*2024/09/05 11:29:00.47 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2019/08/17 19:11:59.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 78516F95 NUMBER OF CHANNELS : 62 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 310 326 2 Bottle_Number n/a 1 17 3 Bottle:Firing_Sequence n/a 1 17 4 Pressure decibar 2.8 300.6 5 Depth metres 2.8 297.9 6 Temperature:Primary 'deg C (ITS90)' 6.5665 17.324 7 Transmissivity %/metre 40.5 57.2 8 Fluorescence:URU:Seapoint mg/m^3 0.11 3.089 9 PAR uE/m^2/sec 0 1135.2 10 Salinity:T0:C0 PSS-78 32.3018 33.9354 11 Oxygen:Dissolved:SBE mL/L 2.21 7.13 12 Oxygen:Dissolved:SBE umol/kg 96.2 310.6 13 Conductivity:Primary S/m 3.405503 4.208841 14 Number_of_bin_records n/a 148 241 15 Nitrate_plus_Nitrite umol/L 0.1E-01 34.7 16 Flag:Nitrate_plus_Nitrite ' ' 17 Silicate umol/L 0.36 53.22 18 Flag:Silicate ' ' 19 Phosphate umol/L 0.347 2.41 20 Flag:Phosphate ' ' 21 Dimethyl_Sulphide nmol/L 0 3.4 22 Dimethylsulfoniopropionate_Dissolved nmol/L 0 3.9 23 Dimethylsulfoniopropionate_Total nmol/L 0.38 120 24 Flag:Dimethylsulfoniopropionate_Total ' ' 25 Chlorophyll:Extracted mg/m^3 0.3E-01 0.9 26 Flag:Chlorophyll:Extracted ' ' 27 Phaeo-Pigment:Extracted mg/m^3 0.1E-01 0.4 28 Transmissivity:Green %/metre 56.6 87.8 29 Flag:Dimethyl_Sulphide ' ' 30 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 31 HPLC:Chl-c3 mg/m^3 0.8E-02 0.185 32 HPLC:Chlide-a mg/m^3 0 0 33 HPLC:MgDVP mg/m^3 0 0.13E-01 34 HPLC:Chl-c2 mg/m^3 0.14E-01 0.19 35 HPLC:Chl-c1 mg/m^3 0 0.1E-02 36 HPLC:Me-chlide mg/m^3 0 0 37 HPLC:Peri mg/m^3 0 0.59E-01 38 HPLC:But-fuco mg/m^3 0.15E-01 0.142 39 HPLC:Fuco mg/m^3 0.6E-02 0.123 40 HPLC:Neo mg/m^3 0 0.2E-01 41 HPLC:Pras mg/m^3 0 0.15E-01 42 HPLC:Viola mg/m^3 0 0.7E-02 43 HPLC:Hex-fuco mg/m^3 0.43E-01 0.522 44 HPLC:Diadino mg/m^3 0.11E-01 0.51E-01 45 HPLC:Allo mg/m^3 0.1E-02 0.11E-01 46 HPLC:Diato mg/m^3 0.1E-02 0.6E-02 47 HPLC:Zea mg/m^3 0.6E-02 0.33E-01 48 HPLC:Lut mg/m^3 0 0.1E-01 49 HPLC:Gyr-de mg/m^3 0 0.13E-01 50 HPLC:Chl-b mg/m^3 0.5E-02 0.18 51 HPLC:c2-MGDG mg/m^3 0.1E-02 0.32E-01 52 HPLC:DVChl-a mg/m^3 0 0 53 HPLC:Chl-a mg/m^3 0.128 0.971 54 HPLC:B-Car mg/m^3 0.4E-02 0.13E-01 55 HPLC:TChl-a mg/m^3 0.128 0.971 56 Flag:HPLC n/a 57 Carbon:Dissolved:Organic uM 66 73 58 Flag:Carbon:Dissolved:Organic n/a 59 Carbon:Total:Organic uM 68.1 74.9 60 Flag:Carbon:Total:Organic n/a 61 CDOM:Available n/a -99 -99 62 Flag:CDOM:Available n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 6 14 -99 ' ' 5 I I 0 15 -99 ' ' 7 F R4 2 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 8 F R4 3 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 7 F R4 2 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 6 F ' ' 1 29 -99 ' ' 3 NQ C ' ' 30 -99 ' ' 3 NQ C ' ' 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 3 NQ C ' ' 57 -99 ' ' 7 F R4 2 58 -99 ' ' 3 NQ C ' ' 59 -99 ' ' 7 F R4 2 60 -99 ' ' 3 NQ C ' ' 61 -99 ' ' 3 I I 0 62 -99 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2019-008 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P12 EVENT NUMBER : 42 LATITUDE : 48 58.20000 N ! (deg min) LONGITUDE : 130 39.99000 W ! (deg min) WATER DEPTH : 3229 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 1763 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 5013 Conductivity:2 ' ' 3394 'Oxygen:SBE 43' ' ' 3234 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1185DR 'Transmissometer:WET Labs C-Star:2' ' ' 1883DG PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 62355 $END $REMARKS Software Version Seasave V 7.26.7.107 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2020/01/24 08:25:03 3916 3916 CLEAN 5.2.3 2020/01/24 