*2023/08/17 16:42:06.89 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2018/09/21 15:48:51.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : C5815CA NUMBER OF CHANNELS : 36 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 760 783 2 Bottle_Number n/a 1 24 3 Bottle:Firing_Sequence n/a 1 24 4 Pressure decibar 2.8 299.9 5 Depth metres 2.7 297.1 6 Temperature:Secondary 'deg C (ITS90)' 4.0554 13.91 7 Transmissivity %/metre 49.3 59.3 8 Fluorescence:URU:Seapoint mg/m^3 0.95E-01 1.613 9 PAR uE/m^2/sec 0 53.4 10 Salinity:T1:C1 PSS-78 32.2665 33.838 11 Oxygen:Dissolved:SBE mL/L 1.97 7.01 12 Oxygen:Dissolved:SBE umol/kg 85.5 305.3 13 Conductivity:Secondary S/m 3.168871 3.891935 14 Number_of_bin_records n/a 38 241 15 Temperature:Draw 'deg C (ITS90)' 5 13.8 16 Oxygen:Dissolved mL/L 1.929 6.971 17 Oxygen:Dissolved umol/kg 83.9 303.5 18 Flag:Oxygen:Dissolved n/a 19 Nitrate_plus_Nitrite umol/L 7.64 39.76 20 Flag:Nitrate_plus_Nitrite n/a 21 Silicate umol/L 16.44 80.51 22 Flag:Silicate n/a 23 Phosphate umol/L 0.861 2.821 24 Flag:Phosphate n/a 25 Carbon:Dissolved:Organic uM 52.4 72.4 26 Flag:Carbon:Dissolved:Organic n/a 27 Carbon:Total:Organic uM 55 75 28 Flag:Carbon:Total:Organic n/a 29 CDOM:Available n/a 1 1 30 Flag:CDOM:Available n/a 31 Nitrogen:Particulate:Organic uM 2.75 17.93 32 Carbon:Particulate:Organic uM 11.97 85.96 33 Flag:Particulate:Organic n/a 34 Nitrogen:Particulate:Total uM 1.84 19.07 35 Carbon:Particulate:Total uM 9.11 87.65 36 Flag:Particulate:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 10 F ' ' 6 14 ' ' ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 8 F R4 2 28 0 ' ' 3 NQ C ' ' 29 -99 ' ' 4 I I 0 30 0 ' ' 3 NQ C ' ' 31 -99 ' ' 9 F R4 2 32 -99 ' ' 9 F R4 2 33 0 ' ' 3 NQ C ' ' 34 -99 ' ' 9 F R4 2 35 -99 ' ' 9 F R4 2 36 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2018-040 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : EX-C EVENT NUMBER : 96 LATITUDE : 50 18.49000 N ! (deg min) LONGITUDE : 144 22.46000 W ! (deg min) WATER DEPTH : 4129 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 5724 Conductivity ' ' 4434 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 5725 Conductivity:2 ' ' 4448 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3641 'Transmissometer:WET Labs C-Star' ' ' 1185DR PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 62355 $END $REMARKS Software Version Seasave V 7.26.7.107 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2019/01/10 08:08:32 3661 3661 CLEAN 5.2.3 2019/01/10 08:09:26 3661 3661 CLEAN 5.2.3 2019/01/10 11:22:49 3661 3661 ADDSAMP 3.6 2019/01/10 11:58:19 3661 3661 BINAVE 4.2 2019/01/15 08:18:31 3661 24 MERGE 3.5 2019/02/13 10:17:50 24 24 CLEAN 5.2.3 2019/02/13 10:19:01 24 24 CALIB 12.0 2019/02/13 10:19:46 24 24 SORT 3.6 2019/02/13 10:19:52 24 24 REMOVECH 8.2 2019/02/13 10:31:13 24 24 CHGUNITS 3.1.1 2019/02/13 10:36:08 24 24 CHGUNITS 3.1.1 2019/02/13 10:36:23 24 24 REORDER 1.3.1 2019/02/13 10:49:57 ? ? HDREDIT2 3.1.1 2019/03/25 11:41:24 ? ? SORT 3.6 2023/08/17 16:21:24 24 24 MERGE 3.6 2023/08/17 16:41:50 24 24 SORT 3.6 2023/08/17 16:42:02 24 24 HDREDIT2 3.2 2023/08/17 16:42:06 ? ? $END $REMARKS -CLEAN functions: 2019/01/10 08:09:02 20 Reset #RECS, MIN & MAX values in header. Set last 4 characters of file name to event -CLEAN functions: 2019/01/10 11:22:24 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2018-040\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2019/02/13 10:17:50 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.samavg Secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.mrgcln1s -------------------------------------------------------------------------- -MERGE *** Secondary file not found *** Primary file : P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.cst Secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.sal -MERGE *** Secondary file not found *** Primary file : P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.mrg1 Secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.chl -The following MERGE parameters were used: 2019/01/22 13:31:58 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw Primary file : P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.mrg2 Secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.oxy -The following MERGE parameters were used: 2019/01/22 13:32:05 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.mrg3 Secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.nut -MERGE *** Secondary file not found *** Primary file : P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.mrg4 Secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.dms -MERGE *** Secondary file not found *** Primary file : P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.mrg5 Secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.dmsp -CLEAN functions: 2019/02/13 09:46:53 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -SORT parameters: 2019/02/13 09:46:59 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2019/02/13 10:18:58 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -CALIB parameters: 2019/02/13 10:19:46 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2018-040\Processing\doc\2018-040-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Salinity:T1:C1 PSS-78 10 -0.2500000E-02 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 10 0.4770000E-01 0.1023700E+01 -SORT parameters: 2019/02/13 10:19:52 Sorted in ascending order of channel Press* -REMOVECH 2019/02/13 10:31:13 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2019/03/25 11:41:24 Applied edit header: P:\Cruise_Data_Processing\2018-040\Processing\doc\HYDRO\2018-040-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 16: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 19: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 21: Silicate [umol/L] Units: ==> umol/L Channel 23: Phosphate [umol/L] Units: ==> umol/L Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 12: Conductivity:Secondary [S/m] Format: F11.6 ==> F10.6 -SORT parameters: 2023/08/17 16:21:24 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2023/08/17 16:41:50 Merge Channel: Sample_Number Merge Scheme Used: 2: Add Secondary to Closest Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Organic [uM], Flag:Carbon:Dissolved:Organic [n/a], Carbon:Total:Organic [uM], Flag:Carbon:Total:Organic [n/a], CDOM:Available [n/a], Flag:CDOM:Available [n/a], Nitrogen:Particulate:Organic [uM], Carbon:Particulate:Organic [uM], Flag:Particulate:Organic [n/a], Nitrogen:Particulate:Total [uM], Carbon:Particulate:Total [uM], Flag:Particulate:Total [n/a] Primary file : D:\Telework\1a-IOS_Tasks\additions-carbon\2018-040\Processing\hydro\2018-040-0096. SORT Secondary file: D:\Telework\1a-IOS_Tasks\additions-carbon\2018-040\Processing\hydro\2018-040-0096. car 13 secondary records matched to primary records. -SORT parameters: 2023/08/17 16:42:02 Sorted in ascending order of channel Pressure [decibar] -HEADER EDITS: 2023/08/17 16:42:06 Channel 18: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 20: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 22: Flag:Silicate [n/a] Units: ==> n/a Channel 24: Flag:Phosphate [n/a] Units: ==> n/a Channel 25: Carbon:Dissolved:Organic [uM] Format: F7.2 ==> F8.2 Channel 27: Carbon:Total:Organic [uM] Format: F7.2 ==> F8.2 Channel 29: CDOM:Available [n/a] Format: I3 ==> I4 Channel 31: Nitrogen:Particulate:Organic [uM] Format: F7.2 ==> F9.2 Channel 34: Nitrogen:Particulate:Total [uM] Format: F7.2 ==> F9.2 Channel 35: Carbon:Particulate:Total [uM] Format: F7.2 ==> F9.2 $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2018-040\2018-040-0096.hex Software