*2023/04/18 15:09:07.25 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2017/06/06 03:49:58.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 19 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : BB167FF1 NUMBER OF CHANNELS : 36 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 76 94 2 Bottle_Number n/a 1 19 3 Bottle:Firing_Sequence n/a 1 19 4 Pressure decibar 4.8 1305.3 5 Depth metres 4.8 1290.2 6 Temperature:Primary 'deg C (ITS90)' 2.8916 12.7462 7 Fluorescence:URU:Seapoint mg/m^3 0.44E-01 1.32 8 PAR uE/m^2/sec 0 0.1 9 Salinity:T0:C0 PSS-78 31.7004 34.4756 10 Oxygen:Dissolved:SBE mL/L 0.24 6.75 11 Oxygen:Dissolved:SBE umol/kg 10.3 293.8 12 Number_of_bin_records n/a 66 241 13 Temperature:Draw 'deg C (ITS90)' 4.7 13.5 14 Salinity:Bottle PSS-78 31.6644 34.4649 15 Flag:Salinity:Bottle n/a 16 Oxygen:Dissolved mL/L 0.237 6.761 17 Oxygen:Dissolved umol/kg 10.3 294.5 18 Flag:Oxygen:Dissolved n/a 19 Nitrate_plus_Nitrite umol/L 0 45 20 Flag:Nitrate_plus_Nitrite n/a 21 Silicate umol/L 2.98 148.03 22 Flag:Silicate n/a 23 Phosphate umol/L 0.221 3.326 24 Flag:Phosphate n/a 25 Carbon:Dissolved:Inorganic umol/kg 1942.1 2170 26 Flag:Carbon:Dissolved:Inorganic n/a 27 Alkalinity:Total umol/kg 2139.4 2244.6 28 Flag:Alkalinity:Total n/a 29 Carbon:Dissolved:Organic uM 48.7 68.6 30 Flag:Carbon:Dissolved:Organic n/a 31 Carbon:Total:Organic uM 41.4 48.8 32 Flag:Carbon:Total:Organic n/a 33 Nitrogen:Total:Dissolved uM 4.5 40.9 34 Flag:Nitrogen:Total:Dissolved n/a 35 Nitrogen:Total uM 41.1 51.6 36 Flag:Nitrogen:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 ' ' ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 9 F R4 4 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 1 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 1 28 0 ' ' 3 NQ C ' ' 29 -99 ' ' ' ' F7.1 R4 ' ' 30 0 ' ' 3 NQ C ' ' 31 -99 ' ' ' ' F7.1 R4 ' ' 32 0 ' ' 3 NQ C ' ' 33 -99 ' ' ' ' F7.1 R4 ' ' 34 0 ' ' 3 NQ C ' ' 35 -99 ' ' ' ' F7.1 R4 ' ' 36 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2017-06 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P4 EVENT NUMBER : 16 LATITUDE : 48 39.13000 N ! (deg min) LONGITUDE : 126 39.98000 W ! (deg min) WATER DEPTH : 1299 ALTIMETER (M) : 10.62 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 4484 Conductivity:2 ' ' 3531 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3685 'Transmissometer:WET Labs C-Star' ' ' 1201DR PAR/Irradiance:Biospherical/Licor ' ' 70613 Altimeter ' ' 62355 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.26.1.8 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.5.2 2017/09/01 10:37:58 4404 4404 CLEAN 5.2.2 2017/09/01 10:39:00 4404 4404 ADDSAMP 3.6 2017/09/01 11:19:57 4404 4404 BINAVE 4.2 2017/09/01 16:15:11 4404 19 MERGE 3.5 2017/09/20 09:53:22 19 19 CLEAN 5.2.2 2017/09/20 09:53:28 19 19 CALIB 11.9 2017/09/20 09:53:36 19 19 SORT 3.6 2017/09/20 15:11:24 19 19 REMOVECH 8.2 2017/09/20 15:11:32 19 19 CHGUNITS 3.1.1 2017/09/20 15:11:49 19 19 CHGUNITS 3.1.1 2017/09/20 15:11:51 19 19 REORDER 1.3.1 2017/09/20 15:12:01 ? ? HDREDIT2 3.1.1 2017/09/20 15:12:08 ? ? SORT 3.6 2021/04/15 15:51:52 19 19 MERGE 3.6 2021/04/15 15:53:33 19 19 SORT 3.6 2021/04/15 15:54:43 19 19 HDREDIT2 3.2 2021/04/15 15:55:43 ? ? SORT 3.6 2021/05/14 13:52:47 19 19 MERGE 3.6 2021/05/14 14:00:13 19 19 SORT 3.6 2021/05/14 14:49:24 19 19 CLEAN 5.2.4 2021/05/14 14:49:36 19 19 HDREDIT2 3.2 2021/05/14 14:49:46 ? ? HDREDIT2 3.2 2023/04/18 15:09:07 ? ? $END $REMARKS -CLEAN functions: 2017/09/01 10:38:56 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2017-06\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2017/09/20 09:53:22 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide, Ammonium, Flag:Ammonium Primary file : P:\Cruise_Data_Processing\2017-06\Processing\hydro\2017-06-0016.samavg Secondary file: P:\Cruise_Data_Processing\2017-06\Processing\hydro\2017-06-0016.