08:36:56 3916 3916 ADDSAMP 3.6 2020/01/24 11:27:43 3916 3916 BINAVE 4.2 2020/01/24 11:29:53 3916 17 MERGE 3.5.1 2020/02/13 14:04:42 17 17 CLEAN 5.2.4 2020/02/24 15:59:43 17 17 CALIB 12.0.1 2020/02/24 16:00:03 17 17 SORT 3.6 2020/02/24 16:00:09 17 17 REMOVECH 8.2 2020/02/24 16:00:46 17 17 CHGUNITS 3.1.2 2020/02/24 16:03:53 17 17 CHGUNITS 3.1.2 2020/02/24 16:04:17 17 17 REORDER 1.3.1 2020/03/17 12:59:06 ? ? REMOVECH 8.2 2020/03/18 10:46:37 17 17 SORT 3.6 2020/03/18 10:54:53 17 17 HDREDIT2 3.2 2020/03/18 10:55:29 ? ? CALIB 12.0.1 2021/01/20 12:16:00 17 17 SORT 3.6 2023/03/12 19:35:38 17 17 REORDER 1.3.1 2023/03/12 19:36:18 ? ? MERGE 3.6 2023/03/12 19:36:51 17 17 SORT 3.6 2023/03/12 19:37:37 17 17 CLEAN 5.3 2023/03/12 19:37:52 17 17 HDREDIT2 3.2 2023/03/19 15:05:51 ? ? REMOVECH 8.2 2023/03/19 15:06:19 17 17 HDREDIT2 3.2 2023/03/19 15:06:46 ? ? CLEAN 5.3 2023/03/28 10:35:14 17 17 SORT 3.6 2024/09/05 11:04:08 17 17 MERGE 3.6 2024/09/05 11:12:07 17 17 SORT 3.6 2024/09/05 11:16:19 17 17 CLEAN 5.3 2024/09/05 11:16:32 17 17 HDREDIT2 3.2 2024/09/05 11:28:30 ? ? $END $REMARKS -CLEAN functions: 2020/01/24 08:36:48 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2020/02/13 14:04:42 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total, HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Gyr-de, HPLC:Chl-b, HPLC:c2-MGDG, HPLC:DVChl-a, HPLC:Chl-a, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC, Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw Primary file : Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0042.samavg Secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0042.mrgcln1s Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0042.mrgcln1s --------------------------------------------------------------------------- -SORT parameters: 2020/02/13 14:01:40 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2020/02/24 15:59:42 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Remove Sea-Bird comments from the header. -CALIB parameters: 2020/02/24 16:00:03 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\doc\2019-008-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Salinity:T0:C0 PSS-78 10 0.8300000E-02 0.1000000E+01 20 Salinity:T1:C1 PSS-78 10 0.4000000E-03 0.1000000E+01 21 Oxygen:Dissolved:SBE mL/L 10 0.1820000E-01 0.1034800E+01 -SORT parameters: 2020/02/24 16:00:09 Sorted in ascending order of channel Press* -REMOVECH 2020/02/24 16:00:46 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -REMOVECH 2020/03/18 10:46:37 The following CHANNEL(S) were removed: HPLC:Chl-c3 HPLC:Chlide-a HPLC:MgDVP HPLC:Chl-c2 HPLC:Chl-c1 HPLC:Me-chlide HPLC:Peri HPLC:But-fuco HPLC:Fuco HPLC:Neo HPLC:Pras HPLC:Viola HPLC:Hex-fuco HPLC:Diadino HPLC:Allo HPLC:Diato HPLC:Zea HPLC:Lut HPLC:Gyr-de HPLC:Chl-b HPLC:c2-MGDG HPLC:DVChl-a HPLC:Chl-a HPLC:B-Car HPLC:TChl-a Flag:HPLC -SORT parameters: 2020/03/18 10:54:53 Sorted in ascending order of channel Press* -HEADER EDITS: 2020/03/18 10:55:29 Applied edit header: D:\Telework\2019-008\Processing\doc\HYDRO\2019-008-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 6: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 Channel 8: Transmissivity:Green [%/metre] Name: Transmissivity2 ==> Transmissivity:Green Channel 10: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 16: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 19: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 21: Silicate [umol/L] Units: ==> umol/L Channel 23: Phosphate [umol/L] Units: ==> umol/L Channel 25: Dimethyl_Sulphide [nmol/L] Units: ==> nmol/L -CALIB parameters: 2021/01/20 12:16:00 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = 2019-008-transcor.