*2021/12/06 15:49:04.76 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2017/06/12 21:51:29.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 21 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 8F848DE6 NUMBER OF CHANNELS : 54 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 578 598 2 Bottle_Number n/a 1 21 3 Bottle:Firing_Sequence n/a 1 21 4 Pressure decibar 2.2 300.3 5 Temperature:Primary 'deg C (ITS90)' 4.7195 8.893 6 Fluorescence:URU:Seapoint mg/m^3 0.49E-01 1.225 7 PAR uE/m^2/sec 0 783.7 8 Salinity:T0:C0 PSS-78 32.4506 33.8921 9 Oxygen:Dissolved:SBE mL/L 2.24 7.18 10 Oxygen:Dissolved:SBE umol/kg 97.3 312.6 11 Number_of_bin_records n/a 80 241 12 Nitrate_plus_Nitrite umol/L 12.32 37.32 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 18.45 70.84 15 Flag:Silicate n/a 16 Phosphate umol/L 1.171 2.639 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 2.77 19 Flag:Dimethyl_Sulphide n/a 20 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 21 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 22 Dimethylsulfoniopropionate_Total nmol/L -99 -99 23 Flag:Dimethylsulfoniopropionate_Total ' ' 24 Chlorophyll:Extracted mg/m^3 0.16 0.38 25 Flag:Chlorophyll:Extracted n/a 26 Phaeo-Pigment:Extracted mg/m^3 0.7E-01 0.26 27 Depth metres 2.2 297.5 28 HPLC:Chl-c3 mg/m^3 0.15E-01 0.62E-01 29 HPLC:Chlide-a mg/m^3 0 0 30 HPLC:MgDVP mg/m^3 0.1E-02 0.5E-02 31 HPLC:Chl-c2 mg/m^3 0.18E-01 0.36E-01 32 HPLC:Chl-c1 mg/m^3 0 0 33 HPLC:Me-chlide mg/m^3 0 0 34 HPLC:Peri mg/m^3 0 0 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0.16E-01 0.34E-01 37 HPLC:Fuco mg/m^3 0.27E-01 0.53E-01 38 HPLC:Neo mg/m^3 0.3E-02 0.1E-01 39 HPLC:Pras mg/m^3 0 0 40 HPLC:Viola mg/m^3 0.2E-02 0.8E-02 41 HPLC:Hex-fuco mg/m^3 0.71E-01 0.135 42 HPLC:Diadino mg/m^3 0.9E-02 0.36E-01 43 HPLC:Allo mg/m^3 0 0.2E-02 44 HPLC:Diato mg/m^3 0 0.6E-02 45 HPLC:Zea mg/m^3 0.14E-01 0.18E-01 46 HPLC:Lut mg/m^3 0.7E-02 0.13E-01 47 HPLC:Chl-b mg/m^3 0.36E-01 0.73E-01 48 HPLC:C2mgdg mg/m^3 0.1E-02 0.7E-02 49 HPLC:DVChl-a mg/m^3 0 0 50 HPLC:Chl-a mg/m^3 0.206 0.299 51 HPLC:Phe mg/m^3 0 0 52 HPLC:B-Car mg/m^3 0.2E-02 0.4E-02 53 HPLC:TChl-a mg/m^3 0.206 0.299 54 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 7 F R4 2 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 7 F R4 2 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 7 F ' ' 1 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2017-06 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P26 EVENT NUMBER : 87 LATITUDE : 50 0.01000 N ! (deg min) LONGITUDE : 144 59.98000 W ! (deg min) WATER DEPTH : 4250 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 4484 Conductivity:2 ' ' 3531 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3685 'Transmissometer:WET Labs C-Star' ' ' 1201DR PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 62355 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.26.1.8 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.5.2 2017/09/01 10:38:20 4498 4498 CLEAN 5.2.2 2017/09/01 10:39:22 4498 4498 ADDSAMP 3.6 2017/09/01 11:20:17 4498 4498 BINAVE 4.2 2017/09/01 16:15:22 4498 21 MERGE 3.5 2017/09/20 09:53:25 21 21 CLEAN 5.2.2 2017/09/20 09:53:30 21 21 CALIB 11.9 2017/09/20 09:53:38 21 21 SORT 3.6 2017/09/20 15:11:25 21 21 REMOVECH 8.2 2017/09/20 15:11:33 21 21 CHGUNITS 3.1.1 2017/09/20 15:11:50 21 21 CHGUNITS 3.1.1 2017/09/20 15:11:53 21 21 REORDER 1.3.1 2017/09/20 15:12:04 ? ? HDREDIT2 3.1.1 2017/09/20 15:12:10 ? ? SORT 3.6 2019/11/27 11:12:27 21 21 HDREDIT2 3.1.1 2019/11/27 11:12:59 ? ? MERGE 3.5 2019/11/27 11:13:04 21 21 SORT 3.6 2019/11/27 11:14:55 21 21 HDREDIT2 3.1.1 2019/11/27 11:15:00 ? ? SORT 3.6 2020/09/02 19:29:36 21 21 REORDER 1.3.1 2021/12/06 15:47:18 ? ? MERGE 3.5.1 2021/12/06 15:47:30 21 21 SORT 3.6 2021/12/06 15:47:39 21 21 CLEAN 5.2.4 2021/12/06 15:47:47 21 21 HDREDIT2 3.2 2021/12/06 15:48:34 ? ? HDREDIT2 3.2 2021/12/06 15:49:04 ? ? $END $REMARKS -CLEAN functions: 2017/09/01 10:38:56 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2017-06\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2017/09/20 09:53:25 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Ammonium, Flag:Ammonium Primary file : P:\Cruise_Data_Processing\2017-06\Processing\hydro\2017-06-0087.samavg Secondary file: P:\Cruise_Data_Processing\2017-06\Processing\hydro\2017-06-0087.