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2017-06\Processing\hydro\2017-06-0016.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2017/09/20 09:18:07 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2017/09/20 09:53:28 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -CALIB parameters: 2017/09/20 09:53:36 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2017-06\Processing\doc\2017-06-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.6450000E-01 0.1039900E+01 -SORT parameters: 2017/09/20 15:11:24 Sorted in ascending order of channel Pressure* -REMOVECH 2017/09/20 15:11:32 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Transmissivity [%/metre] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2017/09/20 15:12:08 Applied edit header: P:\Cruise_Data_Processing\2017-06\Processing\doc\HYDRO\2017-06-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 15: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 16: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 18: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 19: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 20: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 21: Silicate [umol/L] Units: ==> umol/L Channel 22: Flag:Silicate [n/a] Units: ==> n/a Channel 23: Phosphate [umol/L] Units: ==> umol/L Channel 24: Flag:Phosphate [n/a] Units: ==> n/a -SORT parameters: 2021/04/15 15:51:52 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/04/15 15:53:33 Merge Channel: Sample_Number Merge Scheme Used: 2: Add Secondary to Closest Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic [ ], Flag:Carbon:Dissolved:Inorganic [ ], Alkalinity:Total [ ], Flag:Alkalinity:Total [ ] Primary file : C:\Users\huntingtons\Desktop\Carbon Additions\2017-006\Processing\2017-006-0016. srt1 Secondary file: C:\Users\huntingtons\Desktop\Carbon Additions\2017-006\Processing\2017-006-0016.dic 19 secondary records matched to primary records. -SORT parameters: 2021/04/15 15:54:43 Sorted in ascending order of channel Pressure [decibar] -HEADER EDITS: 2021/04/15 15:55:43 Applied edit header: C:\Users\huntingtons\Desktop\Carbon Additions\2017-006\Processing\2017-006_ header.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 25: Carbon:Dissolved:Inorganic [umol/kg] Units: ==> umol/kg Channel 26: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 27: Alkalinity:Total [umol/kg] Units: ==> umol/kg Channel 28: Flag:Alkalinity:Total [n/a] Units: ==> n/a -SORT parameters: 2021/05/14 13:52:47 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/05/14 14:00:13 Merge Channel: Sample_Number Merge Scheme Used: 2: Add Secondary to Closest Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Organic [ ], Flag:Carbon:Dissolved:Organic [ ], Carbon:Total:Organic [ ], Flag:Carbon:Total:Organic [ ], Nitrogen:Total:Dissolved [ ], Flag:Nitrogen:Total:Dissolved [ ], Nitrogen:Total [ ], Flag:Nitrogen:Total [ ] Primary file : C:\Users\huntingtons\Desktop\Total Nitrate Additions\2017-06\Processing\2017-006- 0016.srt1 Secondary file: C:\Users\huntingtons\Desktop\Total Nitrate Additions\2017-06\Processing\2017-006- 0016.TNsrt 18 secondary records matched to primary records. -SORT parameters: 2021/05/14 14:49:24 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/05/14 