*2021/11/26 12:44:10.91 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2017/10/06 00:39:14.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 12 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : E655662E NUMBER OF CHANNELS : 55 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 51 62 2 Bottle_Number n/a 1 12 3 Bottle:Firing_Sequence n/a 1 12 4 Pressure decibar 1.5 172.4 5 Temperature:Primary 'deg C (ITS90)' 7.6445 11.0688 6 Transmissivity %/metre 40.9 55.5 7 Fluorescence:URU:Seapoint mg/m^3 0.65E-01 4.344 8 PAR uE/m^2/sec 0 164.9 9 PAR:Reference uE/m^2/sec 1002.9 1225.7 10 pH:SBE:Nominal n/a 8.43 8.722 11 Salinity:T0:C0 PSS-78 31.2742 33.8701 12 Oxygen:Dissolved:SBE mL/L 1.38 4.72 13 Oxygen:Dissolved:SBE umol/kg 59.9 206 14 Number_of_bin_records n/a 241 241 15 Temperature:Draw 'deg C (ITS90)' 8 10.9 16 Oxygen:Dissolved mL/L 1.375 4.724 17 Oxygen:Dissolved umol/kg 59.8 206 18 Flag:Oxygen:Dissolved ' ' 19 Nitrate_plus_Nitrite umol/L 20.57 32.06 20 Flag:Nitrate_plus_Nitrite ' ' 21 Silicate umol/L 39.64 51.72 22 Flag:Silicate ' ' 23 Phosphate umol/L 1.896 2.533 24 Flag:Phosphate ' ' 25 Chlorophyll:Extracted mg/m^3 3.8 6.62 26 Flag:Chlorophyll:Extracted ' ' 27 Phaeo-Pigment:Extracted mg/m^3 0.53 0.65 28 Depth metres 1.4 170.8 29 HPLC:Chl-c3 mg/m^3 0.78E-01 0.78E-01 30 HPLC:Chlide-a mg/m^3 0.246 0.246 31 HPLC:MgDVP mg/m^3 0.39E-01 0.39E-01 32 HPLC:Chl-c2 mg/m^3 0.463 0.463 33 HPLC:Chl-c1 mg/m^3 0.127 0.127 34 HPLC:Me-chlide mg/m^3 0.434 0.434 35 HPLC:Peri mg/m^3 0.17 0.17 36 HPLC:Pheide-a mg/m^3 0 0 37 HPLC:But-fuco mg/m^3 0.15E-01 0.15E-01 38 HPLC:Fuco mg/m^3 1.963 1.963 39 HPLC:Neo mg/m^3 0 0 40 HPLC:Pras mg/m^3 0 0 41 HPLC:Viola mg/m^3 0.18E-01 0.18E-01 42 HPLC:Hex-fuco mg/m^3 0.13E-01 0.13E-01 43 HPLC:Diadino mg/m^3 0.367 0.367 44 HPLC:Allo mg/m^3 0.27E-01 0.27E-01 45 HPLC:Diato mg/m^3 0.25E-01 0.25E-01 46 HPLC:Zea mg/m^3 0 0 47 HPLC:Lut mg/m^3 0 0 48 HPLC:Chl-b mg/m^3 0.52E-01 0.52E-01 49 HPLC:C2mgdg mg/m^3 0.6E-02 0.6E-02 50 HPLC:DVChl-a mg/m^3 0 0 51 HPLC:Chl-a mg/m^3 3.218 3.218 52 HPLC:Phe mg/m^3 0 0 53 HPLC:B-Car mg/m^3 0.46E-01 0.46E-01 54 HPLC:TChl-a mg/m^3 3.898 3.898 55 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 7 F ' ' 1 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2017-65 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 69 EVENT NUMBER : 20 LATITUDE : 48 15.58000 N ! (deg min) LONGITUDE : 123 43.21000 W ! (deg min) WATER DEPTH : 176 ALTIMETER (M) : 5.27 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 4484 Conductivity:2 ' ' 3531 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3685 pH ' ' 0691 PAR/Irradiance:Biospherical/Licor ' ' '4565 QSP200L4S' Altimeter ' ' 62355 'Transmissometer:WET Labs C-Star' ' ' 1185DR Unavailable ' ' ' ' 'SPAR/Surface Irradiance' ' ' 20518 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.26.2.13 Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.samavg2 ----------------------------------------------------------------------- SOFTWARE VERSION SEASAVE V 7.26.2.13 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.5.2 2018/02/22 16:45:15 2892 2892 CLEAN 5.2.2 2018/02/22 16:45:39 2892 2892 ADDSAMP 3.6 2018/02/23 09:57:39 2892 2892 BINAVE 4.2 2018/02/23 09:58:11 2892 12 MERGE 3.5 2018/03/06 12:16:59 12 12 MERGE 3.5 2018/03/06 12:31:09 12 12 CLEAN 5.2.2 2018/03/06 12:31:20 12 12 CALIB 11.9 2018/03/06 12:32:24 12 12 SORT 3.6 2018/03/06 12:32:38 12 12 REMOVECH 8.2 2018/03/06 12:32:46 12 12 CHGUNITS 3.1.1 2018/03/06 12:32:54 12 12 CHGUNITS 3.1.1 2018/03/06 12:33:02 12 12 REORDER 1.3.1 2018/03/06 12:33:24 ? ? HDREDIT2 3.1.1 2018/03/06 12:37:40 ? ? SORT 3.6 2020/10/03 17:40:26 12 12 REORDER 1.3.1 2021/11/26 12:43:00 ? ? MERGE 3.5.1 2021/11/26 12:43:09 12 12 SORT 3.6 2021/11/26 12:43:17 12 12 CLEAN 5.2.4 2021/11/26 12:43:24 12 12 HDREDIT2 3.2 2021/11/26 12:43:49 ? ? HDREDIT2 3.2 2021/11/26 12:44:10 ? ? $END $REMARKS -CLEAN functions: 2018/02/22 16:45:37 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2017-65\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number [n/a] -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2018/03/06 12:16:59 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: PAR:Reference, pH:SBE Primary file : P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.samavg1 Secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.samavg2 Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.samavg2 ----------------------------------------------------------------------- -CLEAN functions: 2018/03/06 12:07:29 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2017-65\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number [n/a] -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2018/03/06 12:31:09 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.samavg Secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2018/02/23 09:55:17 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2018/03/06 12:31:20 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Delete Empty Channels: 0 deleted. -CALIB parameters: 2018/03/06 12:32:24 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2017-65\Processing\doc\2017-65-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Oxygen:Dissolved:SBE mL/L 10 0.4470000E-01 0.1082600E+01 -SORT parameters: 2018/03/06 12:32:38 Sorted in ascending order of channel Pressure* -REMOVECH 2018/03/06 12:32:46 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2018/03/06 12:37:40 Applied edit header: P:\Cruise_Data_Processing\2017-65\Processing\doc\HYDRO\2017-65-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 12: Oxygen:Dissolved:SBE [mL/L] Format: F11.3 ==> F7.2 Channel 16: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 17: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 19: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 20: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 23: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 25: Silicate [umol/L] Units: ==> umol/L Channel 27: Phosphate [umol/L] Units: ==> umol/L Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a Channel 4: Depth [metres] Name: Depth:Salt_Water ==> Depth Format: F10.3 ==> F7.1 Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 -SORT parameters: 2020/10/03 17:40:26 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/26 12:43:09 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065_Nov2021\Processing\ IOS\2017-065-0020.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065_Nov2021\Processing\ IOS\2017-065-0020.hplc -SORT parameters: 2021/11/26 12:43:17 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/26 12:43:24 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/26 12:43:49 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 29: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/26 12:44:10 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2017-65\2017-65-0020.hex Software Version Seasave V 7.26.2.13 Temperature SN = 4054 Conductivity SN = 1766 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Oct 05 2017 17:43:01 NMEA Latitude = 48 15.58 N NMEA Longitude = 123 43.21 W NMEA UTC (Time) = Oct 06 2017 00:39:14 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 5 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds advance voltage 6 0.000 seconds advance voltage 7 0.000 seconds S> Vector: 2017-65 Station: 69 Depth: 176 System UTC = Oct 06 2017 00:43:01 # nquan = 20 # nvalues = 2892 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = altM: Altimeter [m] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Oct 06 2017 00:39:14 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4054 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616406e-003 # 6.44028261e-004 # 2.29631886e-005 # 2.07487665e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12892961e+000 # 4.88377974e-001 # -6.29237468e-004 # 5.38259078e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 24-Feb-17 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99995690 # 0.08882 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4484 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39937667e-003 # 6.40472023e-004 # 2.15385278e-005 # 1.84322868e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02129539e+001 # 1.56309188e+000 # -2.40628351e-003 # 2.66312047e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 