*2017/11/09 16:12:37.25 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2017/07/15 16:26:21.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 10 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 648A0B80 NUMBER OF CHANNELS : 16 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 10 2 Bottle:Firing_Sequence n/a 1 10 3 Pressure decibar 1.031 114.222 4 Depth metres 1.023 113.221 5 Temperature:Primary 'deg C (ITS90)' 8.7528 16.3608 6 Transmissivity %/metre 35.2 58.6 7 Fluorescence:URU:Seapoint mg/m^3 0.135 1.553 8 Salinity:T0:C0 PSS-78 26.1836 32.5007 9 Oxygen:Dissolved:SBE mL/L 0.53E-01 8.239 10 Oxygen:Dissolved:SBE umol/kg 2.3 359.2 11 Number_of_bin_records n/a 39 241 12 Sample_Number n/a 304 313 13 Temperature:Draw 'deg C (ITS90)' 9.1 17.4 14 Oxygen:Dissolved mL/L 0 7.318 15 Oxygen:Dissolved umol/kg 0 319.0683 16 Flag:Oxygen:Dissolved n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 ' ' ' ' 5 I I 0 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2017-23 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : OSD Moorings Cruise SCIENTIST : Spear D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : B.C. Coast STATION : EFF03 EVENT NUMBER : 94 LATITUDE : 49 4.21000 N ! (deg min) LONGITUDE : 125 9.37000 W ! (deg min) WATER DEPTH : 119 ALTIMETER (M) : 4.1 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! --------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 4484 Conductivity:2 ' ' 3531 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3685 Altimeter ' ' 62355 'Transmissometer:WET Labs C-Star' ' ' 1396DR $END $REMARKS SOFTWARE VERSION SEASAVE V 7.26.2.13 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.5.2 2017/10/25 15:52:32 2201 2201 CLEAN 5.2.2 2017/10/25 15:53:51 2201 2201 ADDSAMP 3.6 2017/10/26 11:03:50 2201 2201 BINAVE 4.2 2017/10/27 13:52:17 2201 10 MERGE 3.5 2017/10/27 15:09:18 10 10 CLEAN 5.2.2 2017/10/27 15:09:25 10 10 CALIB 11.9 2017/11/08 09:37:22 10 10 SORT 3.6 2017/11/08 13:57:20 10 10 REMOVECH 8.2 2017/11/08 13:57:54 10 10 CHGUNITS 3.1.1 2017/11/08 13:59:35 10 10 CHGUNITS 3.1.1 2017/11/08 13:59:45 10 10 REORDER 1.3.1 2017/11/08 14:00:36 ? ? HDREDIT2 3.1.1 2017/11/09 16:12:37 ? ? $END $REMARKS -CLEAN functions: 2017/10/25 15:53:39 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2017-23\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2017/10/27 15:09:18 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Ammonium, Flag:Ammonium Primary file : P:\Cruise_Data_Processing\2017-23\Processing\hydro\2017-23-0094.samavg Secondary file: P:\Cruise_Data_Processing\2017-23\Processing\hydro\2017-23-0094.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2017-23\Processing\hydro\2017-23-0094.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2017/10/27 15:08:51 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2017/10/27 15:09:23 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -CALIB parameters: 2017/11/08 09:37:22 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2017-23\Processing\doc\2017-23-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Oxygen:Dissolved:SBE mL/L 10 0.4800000E-01 0.1054000E+01 -SORT parameters: 2017/11/08 13:57:20 Sorted in ascending order of channel Pressure* -REMOVECH 2017/11/08 13:57:54 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2017/11/09 16:12:37 Applied edit header: P:\Cruise_Data_Processing\2017-23\Processing\doc\HYDRO\2017-23-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2017-23\2017-23-0094.hex Software Version Seasave V 7.26.2.13 Temperature SN = 4054 Conductivity SN = 1766 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jul 15 2017 09:26:05 NMEA Latitude = 49 04.21 N NMEA Longitude = 125 09.37 W NMEA UTC (Time) = Jul 15 2017 16:26:21 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Tully: 2017-23 Station: EFF03 Depth: 119 System UTC = Jul 15 2017 16:26:05 # nquan = 19 # nvalues = 2201 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = dz/dtM: Descent Rate [m/s] # name 13 = altM: Altimeter [m] # name 14 = pumps: Pump Status # name 15 = sal00: Salinity, Practical [PSU] # name 16 = sal11: Salinity, Practical, 2 [PSU] # name 17 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 18 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jul 15 2017 16:26:21 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4054 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616406e-003 # 6.44028261e-004 # 2.29631886e-005 # 2.07487665e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12892961e+000 # 4.88377974e-001 # -6.29237468e-004 # 5.38259078e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 24-Feb-17 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99995690 # 0.08882 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4484 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39937667e-003 # 6.40472023e-004 # 2.15385278e-005 # 1.84322868e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02129539e+001 # 1.56309188e+000 # -2.40628351e-003 # 2.66312047e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 28-Mar-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.7570e-001 # -0.5165 # -3.9454e-003 # 1.7154e-004 # -2.7543e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.8000e-002 # 1.0300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # 13-Mar-17 # # 2 # 0.000 # # # # # # # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # # # 1396DR # Feb 2nd 2016 # 19.3228 # -0.0193 # 0.250 # # # # # # # datcnv_date = Oct 25 2017 13:24:34, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2017-23\RAW\CTD\2017-23-0094.hex P:\Crui se_Data_Processing\2017-23\Processing\doc\2017-23-ctd2.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2017-23\Processing\hydro\2017-23-0094.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2017-23\Processing\hydro\2017-23-0094.oxy ------------------------------------------------------------------- Sample_Number 304: OXY: Anoxic and clear at outset of titration. Sample was stinky. Sample_Number 306: OXY: Anoxic and clear at outset of titration. Sample was stinky. Sample_Number 307: OXY: Anoxic and clear at outset of titration. Sample was stinky. Sample_Number 311: OXY: Replicate outliers. Sample_Number 313: OXY: Dropped 2 stir bars in at first. One retrieved prior to titration. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~1 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.24-22.75 ug/l. Average %CV for this cruise was 4.07 with 4 out of 61 duplicate pairs having a CV>10% and 0 out of 61 duplicate pairs having a CV>30%. Our average dataset %CV is 2.84% for 2013 - 2016 so the overall quality of this dataset is good. For details see worksheet “CV%” in file QF2017-23CHL*.xls. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2017-23OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 12 to 21 days after collection. For details including a duplicate analysis see document QF2017-23SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20C freezer. One set of samples is collected and frozen immediatedly. Another set of samples from 400m and deeper (to be used for silicate analysis) is collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a precision study, see document NUTS_QF2017-23*.xlsx. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence:URU:Seapoint and PAR data (event #1 only) are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2017-23_Processing_Report.doc. -------------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.48E-01 1.054) $END !1- 2- --3--- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- -12- --13- ---14-- --15- 16 !Bo Bo Pressu Depth Temperat Trans Fluores Salinity Oxygen Oxyge Numb Samp Tempe Oxygen: Oxyge Fl !tt tt re ure: missi cence: :T0:C0 : n: er_o le_ ratur Dissolv n: ag !~u ~u Primary vity URU: Dissol Disso ~bin Numb e: ed Disso ~o !mb en Seapoin ved: lved: _rec er Draw lved lv !er ce t SBE SBE ords ed !-- -- ------ ------ -------- ----- ------- -------- ------ ----- ---- ---- ----- ------- ----- -- *END OF HEADER 10 10 1.0 1.0 16.3608 35.2 0.937 26.1836 8.15 357.0 234 313 17.4 6.979 305.9 3 9 9 10.5 10.4 10.7676 42.2 1.392 31.2261 8.24 359.2 241 312 10.6 7.318 319.1 0 8 8 20.1 19.9 9.5591 48.2 1.553 31.5920 3.57 155.5 241 311 9.8 3.461 150.8 46 7 7 30.6 30.3 9.4144 57.5 0.540 31.8970 3.12 136.0 241 310 9.7 3.024 131.8 0 6 6 50.1 49.7 9.3122 58.1 0.159 32.2320 2.48 108.0 241 309 9.5 2.440 106.3 0 5 5 60.2 59.7 9.2792 57.5 0.135 32.2857 2.07 90.3 241 308 9.6 2.039 88.8 0 4 4 75.5 74.9 9.0673 47.8 0.136 32.4663 0.05 2.3 241 307 9.3 0.000 0.0 2 3 3 90.5 89.7 8.9054 58.6 0.139 32.5007 0.06 2.4 241 306 9.3 0.000 0.0 2 2 2 114.2 113.2 8.7528 55.5 0.162 32.4939 0.06 2.7 241 305 -99.0 -99.000 -99.0 0 1 1 114.2 113.2 8.7551 55.5 0.175 32.4943 0.06 2.8 39 304 9.1 0.000 0.0 2