*2023/03/28 09:45:51.25 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2018/02/26 22:03:10.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 733635FF NUMBER OF CHANNELS : 57 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 251 270 2 Bottle_Number n/a 1 20 3 Bottle:Firing_Sequence n/a 1 20 4 Pressure decibar 5.4 300.4 5 Depth metres 5.3 297.6 6 Temperature:Secondary 'deg C (ITS90)' 4.0137 5.9306 7 Conductivity:Secondary S/m 3.170275 3.20912 8 Transmissivity %/metre 48.7 55.2 9 Fluorescence:URU:Seapoint mg/m^3 0.72E-01 1.206 10 PAR uE/m^2/sec 0 196.8 11 Salinity:T1:C1 PSS-78 32.5027 33.8659 12 Oxygen:Dissolved:SBE mL/L 1.81 7.18 13 Oxygen:Dissolved:SBE umol/kg 78.6 312.6 14 Number_of_bin_records n/a 81 241 15 Nitrate_plus_Nitrite umol/L 14.55 39.22 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 21.32 82.32 18 Flag:Silicate n/a 19 Phosphate umol/L 1.316 2.801 20 Flag:Phosphate n/a 21 Dimethyl_Sulphide nmol/L 0 0.59 22 Flag:Dimethyl_Sulphide n/a 23 Dimethylsulfoniopropionate_Dissolved nmol/L 0 0 24 Flag:Dimethylsulfoniopropionate_Dissolved n/a 25 Dimethylsulfoniopropionate_Total nmol/L 0.39 23.5 26 Flag:Dimethylsulfoniopropionate_Total n/a 27 Chlorophyll:Extracted mg/m^3 0.33 0.44 28 Flag:Chlorophyll:Extracted n/a 29 Phaeo-Pigment:Extracted mg/m^3 0.1 0.14 30 HPLC:Chl-c3 mg/m^3 0.71E-01 0.86E-01 31 HPLC:Chlide-a mg/m^3 0 0 32 HPLC:MgDVP mg/m^3 0.2E-02 0.6E-02 33 HPLC:Chl-c2 mg/m^3 0.61E-01 0.76E-01 34 HPLC:Chl-c1 mg/m^3 0 0.4E-02 35 HPLC:Me-chlide mg/m^3 0.8E-02 0.18E-01 36 HPLC:Peri mg/m^3 0 0.7E-02 37 HPLC:Pheide-a mg/m^3 0 0 38 HPLC:But-fuco mg/m^3 0.68E-01 0.79E-01 39 HPLC:Fuco mg/m^3 0.113 0.13 40 HPLC:Neo mg/m^3 0 0.6E-02 41 HPLC:Pras mg/m^3 0 0 42 HPLC:Viola mg/m^3 0 0 43 HPLC:Hex-fuco mg/m^3 0.131 0.149 44 HPLC:Diadino mg/m^3 0.21E-01 0.34E-01 45 HPLC:Allo mg/m^3 0 0 46 HPLC:Diato mg/m^3 0 0.3E-02 47 HPLC:Zea mg/m^3 0 0 48 HPLC:Lut mg/m^3 0 0 49 HPLC:Gyr-de mg/m^3 0 0.2E-02 50 HPLC:Chl-b mg/m^3 0.16E-01 0.27E-01 51 HPLC:C2mgdg mg/m^3 0.4E-02 0.8E-02 52 HPLC:DVChl-a mg/m^3 0 0 53 HPLC:Chl-a mg/m^3 0.406 0.462 54 HPLC:Phe mg/m^3 0 0 55 HPLC:B-Car mg/m^3 0.2E-02 0.6E-02 56 HPLC:TChl-a mg/m^3 0.418 0.472 57 Flag:HPLC n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 10 F ' ' 6 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 7 F ' ' 1 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 5 I I 0 15 -99 ' ' 7 F R4 2 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 8 F R4 3 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 8 F R4 3 57 -99 ' ' 3 NQ C ' ' $END $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment 3 = Questionable measurement (Probably Good) 4 = Poor measurement (Probably Bad) 5 = Measurement not reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2018-01 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : Sir Wilfrid Laurier *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P26 EVENT NUMBER : 56 LATITUDE : 50 0.03000 N ! (deg min) LONGITUDE : 144 59.98000 W ! (deg min) WATER DEPTH : 4250 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2710 Conductivity ' ' 2128 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 4752 Conductivity:2 ' ' 2399 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3641 'Transmissometer:WET Labs C-Star' ' ' 1185DR PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 62355 $END $REMARKS Software Version Seasave V 7.26.2.13 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 4.2.2 2018/04/19 10:03:08 4450 4450 CLEAN 5.2.2 2018/04/19 10:03:26 4450 4450 ADDSAMP 3.6 2018/04/19 10:06:47 4450 4450 BINAVE 4.2 2018/04/19 10:10:34 4450 20 MERGE 3.5 2018/05/15 08:45:59 20 20 CLEAN 5.2.2 2018/05/15 08:46:10 20 20 CALIB 11.9 2018/06/04 14:56:27 20 20 SORT 3.6 2018/06/04 14:56:53 20 