Version Seasave V 7.26.7.107 Temperature SN = 5724 Conductivity SN = 4434 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Sep 21 2018 15:52:29 NMEA Latitude = 50 18.49 N NMEA Longitude = 144 22.46 W NMEA UTC (Time) = Sep 21 2018 15:48:51 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Tully: 2018-040 Station: EX-C Depth: 4129 Chemistry cast System UTC = Sep 21 2018 15:52:29 # nquan = 20 # nvalues = 3661 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = altM: Altimeter [m] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Sep 21 2018 15:48:51 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 5724 # 02-Sep-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.37917897e-003 # 6.40303272e-004 # 2.26752184e-005 # 2.12320992e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 4434 # 06-Sep-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.81051120e+000 # 1.71330631e+000 # -1.27234132e-003 # 1.93420672e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0585 # 18-Sep-17 # -3.951550e+004 # -4.415130e-001 # 1.282560e-002 # 3.560600e-002 # 0.000000e+000 # 3.030045e+001 # -4.415690e-004 # 4.342710e-006 # 1.736800e-009 # 0.99993995 # -2.10363 # 0.000000e+000 # 1.288270e-002 # -8.164490e+000 # # # # # # 5725 # 02-Sep-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38067653e-003 # 6.41110842e-004 # 2.28044900e-005 # 2.13008714e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 4448 # 06-Sep-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.85435250e+000 # 1.66702837e+000 # -3.13982229e-003 # 3.51172336e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0997 # 02-Sep-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 3.9659e-001 # -0.6998 # -3.9462e-003 # 1.8647e-004 # -3.0185e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6200e-002 # 2.1600 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3641 # # # 2 # 0.000 # # # # # # 1185DR # 2017 # 19.4021 # -1.1059 # 0.250 # # # # # # # # # 70613 # 03/21/16 # 1.00000000 # 0.00000000 # 11876484560.57000000 # 1.00000000 # -0.08460000 # # # # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # datcnv_date = Jan 09 2019 16:47:27, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2018-040\RAW\CTD\2018-040-0096.hex P:\Cr uise_Data_Processing\2018-040\Processing\doc\2018-040-ctd2.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.mrgcln1s -------------------------------------------------------------------------- Comments from secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.oxy --------------------------------------------------------------------- Sample_Number 764: OXY-1: Sample over-titrated. Endpoint was very late on first titration. Sample_Number 770: OXY: Sample over-titrated. Endpoint late on first titration. Comments from secondary file: P:\Cruise_Data_Processing\2018-040\Processing\hydro\2018-040-0096.nut --------------------------------------------------------------------- Sample_Number 768: SIL: Bad data due to analysis problems Sample_Number 770: SIL: Bad data due to analysis problems Sample_Number 772: SIL: Bad data due to analysis problems Sample_Number 774: SIL: Bad data due to analysis problems Sample_Number 776: SIL: Bad data due to analysis problems Sample_Number 778: SIL: Bad data due to analysis problems Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~6 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.02-4.76ug/l in 152 samples. Average %CV for this cruise was 4.06% with 2 out of 42 duplicate pairs having a CV>10% and 0 out of 42 duplicate pairs having a CV>30%. Our average dataset %CV is 3.73% for 2013 - 2017 so the overall quality of this dataset is very good. For details see worksheet “CV%” in file QF2018-040CHL*.xls. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2018-040OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. 