14:49:36 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/05/14 14:49:46 Applied edit header: C:\Users\huntingtons\Desktop\Total Nitrate Additions\TN_header.txt Channel 29: Carbon:Dissolved:Organic [uM] Units: ==> uM Channel 30: Flag:Carbon:Dissolved:Organic [n/a] Units: ==> n/a Channel 31: Carbon:Total:Organic [uM] Units: ==> uM Channel 32: Flag:Carbon:Total:Organic [n/a] Units: ==> n/a Channel 33: Nitrogen:Total:Dissolved [uM] Units: ==> uM Channel 34: Flag:Nitrogen:Total:Dissolved [n/a] Units: ==> n/a Channel 35: Nitrogen:Total [uM] Units: ==> uM Channel 36: Flag:Nitrogen:Total [n/a] Units: ==> n/a -HEADER EDITS: 2023/04/18 15:09:07 Channel 25: Carbon:Dissolved:Inorganic [umol/kg] Format: F8.2 ==> F7.1 $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2017-06\2017-06-0016.hex Software Version Seasave V 7.26.1.8 Temperature SN = 4054 Conductivity SN = 1766 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jun 06 2017 03:51:38 NMEA Latitude = 48 39.13 N NMEA Longitude = 126 39.98 W NMEA UTC (Time) = Jun 06 2017 03:49:58 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Mission: 2017-05 Ship: J.P. Tully Station: P4 Depth: 1320 System UTC = Jun 06 2017 03:51:38 # nquan = 20 # nvalues = 4404 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = depSM: Depth [salt water, m] # name 5 = t090C: Temperature [ITS-90, deg C] # name 6 = t190C: Temperature, 2 [ITS-90, deg C] # name 7 = c0S/m: Conductivity [S/m] # name 8 = c1S/m: Conductivity, 2 [S/m] # name 9 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 10 = flSP: Fluorescence, Seapoint # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = par: PAR/Irradiance, Biospherical/Licor # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = altM: Altimeter [m] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jun 06 2017 03:49:58 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4054 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38616406e-003 # 6.44028261e-004 # 2.29631886e-005 # 2.07487665e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12892961e+000 # 4.88377974e-001 # -6.29237468e-004 # 5.38259078e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 24-Feb-17 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 0.99995690 # 0.08882 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4484 # 22-Feb-17 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39937667e-003 # 6.40472023e-004 # 2.15385278e-005 # 1.84322868e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 30-Mar-17 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02129539e+001 # 1.56309188e+000 # -2.40628351e-003 # 2.66312047e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 28-Mar-17 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 5.7570e-001 # -0.5165 # -3.9454e-003 # 1.7154e-004 # -2.7543e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.8000e-002 # 1.0300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3685 # 13-Mar-17 # # 2 # 0.000 # # # # # # 1201DR # 15 April 2016 # 19.2119 # -0.1153 # 0.250 # # # # # # # # # 70613 # 03/21/16 # 1.00000000 # 0.00000000 # 11876484560.57000000 # 1.00000000 # -0.08460000 # # # # # # # # # 62355 # # 15.000 # 0.000 # # # # # # # datcnv_date = Sep 01 2017 10:35:08, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2017-06\RAW\CTD\2017-06-0016.hex P:\Crui se_Data_Processing\2017-06\Processing\doc\2017-06-ctd.xmlcon # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2017-06\Processing\hydro\2017-06-0016.