven-dried KCFC resins in the laboratory using high purity Ge well detectors. All data were decay-corrected to the time of sampling. A second level of analysis was often undertaken by subsequently decay correcting the data to April 6 2011 which was the time of maximum discharges from Fukushima. Detection limits (DL) for 137Cs and 134Cs were generally 0.10 Bq/m3 and 0.13 Bq/m3 respectively so "0" values should be interpreted as < detection limit. Detector efficiencies were measured using National Institute of Standards and Technology (NIST) and National Bureau of Sciences (NBS) calibration standards (e.g., NBS 4350B river sediment) and IAEA reference materials All the CTD variables are averaged over the same pressures in order to have one line of data per sample. The lowest sample number was used to represent a sample. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on the processing see the report: 2019-008_Processing_Report.doc. --------------------------------------------------------------------------------- HPLC data will be available in March 2022. Comments from secondary file: C:\Users\huntingtons\Desktop\Cesium_additions\2019-008\Processing\IOS\2019-008-0095.csm --------------------------------------------------------------------------- Sample_Number 766: Cesium: value not reported Sample_Number 772: Cesium: DL = 0.20 for this sample Sample_Number 778: Cesium: DL = 0.20 for this sample Sample_Number 784: Cesium: DL = 0.32 for this sample *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.83E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (0.4E-03 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.182E-01 1.0348) Transmissivity:Green %/metre 10 -99 () (-0.2E-01 1.4398) $END !-1-- 2- 3- --4--- --5--- ---6---- ----7---- --8-- --9-- ---10-- --11-- ---12--- --13-- --14- -15- --16-- --17-- --18-- --19-- 20 !Samp Bo Bo Pressu Depth Temperat Conductiv Trans Trans Fluores PAR Salinity Oxygen Oxyge Numb Cesium Cesium Cesium Cesium Fl !le_ tt tt re ure: ity: missi missi cence: :T0:C0 : n: er_o -134 -134: -137 -137: ag !Numb ~u ~u Primary Primary vity vity: URU: Dissol Disso ~bin Uncert Uncert : !er mb en Green Seapoin ved: lved: _rec ainty ainty Cs ! er ce t SBE SBE ords !---- -- -- ------ ------ -------- --------- ----- ----- ------- ------ -------- ------ ----- ---- ------ ------ ------ ------ -- *END OF HEADER 784 19 19 201.1 199.3 4.7660 3.2202 56.1 85.6 0.144 0.0 33.6899 3.48 151.0 206 0.00 -99.00 1.71 0.15 2 778 13 13 300.5 297.7 4.2090 3.1889 56.8 86.7 0.133 0.0 33.8404 2.02 87.8 241 0.00 -99.00 1.07 0.11 2 772 7 7 400.5 396.7 3.9034 3.1756 57.2 87.7 0.123 0.0 33.9460 1.23 53.2 200 0.00 -99.00 0.64 0.10 2 766 1 1 499.9 495.0 3.9189 3.1906 57.4 88.1 0.122 0.0 34.0561 0.92 40.1 182 -99.00 -99.00 -99.00 -99.00 9