*2023/03/28 10:09:15.09 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2018/11/22 07:26:40.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 14 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 9BFB5732 NUMBER OF CHANNELS : 59 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 10 23 2 Bottle_Number n/a 1 14 3 Bottle:Firing_Sequence n/a 1 14 4 Pressure decibar 2 237.8 5 Depth metres 2 235.7 6 Temperature:Primary 'deg C (ITS90)' 9.0293 9.5579 7 Conductivity:Primary S/m 3.288682 3.460471 8 Transmissivity %/metre 34.4 45.7 9 Fluorescence:URU:Seapoint mg/m^3 0.159 0.349 10 PAR uE/m^2/sec 0 4.8 11 PAR:Reference uE/m^2/sec 8 8.6 12 pH:SBE:Nominal n/a 8.54 8.59 13 Salinity:T0:C0 PSS-78 30.0986 32.2172 14 Oxygen:Dissolved:SBE mL/L 3.07 4.16 15 Oxygen:Dissolved:SBE umol/kg 133.6 181.4 16 Number_of_bin_records n/a 241 241 17 Temperature:Draw 'deg C (ITS90)' 8.9 11.1 18 Salinity:Bottle PSS-78 32.0157 32.0157 19 Flag:Salinity:Bottle n/a 20 Oxygen:Dissolved mL/L 3.053 4.11 21 Oxygen:Dissolved umol/kg 133 179.4 22 Flag:Oxygen:Dissolved n/a 23 Nitrate_plus_Nitrite umol/L 26.52 29 24 Flag:Nitrate_plus_Nitrite n/a 25 Silicate umol/L 49.88 51.01 26 Flag:Silicate n/a 27 Phosphate umol/L 2.262 2.387 28 Flag:Phosphate n/a 29 Chlorophyll:Extracted mg/m^3 0.52 0.59 30 Flag:Chlorophyll:Extracted n/a 31 Phaeo-Pigment:Extracted mg/m^3 0.44 0.62 32 HPLC:Chl-c3 mg/m^3 0.13E-01 0.13E-01 33 HPLC:Chlide-a mg/m^3 0.14E-01 0.14E-01 34 HPLC:MgDVP mg/m^3 0.7E-02 0.7E-02 35 HPLC:Chl-c2 mg/m^3 0.47E-01 0.47E-01 36 HPLC:Chl-c1 mg/m^3 0.17E-01 0.17E-01 37 HPLC:Me-chlide mg/m^3 0 0 38 HPLC:Peri mg/m^3 0.6E-02 0.6E-02 39 HPLC:Pheide-a mg/m^3 0 0 40 HPLC:But-fuco mg/m^3 0.3E-02 0.3E-02 41 HPLC:Fuco mg/m^3 0.219 0.219 42 HPLC:Neo mg/m^3 0.7E-02 0.7E-02 43 HPLC:Pras mg/m^3 0.11E-01 0.11E-01 44 HPLC:Viola mg/m^3 0.2E-02 0.2E-02 45 HPLC:Hex-fuco mg/m^3 0 0 46 HPLC:Diadino mg/m^3 0.14E-01 0.14E-01 47 HPLC:Allo mg/m^3 0.23E-01 0.23E-01 48 HPLC:Diato mg/m^3 0 0 49 HPLC:Zea mg/m^3 0 0 50 HPLC:Lut mg/m^3 0.1E-02 0.1E-02 51 HPLC:Gyr-de mg/m^3 0 0 52 HPLC:Chl-b mg/m^3 0.4E-01 0.4E-01 53 HPLC:C2mgdg mg/m^3 0 0 54 HPLC:DVChl-a mg/m^3 0 0 55 HPLC:Chl-a mg/m^3 0.498 0.498 56 HPLC:Phe mg/m^3 0 0 57 HPLC:B-Car mg/m^3 0.1E-01 0.1E-01 58 HPLC:TChl-a mg/m^3 0.512 0.512 59 Flag:HPLC n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 10 F ' ' 6 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 7 F ' ' 1 11 -99 ' ' 7 F ' ' 1 12 -99 ' ' 8 F ' ' 3 13 -99 ' ' 9 F ' ' 4 14 -99 ' ' 7 F ' ' 2 15 -99 ' ' 6 F ' ' 1 16 -99 ' ' 5 I I 0 17 -99 ' ' 6 F R4 1 18 -99 ' ' 9 F R4 4 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 8 F R4 3 21 -99 ' ' 6 F ' ' 1 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 8 F R4 3 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 3 NQ C ' ' 31 -99 ' ' 7 F R4 2 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 8 F R4 3 57 -99 ' ' 8 F R4 3 58 -99 ' ' 8 F R4 3 59 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2018-032 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 59 EVENT NUMBER : 4 LATITUDE : 48 37.90000 N ! (deg min) LONGITUDE : 123 14.41000 W ! (deg min) WATER DEPTH : 240 ALTIMETER (M) : 4.84 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0941 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 1763 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 5013 Conductivity:2 ' ' 3394 'Oxygen:SBE 43' ' ' 3234 Fluorometer:Seapoint ' ' 3685 'Transmissometer:WET Labs C-Star' ' ' 953DR pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' '4565 QSP200L4S' Altimeter ' ' ' ' Unavailable ' ' ' ' 'SPAR/Surface Irradiance' ' ' 20518 $END $REMARKS Software Version