*2021/11/26 12:44:12.51 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2017/10/08 11:07:14.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 11 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 1EC2952B NUMBER OF CHANNELS : 57 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 294 304 2 Bottle_Number n/a 1 11 3 Bottle:Firing_Sequence n/a 1 11 4 Pressure decibar 1.4 152.6 5 Temperature:Primary 'deg C (ITS90)' 9.9609 10.2605 6 Transmissivity %/metre 50 51 7 Fluorescence:URU:Seapoint mg/m^3 0.347 0.53 8 PAR uE/m^2/sec 0 6.1 9 PAR:Reference uE/m^2/sec 14.5 15.9 10 pH:SBE:Nominal n/a 8.509 8.568 11 Salinity:T0:C0 PSS-78 29.7221 30.0897 12 Oxygen:Dissolved:SBE mL/L 3.42 3.82 13 Oxygen:Dissolved:SBE umol/kg 149.2 166.6 14 Number_of_bin_records n/a 241 241 15 Temperature:Draw 'deg C (ITS90)' 9.9 10.1 16 Salinity:Bottle PSS-78 30.0852 30.0852 17 Flag:Salinity:Bottle ' ' 18 Oxygen:Dissolved mL/L 3.429 3.836 19 Oxygen:Dissolved umol/kg 149.6 167.4 20 Flag:Oxygen:Dissolved ' ' 21 Nitrate_plus_Nitrite umol/L 22.81 24.2 22 Flag:Nitrate_plus_Nitrite ' ' 23 Silicate umol/L 54.46 55.54 24 Flag:Silicate ' ' 25 Phosphate umol/L 2.241 2.304 26 Flag:Phosphate ' ' 27 Chlorophyll:Extracted mg/m^3 0.69 0.89 28 Flag:Chlorophyll:Extracted ' ' 29 Phaeo-Pigment:Extracted mg/m^3 0.48 0.57 30 Depth metres 1.4 151.2 31 HPLC:Chl-c3 mg/m^3 0.21E-01 0.21E-01 32 HPLC:Chlide-a mg/m^3 0.21E-01 0.21E-01 33 HPLC:MgDVP mg/m^3 0.11E-01 0.11E-01 34 HPLC:Chl-c2 mg/m^3 0.62E-01 0.62E-01 35 HPLC:Chl-c1 mg/m^3 0.19E-01 0.19E-01 36 HPLC:Me-chlide mg/m^3 0.12E-01 0.12E-01 37 HPLC:Peri mg/m^3 0 0 38 HPLC:Pheide-a mg/m^3 0 0 39 HPLC:But-fuco mg/m^3 0.9E-02 0.9E-02 40 HPLC:Fuco mg/m^3 0.265 0.265 41 HPLC:Neo mg/m^3 0.6E-02 0.6E-02 42 HPLC:Pras mg/m^3 0 0 43 HPLC:Viola mg/m^3 0.4E-02 0.4E-02 44 HPLC:Hex-fuco mg/m^3 0.9E-02 0.9E-02 45 HPLC:Diadino mg/m^3 0.18E-01 0.18E-01 46 HPLC:Allo mg/m^3 0.28E-01 0.28E-01 47 HPLC:Diato mg/m^3 0 0 48 HPLC:Zea mg/m^3 0.6E-02 0.6E-02 49 HPLC:Lut mg/m^3 0.3E-02 0.3E-02 50 HPLC:Chl-b mg/m^3 0.17E-01 0.17E-01 51 HPLC:C2mgdg mg/m^3 0 0 52 HPLC:DVChl-a mg/m^3 0 0 53 HPLC:Chl-a mg/m^3 0.632 0.632 54 HPLC:Phe mg/m^3 0 0 55 HPLC:B-Car mg/m^3 0.11E-01 0.11E-01 56 HPLC:TChl-a mg/m^3 0.665 0.665 57 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 9 F R4 4 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 8 F R4 3 19 -99 ' ' 6 F ' ' 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 7 F ' ' 1 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 8 F R4 3 57 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2017-65 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 16 EVENT NUMBER : 104 LATITUDE : 49 57.69000 N ! (deg min) LONGITUDE : 125 8.80000 W ! (deg min) WATER DEPTH : 153 ALTIMETER (M) : 3.27 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 4484 Conductivity:2 ' ' 3531 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3685 pH ' ' 0691 PAR/Irradiance:Biospherical/Licor ' ' '4565 QSP200L4S' Altimeter ' ' 62355 'Transmissometer:WET Labs C-Star' ' ' 1185DR Unavailable ' ' ' ' 'SPAR/Surface Irradiance' ' ' 20518 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.26.2.13 Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.samavg2 ----------------------------------------------------------------------- SOFTWARE VERSION SEASAVE V 7.26.2.13 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.5.2 2018/02/22 16:45:23 2651 2651 CLEAN 5.2.2 2018/02/22 16:45:47 2651 2651 ADDSAMP 3.6 2018/02/23 09:57:47 2651 2651 BINAVE 4.2 2018/02/23 09:58:15 2651 11 MERGE 3.5 2018/03/06 12:17:01 11 11 MERGE 3.5 2018/03/06 12:31:11 11 11 CLEAN 5.2.2 2018/03/06 12:31:22 11 11 CALIB 11.9 2018/03/06 12:32:26 11 11 SORT 3.6 2018/03/06 12:32:39 11 11 REMOVECH 8.2 2018/03/06 12:32:47 11 11 CHGUNITS 3.1.1 2018/03/06 12:32:55 11 11 CHGUNITS 3.1.1 2018/03/06 12:33:03 11 11 REORDER 1.3.1 2018/03/06 12:33:25 ? ? HDREDIT2 3.1.1 2018/03/06 12:37:42 ? ? SORT 3.6 2020/10/03 17:40:27 11 11 REORDER 1.3.1 2021/11/26 12:43:02 ? ? MERGE 3.5.1 2021/11/26 12:43:10 11 11 SORT 3.6 2021/11/26 12:43:17 11 11 CLEAN 5.2.4 2021/11/26 12:43:25 11 11 HDREDIT2 3.2 