14 samples were analyzed at the Institute of Ocean Sciences in a temperature- controlled lab on a Guildline 8400B Salinometer (#68572) about 4 weeks after collection. The salinometer then malfunctioned so the remainder of the samples were analyzed off-site at AML using another Guildline 8400B Salinometer. Those samples were analyzed between 61 and 76 days after collection. No details are available regarding the conditions under which the samples were analyzed at AML or the condition of the instrument itself. All samples analyzed on instrument #68572 are flagged 2 with a comment. For details including a duplicate analysis, see document QF2018-040SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2018-040nuts*.xls. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100 deg C (with a dewar containing boiling water) onto a Choromasorb 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. For more detail see file "2018-040DMS report.doc" and for data and duplicate analysis see "DMS summary (2018-040).xls." The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.1nmol/L. DMSP-D: 20-75mL of seawater is drained from the niskin into a magnetic filtration funnel containing a 0.7 µM GF/F filter. The first 3.5 mL from the funnel is collected in a polypropylene tube containing 50µL of H2SO4 (50%). A new funnel and filter are used for each sample. DMPS-T: 3.5 mL of seawater is collected directly from the Niskin into a polypropylene tube containing 50µL of H2SO4 (50%) DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. For details on analysis and raw data, see document "2018-40 dmsp QF summary.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2018-040_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: D:\Telework\1a-IOS_Tasks\additions-carbon\2018-040\Processing\hydro\2018-040-0096.car --------------------------------------------------------------------------- Sample_Number 761: DOC: duplicate planned for 765 but taken at 761: TOC supposed to be duplicate, only one reported. Sample_Number 765: DOC & TOC: Values not reported Sample_Number 767: DOC & TOC: Values not reported Sample_Number 769: DOC & TOC: Values not reported Sample_Number 771: DOC & TOC: Values not reported Sample_Number 781: TOC: bad value. Sample_Number 783: DOC & TOC: Values not reported *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.25E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.477E-01 1.0237) $END !-1-- 2- 3- --4--- --5--- ---6---- --7-- ---8--- --9--- ---10--- --11-- --12- ----13--- -14- --15- ---16-- --17- 18 --19-- 20 --21-- 22 ---23-- 24 ---25-- 26 ---27-- 28 -29 30 ---31--- ---32--- 33 ---34--- ---35--- 36 !Samp Bo Bo Pressu Depth Temperat Trans Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Carbon: Fl Carbon: Fl CDO Fl Nitrogen Carbon: Fl Nitrogen Carbon: Fl !le_ tt tt re ure: missi cence: :T1:C1 : n: ity: er_o ratur Dissolv n: ag e_ ag te ag te ag Dissolv ag Total: ag M: ag : Particul ag : Particul ag !Numb ~u ~u Secondar vity URU: Dissol Disso Secondary ~bin e: ed Disso ~o plus_ ~t ~i ~p ed: ~g Organic ~g Ava ~l Particul ate: ~g Particul ate: ~T !er mb en y Seapoin ved: lved: _rec Draw lved lv Nitrit ri ca ha Organic an an ila ab ate: Organic an ate: Total ot ! er ce t SBE SBE ords ed e te te te ic ic ble le Organic ic Total al !