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Transmissivity:Green %/metre 10 -0.2000000E-01 0.1439800E+01 -SORT parameters: 2023/03/12 19:35:38 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2023/03/12 19:36:51 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:Pheide-a, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Gyr-de, HPLC:Chl-b, HPLC:c2-MGDG, HPLC:DVChl-a, HPLC:Phe, HPLC:Chl-a, HPLC:B-Car, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC Primary file : C:\Users\jared\OneDrive\Documents\DFO\HPLC\2019-008\Processing\IOS\2019-008-0042. che2 Secondary file: C:\Users\jared\OneDrive\Documents\DFO\HPLC\2019-008\Processing\IOS\2019-008-0042. hplc 6 secondary records matched to primary records. -SORT parameters: 2023/03/12 19:37:37 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2023/03/12 19:37:52 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2023/03/19 15:05:51 - none. -REMOVECH 2023/03/19 15:06:19 The following CHANNEL(S) were removed: HPLC:B-Car -HEADER EDITS: 2023/03/19 15:06:46 Channel 31: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:c2-MGDG [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Gyr-de [mg/m^3] Units: ==> mg/m^3 -CLEAN functions: 2023/03/28 10:35:13 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -SORT parameters: 2024/09/05 11:04:08 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2024/09/05 11:12:07 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Organic, Flag:Carbon:Dissolved:Organic, Carbon:Total:Organic, Flag:Carbon:Total:Organic, CDOM:Available, Flag:CDOM:Available Primary file : C:\Users\huntingtons\Desktop\Additions\Carbon Additions\2019-008\Processing\IOS\ 2019-008-0042.srt Secondary file: C:\Users\huntingtons\Desktop\Additions\Carbon Additions\2019-008\Processing\IOS\ 2019-008-0042.car 2 secondary records matched to primary records. -SORT parameters: 2024/09/05 11:16:19 Sorted in ascending order of channel Pressure -CLEAN functions: 2024/09/05 11:16:32 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2024/09/05 11:28:30 Applied edit header: C:\Users\huntingtons\Desktop\Additions\Carbon Additions\2019-008\Processing\ DOC\2019-008_header1.txt -HEADER EDITS: 2024/09/05 11:29:00 Applied edit header: C:\Users\huntingtons\Desktop\Additions\Carbon Additions\2019-008\Processing\ DOC\2019-008_header2.txt $END *COMMENTS Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0042.mrgcln1s --------------------------------------------------------------------------- Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0042.nut --------------------------------------------------------------------------- Sample_Number 312: NUTS: Sample intended as a duplicate, however, analysis problem resulted in one sample with bad data Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0042.dms --------------------------------------------------------------------------- Sample_Number 321: DMS: %relative difference >20% but <49% Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0042.dmsp --------------------------------------------------------------------------- Sample_Number 321: DMSP-D: %relative difference >20% but <49% Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\2019-008\Processing\hydro\2019-008-0042.hplc --------------------------------------------------------------------------- Sample_Number 324: HPLC: >10%CV for TChl-a Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~2 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.03-10.66ug/l in 115 samples. Average %CV for this cruise was 2.80% with 0 out of 35 duplicate pairs having a CV>10% and 0 duplicate pairs having a CV>30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is excellent. For details see worksheet “CV%” in file QF2019-008CHL*.xlsx. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF2019-008_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2019-008OXY*.xlsx. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 13 - 25 days after collection. For details including a duplicate analysis, see document QF2019-008SAL*.xlsx. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2019-008nuts*.xlsx. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed into a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100 deg C (with a dewar containing boiling water) onto a Chromosil 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.1nmol/L. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For more detail see file "2019-008 DMS report.doc" and for data and duplicate analysis see "QF2019-008_DMS*.xlsx." DMSP-D: Approximately 20-75mL of seawater was allowed to flow directly from the niskin into a magnetic filtration funnel containing a 0.7um GF/F filter. The first 3.5mL was collected in a polypropylene tube (15mL) containing 50uL of a 50% sulphuric acid solution. A new funnel and filter are used for each sample. Samples are hydrolized and run at IOS when time permits. DMPS-T: 3.5mL of seawater was collected directly from the niskin into a polypropylene tube (15mL) containing 50uL of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is <20%. For details on analysis and raw data, see document "QF2019-008 dmsp*.xlsx. DOC and TOC samples were collected in 80 mL polycarbonate bottles and frozen until analysis. DOC samples were filtered inline from the Niskin bottles, using acid-washed filter holders and tubing and pre-combusted Whatman 25 mm GF/C filters (~1.2 ?m pore size). For analysis, samples were thawed and acidified with 4M HCl at a ratio of 100 uL HCL to 40 mL seawater. DOC samples were collected for depths <250 meters, and TOC/TDN samples were collected for depths >250 meters. For full details on analysis and processing see: Johannessen, S., Fassbender, A. J., Long, J. S., Wright, C. (2021) DOC and TOC of seawater collected during CCGS John P. Tully cruises in the northeast Pacific Ocean from Vancouver Island to Station P from 2018 to 2020. Biological and Chemical Oceanography Data Management Office (BCO-DMO). https://www.bco-dmo.org/dataset/865829 Non-OSD researchers needing access to the data should send a request to: DFO.PACSCIIOSData-DonneesISOSCIPAC.MPO@dfo-mpo.gc.ca The following samples were collected on Cruise 2019-008. These were collected as part of the EXPORTS Program, in collaboration with Andrea Fassbender (NOAA). Cruise log and sampling logs are available upon request. Water samples for CDOM analysis were passed through a Millipore Opticap XL Durapore 0.22 µm inline filter cartridge (Product No. KVGLA04HH3) into 125 ml amber glass bottles, directly from the original Niskin bottles. Samples were refrigerated and returned to the Institute of Ocean Sciences, where they were analyzed within one year of collection. Spectral absorbance (280-700 nm at 1nm resolution) was measured with a HP Agilent 8453 spectrophotometer, using a quartz cell with a 10-cm pathlength. Absorbance, ACDOM (dimensionless), was converted to the absorption coefficient, aCDOM (m-1): aCDOM(l) = ACDOM(l)x2.303/pathlength, where l is wavelength (See Johannessen and Miller, 2001 and Stedmon et al., 2000). Spectral absorption was measured against a distilled water blank, but no offset correction was applied. Cruise logs, sampling logs and other data products from this cruise are available electronically on request from the IOS data archive (http://www-sci.pac.dfo-mpo.gc.ca/osap/data/default_e.htm) or from the authors. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, B. A., and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. 7. Johannessen, S. C. and Miller, W. L. 2001. Quantum yield for the photochemical production of dissolved inorganic carbon in seawater. Marine Chemistry 76: 271-283. 8. Stedmon, C.A., Markager, S., Kaas, H. 2000. Optical properties and signatures of chromophoric dissolved organic matter (CDOM) in Danish coastal waters. Est. Coast. Shelf Sci. 51:567-578. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Channel Transmissometer refers to sensor #1185DR (650nm - red) Channel Transmissometer:Green refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650nm unless otherwise stated. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on the processing see the report: 2019-008_Processing_Report.doc. --------------------------------------------------------------------------------- . Comments from secondary file: C:\Users\jared\OneDrive\Documents\DFO\HPLC\2019-008\Processing\IOS\2019-008-0042.hplc --------------------------------------------------------------------------- Sample_Number 324: HPLC: >10%CV for TChl-a Comments from secondary file: C:\Users\huntingtons\Desktop\Additions\Carbon Additions\2019-008\Processing\IOS\2019-008-0042.car --------------------------------------------------------------------------- Sample_Number 317: CDOM: Value not reported. Sample_Number 326: CDOM: Value not reported. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.83E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (0.4E-03 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.182E-01 1.0348) Transmissivity:Green %/metre 10 -99 () (-0.2E-01 1.4398) $END !-1-- 2- 3- --4--- --5--- ---6---- --7-- ---8--- --9--- ---10--- --11-- --12- ----13--- -14- --15-- 16 --17-- 18 ---19-- 20 --21-- --22-- --23-- 24 --25-- 26 --27-- --28- 29 30 ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- 56 --57-- 58 --59-- 60 61 62 !Samp Bo Bo Pressu Depth Temperat Trans Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Dimeth Dimeth Fl Chloro Fl Phaeo- Trans Fl Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl Carbon Fl Carbon Fl CD Fl !le_ tt tt re ure: missi cence: :T0:C0 : n: ity: er_o e_ ag te ag te ag yl_ ylsulf ylsulf ag phyll: ag Pigmen missi ag ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Gyr-de Chl-b c2-MGDG DVChl-a Chl-a Car TChl-a ag : ag : ag OM ag !Numb ~u ~u Primary vity URU: Dissol Disso Primary ~bin plus_ ~t ~i ~p Sulphi ~piona ~oprop ~T Extrac ~a t: vity: ~p ~o a chlide fuco fuco : Dissol ~g Total: ~g ~l ~l !er mb en Seapoin ved: lved: _rec Nitrit ri ca ha de te_Dis ionate ot ted ct Extrac Green hi lv HP ved:Or an Organi an ab ab ! er ce t SBE SBE ords e te te te solved _Total al ed ted de ed LC ganic ic c ic le le !---- -- -- ------ ------ -------- ----- ------- ------ -------- ------ ----- --------- ---- ------ -- ------ -- ------- -- ------ ------ ------ -- ------ -- ------ ----- -- -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- ------ -- ------ -- -- -- *END OF HEADER 326 17 17 2.8 2.8 17.3236 51.6 0.202 1135.2 32.3063 5.75 250.9 4.208769 241 -99.00 0 -99.00 0 -99.000 0 -99.00 -99.00 -99.00 0 -99.00 0 -99.00 77.6 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 73.00 6 74.90 6 -99 9 325 16 16 3.2 3.1 17.3240 51.6 0.207 965.0 32.3065 5.75 250.8 4.208841 148 1.13 0 0.40 0 0.363 0 1.30 1.10 27.00 0 0.13 0 0.01 77.4 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0 324 15 15 5.1 5.1 17.3206 