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2017-06\Processing\hydro\2017-06-0016.oxy ------------------------------------------------------------------- Sample_Number 78: OXY-1: Sample over-titrated. Sample_Number 76: DIC & ALK: Values not reported Sample_Number 77: DIC & ALK: Values not reported Sample_Number 78: DIC & ALK: Values not reported Sample_Number 79: DIC & ALK: Values not reported Sample_Number 80: DIC & ALK: Values not reported Sample_Number 81: DIC & ALK: Values not reported Sample_Number 82: DIC & ALK: Values not reported Sample_Number 83: DIC & ALK: Values not reported Sample_Number 84: DIC & ALK: Values not reported Sample_Number 85: DIC & ALK: Values not reported Sample_Number 86: DIC & ALK: Values not reported Sample_Number 87: DIC & ALK: Values not reported Sample_Number 90: DIC: Does not fit local oceanographic context Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 within ~5 weeks of the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.04-12.68ug/l. Average %CV for this cruise was 1.96% with 1 out of 60 duplicate pairs having a CV>10% and 0 out of 60 duplicate pairs having a CV>30%. Our average dataset %CV is 3.72% for 2013 - 2016 so the overall quality of this dataset is excellent. For details see worksheet “CV%” in file QF2017-06CHL*.xls. Oxygen samples were analyzed at sea using an automated Winkler titration System (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2017-06OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 5 - 18 days after collection. For details including a duplicate analysis, see document QF2017-06SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2017-06nuts*.xls. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100 deg C (with a dewar containing boiling water) onto a Choromasorb 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. For more detail see file "2017-06 DMS report.doc" and for data and duplicate analysis see "DMS summary (2017-06).xls." The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.1nmol/L. DOC, TOC, TDN, and TN samples were collected in 80 mL polycarbonate bottles and frozen until analysis. DOC/TDN samples were filtered inline from the Niskin bottles, using acid-washed filter holders and tubing and pre-combusted GF/F filters. For analysis, samples were thawed and acidified with 4M HCl at a ratio of 100 uL HCL to 40 mL seawater. DOC/TDN samples were collected for depths <250 meters, and TOC/TN samples were collected for depths >250 meters. The full data set may be found in document LineP-DOC-TOC-TN-TDN.xlsx. For details on analysis of Dissolved inorganic carbon (DIC) and Total alkalinity (Alk) refer to: https://www.ncei.noaa.gov/access/metadata/landing-page/bin/iso?id=gov.noaa.nodc:0225534. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. Transmissivity data were removed because they were clearly bad below about 250m of the downcast and through most of the upcast. Similar results were found when this sensor was used during other recent cruises. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2017-06_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.645E-01 1.0399) $END !-1-- -2-- -3-- --4--- --5--- ---6---- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14--- 15 ---16-- --17- 18 --19-- 20 --21-- 22 ---23-- 24 --25-- 26 --27-- 28 --29-- 30 --31-- 32 --33-- 34 --35-- 36 !Samp Bott Bott Pressu Depth Temperat Fluores PAR Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Carbon Fl Alkali Fl Carbon Fl Carbon Fl Nitrog Fl Nitrog Fl !le_ le_ le:F re ure: cence: :T0:C0 : n: er_o ratur :Bottle ag Dissolv n: ag e_ ag te ag te ag :Disso ag nity: ag : ag : ag en: ag en: ag !Numb Numb ~ng_ Primary URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p lved: ~g Total ~T Dissol ~g Total: ~g Total: ~o Total ~T !er er Sequ Seapoin ved: lved: _rec Draw tt lved lv Nitrit ri ca ha Inorga an ot ved:Or an Organi an Dissol lv ot ! ence t SBE SBE ords le ed e te te te nic ic al ganic ic c ic ved ed al !