*2021/11/26 12:38:39.26 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2017/04/11 22:35:10.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 1BFB7636 NUMBER OF CHANNELS : 56 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 176 192 2 Bottle_Number n/a 1 17 3 Bottle:Firing_Sequence n/a 1 17 4 Pressure decibar 1.6 339.8 5 Temperature:Primary 'deg C (ITS90)' 8.2812 9.7315 6 Fluorescence:URU:Seapoint mg/m^3 0.109 18.703 7 PAR uE/m^2/sec 0 772.2 8 PAR:Reference uE/m^2/sec 1785.9 1888 9 pH:SBE:Nominal n/a 7.823 8.717 10 Salinity:T0:C0 PSS-78 26.8873 31.1045 11 Oxygen:Dissolved:SBE mL/L 2.32 9.68 12 Oxygen:Dissolved:SBE umol/kg 101.1 423.5 13 Number_of_bin_records n/a 44 241 14 Temperature:Draw 'deg C (ITS90)' 8.5 9.9 15 Salinity:Bottle PSS-78 31.0557 31.0557 16 Flag:Salinity:Bottle n/a 17 Oxygen:Dissolved mL/L 2.35 9.598 18 Oxygen:Dissolved umol/kg 102.5 419.8 19 Flag:Oxygen:Dissolved n/a 20 Nitrate_plus_Nitrite umol/L 0.25 28.88 21 Flag:Nitrate_plus_Nitrite n/a 22 Silicate umol/L 4.7 67.33 23 Flag:Silicate n/a 24 Phosphate umol/L 0.645 2.906 25 Flag:Phosphate n/a 26 Chlorophyll:Extracted mg/m^3 0.6 32.39 27 Flag:Chlorophyll:Extracted n/a 28 Phaeo-Pigment:Extracted mg/m^3 0.97 2.75 29 Depth metres 1.6 336.6 30 HPLC:Chl-c3 mg/m^3 0.54E-01 0.54E-01 31 HPLC:Chlide-a mg/m^3 1.811 1.811 32 HPLC:MgDVP mg/m^3 0.205 0.205 33 HPLC:Chl-c2 mg/m^3 2.105 2.105 34 HPLC:Chl-c1 mg/m^3 1.735 1.735 35 HPLC:Me-chlide mg/m^3 3.581 3.581 36 HPLC:Peri mg/m^3 0 0 37 HPLC:Pheide-a mg/m^3 0 0 38 HPLC:But-fuco mg/m^3 0 0 39 HPLC:Fuco mg/m^3 11.568 11.568 40 HPLC:Neo mg/m^3 0 0 41 HPLC:Pras mg/m^3 0 0 42 HPLC:Viola mg/m^3 0.21E-01 0.21E-01 43 HPLC:Hex-fuco mg/m^3 0 0 44 HPLC:Diadino mg/m^3 1.365 1.365 45 HPLC:Allo mg/m^3 0.25E-01 0.25E-01 46 HPLC:Diato mg/m^3 0.197 0.197 47 HPLC:Zea mg/m^3 0.11E-01 0.11E-01 48 HPLC:Lut mg/m^3 0 0 49 HPLC:Chl-b mg/m^3 0 0 50 HPLC:C2mgdg mg/m^3 0 0 51 HPLC:DVChl-a mg/m^3 0 0 52 HPLC:Chl-a mg/m^3 18.826 18.826 53 HPLC:Phe mg/m^3 0.171 0.171 54 HPLC:B-Car mg/m^3 0.245 0.245 55 HPLC:TChl-a mg/m^3 24.218 24.218 56 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 5 I I 0 14 -99 ' ' 6 F R4 1 15 -99 ' ' 9 F R4 4 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 -99 ' ' 6 F ' ' 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 3 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 7 F ' ' 1 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2017-63 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Romaine S. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 27 EVENT NUMBER : 76 LATITUDE : 49 19.10000 N ! (deg min) LONGITUDE : 123 47.94000 W ! (deg min) WATER DEPTH : 346 ALTIMETER (M) : 5.57 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 4484 Conductivity:2 ' ' 3531 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3685 'Transmissometer:WET Labs C-Star' ' ' 1185DR Altimeter ' ' ' ' pH ' ' 0691 PAR/Irradiance:Biospherical/Licor ' ' '4565 QSP200L4S' Unavailable ' ' ' ' 'SPAR/Surface Irradiance' ' ' 20518 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.26.2.13 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.5.2 2017/05/17 13:21:18 3900 3900 CLEAN 5.2.2 2017/05/17 13:28:09 3900 3900 ADDSAMP 3.6 2017/05/18 15:49:21 3900 3900 BINAVE 4.2 2017/05/18 15:50:44 3900 17 MERGE 3.5 2017/06/01 09:48:18 17 17 CLEAN 5.2.2 2017/06/01 09:49:04 17 17 CALIB 11.9 2017/06/01 09:49:37 17 17 SORT 3.6 2017/06/01 09:49:46 17 17 REMOVECH 8.2 2017/06/01 09:50:03 17 17 CHGUNITS 3.1.1 2017/06/01 09:50:24 17 17 CHGUNITS 3.1.1 2017/06/01 10:09:27 17 17 REORDER 1.3.1 2017/06/01 10:09:37 ? ? HDREDIT2 3.1.1 2017/07/18 14:28:07 ? ? SORT 3.6 2020/10/03 15:37:39 17 17 REORDER 1.3.1 2021/11/26 12:37:24 ? ? MERGE 3.5.1 2021/11/26 12:37:36 17 17 SORT 3.6 2021/11/26 12:37:45 17 17 CLEAN 5.2.4 2021/11/26 12:37:53 17 17 HDREDIT2 3.2 2021/11/26 12:38:13 ? ? HDREDIT2 3.2 2021/11/26 12:38:39 ? ? $END $REMARKS -CLEAN functions: 2017/05/17 13:27:58 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2017-63\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2017/06/01 09:48:18 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2017-63\Processing\hydro\2017-63-0076.samavg Secondary file: P:\Cruise_Data_Processing\2017-63\Processing\hydro\2017-63-0076.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2017-63\Processing\hydro\2017-63-0076.