28-Mar-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.7570e-001 # -0.5165 # -3.9454e-003 # 1.7154e-004 # -2.7543e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.7500e-002 # 1.0300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # 13-Mar-17 # # 2 # 0.000 # # # # # # 0691 # 15-Jan-15 # 4.6262 # 2.5140 # # # # # # 4565 QSP200L4S # 16-Mar-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # # # 1185DR # 2017 # 19.4021 # -1.1059 # 0.250 # # # # # # # # # # # # 20518 # 21-MAR-2016 # 1627.06600000 # 1.00000000 # # # # datcnv_date = Feb 22 2018 13:24:38, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2017-65\RAW\CTD\2017-65-0020.hex P:\Crui se_Data_Processing\2017-65\Processing\doc\2017-65-ctd.XMLCON # datcnv_ox_hysteresis_correction = no # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.samavg2 ----------------------------------------------------------------------- SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2017-65\2017-65-0020.hex Software Version Seasave V 7.26.2.13 Temperature SN = 4054 Conductivity SN = 1766 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Oct 05 2017 17:43:01 NMEA Latitude = 48 15.58 N NMEA Longitude = 123 43.21 W NMEA UTC (Time) = Oct 06 2017 00:39:14 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 5 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds advance voltage 6 0.000 seconds advance voltage 7 0.000 seconds S> Vector: 2017-65 Station: 69 Depth: 176 System UTC = Oct 06 2017 00:43:01 # nquan = 6 # nvalues = 2892 # units = specified # name 0 = scan: Scan Count # name 1 = prDM: Pressure, Digiquartz [db] # name 2 = spar: SPAR/Surface Irradiance # name 3 = ph: pH # name 4 = nbf: Bottles Fired # name 5 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Oct 06 2017 00:39:14 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4054 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616406e-003 # 6.44028261e-004 # 2.29631886e-005 # 2.07487665e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12892961e+000 # 4.88377974e-001 # -6.29237468e-004 # 5.38259078e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 24-Feb-17 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99995690 # 0.08882 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4484 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39937667e-003 # 6.40472023e-004 # 2.15385278e-005 # 1.84322868e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02129539e+001 # 1.56309188e+000 # -2.40628351e-003 # 2.66312047e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 28-Mar-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.7570e-001 # -0.5165 # -3.9454e-003 # 1.7154e-004 # -2.7543e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.7500e-002 # 1.0300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # 13-Mar-17 # # 2 # 0.000 # # # # # # 0691 # 15-Jan-15 # 4.6262 # 2.5140 # # # # # # 4565 QSP200L4S # 16-Mar-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # # # 1185DR # 2017 # 19.4021 # -1.1059 # 0.250 # # # # # # # # # # # # 20518 # 21-MAR-2016 # 1627.06600000 # 1.00000000 # # # # datcnv_date = Mar 06 2018 12:04:21, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2017-65\RAW\CTD\2017-65-0020.hex P:\Crui se_Data_Processing\2017-65\Processing\doc\2017-65-ctd.XMLCON # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.oxy ------------------------------------------------------------------- Sample_Number 51: OXY: Niskin top end cap was not seated and caused a leak. Sample_Number 52: OXY: One of the Niskin end caps was leaking. Sample_Number 56: OXY: Two stir bars mistakenly put into flask. Value seems high. Sample_Number 59: OXY: Sample redrawn due to a bubble inside flask. Comments from secondary file: P:\Cruise_Data_Processing\2017-65\Processing\hydro\2017-65-0020.nut ------------------------------------------------------------------- Sample_Number 54: NO3, SIL: Chauvenet outlier in duplicate study Sample_Number 56: NUTS: Chauvenet outlier in duplicate study Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~2 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.16-22.27 ug/l. Average %CV for this cruise was 4.50 with 