*2019/01/02 13:29:19.93 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2018/08/17 19:15:01.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 8 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 9840749A NUMBER OF CHANNELS : 18 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 8 2 Bottle:Firing_Sequence n/a 1 8 3 Pressure decibar 2.194 150.272 4 Depth metres 2.176 148.943 5 Temperature:Primary 'deg C (ITS90)' 8.6562 16.2785 6 Transmissivity %/metre 15.4 52.6 7 Fluorescence:URU:Seapoint mg/m^3 0.111 4.489 8 PAR uE/m^2/sec 0 170.346 9 Salinity:T0:C0 PSS-78 29.6352 32.8718 10 Oxygen:Dissolved:SBE mL/L 0.965 6.658 11 Oxygen:Dissolved:SBE umol/kg 42 291 12 Conductivity:Primary S/m 3.481986 3.805629 13 Number_of_bin_records n/a 241 241 14 Sample_Number n/a 42 49 15 Temperature:Draw 'deg C (ITS90)' 9.2 17.1 16 Oxygen:Dissolved mL/L 0.922 6.668 17 Oxygen:Dissolved umol/kg 40.14251 291.4476 18 Flag:Oxygen:Dissolved ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 10 F ' ' 6 13 ' ' ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 0 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2018-025 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Moorings SCIENTIST : Spear D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI / Strait of Georgia STATION : EFF06 EVENT NUMBER : 16 LATITUDE : 49 1.83000 N ! (deg min) LONGITUDE : 125 9.17000 W ! (deg min) WATER DEPTH : 155 ALTIMETER (M) : 9.5 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4484 Conductivity ' ' 2128 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 4752 Conductivity:2 ' ' 2399 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3641 'Transmissometer:WET Labs C-Star' ' ' 1185DR PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 62355 $END $REMARKS Software Version Seasave V 7.26.7.107 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2018/12/04 16:33:16 1928 1928 CLEAN 5.2.3 2018/12/04 16:36:06 1928 1928 ADDSAMP 3.6 2018/12/05 11:28:41 1928 1928 BINAVE 4.2 2018/12/11 15:39:01 1928 8 MERGE 3.5 2018/12/11 15:39:26 8 8 CLEAN 5.2.3 2018/12/11 15:42:17 8 8 CALIB 12.0 2018/12/20 09:01:54 8 8 SORT 3.6 2018/12/21 12:59:37 8 8 REMOVECH 8.2 2019/01/02 12:58:59 8 8 CHGUNITS 3.1.1 2019/01/02 13:14:34 8 8 CHGUNITS 3.1.1 2019/01/02 13:21:12 8 8 REORDER 1.3.1 2019/01/02 13:22:42 ? ? HDREDIT2 3.1.1 2019/01/02 13:29:19 ? ? $END $REMARKS -CLEAN functions: 2018/12/04 16:36:03 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2018-025\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2018/12/11 15:39:26 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2018-025\Processing\hydro\2018-025-0016.samavg Secondary file: P:\Cruise_Data_Processing\2018-025\Processing\hydro\2018-025-0016.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2018-025\Processing\hydro\2018-025-0016.mrgcln1s -------------------------------------------------------------------------- -CLEAN functions: 2018/12/10 14:18:59 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2018/12/10 14:19:05 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2018/12/11 15:42:16 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -CALIB parameters: 2018/12/20 09:01:54 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2018-025\Processing\doc\2018-025-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T0:C0 PSS-78 10 0.1200000E-02 0.1000000E+01 18 Salinity:T1:C1 PSS-78 10 0.9200000E-02 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 10 0.4770000E-01 0.1027600E+01 -SORT parameters: 2018/12/21 12:59:37 Sorted in ascending order of channel Press* -REMOVECH 2019/01/02 12:58:59 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2019/01/02 13:29:19 Applied edit header: P:\Cruise_Data_Processing\2018-025\Processing\doc\HYDRO\2018-025-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 16: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 12: Conductivity:Primary [S/m] Format: F11.6 ==> F10.6 $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2018-025\2018-025-00016.hex Software Version Seasave V 7.26.7.107 Temperature SN = 4484 Conductivity SN = 2128 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Aug 17 2018 19:20:16 NMEA Latitude = 49 01.83 N NMEA Longitude = 125 09.17 W NMEA UTC (Time) = Aug 17 2018 19:15:01 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Tully: 2018-25 Station: EFF06 Depth: 150 System UTC = Aug 17 2018 19:20:16 # nquan = 20 # nvalues = 1928 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = altM: Altimeter [m] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Aug 17 2018 19:15:01 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4484 # 15-Feb-18 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39921216e-003 # 6.40123895e-004 # 2.12994091e-005 # 1.78931585e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2128 # 14-Sep-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02716519e+001 # 1.47416353e+000 # -5.26731026e-003 # 4.32020637e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0443 # 31-Aug-17 # -4.435292e+004 # -1.635794e-001 # 1.192740e-002 # 3.979900e-002 # 0.000000e+000 # 2.993627e+001 # -3.271008e-004 # 3.759160e-006 # 1.565300e-009 # 0.99987037 # -2.18884 # 0.000000e+000 # 1.282462e-002 # -8.599824e+000 # # # # # # 4752 # 02-Sep-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.35928268e-003 # 6.36988092e-004 # 2.10291075e-005 # 1.80213693e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2399 # 14-Sep-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.98905621e+000 # 1.49210202e+000 # 9.67601751e-005 # 7.96101898e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0997 # 02-Sep-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 3.9659e-001 # -0.6998 # -3.9462e-003 # 1.8647e-004 # -3.0185e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6300e-002 # 2.1600 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3641 # # # 2 # 0.000 # # # # # # 1185DR # 2017 # 19.4021 # -1.1059 # 0.250 # # # # # # # # # 70613 # 03/21/16 # 1.00000000 # 0.00000000 # 11876484560.57000000 # 1.00000000 # -0.08460000 # # # # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # datcnv_date = Dec 04 2018 16:03:50, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2018-025\RAW\CTD\2018-025-0016.hex P:\Cr uise_Data_Processing\2018-025\Processing\doc\2018-025-0443-ctd1.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2018-025\Processing\hydro\2018-025-0016.mrgcln1s -------------------------------------------------------------------------- Comments from secondary file: P:\Cruise_Data_Processing\2018-025\Processing\hydro\2018-025-0016.oxy --------------------------------------------------------------------- Sample_Number 42: OXY: Water seal evaporated or missing. Sample_Number 43: OXY: Water seal evaporated or missing. Sample_Number 44: OXY: Water seal evaporated or missing. Sample_Number 45: OXY: Water seal evaporated or missing. Several black particles inside sample. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~10 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.03-27.86ug/l in 141 samples. Average %CV for this cruise was 5.15% with 12 out of 141 duplicate pairs having a CV>10% and 0 duplicate pairs having a CV>30%. Our average dataset %CV is 3.73% for 2013 - 2017 so the overall quality of this dataset is good. For details see worksheet “CV%” in file QF2018-25CHL*.xls. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2018-25OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 10-30 days after collection. A precision study was not conducted as there were only 2 duplicate samples. For details see document QF2018-025SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2018-25nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2018-25 NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Conductivity, Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". For events #96 to #182 2 fluorometers were in use. The extra fluorometer has channel name Fluorescence:URU:Seapoint:2. It was attached to the rosette about half-way up. The sensor was not pumped and the data have not been filtered. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the CTD data processing see document: 2018-025_Processing_Report.doc. ------------------------------------------------------------------------------------ *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.12E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (0.92E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.477E-01 1.0276) $END !1- 2- --3--- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- ----12--- -13- -14- --15- ---16-- --17- 18 !Bo Bo Pressu Depth Temperat Trans Fluores PAR Salinity Oxygen Oxyge Conductiv Numb Samp Tempe Oxygen: Oxyge Fl !tt tt re ure: missi cence: :T0:C0 : n: ity: er_o le_ ratur Dissolv n: ag !~u ~u Primary vity URU: Dissol Disso Primary ~bin Numb e: ed Disso ~o !mb en Seapoin ved: lved: _rec er Draw lved lv !er ce t SBE SBE ords ed !-- -- ------ ------ -------- ----- ------- ------ -------- ------ ----- --------- ---- ---- ----- ------- ----- -- *END OF HEADER 8 8 2.2 2.2 16.2785 15.4 4.489 170.3 29.6352 6.66 291.0 3.805629 241 49 17.1 6.668 291.4 0 7 7 10.1 10.0 10.8804 44.4 1.320 6.2 31.7258 3.92 170.9 3.564213 241 48 11.0 3.644 158.8 0 6 6 19.9 19.8 10.0613 51.5 0.983 0.9 31.9971 3.25 141.7 3.520049 241 47 10.4 2.947 128.4 6 5 5 30.3 30.0 9.6362 52.6 0.593 0.2 32.2050 2.64 115.0 3.503691 241 46 10.1 2.652 115.5 0 4 4 50.4 50.0 8.8164 50.7 0.177 0.0 32.7176 1.23 53.7 3.481986 241 45 9.2 1.210 52.7 3 3 3 75.5 74.8 8.7038 48.2 0.131 0.0 32.8206 0.96 42.0 3.482965 241 44 9.3 0.922 40.1 3 2 2 99.8 99.0 8.6787 45.9 0.111 0.0 32.8413 1.15 50.2 3.483783 241 43 9.2 1.103 48.0 3 1 1 150.3 148.9 8.6562 42.7 0.111 0.0 32.8718 1.23 53.6 3.486873 241 42 9.2 1.173 51.1 3