Seasave V 7.26.2.13 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2019/03/08 08:20:41 3374 3374 CLEAN 5.2.3 2019/03/08 08:21:08 3374 3374 ADDSAMP 3.6 2019/03/12 10:28:00 3374 3374 BINAVE 4.2 2019/03/12 10:29:07 3374 14 MERGE 3.5 2019/03/12 11:35:19 14 14 CLEAN 5.2.3 2019/03/12 11:35:23 14 14 CALIB 12.0 2019/04/02 14:26:32 14 14 CALIB 12.0 2019/04/02 14:31:41 14 14 SORT 3.6 2019/04/02 16:56:03 14 14 REMOVECH 8.2 2019/04/02 16:57:18 14 14 CHGUNITS 3.1.1 2019/04/02 16:58:22 14 14 CHGUNITS 3.1.1 2019/04/02 16:58:39 14 14 REORDER 1.3.1 2019/04/02 16:58:54 ? ? HDREDIT2 3.1.1 2019/04/03 08:45:18 ? ? SORT 3.6 2023/03/27 11:21:56 14 14 REORDER 1.3.1 2023/03/27 11:22:11 ? ? MERGE 3.6 2023/03/27 11:31:28 14 14 SORT 3.6 2023/03/27 11:31:36 14 14 CLEAN 5.3 2023/03/27 11:31:42 14 14 HDREDIT2 3.2 2023/03/27 11:32:03 ? ? HDREDIT2 3.2 2023/03/27 11:32:29 ? ? CLEAN 5.3 2023/03/28 10:09:15 14 14 $END $REMARKS -CLEAN functions: 2019/03/08 08:21:07 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2018-032\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2019/03/12 11:35:19 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Sample_number, Bottle_Number, Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, Temperature:Draw Primary file : P:\Cruise_Data_Processing\2018-032\Processing\hydro\2018-032-0004.samavg Secondary file: P:\Cruise_Data_Processing\2018-032\Processing\hydro\2018-032-0004.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2018-032\Processing\hydro\2018-032-0004.mrgcln1s -------------------------------------------------------------------------- -SORT parameters: 2019/03/12 11:35:13 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2019/03/12 11:35:23 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Delete Empty Channels: 0 deleted. Set event to last 4 characters of file name -CALIB parameters: 2019/04/02 14:26:32 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2018-032\Processing\doc\2018-032-recal-sal-bot1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 26 Salinity:Bottle 10 -0.3976000E+00 0.1011350E+01 -CALIB parameters: 2019/04/02 14:31:40 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2018-032\Processing\doc\2018-032-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Salinity:T0:C0 PSS-78 10 0.2000000E-02 0.1000000E+01 21 Oxygen:Dissolved:SBE mL/L 10 0.9600000E-02 0.1032400E+01 -SORT parameters: 2019/04/02 16:56:03 Sorted in ascending order of channel Press* -REMOVECH 2019/04/02 16:57:18 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2019/04/03 08:45:18 Applied edit header: P:\Cruise_Data_Processing\2018-032\Processing\doc\HYDRO\2018-032-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 17: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 18: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 19: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 20: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 22: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 23: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 26: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 28: Silicate [umol/L] Units: ==> umol/L Channel 30: Phosphate [umol/L] Units: ==> umol/L Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 14: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 -SORT parameters: 2023/03/27 11:21:56 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2023/03/27 11:31:28 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Gyr-de [ ], HPLC:Chl-b [ ], HPLC:C2mgdg [ ], HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [] Primary file : C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-032\Processing\IOS\ 