51.6 0.230 541.9 32.3066 5.75 250.7 4.208634 241 1.03 0 0.38 0 0.362 0 1.40 1.20 34.00 0 0.13 0 0.02 77.4 0 0 0.009 0.000 0.000 0.014 0.000 0.000 0.000 0.015 0.006 0.000 0.000 0.000 0.043 0.025 0.001 0.005 0.006 0.001 0.000 0.005 0.001 0.000 0.128 0.004 0.128 36 -99.00 0 -99.00 0 -99 0 323 14 14 10.3 10.2 17.2925 51.5 0.287 246.1 32.3079 5.75 250.8 4.206370 241 0.34 0 0.36 0 0.347 0 1.60 -99.00 -99.00 0 0.13 0 0.02 77.3 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0 322 13 13 15.0 14.9 17.2662 51.3 0.306 222.0 32.3081 5.75 251.0 4.204137 241 0.01 0 0.36 0 0.362 0 1.80 -99.00 -99.00 0 0.13 0 0.02 77.2 0 0 0.008 0.000 0.000 0.015 0.000 0.000 0.000 0.016 0.007 0.000 0.000 0.001 0.044 0.025 0.001 0.002 0.007 0.000 0.000 0.006 0.001 0.000 0.133 0.004 0.133 6 -99.00 0 -99.00 0 -99 0 321 12 12 20.3 20.1 16.2673 49.9 0.409 154.7 32.3018 6.03 262.8 4.110915 241 0.10 0 0.40 0 0.383 0 1.60 1.70 49.00 6 0.18 0 0.03 74.1 36 36 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0 320 11 11 25.0 24.8 14.1851 46.2 0.909 116.5 32.3436 6.76 294.9 3.924445 241 0.27 0 0.40 0 0.412 0 2.40 -99.00 -99.00 0 0.30 6 0.05 66.9 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0 319 10 10 30.0 29.8 12.8393 40.5 2.331 53.9 32.3647 7.13 310.6 3.804668 241 0.09 0 0.69 0 0.442 0 3.40 3.90 120.00 0 0.60 0 0.22 56.6 0 0 0.098 0.000 0.007 0.104 0.000 0.000 0.013 0.087 0.038 0.013 0.015 0.007 0.338 0.051 0.004 0.006 0.013 0.007 0.008 0.109 0.012 0.000 0.555 0.012 0.555 6 -99.00 0 -99.00 0 -99 0 318 9 9 39.9 39.5 10.9074 43.0 3.089 16.8 32.3650 7.03 306.4 3.631730 241 2.27 0 3.51 0 0.602 0 2.40 -99.00 -99.00 0 0.90 0 0.40 61.3 0 0 0.185 0.000 0.013 0.190 0.000 0.000 0.059 0.142 0.123 0.020 0.015 0.007 0.522 0.041 0.011 0.004 0.033 0.010 0.013 0.180 0.025 0.000 0.971 0.013 0.971 6 -99.00 0 -99.00 0 -99 0 316 7 7 50.1 49.6 9.5404 49.0 2.068 5.2 32.3871 6.53 284.5 3.513224 153 5.59 0 5.88 0 0.804 0 1.40 -99.00 -99.00 0 0.78 6 0.32 71.8 0 0 0.163 0.000 0.009 0.123 0.000 0.000 0.040 0.087 0.122 0.013 0.007 0.002 0.401 0.021 0.004 0.002 0.022 0.006 0.009 0.106 0.032 0.000 0.721 0.010 0.721 6 -99.00 0 -99.00 0 -99 0 317 8 8 50.1 49.7 9.5374 49.0 2.064 5.2 32.3873 6.53 284.5 3.512985 241 -99.00 0 -99.00 0 -99.000 0 -99.00 -99.00 -99.00 0 -99.00 0 -99.00 71.8 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 66.00 0 68.10 0 -99 9 315 6 6 59.4 58.9 8.8938 52.1 1.173 2.1 32.4441 6.18 269.3 3.462275 241 8.78 0 8.81 0 0.956 0 -99.00 -99.00 -99.00 0 0.50 0 0.27 77.6 0 0 0.114 0.000 0.007 0.068 0.001 0.000 0.013 0.056 0.111 0.009 0.009 0.001 0.182 0.011 0.009 0.001 0.011 0.001 0.003 0.068 0.018 0.000 0.504 0.009 0.504 6 -99.00 0 -99.00 0 -99 0 314 5 5 74.8 74.2 8.3189 55.7 0.439 0.6 32.5121 6.00 261.2 3.419022 241 10.54 0 9.70 0 1.033 0 0.65 -99.00 -99.00 0 0.21 0 0.14 84.8 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0 313 4 4 100.4 99.6 8.1742 56.9 0.152 0.1 33.0335 4.54 197.8 3.456659 241 19.03 0 20.97 0 1.499 0 0.23 -99.00 -99.00 0 0.03 0 0.04 87.4 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0 312 3 3 150.3 149.0 8.3431 56.8 0.115 0.0 33.7070 2.83 123.2 3.537480 241 28.56 2 34.86 2 2.048 2 0.00 0.12 0.72 0 -99.00 0 -99.00 86.9 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0 311 2 2 200.5 198.7 7.6602 56.9 0.111 0.0 33.8861 2.41 104.9 3.494807 241 32.07 0 42.30 0 2.229 0 0.00 0.00 0.38 0 -99.00 0 -99.00 87.2 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0 310 1 1 300.6 297.9 6.5665 57.2 0.110 0.0 33.9354 2.21 96.2 3.405503 241 34.70 0 53.22 0 2.410 0 0.00 -99.00 -99.00 0 -99.00 0 -99.00 87.8 0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.00 0 -99.00 0 -99 0