2021/11/26 12:43:52 ? ? HDREDIT2 3.2 2021/11/26 12:44:12 ? ? $END $REMARKS -CLEAN functions: 2018/02/22 16:45:37 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2017-65\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number [n/a] -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2018/03/06 12:17:01 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: PAR:Reference, pH:SBE Primary file : P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.samavg1 Secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.samavg2 Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.samavg2 ----------------------------------------------------------------------- -CLEAN functions: 2018/03/06 12:07:29 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2017-65\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number [n/a] -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2018/03/06 12:31:11 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.samavg Secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2018/02/23 09:55:18 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2018/03/06 12:31:20 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Delete Empty Channels: 0 deleted. -CALIB parameters: 2018/03/06 12:32:26 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2017-65\Processing\doc\2017-65-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Oxygen:Dissolved:SBE mL/L 10 0.4470000E-01 0.1082600E+01 -SORT parameters: 2018/03/06 12:32:39 Sorted in ascending order of channel Pressure* -REMOVECH 2018/03/06 12:32:47 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2018/03/06 12:37:42 Applied edit header: P:\Cruise_Data_Processing\2017-65\Processing\doc\HYDRO\2017-65-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F11.3 ==> F7.2 Channel 16: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 17: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 19: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 21: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 22: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 25: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 27: Silicate [umol/L] Units: ==> umol/L Channel 29: Phosphate [umol/L] Units: ==> umol/L Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 -SORT parameters: 2020/10/03 17:40:27 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/26 12:43:10 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065_Nov2021\Processing\ IOS\2017-065-0104.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065_Nov2021\Processing\ IOS\2017-065-0104.hplc -SORT parameters: 2021/11/26 12:43:17 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/26 12:43:24 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/26 12:43:52 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 31: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/26 12:44:12 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2017-65\2017-65-0104.hex Software Version Seasave V 7.26.2.13 Temperature SN = 4054 Conductivity SN = 1766 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Oct 08 2017 04:08:05 NMEA Latitude = 49 57.69 N NMEA Longitude = 125 08.80 W NMEA UTC (Time) = Oct 08 2017 11:07:14 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 5 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds advance voltage 6 0.000 seconds advance voltage 7 0.000 seconds S> Vector: 2017-65 Station: 16 Depth: 153 System UTC = Oct 08 2017 11:08:05 # nquan = 20 # nvalues = 2651 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = altM: Altimeter [m] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Oct 08 2017 11:07:14 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4054 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616406e-003 # 6.44028261e-004 # 2.29631886e-005 # 2.07487665e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12892961e+000 # 4.88377974e-001 # -6.29237468e-004 # 5.38259078e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 24-Feb-17 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99995690 # 0.08882 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4484 