20 REMOVECH 8.2 2018/06/04 15:13:51 20 20 CHGUNITS 3.1.1 2018/06/04 15:14:34 20 20 CHGUNITS 3.1.1 2018/06/04 15:14:49 20 20 REORDER 1.3.1 2018/06/04 15:16:20 ? ? HDREDIT2 3.1.1 2018/06/27 08:54:18 ? ? HDREDIT2 3.1.1 2019/11/27 11:42:33 ? ? SORT 3.6 2019/11/27 12:00:32 20 20 HDREDIT2 3.1.1 2019/11/27 12:00:47 ? ? MERGE 3.5 2019/11/27 12:01:00 20 20 SORT 3.6 2019/11/27 12:01:36 20 20 HDREDIT2 3.1.1 2019/11/27 12:01:53 ? ? CLEAN 5.2.3 2020/02/06 16:21:38 20 20 HDREDIT2 3.2 2020/02/06 16:21:54 ? ? SORT 3.6 2023/03/26 11:46:07 20 20 REORDER 1.3.1 2023/03/26 11:53:24 ? ? MERGE 3.6 2023/03/26 15:20:47 20 20 SORT 3.6 2023/03/26 15:21:50 20 20 CLEAN 5.3 2023/03/26 15:21:59 20 20 HDREDIT2 3.2 2023/03/26 15:22:24 ? ? HDREDIT2 3.2 2023/03/26 15:22:47 ? ? CLEAN 5.3 2023/03/28 09:45:51 20 20 $END $REMARKS -CLEAN functions: 2018/04/19 10:03:23 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2018-01\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number [n/a] -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2018/05/15 08:45:59 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2018-01\Processing\hydro\2018-01-0056.samavg Secondary file: P:\Cruise_Data_Processing\2018-01\Processing\hydro\2018-01-0056.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2018-01\Processing\hydro\2018-01-0056.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2018/05/15 08:44:35 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2018/05/15 08:46:08 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Delete Empty Channels: 0 deleted. -CALIB parameters: 2018/06/04 14:56:27 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Salinity is computed Calibration file = P:\Cruise_Data_Processing\2018-01\Processing\doc\2018-01-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Salinity:T1:C1 PSS-78 10 -0.7000000E-03 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 10 0.4910000E-01 0.1028300E+01 Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T0:C0 PSS-78 130 Pressure Temperature:Primary Conductivity:Primary -SORT parameters: 2018/06/04 14:56:53 Sorted in ascending order of channel Pressure* -REMOVECH 2018/06/04 15:13:51 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 [PSS-78] - No units changed -HEADER EDITS: 2018/06/27 08:54:18 Applied edit header: P:\Cruise_Data_Processing\2018-01\Processing\doc\HYDRO\2018-01-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 20: Silicate [umol/L] Units: ==> umol/L Channel 22: Phosphate [umol/L] Units: ==> umol/L Channel 24: Dimethyl_Sulphide [nmol/L] Units: ==> nmol/L Channel 25: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 -HEADER EDITS: 2019/11/27 11:42:33 Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F11.3 ==> F7.2 Channel 12: Conductivity:Secondary [S/m] Name: mS/cm ==> Conductivity:Secondary -SORT parameters: 2019/11/27 12:00:32 Sorted in ascending order of channel Sample_number -HEADER EDITS: 2019/11/27 12:00:47 -The following MERGE parameters were used: 2019/11/27 12:01:00 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\2018-001\Processing\Bottle\2018-001-0056.rem Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2018-001\Processing\Bottle\2018-001-0056. dmsp -SORT parameters: 2019/11/27 12:01:36 Sorted in ascending order of channel Pressure -HEADER EDITS: 2019/11/27 12:01:53 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2018-001\Processing\DOC\2018-001-dmsp- hdr.txt -CLEAN functions: 2020/02/06 16:21:37 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2020/02/06 16:21:54 Channel 27: Flag:Dimethylsulfoniopropionate_Dissolved [] Name: Flag:Dimethylsulfoniopropionate_Dissolve ==> Flag:Dimethylsulfoniopropionate_Dissolved -SORT parameters: 2023/03/26 11:46:07 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2023/03/26 