---- -- -- ------ ------ -------- ----- ------- ------ -------- ------ ----- --------- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- ------- -- ------- -- --- -- -------- -------- -- -------- -------- -- *END OF HEADER 783 24 24 2.8 2.7 13.9042 49.3 1.550 53.4 32.2703 6.16 268.6 3.891131 241 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 9 -99.00 9 1 0 -99.00 -99.00 0 -99.00 -99.00 0 781 22 22 5.3 5.2 13.9100 49.4 1.550 35.8 32.2701 6.16 268.5 3.891742 110 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 69.40 0 -99.00 5 1 0 17.93 85.96 0 18.29 87.65 0 782 23 23 5.3 5.3 13.9086 49.4 1.545 35.7 32.2701 6.14 267.5 3.891630 241 13.8 6.114 266.5 0 7.64 0 16.44 0 0.861 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 779 20 20 10.4 10.3 13.9064 49.4 1.595 20.9 32.2697 6.09 265.4 3.891596 44 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 72.40 0 73.20 0 1 0 17.53 80.62 0 18.14 83.11 0 780 21 21 10.5 10.4 13.9064 49.3 1.613 21.0 32.2697 6.11 266.6 3.891599 241 13.7 6.113 266.5 0 7.83 0 16.49 0 0.870 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 778 19 19 25.6 25.4 13.9061 49.3 1.600 7.1 32.2672 6.11 266.2 3.891935 241 13.6 6.109 266.3 0 7.76 0 -99.00 5 0.871 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 777 18 18 25.7 25.4 13.9032 49.3 1.596 7.0 32.2665 6.11 266.2 3.891594 43 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 67.90 0 75.00 0 1 6 17.59 81.15 0 19.07 85.49 0 776 17 17 50.4 49.9 7.8602 54.2 1.290 1.3 32.4628 7.01 305.3 3.374295 241 8.1 6.971 303.5 0 11.44 0 -99.00 5 1.145 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 775 16 16 50.7 50.2 7.8534 54.3 1.272 1.3 32.4627 7.01 305.1 3.373697 45 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 64.70 0 65.60 0 1 0 10.97 49.47 0 9.14 43.98 0 773 14 14 75.7 75.1 6.3685 57.6 0.616 0.2 32.5625 6.90 300.4 3.255313 47 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 62.20 0 66.50 0 1 0 5.81 23.59 0 4.73 21.41 0 774 15 15 75.8 75.2 6.3695 57.6 0.615 0.2 32.5625 6.90 300.3 3.255409 241 6.9 6.868 299.0 6 15.91 0 -99.00 5 1.396 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 772 13 13 101.2 100.3 5.5493 58.6 0.353 0.1 32.7767 6.28 273.3 3.205009 241 6.3 6.237 271.4 0 19.99 0 -99.00 5 1.603 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 771 12 12 101.5 100.6 5.5492 58.6 0.348 0.0 32.7768 6.29 273.6 3.205028 38 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 9 -99.00 9 1 0 4.14 15.52 0 3.79 15.36 0 770 11 11 126.2 125.1 5.1196 59.0 0.182 0.0 33.2282 5.17 224.9 3.208592 241 5.9 5.164 224.7 2 25.43 0 -99.00 5 1.869 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 769 10 10 126.6 125.4 5.1171 59.0 0.189 0.0 33.2327 5.17 224.8 3.208788 38 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 9 -99.00 9 1 0 5.15 18.71 0 3.44 14.91 0 768 9 9 150.0 148.6 4.6893 59.1 0.125 0.0 33.5248 4.27 185.6 3.197959 241 5.6 4.288 186.5 0 30.12 0 -99.00 5 2.127 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 767 8 8 150.5 149.1 4.6888 59.1 0.125 0.0 33.5272 4.26 185.1 3.198143 40 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 9 -99.00 9 1 0 3.35 16.09 0 2.91 11.92 0 765 6 6 175.6 174.1 4.6976 59.2 0.107 0.0 33.6643 3.80 165.4 3.211835 42 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 -99.00 9 -99.00 9 1 0 3.50 13.33 0 3.04 17.24 0 766 7 7 176.0 174.4 4.7023 59.2 0.109 0.0 33.6650 3.81 165.7 3.212320 241 5.6 3.802 165.3 0 31.45 6 53.85 6 2.244 6 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 763 4 4 200.7 198.8 4.3127 59.1 0.100 0.0 33.6882 3.39 147.4 3.181425 41 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 61.30 0 60.60 0 1 0 3.31 12.47 0 3.80 10.62 0 764 5 5 200.9 199.0 4.3136 59.1 0.101 0.0 33.6881 3.39 147.4 3.181517 241 5.3 3.390 147.4 26 33.98 0 60.65 0 2.403 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 761 2 2 250.0 247.7 4.0695 59.3 0.098 0.0 33.7637 2.59 112.4 3.168871 40 -99.0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 52.40 26 55.00 2 1 0 3.68 12.65 0 3.18 11.82 0 762 3 3 250.4 248.1 4.0700 59.3 0.097 0.0 33.7639 2.59 112.4 3.168949 241 5.0 2.581 112.2 0 29.47 0 66.44 0 2.658 0 -99.00 -99.00 -99 -99.00 -99.00 -99.00 -99.00 760 1 1 299.9 297.1 4.0554 59.3 0.095 0.0 33.8380 1.97 85.5 3.176146 241 5.2 1.929 83.9 0 39.76 0 80.51 0 2.821 0 55.10 0 56.50 0 1 0 2.75 11.97 0 1.84 9.11 0