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39937667e-003 # 6.40472023e-004 # 2.15385278e-005 # 1.84322868e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02129539e+001 # 1.56309188e+000 # -2.40628351e-003 # 2.66312047e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 28-Mar-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.7570e-001 # -0.5165 # -3.9454e-003 # 1.7154e-004 # -2.7543e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.7500e-002 # 1.0300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # 13-Mar-17 # # 2 # 0.000 # # # # # # 0691 # 15-Jan-15 # 4.6262 # 2.5140 # # # # # # 4565 QSP200L4S # 16-Mar-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # # # 1185DR # 2017 # 19.4021 # -1.1059 # 0.250 # # # # # # # # # # # # 20518 # 21-MAR-2016 # 1627.06600000 # 1.00000000 # # # # datcnv_date = Feb 22 2018 13:25:42, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2017-65\RAW\CTD\2017-65-0104.hex P:\Crui se_Data_Processing\2017-65\Processing\doc\2017-65-ctd.XMLCON # datcnv_ox_hysteresis_correction = no # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.samavg2 ----------------------------------------------------------------------- SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2017-65\2017-65-0104.hex Software Version Seasave V 7.26.2.13 Temperature SN = 4054 Conductivity SN = 1766 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Oct 08 2017 04:08:05 NMEA Latitude = 49 57.69 N NMEA Longitude = 125 08.80 W NMEA UTC (Time) = Oct 08 2017 11:07:14 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 5 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds advance voltage 6 0.000 seconds advance voltage 7 0.000 seconds S> Vector: 2017-65 Station: 16 Depth: 153 System UTC = Oct 08 2017 11:08:05 # nquan = 6 # nvalues = 2651 # units = specified # name 0 = scan: Scan Count # name 1 = prDM: Pressure, Digiquartz [db] # name 2 = spar: SPAR/Surface Irradiance # name 3 = ph: pH # name 4 = nbf: Bottles Fired # name 5 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Oct 08 2017 11:07:14 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4054 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616406e-003 # 6.44028261e-004 # 2.29631886e-005 # 2.07487665e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12892961e+000 # 4.88377974e-001 # -6.29237468e-004 # 5.38259078e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 24-Feb-17 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99995690 # 0.08882 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4484 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39937667e-003 # 6.40472023e-004 # 2.15385278e-005 # 1.84322868e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02129539e+001 # 1.56309188e+000 # -2.40628351e-003 # 2.66312047e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 28-Mar-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.7570e-001 # -0.5165 # -3.9454e-003 # 1.7154e-004 # -2.7543e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.7500e-002 # 1.0300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # 13-Mar-17 # # 2 # 0.000 # # # # # # 0691 # 15-Jan-15 # 4.6262 # 2.5140 # # # # # # 4565 QSP200L4S # 16-Mar-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # # # 1185DR # 2017 # 19.4021 # -1.1059 # 0.250 # # # # # # # # # # # # 20518 # 21-MAR-2016 # 1627.06600000 # 1.00000000 # # # # datcnv_date = Mar 06 2018 12:05:11, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2017-65\RAW\CTD\2017-65-0104.hex P:\Crui se_Data_Processing\2017-65\Processing\doc\2017-65-ctd.XMLCON # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.chl ------------------------------------------------------------------- Sample_Number 302: CHL: %CV>10 Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0104.nut ------------------------------------------------------------------- Sample_Number 300: NUTS: Sample cracked and compromised Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~2 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.16-22.27 ug/l. Average %CV for this cruise was 4.50 with 7 out of 81 duplicate pairs having a