15:20:47 Merge Channel: Sample_Number Merge Scheme Used: 4: Add Secondary to Matching Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Gyr-de [ ], HPLC:Chl-b [ ], HPLC:C2mgdg [ ], HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [] Primary file : C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-001\Processing\IOS\ 2018-001-0056.che2 Secondary file: C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-001\Processing\IOS\ 2018-001-0056.hplc 6 secondary records matched to primary records. -SORT parameters: 2023/03/26 15:21:50 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2023/03/26 15:21:58 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2023/03/26 15:22:24 Applied edit header: C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-001\ Processing\DOC\2018-001-hdr1.txt Channel 30: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 57: Flag:HPLC [n/a] Units: ==> n/a Channel 49: HPLC:Gyr-de [mg/m^3] Units: ==> mg/m^3 Channel 16: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 18: Flag:Silicate [n/a] Units: ==> n/a Channel 20: Flag:Phosphate [n/a] Units: ==> n/a Channel 24: Flag:Dimethylsulfoniopropionate_Dissolved [n/a] Units: ==> n/a Channel 26: Flag:Dimethylsulfoniopropionate_Total [n/a] Units: ==> n/a Channel 28: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a -HEADER EDITS: 2023/03/26 15:22:47 Applied edit header: C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-001\ Processing\DOC\2018-001-hdr2.txt -CLEAN functions: 2023/03/28 09:45:50 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2018-01\2018-01-0056.hex Software Version Seasave V 7.26.2.13 Temperature SN = 2710 Conductivity SN = 2128 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Feb 26 2018 22:04:25 NMEA Latitude = 50 00.03 N NMEA Longitude = 144 59.98 W NMEA UTC (Time) = Feb 26 2018 22:03:10 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Laurier: 2018-01 Station: P26 Depth: 4250 DMS cast System UTC = Feb 26 2018 22:04:25 # nquan = 20 # nvalues = 4450 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = altM: Altimeter [m] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Feb 26 2018 22:03:10 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 2710 # 02-Sep-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36745489e-003 # 6.47253874e-004 # 2.38788836e-005 # 2.30793641e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2128 # 14-Sep-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02716519e+001 # 1.47416353e+000 # -5.26731026e-003 # 4.32020637e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0443 # 31-Aug-17 # -4.435292e+004 # -1.635794e-001 # 1.192740e-002 # 3.979900e-002 # 0.000000e+000 # 2.993627e+001 # -3.271008e-004 # 3.759160e-006 # 1.565300e-009 # 0.99987037 # -2.18884 # 0.000000e+000 # 1.282462e-002 # -8.599824e+000 # # # # # # 4752 # 02-Sep-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.35928268e-003 # 6.36988092e-004 # 2.10291075e-005 # 1.80213693e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2399 # 14-Sep-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.98905621e+000 # 1.49210202e+000 # 9.67601751e-005 # 7.96101898e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0997 # 02-Sep-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 3.9659e-001 # -0.6998 # -3.9462e-003 # 1.8647e-004 # -3.0185e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6300e-002 # 2.1600 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3641 # # # 1 # 0.000 # # # # # # 1185DR # 2017 # 19.4021 # -1.1059 # 0.250 # # # # # # # # # 70613 # 03/21/16 # 1.00000000 # 0.00000000 # 11876484560.57000000 # 1.00000000 # -0.08460000 # # # # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # datcnv_date = Apr 19 2018 09:52:21, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2018-01\RAW\CTD\2018-01-0056.hex P:\Crui se_Data_Processing\2018-01\Processing\doc\2018-01-ctd2.