2018-032-0004.che2 Secondary file: C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-032\Processing\IOS\ 2018-032-0004.hplc 1 secondary records matched to primary records. -SORT parameters: 2023/03/27 11:31:36 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2023/03/27 11:31:42 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2023/03/27 11:32:03 Applied edit header: C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-032\ Processing\DOC\2018-032-hdr1.txt Channel 32: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 57: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 58: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 59: Flag:HPLC [n/a] Units: ==> n/a Channel 51: HPLC:Gyr-de [mg/m^3] Units: ==> mg/m^3 Channel 22: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 24: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 26: Flag:Silicate [n/a] Units: ==> n/a Channel 28: Flag:Phosphate [n/a] Units: ==> n/a Channel 30: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a -HEADER EDITS: 2023/03/27 11:32:29 Applied edit header: C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-032\ Processing\DOC\2018-032-hdr2.txt -CLEAN functions: 2023/03/28 10:09:15 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2018-032\2018-032-0004.hex Software Version Seasave V 7.26.2.13 Temperature SN = 2023 Conductivity SN = 1763 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Nov 22 2018 07:28:53 NMEA Latitude = 48 37.90 N NMEA Longitude = 123 14.41 W NMEA UTC (Time) = Nov 22 2018 07:26:40 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 0 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> VECTOR: 2018-032 Station: 59 Depth: 240 System UTC = Nov 22 2018 07:28:53 # nquan = 22 # nvalues = 3374 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = spar: SPAR/Surface Irradiance # name 14 = ph: pH # name 15 = dz/dtM: Descent Rate [m/s] # name 16 = altM: Altimeter [m] # name 17 = pumps: Pump Status # name 18 = sal00: Salinity, Practical [PSU] # name 19 = sal11: Salinity, Practical, 2 [PSU] # name 20 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 21 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Nov 22 2018 07:26:40 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 2023 # 06-Sep-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.11048941e-003 # 6.24651386e-004 # 1.97786660e-005 # 1.89356115e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1763 # 06-Sep-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.22550040e+000 # 5.08226275e-001 # -5.91965887e-004 # 5.42751175e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0506 # 13-Mar-18 # -4.957807e+004 # -1.280011e+000 # 1.485710e-002 # 4.021200e-002 # 0.000000e+000 # 3.037224e+001 # -6.696188e-004 # 3.897170e-006 # 3.287590e-009 # 0.99994571 # 0.01092 # 0.000000e+000 # 1.280810e-002 # -9.210198e+000 # # # # # # 5013 # 02-Sep-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36842897e-003 # 6.37960145e-004 # 2.10239596e-005 # 1.77320718e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3394 # 06-Sep-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.62774811e+000 # 1.47740759e+000 # -2.06393864e-003 # 2.42854326e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 3234 # 16-Feb-18 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.5104e-001 # -0.5533 # -4.1134e-003 # 1.8160e-004 # -2.7648e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.2200 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # # # 1 # 0.000 # # # # # # 953DR # Aug 9th 2017 # 19.2982 # -1.1000 # 0.250 # # # # # # # # # 0692 # 02-Mar-18 # 4.6399 # 2.5177 # # # # # # 4565 QSP200L4S # 