CV>10% and 0 out of 81 duplicate pairs having a CV>30%. Our average dataset %CV is 2.84% for 2013 - 2016 so the overall quality of this dataset is good. For details see worksheet “CV%” in file QF2017-65CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2017-065HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2017-65OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 3 to 8 days after collection. No duplicate samples were collected. For details see document QF2017-65SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document NUTS_QF2017-65*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence:URU:Seapoint, pH:SBE, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2017-65_Processing_Report.doc. -------------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065_Nov2021\Processing\IOS\2017-065-0104. hplc --------------------------------------------------------------------------- Sample_Number 304: HPLC: replicate thawed piror to analysis, removed *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.447E-01 1.0826) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10-- ---11--- --12-- --13- -14- --15- ---16--- 17 ---18-- --19- 20 --21-- 22 --23-- 24 ---25-- 26 --27-- 28 --29-- --30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- ---56-- 57 !Samp Bott Bott Pressu Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Chloro Fl Phaeo- Depth HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: Refere Nominal :T0:C0 : n: er_o ratur :Bottle ag Dissolv n: ag e_ ag te ag te ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity URU: nce Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Draw tt lved lv Nitrit ri ca ha ted ct Extrac HP ! ence t SBE SBE ords le ed e te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 304 11 11 1.4 10.2134 50.7 0.530 6.1 14.7 8.563 29.7792 3.80 166.0 241 10.1 -99.0000 0 3.836 167.4 0 22.81 0 55.52 0 2.270 0 0.89 6 0.57 1.4 0.021 0.021 0.011 0.062 0.019 0.012 0.000 0.000 0.009 0.265 0.006 0.000 0.004 0.009 0.018 0.028 0.000 0.006 0.003 0.017 0.000 0.000 0.632 0.000 0.011 0.665 2 303 10 10 4.9 10.2003 50.4 0.478 0.1 14.5 8.557 29.7962 3.73 163.0 241 10.1 -99.0000 0 3.693 161.2 0 23.88 0 55.54 0 2.304 0 -99.00 0 -99.00 4.8 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 302 9 9 10.2 10.2605 50.5 0.524 0.0 14.8 8.568 29.7221 3.82 166.6 241 10.1 -99.0000 0 3.792 165.5 0 23.23 0 54.46 0 2.241 0 0.89 36 0.57 10.1 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 301 8 8 19.6 10.0997 50.0 0.411 0.0 15.2 8.538 29.9145 3.65 159.2 241 10.1 -99.0000 0 3.652 159.4 6 23.64 0 54.73 0 2.264 0 0.69 6 0.48 19.4 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 300 7 7 29.6 10.0858 50.0 0.401 0.0 15.2 8.534 29.9349 3.62 157.8 241 10.0 -99.0000 0 3.624 158.1 0 -99.00 5 -99.00 5 -99.000 5 -99.00 0 -99.00 29.3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 299 6 6 40.4 10.0766 50.0 0.397 0.0 15.2 8.532 29.9477 3.62 157.9 241 10.0 -99.0000 0 3.631 158.5 0 24.20 0 55.18 0 2.299 0 -99.00 0 -99.00 40.1 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 298 5 5 50.3 10.0713 50.1 0.410 0.0 14.9 8.531 29.9562 3.60 157.1 241 10.0 -99.0000 0 3.609 157.5 0 24.05 0 54.75 0 2.273 0 -99.00 0 -99.00 49.9 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 297 4 4 75.5 10.0729 50.1 0.410 0.0 15.4 8.530 29.9608 3.60 157.1 241 10.0 -99.0000 0 3.607 157.4 6 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 74.8 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 296 3 3 100.1 10.0503 50.5 0.384 0.0 15.5 8.525 29.9906 3.56 155.2 241 9.9 -99.0000 0 3.579 156.2 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 99.2 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 295 2 2 125.6 9.9609 51.0 0.347 0.0 15.8 8.509 30.0897 3.42 149.2 241 9.9 30.0852 0 3.429 149.6 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 124.5 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 294 1 1 152.6 9.9947 51.0 0.354 0.0 15.9 8.513 30.0579 3.47 151.5 241 9.9 -99.0000 0 3.466 151.2 0 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 151.2 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0