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2017-06\Processing\hydro\2017-06-0087.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2017/09/20 09:34:53 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2017/09/20 09:53:28 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -CALIB parameters: 2017/09/20 09:53:38 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2017-06\Processing\doc\2017-06-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.6450000E-01 0.1039900E+01 -SORT parameters: 2017/09/20 15:11:25 Sorted in ascending order of channel Pressure* -REMOVECH 2017/09/20 15:11:33 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Transmissivity [%/metre] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2017/09/20 15:12:10 Applied edit header: P:\Cruise_Data_Processing\2017-06\Processing\doc\HYDRO\2017-06-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 14: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 17: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 18: Silicate [umol/L] Units: ==> umol/L Channel 19: Flag:Silicate [n/a] Units: ==> n/a Channel 20: Phosphate [umol/L] Units: ==> umol/L Channel 21: Flag:Phosphate [n/a] Units: ==> n/a Channel 22: Dimethyl_Sulphide [nmol/L] Units: ==> nmol/L Channel 23: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a -SORT parameters: 2019/11/27 11:12:27 Sorted in ascending order of channel Sample_number -HEADER EDITS: 2019/11/27 11:12:59 -The following MERGE parameters were used: 2019/11/27 11:13:04 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\2017-006\Processing\Bottle\2017-006-0087.rem Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2017-006\Processing\Bottle\2017-006-0087. dmsp -SORT parameters: 2019/11/27 11:14:55 Sorted in ascending order of channel Pressure -HEADER EDITS: 2019/11/27 11:15:00 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2017-006\Processing\Bottle\2017-006- dmsp-hdr.txt -SORT parameters: 2020/09/02 19:29:36 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/12/06 15:47:30 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-006_Nov2021\Processing\ IOS\2017-006-0087.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-006_Nov2021\Processing\ IOS\2017-006-0087.hplc -SORT parameters: 2021/12/06 15:47:39 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/12/06 15:47:46 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/12/06 15:48:34 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-006-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/12/06 15:49:04 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-006-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2017-06\2017-06-0087.hex Software Version Seasave V 7.26.1.8 Temperature SN = 4054 Conductivity SN = 1766 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jun 12 2017 21:57:07 NMEA Latitude = 50 00.01 N NMEA Longitude = 144 59.98 W NMEA UTC (Time) = Jun 12 2017 21:51:29 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Mission: 2017-05 Ship: J.P. Tully Station: P26 Depth: 4225 DMS cast System UTC = Jun 12 2017 21:57:07 # nquan = 20 # nvalues = 4498 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = altM: Altimeter [m] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jun 12 2017 21:51:29 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4054 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616406e-003 # 6.44028261e-004 # 2.29631886e-005 # 2.07487665e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12892961e+000 # 4.88377974e-001 # -6.29237468e-004 # 5.38259078e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 24-Feb-17 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99995690 # 0.08882 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4484 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39937667e-003 # 6.40472023e-004 # 2.15385278e-005 # 1.84322868e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02129539e+001 # 1.56309188e+000 # -2.40628351e-003 # 2.66312047e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 28-Mar-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.7570e-001 # -0.5165 # -3.9454e-003 # 1.7154e-004 # -2.7543e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.8000e-002 # 1.0300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # 13-Mar-17 # # 2 # 0.000 # # # # # # 1201DR # 15 April 2016 # 19.2119 # -0.1153 # 0.250 # # # # # # # # # 70613 # 03/21/16 # 1.00000000 # 0.00000000 # 11876484560.57000000 # 1.00000000 # -0.08460000 # # # # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # datcnv_date = Sep 01 2017 10:37:52, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2017-06\RAW\CTD\2017-06-0087.hex P:\Crui se_Data_Processing\2017-06\Processing\doc\2017-06-ctd.xmlcon # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2017-006\Processing\Bottle\2017-006-0087.dmsp --------------------------------------------------------------------------- Sample_Number 579: DMSP-D & DMSP-T: Elevated results due to contamination Sample_Number 580: DMSP-D & DMSP-T: Elevated results due to contamination Sample_Number 586: DMSP-D & DMSP-T: Elevated results due to contamination Sample_Number 588: DMSP-D & DMSP-T: Elevated results due to contamination Sample_Number 591: DMSP-D & DMSP-T: Elevated results due to contamination Sample_Number 592: DMSP-D & DMSP-T: Elevated results due to contamination Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 within ~5 weeks of the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.04-12.68ug/l. Average %CV for this cruise was 1.96% with 1 out of 60 duplicate pairs having a CV>10% and 0 out of 60 duplicate pairs having a CV>30%. Our average dataset %CV is 3.72% for 2013 - 2016 so the overall quality of this dataset is excellent. For details see worksheet “CV%” in file QF2017-06CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2017-006_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2017-06OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 5 - 18 days after collection. For details including a duplicate analysis, see document QF2017-06SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2017-06nuts*.xls. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100 deg C (with a dewar containing boiling water) onto a Choromasorb 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. For more detail see file "2017-06 DMS report.doc" and for data and duplicate analysis see "DMS summary (2017-06).xls." The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.1nmol/L. DMSP-D: 20-75mL of seawater was allowed to flow directly from the niskin into a magnetic filtration funnel containing a 0.7um GF/F filter. The first 3.5mL was collected in a polypropylene tube containing 50uL of a 50% sulphuric acid solution. DMPS-T: 3.5mL of seawater was collected directly from the niskin into a polypropylene tube containing 50uL of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. For details on analysis and raw data, see document "QF 2017-006 dmsp*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. Transmissivity data were removed because they were clearly bad below about 250m of the downcast and through most of the upcast. Similar results were found when this sensor was used during other recent cruises. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2017-06_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2017\2017-006_Nov2021\Processing\IOS\2017-006-0087. hplc --------------------------------------------------------------------------- Sample_Number 589: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.645E-01 1.0399) $END !-1-- -2-- -3-- --4--- ---5---- ---6--- --7--- ---8---- --9--- --10- -11- --12-- 13 --14-- 15 ---16-- 17 --18-- 19 --20-- 21 --22-- 23 --24-- 25 --26-- --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- 54 !Samp Bott Bott Pressu Temperat Fluores PAR Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl Phaeo- Depth HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: cence: :T0:C0 : n: er_o e_ ag te ag te ag yl_ ag ylsulf ag ylsulf ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Nitrit ri ca ha de hi te_Dis lv ionate ot ted ct Extrac HP ! ence t SBE SBE ords e te te te de solved ed _Total al ed ted LC !---- ---- ---- ------ -------- ------- ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------ -- ------ ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 592 15 20 2.2 8.8876 0.232 754.9 32.4527 6.78 295.5 83 12.32 0 18.58 0 1.196 0 2.77 0 -99.00 5 -99.00 5 0.23 0 0.08 2.2 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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