16-Mar-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # # # 15.000 # 0.000 # # # # # # # # # # # # 20518 # 21-MAR-2016 # 1627.06600000 # 1.00000000 # # # # datcnv_date = Jan 04 2019 16:33:45, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2018-032\RAW\CTD\2018-032-0004.hex P:\Cr uise_Data_Processing\2018-032\Processing\doc\2018-032-ctd.XMLCON # datcnv_ox_hysteresis_correction = no # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2018-032\Processing\hydro\2018-032-0004.mrgcln1s -------------------------------------------------------------------------- Comments from secondary file: P:\Cruise_Data_Processing\2018-032\Processing\hydro\2018-032-0004.chl --------------------------------------------------------------------- Sample_Number 23: CHL: no sample received All Salinity:Bottle samples: Values have been flagged 3 due to problems outlined below in the Analysis methods. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~1 week after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.07 - 30.42 ug/l in 103 samples. Average %CV for this cruise was 3.58 with 2 out of 26 duplicate pairs having a CV>10% and 0 duplicate pairs having a CV>30%. Our average dataset %CV is 3.73% for 2013 - 2017 so the overall quality of this dataset is excellent. For details see worksheet “CV%” in file QF2018-32CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 weeks after collection The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2018-032HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2018-32OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 66-71 days after collection. There were no duplicates. For details see document QF2018-32SAL*.xls. NOTE: Large errors due to poor calibration of the Autosal were discovered after analysis. The values in this file have been recalibrated using a linear correction based on tests analyzing duplicates on two different Autosals. For details see documents "Salinometer-68572 study_20Mar2019.xlsx" and "March 2019 Salinity Linearity and Dilution Test Methods.docx." Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document NUTS_QF2018-32*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence:URU:Seapoint, pH:SBE, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. There was a problem with the salinometer used to analyze samples for this cruise. Tests were run and are described in document “Salinometer-68572 study_20Mar2019.xlsx”. They established a linear correction to be applied to all salinity analyzed on salinometer #68572 between January and March 2019. Based on those corrected bottle values and the histor of the sensors, the CTD salinity values are believed to be within +/-0.004psu. The fluorescence values look lower compared to extracted chlorophyll than usual, but it is hard to judge this since most chlorophyll values were very low. When the fluorometer plumbin was cleaned in spring 2019, a small obstruction at the intake was found. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see document: 2018-032_Processing_Report.doc. -------------------------------------------------------------------------------------- Comments from secondary file: C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-032\Processing\IOS\2018-032-0004. hplc --------------------------------------------------------------------------- Sample_Number 23: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:Bottle ' ' 10 -99 () (-0.3976 1.01135) Salinity:T0:C0 PSS-78 10 -99 () (0.2E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.96E-02 1.0324) $END !