7 out of 81 duplicate pairs having a CV>10% and 0 out of 81 duplicate pairs having a CV>30%. Our average dataset %CV is 2.84% for 2013 - 2016 so the overall quality of this dataset is good. For details see worksheet “CV%” in file QF2017-65CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2017-065HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2017-65OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 3 to 8 days after collection. No duplicate samples were collected. For details see document QF2017-65SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document NUTS_QF2017-65*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence:URU:Seapoint, pH:SBE, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2017-65_Processing_Report.doc. -------------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-065_Nov2021\Processing\IOS\2017-065-0020. hplc --------------------------------------------------------------------------- Sample_Number 62: HPLC: replicate thawed prior to analysis, removed *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.447E-01 1.0826) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10-- ---11--- --12-- --13- -14- --15- ---16-- --17- 18 --19-- 20 --21-- 22 ---23-- 24 --25-- 26 --27-- --28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- 55 !Samp Bott Bott Pressu Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Chloro Fl Phaeo- Depth HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: Refere Nominal :T0:C0 : n: er_o ratur Dissolv n: ag e_ ag te ag te ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity URU: nce Dissol Disso ~bin e: ed Disso ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Draw lved lv Nitrit ri ca ha ted ct Extrac HP ! ence t SBE SBE ords ed e te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 62 12 12 1.5 11.0688 42.8 3.174 164.9 1002.9 8.722 31.2742 4.72 206.0 241 10.9 4.724 206.0 0 20.57 0 40.08 0 1.896 0 5.36 6 0.53 1.4 0.078 0.246 0.039 0.463 0.127 0.434 0.170 0.000 0.015 1.963 0.000 0.000 0.018 0.013 0.367 0.027 0.025 0.000 0.000 0.052 0.006 0.000 3.218 0.000 0.046 3.898 2 61 11 11 5.2 10.6685 40.9 4.344 43.9 1008.4 8.713 31.3443 4.57 199.2 241 10.7 4.502 196.3 0 21.57 0 41.32 0 2.036 0 -99.00 0 -99.00 5.1 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 60 10 10 10.3 10.4517 41.7 3.671 10.2 1020.1 8.675 31.4395 4.23 184.4 241 10.4 4.204 183.3 0 21.98 0 41.10 0 2.005 0 6.62 6 0.62 10.2 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 59 9 9 20.2 9.8398 47.1 1.919 1.1 1046.3 8.581 31.8156 3.35 145.8 241 9.8 3.271 142.5 2 24.62 0 43.50 0 2.069 0 3.80 6 0.65 20.0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 58 8 8 30.4 9.7128 49.5 1.227 0.2 1078.9 8.557 31.9601 3.13 136.4 241 9.7 3.109 135.5 6 25.24 0 44.05 0 2.143 0 -99.00 0 -99.00 30.1 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 57 7 7 40.5 9.6613 53.7 0.674 0.0 1113.4 8.539 32.1503 2.99 130.3 241 9.6 2.966 129.2 0 23.10 0 39.64 0 2.028 0 -99.00 0 -99.00 40.2 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 56 6 6 50.2 9.4061 55.5 0.379 0.0 1134.4 8.516 32.4063 2.73 118.9 241 9.4 2.695 117.4 36 23.97 36 40.07 36 1.961 36 -99.00 0 -99.00 49.8 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 55 5 5 75.4 8.5363 52.9 0.140 0.0 1153.3 8.471 33.2778 2.03 88.2 241 8.7 2.051 89.3 0 28.85 0 44.20 0 2.231 0 -99.00 0 -99.00 74.8 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 54 4 4 100.4 7.6577 51.5 0.065 0.0 1169.6 8.434 33.8598 1.46 63.3 241 8.0 1.486 64.6 0 29.09 36 45.94 36 2.307 6 -99.00 0 -99.00 99.6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 53 3 3 125.3 7.6480 50.5 0.068 0.0 1190.4 8.430 33.8669 1.40 61.0 241 8.0 1.409 61.3 0 31.51 0 51.12 0 2.502 0 -99.00 0 -99.00 124.2 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 52 2 2 150.3 7.6462 50.2 0.072 0.0 1205.1 8.431 33.8680 1.39 60.6 241 8.0 1.387 60.3 3 31.73 0 51.35 0 2.533 0 -99.00 0 -99.00 149.0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 51 1 1 172.4 7.6445 49.5 0.071 0.0 1225.7 8.436 33.8701 1.38 59.9 241 8.0 1.375 59.8 3 32.06 0 51.72 0 2.502 0 -99.00 0 -99.00 170.8 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0