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~4 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.01-8.51ug/l. Average %CV for this cruise was 3.86% with 3 out of 56 duplicate pairs having a CV>10% and 0 out of 56 duplicate pairs having a CV>30%. Our average dataset %CV is 3.73% for 2013 - 2017 so the overall quality of this dataset is very good. For details see worksheet “CV%” in file QF2018-01CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1 month after collection The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2018-001HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2018-01OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 13 - 30 days after collection. For details including a duplicate analysis, see document QF2018-01SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2018-01nuts*.xls. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100 deg C (with a dewar containing boiling water) onto a Choromasorb 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. For more detail see file "2018-01DMS report.doc" and for data and duplicate analysis see "DMS summary (2018-01).xls." The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.1nmol/L. DMSP-D: 20-75mL of seawater was allowed to flow directly from the niskin into a magnetic filtration funnel containing a 0.7um GF/F filter. The first 3.5mL was collected in a polypropylene tube containing 50uL of a 50% sulphuric acid solution. DMPS-T: 3.5mL of seawater was collected directly from the niskin into a polypropylene tube containing 50uL of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. For details on analysis and raw data, see document "QF 2018-001 dmsp*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2018-01_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\huntingtons\Desktop\HPLC notes\Jared_cruises\2018\2018-001\Processing\IOS\2018-001-0056. hplc --------------------------------------------------------------------------- Sample_Number 258: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CALCULATED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 130 -99 (Pressure Temperature:Primary Conductivity:Primary) () $END $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.7E-03 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.491E-01 1.0283) $END !-1-- 2- 3- --4--- --5--- ---6---- ----7---- --8-- ---9--- --10-- ---11--- --12-- --13- -14- --15-- 16 --17-- 18 ---19-- 20 --21-- 22 --23-- 24 --25-- 26 --27-- 28 --29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- ---56-- 57 !Samp Bo Bo Pressu Depth Temperat Conductiv Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ tt tt re ure: ity: missi cence: :T1:C1 : n: er_o e_ ag te ag te ag yl_ ag ylsulf ag ylsulf ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Gyr-de Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb ~u ~u Secondar Secondary vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a t: a chlide a fuco fuco : !er mb en y Seapoin ved: lved: _rec Nitrit ri ca ha de hi te_Dis lv ionate ot ted ct Extrac HP ! er ce t SBE SBE ords e te te te de solved ed _Total al ed ted LC !