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2017/06/01 09:16:34 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2017/06/01 09:49:03 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -CALIB parameters: 2017/06/01 09:49:37 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2017-63\Processing\doc\2017-63-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Salinity:T1:C1 PSS-78 10 -0.4000000E-02 0.1000000E+01 21 Oxygen:Dissolved:SBE mL/L 10 0.3580000E-01 0.1042200E+01 -SORT parameters: 2017/06/01 09:49:46 Sorted in ascending order of channel Pressure* -REMOVECH 2017/06/01 09:50:03 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Transmissivity [%/metre] Oxygen:Voltage:SBE [volts] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary [deg C (ITS90)] Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2017/07/18 14:28:07 Applied edit header: P:\Cruise_Data_Processing\2017-63\Processing\doc\HYDRO\2017-63-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 16: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 17: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 18: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 19: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 20: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 21: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 23: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 24: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 25: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 26: Silicate [umol/L] Units: ==> umol/L Channel 27: Flag:Silicate [n/a] Units: ==> n/a Channel 28: Phosphate [umol/L] Units: ==> umol/L Channel 29: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a -SORT parameters: 2020/10/03 15:37:39 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/26 12:37:36 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-063_Nov2021\Processing\ IOS\2017-063-0076.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-063_Nov2021\Processing\ IOS\2017-063-0076.hplc -SORT parameters: 2021/11/26 12:37:45 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/26 12:37:52 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/26 12:38:13 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-063-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 30: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/26 12:38:39 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-063-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2017-63\2017-63-0076.hex Software Version Seasave V 7.26.2.13 Temperature SN = 4054 Conductivity SN = 1766 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Apr 11 2017 15:36:37 NMEA Latitude = 49 19.10 N NMEA Longitude = 123 47.94 W NMEA UTC (Time) = Apr 11 2017 22:35:10 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 5 Latitude/Longitude added to scan GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds advance voltage 6 0.000 seconds advance voltage 7 0.000 seconds S> Vector: 2017-63 Station: 27 Depth: 349 System UTC = Apr 11 2017 22:36:37 # nquan = 22 # nvalues = 3900 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = spar: SPAR/Surface Irradiance # name 14 = ph: pH # name 15 = dz/dtM: Descent Rate [m/s] # name 16 = altM: Altimeter [m] # name 17 = pumps: Pump Status # name 18 = sal00: Salinity, Practical [PSU] # name 19 = sal11: Salinity, Practical, 2 [PSU] # name 20 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 21 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Apr 11 2017 22:35:10 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4054 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616406e-003 # 6.44028261e-004 # 2.29631886e-005 # 2.07487665e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12892961e+000 # 4.88377974e-001 # -6.29237468e-004 # 5.38259078e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 24-Feb-17 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99995690 # 0.08882 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4484 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39937667e-003 # 6.40472023e-004 # 2.15385278e-005 # 1.84322868e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02129539e+001 # 1.56309188e+000 # -2.40628351e-003 # 2.66312047e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 28-Mar-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.7570e-001 # -0.5165 # -3.9454e-003 # 1.7154e-004 # -2.7543e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.0300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # 13-Mar-17 # # 2 # 0.000 # # # # # # 1185DR # APR 27. 