-1-- 2- 3- --4--- --5--- ---6---- ----7---- --8-- ---9--- --10-- --11-- ---12-- ---13--- --14-- --15- -16- --17- ---18--- 19 ---20-- --21- 22 --23-- 24 --25-- 26 ---27-- 28 --29-- 30 --31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- ---56-- ---57-- ---58-- 59 !Samp Bo Bo Pressu Depth Temperat Conductiv Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ tt tt re ure: ity: missi cence: Refere Nominal :T0:C0 : n: er_o ratur :Bottle ag Dissolv n: ag e_ ag te ag te ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Gyr-de Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb ~u ~u Primary Primary vity URU: nce Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er mb en Seapoin ved: lved: _rec Draw tt lved lv Nitrit ri ca ha ted ct Extrac HP ! er ce t SBE SBE ords le ed e te te te ed ted LC !---- -- -- ------ ------ -------- --------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 23 14 14 2.0 2.0 9.5579 3.288682 40.1 0.343 4.8 8.0 8.590 30.0986 4.16 181.4 241 11.1 -99.0000 0 4.110 179.4 0 26.52 0 51.00 0 2.262 0 -99.00 9 -99.00 0.013 0.014 0.007 0.047 0.017 0.000 0.006 0.000 0.003 0.219 0.007 0.011 0.002 0.000 0.014 0.023 0.000 0.000 0.001 0.000 0.040 0.000 0.000 0.498 0.000 0.010 0.512 36 22 13 13 5.0 4.9 9.5477 3.293659 40.4 0.349 1.4 8.0 8.587 30.1564 4.10 178.7 241 10.1 -99.0000 0 4.085 178.2 0 26.60 0 51.01 0 2.290 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 21 12 12 10.0 9.9 9.5340 3.298224 40.8 0.343 0.2 8.0 8.586 30.2121 4.05 176.8 241 9.8 -99.0000 0 4.047 176.6 0 26.78 0 51.01 0 2.301 0 0.59 0 0.62 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 20 11 11 20.1 19.9 9.5145 3.302295 42.1 0.328 0.0 8.0 8.582 30.2657 4.02 175.2 241 9.6 -99.0000 0 4.019 175.3 0 26.90 0 50.90 0 2.306 0 0.52 6 0.44 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 19 10 10 30.0 29.7 9.5144 3.302930 41.9 0.314 0.0 8.0 8.582 30.2681 4.03 175.9 241 9.4 -99.0000 0 4.012 175.0 0 26.99 0 50.82 0 2.300 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 18 9 9 40.1 39.7 9.4814 3.312307 45.0 0.300 0.0 8.1 8.578 30.3870 3.99 174.1 241 9.3 -99.0000 0 3.973 173.3 0 27.37 0 50.95 0 2.301 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 17 8 8 50.0 49.6 9.4584 3.324043 45.7 0.293 0.0 8.1 8.577 30.5218 3.95 172.3 241 9.3 -99.0000 0 3.935 171.6 6 27.21 0 50.77 0 2.318 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 16 7 7 75.0 74.4 9.3863 3.350401 44.8 0.276 0.0 8.1 8.573 30.8416 3.86 168.2 241 9.2 -99.0000 0 3.848 167.8 0 27.50 6 50.53 6 2.321 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 15 6 6 100.0 99.1 9.2676 3.388133 44.2 0.231 0.0 8.0 8.559 31.3201 3.58 155.9 241 9.1 -99.0000 0 3.540 154.3 0 27.97 0 50.15 0 2.321 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 14 5 5 125.1 124.0 9.1751 3.414191 42.0 0.194 0.0 8.1 8.551 31.6584 3.36 146.5 241 9.0 -99.0000 0 3.346 145.8 0 28.35 6 50.00 6 2.319 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 13 4 4 150.4 149.1 9.1705 3.417360 41.5 0.190 0.0 8.4 8.548 31.6841 3.35 146.0 241 9.0 -99.0000 0 3.328 145.0 0 28.38 0 50.00 0 2.333 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 12 3 3 174.6 173.1 9.1337 3.428856 40.6 0.183 0.0 8.5 8.550 31.8247 3.28 142.7 241 9.0 -99.0000 0 3.258 141.9 6 28.66 0 49.99 0 2.350 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 11 2 2 201.2 199.4 9.0903 3.441938 38.4 0.170 0.0 8.6 8.546 31.9868 3.19 138.9 241 8.9 32.0157 3 3.168 138.0 0 28.61 0 49.91 0 2.387 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 10 1 1 237.8 235.7 9.0293 3.460471 34.4 0.159 0.0 8.6 8.540 32.2172 3.07 133.6 241 8.9 -99.0000 0 3.053 133.0 0 29.00 0 49.88 0 2.382 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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