---- ---- ---- ------ ------ -------- ------- ------ -------- ------ ----- ---- ----- -------- -- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------ -- ------ -- ------ -- *END OF HEADER 94 19 19 4.8 4.8 12.7462 0.295 0.1 31.7004 6.41 279.3 241 13.5 31.6644 0 6.419 279.9 6 0.00 0 2.98 0 0.221 0 1942.1 0 2139.4 0 68.6 0 -99.0 0 4.5 0 -99.0 0 93 18 18 10.4 10.3 12.0967 0.365 0.1 31.9021 6.55 285.6 241 12.6 -99.0000 0 6.582 286.9 0 0.00 0 3.62 0 0.255 0 1987.7 0 2152.1 0 66.7 0 -99.0 0 4.6 0 -99.0 0 92 17 17 25.0 24.8 9.8876 1.320 0.0 32.4349 6.75 293.8 241 10.6 -99.0000 0 6.761 294.5 0 2.18 0 6.29 0 0.475 0 2033.2 0 2168.1 0 65.1 0 -99.0 0 6.7 0 -99.0 0 91 16 16 50.3 49.9 9.0309 0.603 0.0 32.7271 5.71 248.6 241 9.9 -99.0000 0 5.713 248.8 0 9.51 0 10.09 0 0.933 0 2088.5 0 2185.9 0 56.8 0 -99.0 0 12.3 0 -99.0 0 90 15 15 75.5 74.8 9.0452 0.244 0.0 33.2406 4.22 183.8 241 9.9 -99.0000 0 4.403 191.7 0 17.60 0 18.54 0 1.408 0 1949.3 3 2206.8 0 56.0 0 -99.0 0 20.4 0 -99.0 0 89 14 14 101.1 100.2 8.6230 0.123 0.0 33.6223 3.42 149.0 241 9.5 -99.0000 0 3.456 150.4 0 24.49 0 27.29 0 1.798 0 2156.1 0 2232.6 0 63.7 0 -99.0 0 27.4 0 -99.0 0 88 13 13 125.6 124.5 8.2818 0.073 0.0 33.7545 3.21 139.8 241 9.1 -99.0000 0 3.235 140.7 0 26.51 6 31.34 6 1.905 6 2170.0 0 2244.6 0 53.4 0 -99.0 0 28.5 0 -99.0 0 87 12 12 150.1 148.8 7.9461 0.057 0.0 33.8576 2.81 122.2 241 8.8 -99.0000 0 2.806 122.1 0 29.01 0 36.82 0 2.116 0 -99.0 1 -99.0 1 51.0 0 -99.0 0 31.7 0 -99.0 0 86 11 11 174.9 173.3 7.5320 0.052 0.0 33.9137 2.56 111.1 241 8.5 -99.0000 0 2.575 112.0 6 30.66 0 41.53 0 2.241 0 -99.0 1 -99.0 1 49.8 0 -99.0 0 34.9 0 -99.0 0 85 10 10 200.4 198.6 7.1359 0.050 0.0 33.9512 2.21 96.0 241 8.1 -99.0000 0 2.210 96.1 0 32.69 0 47.24 0 2.396 0 -99.0 1 -99.0 1 48.7 0 -99.0 0 37.0 0 -99.0 0 84 9 9 250.2 247.9 6.4496 0.049 0.0 33.9854 1.78 77.2 241 7.6 -99.0000 0 1.778 77.3 0 35.65 0 56.37 0 2.572 0 -99.0 1 -99.0 1 55.2 0 -99.0 0 40.9 0 -99.0 0 83 8 8 300.6 297.8 5.9958 0.049 0.0 33.9954 1.53 66.4 241 7.3 -99.0000 0 1.523 66.2 0 37.43 0 62.67 0 2.825 0 -99.0 1 -99.0 1 -99.0 0 48.8 0 -99.0 0 41.1 0 82 7 7 401.2 397.4 5.3104 0.049 0.0 34.0419 1.03 44.6 241 6.7 -99.0000 0 1.022 44.4 0 40.42 0 75.99 0 2.889 0 -99.0 1 -99.0 1 -99.0 0 47.1 0 -99.0 0 45.6 0 81 6 6 600.5 594.5 4.2855 0.048 0.0 34.1283 0.59 25.6 241 5.9 -99.0000 0 0.603 26.2 0 43.52 6 99.39 6 3.144 6 -99.0 1 -99.0 1 -99.0 0 48.1 0 -99.0 0 49.1 0 80 5 5 800.2 791.9 3.9948 0.047 0.0 34.2905 0.24 10.3 241 5.8 34.2881 0 0.237 10.3 0 44.33 0 114.37 0 3.256 0 -99.0 1 -99.0 1 -99.0 0 45.2 0 -99.0 0 50.3 0 79 4 4 1000.4 989.5 3.5733 0.045 0.0 34.3880 0.26 11.4 241 5.4 34.3882 6 0.270 11.7 0 44.63 0 128.50 0 3.326 0 -99.0 1 -99.0 1 -99.0 0 44.6 0 -99.0 0 51.6 0 78 3 3 1251.0 1236.7 2.9952 0.044 0.0 34.4638 0.42 18.2 241 4.9 34.4649 6 0.431 18.7 26 44.55 0 144.75 0 3.289 0 -99.0 1 -99.0 1 -99.0 0 -99.0 0 -99.0 0 -99.0 0 77 2 2 1251.1 1236.8 2.9953 0.044 0.0 34.4637 0.42 18.2 66 4.7 34.4647 0 0.412 17.9 0 45.00 0 144.70 0 3.291 0 -99.0 1 -99.0 1 -99.0 0 41.5 0 -99.0 0 50.7 0 76 1 1 1305.3 1290.2 2.8916 0.046 0.0 34.4756 0.46 20.0 241 4.7 -99.0000 0 0.450 19.6 0 44.25 0 148.03 0 3.280 0 -99.0 1 -99.0 1 -99.0 0 41.4 0 -99.0 0 49.9 0