2016 # 19.3479 # -1.1028 # 0.250 # # # # # # # # # # # 15.000 # 0.000 # # # # # # # # # 0691 # 15-Jan-15 # 4.6262 # 2.5140 # # # # # # 4565 QSP200L4S # 16-Mar-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # # # # 20518 # 21-MAR-2016 # 1627.06600000 # 1.00000000 # # # # datcnv_date = May 17 2017 13:00:26, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2017-63\RAW\CTD\2017-63-0076.hex P:\Crui se_Data_Processing\2017-63\Processing\doc\2017-63-ctd.xmlcon # datcnv_ox_hysteresis_correction = no # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2017-63\Processing\hydro\2017-63-0076.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2017-63\Processing\hydro\2017-63-0076.oxy ------------------------------------------------------------------- Sample_Number 176: OXY: Analyst may have left a drop of Thio on dose tip, reducing the volume of titrant required to titrate sample. Sample_Number 190: OXY-2: Endpoint was late due to a blip in the curve near the end of the titration. Endpoint position adjusted and value recalculated. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 within ~2 weeks of the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.39-32.39 ug/l. Average %CV for this cruise was 4.37 with 9 out of 82 duplicate pairs having a CV>10% and 0 out of 82 duplicate pairs having a CV>30%. Our average dataset %CV is 2.83% for 2013 - 2015 so the overall quality of this dataset is within 1 standard deviation of this average and is very good. For details see worksheet “CV%” in file QF2017-63CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1 month after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2017-063HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2017-63OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 14 to 19 days after collection. For details including a duplicate analysis see document QF2017-63SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document NUTS_QF2017-63*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Data Processing Notes: ---------------------- Fluorescence:URU:Seapoint, pH:SBE, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. The Transmissivity channel was removed because of frequent shifts in values during casts and large variations between values during repeat casts. The data are available, by request, from the chief scientist. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2017-63_Processing_Report.doc. -------------------------------------------------------------------------------------- Warning: For casts #1 to 9 there were problems with NMEA times. A correction was made by subtracting 20 minutes from those times, but this should be considered an estimate. For details see section 3 of document 2017-63_Processing_Report.doc. ------------------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-063_Nov2021\Processing\IOS\2017-063-0076. hplc --------------------------------------------------------------------------- Sample_Number 191: HPLC: Discrepancy between Fluorometric Chl *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.4E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.358E-01 1.0422) $END !-1-- -2-- -3-- --4--- ---5---- ---6--- --7--- --8--- ---9--- ---10--- --11-- --12- -13- --14- ---15--- 16 ---17-- --18- 19 --20-- 21 --22-- 23 ---24-- 25 --26-- 27 --28-- --29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- 56 !Samp Bott Bott Pressu Temperat Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Chloro Fl Phaeo- Depth HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: cence: Refere Nominal :T0:C0 : n: er_o ratur :Bottle ag Dissolv n: ag e_ ag te ag te ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary URU: nce Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Draw tt lved lv Nitrit ri ca ha ted ct Extrac HP ! ence t SBE SBE ords le ed e te te te ed ted LC !---- ---- ---- ------ -------- ------- ------ ------ ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 191 16 16 1.6 9.1667 18.703 766.1 1828.1 8.715 26.8878 9.68 423.4 44 9.4 -99.0000 0 9.598 419.8 0 0.25 0 4.70 0 0.645 0 32.39 6 2.75 1.6 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