---- -- -- ------ ------ -------- --------- ----- ------- ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 267 17 17 5.4 5.4 5.8910 3.205719 48.8 0.689 190.0 32.5027 7.16 311.7 145 14.67 0 21.36 0 1.326 0 -99.00 0 -99.00 0 -99.00 0 0.44 0 0.10 0.086 0.000 0.004 0.067 0.000 0.008 0.000 0.000 0.072 0.115 0.000 0.000 0.000 0.149 0.033 0.000 0.003 0.000 0.000 0.002 0.020 0.006 0.000 0.455 0.000 0.003 0.463 6 268 18 18 5.4 5.3 5.8913 3.205741 48.9 0.710 180.2 32.5028 7.16 311.6 212 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 269 19 19 5.5 5.5 5.8922 3.205820 49.0 0.723 196.5 32.5028 7.17 312.1 241 -99.00 0 -99.00 0 -99.000 0 0.58 0 0.00 0 22.20 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 270 20 20 5.5 5.5 5.9306 3.209120 48.7 0.629 196.8 32.5028 7.17 312.1 241 14.71 0 21.45 0 1.317 0 0.58 0 0.00 0 10.30 0 0.40 0 0.12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 266 16 16 10.6 10.5 5.8904 3.205880 48.9 0.761 143.1 32.5027 7.16 311.8 241 14.70 0 21.47 0 1.322 0 0.58 0 -99.00 0 -99.00 0 0.39 0 0.13 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 265 15 15 15.3 15.1 5.8895 3.206019 49.1 1.007 103.4 32.5027 7.17 312.1 241 14.68 0 21.37 0 1.323 0 0.59 0 -99.00 0 -99.00 0 0.42 0 0.12 0.071 0.000 0.002 0.064 0.000 0.010 0.000 0.000 0.075 0.130 0.006 0.000 0.000 0.136 0.031 0.000 0.001 0.000 0.000 0.002 0.021 0.005 0.000 0.462 0.000 0.002 0.472 6 264 14 14 20.2 20.0 5.8853 3.205875 49.3 1.108 59.4 32.5027 7.18 312.6 241 14.71 0 21.38 0 1.327 0 0.58 6 0.00 6 23.50 6 0.41 0 0.14 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 263 13 13 25.0 24.8 5.8997 3.207319 49.3 1.090 51.3 32.5028 7.18 312.6 241 14.71 0 21.39 0 1.320 0 0.56 0 -99.00 0 -99.00 0 0.41 6 0.12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 262 12 12 30.6 30.3 5.8913 3.206848 49.7 1.197 36.2 32.5028 7.18 312.4 241 14.65 0 21.38 0 1.322 0 0.52 0 0.00 0 14.80 0 0.41 0 0.12 0.077 0.000 0.005 0.061 0.004 0.018 0.000 0.000 0.069 0.120 0.004 0.000 0.000 0.131 0.030 0.000 0.002 0.000 0.000 0.000 0.020 0.005 0.000 0.428 0.000 0.005 0.446 6 261 11 11 41.1 40.7 5.8924 3.207400 50.5 1.206 19.8 32.5028 7.18 312.6 241 14.61 0 21.42 0 1.319 0 0.56 0 -99.00 0 -99.00 0 0.42 6 0.12 0.078 0.000 0.004 0.061 0.000 0.017 0.005 0.000 0.068 0.122 0.003 0.000 0.000 0.137 0.034 0.000 0.001 0.000 0.000 0.000 0.027 0.006 0.000 0.436 0.000 0.002 0.454 6 259 9 9 50.3 49.8 5.8862 3.207262 51.0 1.183 13.1 32.5028 7.17 312.2 156 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 260 10 10 50.4 50.0 5.8871 3.207346 50.9 1.179 12.8 32.5028 7.17 312.2 241 14.61 0 21.72 0 1.324 0 0.55 0 -99.00 0 -99.00 0 0.39 0 0.13 0.083 0.000 0.006 0.076 0.000 0.010 0.007 0.000 0.079 0.129 0.006 0.000 0.000 0.140 0.029 0.000 0.000 0.000 0.000 0.002 0.027 0.008 0.000 0.456 0.000 0.006 0.465 6 258 8 8 60.5 60.0 5.8876 3.207839 51.1 1.175 7.4 32.5029 7.16 311.7 241 14.55 0 21.40 0 1.316 0 -99.00 0 -99.00 0 -99.00 0 0.41 0 0.13 0.078 0.000 0.002 0.068 0.000 0.012 0.004 0.000 0.074 0.113 0.000 0.000 0.000 0.136 0.021 0.000 0.000 0.000 0.000 0.002 0.016 0.004 0.000 0.406 0.000 0.006 0.418 36 257 7 7 76.0 75.3 5.8870 3.208478 51.5 1.190 2.7 32.5031 7.15 311.3 241 14.58 0 21.32 0 1.336 0 0.47 0 -99.00 0 -99.00 0 0.33 0 0.12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 255 5 5 99.8 98.9 5.8683 3.208200 51.4 1.042 0.6 32.5064 7.07 307.5 81 14.68 0 21.55 0 1.326 0 0.47 0 -99.00 0 -99.00 0 0.36 0 0.13 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 256 6 6 99.8 98.9 5.8694 3.208333 51.3 1.039 0.6 32.5067 7.08 308.2 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 254 4 4 149.9 148.6 4.3924 3.175251 54.3 0.085 0.0 33.5627 4.13 179.6 241 29.27 0 51.21 0 2.178 0 0.00 0 0.00 0 1.20 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 253 3 3 200.5 198.7 4.2212 3.174845 54.4 0.074 0.0 33.7062 3.33 144.9 241 33.03 0 61.79 0 2.401 0 0.00 0 0.00 0 0.39 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 252 2 2 250.3 248.0 4.0662 3.170275 54.9 0.074 0.0 33.7853 2.48 107.7 241 36.66 6 73.17 6 2.633 6 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 251 1 1 300.4 297.6 4.0137 3.174741 55.2 0.072 0.0 33.8659 1.81 78.6 241 39.22 0 82.32 0 2.801 0 0.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0