*2021/11/25 16:03:21.83 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2016/05/26 05:45:36.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 1 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : D23F4D91 NUMBER OF CHANNELS : 49 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 25 25 2 Bottle_Number n/a 1 1 3 Bottle:Firing_Sequence n/a 1 1 4 Pressure decibar 4.4 4.4 5 Temperature:Secondary 'deg C (ITS90)' 11.9951 11.9951 6 Transmissivity %/metre 28.3 28.3 7 Fluorescence:URU:Seapoint mg/m^3 3.966 3.966 8 PAR uE/m^2/sec 0 0 9 PAR1 uE/m^2/sec 0.1 0.1 10 Salinity:T1:C1 PSS-78 30.7968 30.7968 11 Oxygen:Dissolved:SBE mL/L 6.6 6.6 12 Oxygen:Dissolved:SBE umol/kg 287.8 287.8 13 Number_of_bin_records n/a 241 241 14 Nitrate_plus_Nitrite umol/L 15.52 15.52 15 Flag:Nitrate_plus_Nitrite ' ' 16 Silicate umol/L 32.19 32.19 17 Flag:Silicate ' ' 18 Phosphate umol/L 1.335 1.335 19 Flag:Phosphate ' ' 20 Chlorophyll:Extracted mg/m^3 5.15 5.15 21 Flag:Chlorophyll:Extracted ' ' 22 Phaeo-Pigment:Extracted mg/m^3 1.1 1.1 23 HPLC:Chl-c3 mg/m^3 0.67E-01 0.67E-01 24 HPLC:Chlide-a mg/m^3 0.89E-01 0.89E-01 25 HPLC:MgDVP mg/m^3 0.57E-01 0.57E-01 26 HPLC:Chl-c2 mg/m^3 0.442 0.442 27 HPLC:Chl-c1 mg/m^3 0.55E-01 0.55E-01 28 HPLC:Me-chlide mg/m^3 0.117 0.117 29 HPLC:Peri mg/m^3 0.508 0.508 30 HPLC:Pheide-a mg/m^3 0 0 31 HPLC:But-fuco mg/m^3 0.58E-01 0.58E-01 32 HPLC:Fuco mg/m^3 0.995 0.995 33 HPLC:Neo mg/m^3 0.11 0.11 34 HPLC:Pras mg/m^3 0.82E-01 0.82E-01 35 HPLC:Viola mg/m^3 0.75E-01 0.75E-01 36 HPLC:Hex-fuco mg/m^3 0.71E-01 0.71E-01 37 HPLC:Diadino mg/m^3 0.381 0.381 38 HPLC:Allo mg/m^3 0.427 0.427 39 HPLC:Diato mg/m^3 0.47E-01 0.47E-01 40 HPLC:Zea mg/m^3 0.13E-01 0.13E-01 41 HPLC:Lut mg/m^3 0.17E-01 0.17E-01 42 HPLC:Chl-b mg/m^3 0.5 0.5 43 HPLC:C2mgdg mg/m^3 0.31E-01 0.31E-01 44 HPLC:DVChl-a mg/m^3 0 0 45 HPLC:Chl-a mg/m^3 4.256 4.256 46 HPLC:Phe mg/m^3 0 0 47 HPLC:B-Car mg/m^3 0.206 0.206 48 HPLC:TChl-a mg/m^3 4.462 4.462 49 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 -99 ' ' 5 I I 0 14 -99 ' ' 7 F R4 2 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 8 F R4 3 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2016-47 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse Zooplankton Monitoring SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LB03 EVENT NUMBER : 8 LATITUDE : 48 37.31000 N ! (deg min) LONGITUDE : 125 5.65000 W ! (deg min) WATER DEPTH : 95 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2663 Conductivity:2 ' ' 2754 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1185DR Altimeter ' ' 62354 PAR/Irradiance:Biospherical/Licor ' ' 70613 PAR/Irradiance:Biospherical/Licor:2 ' ' 4615 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.23.2 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.5 2016/08/05 16:17:57 241 241 CLEAN 5.2.1 2016/08/05 16:25:48 241 241 ADDSAMP 3.6 2016/08/05 17:25:52 241 241 BINAVE 4.2 2016/08/05 17:26:30 241 1 MERGE 3.5 2016/08/09 09:17:47 1 1 CLEAN 5.2.1 2016/08/09 09:17:54 1 1 CALIB 11.8.1 2016/08/23 09:39:33 1 1 CALIB 11.8.1 2016/08/23 09:39:50 1 1 SORT 3.6 2016/08/23 09:40:04 1 1 REMOVECH 8.2 2016/08/23 09:40:16 1 1 CHGUNITS 3.1 2016/08/23 09:42:13 1 1 CHGUNITS 3.1 2016/08/23 09:42:37 1 1 REORDER 1.3.1 2016/08/23 09:42:50 ? ? HDREDIT2 3.0.2 2016/08/23 09:42:57 ? ? HDREDIT2 3.0.2 2016/09/13 09:17:34 ? ? SORT 3.6 2020/08/10 19:06:13 1 1 REORDER 1.3.1 2021/11/25 16:00:27 ? ? MERGE 3.5.1 2021/11/25 16:00:44 1 1 SORT 3.6 2021/11/25 16:00:54 1 1 CLEAN 5.2.4 2021/11/25 16:01:02 1 1 HDREDIT2 3.2 2021/11/25 16:02:25 ? ? HDREDIT2 3.2 2021/11/25 16:03:21 ? ? $END $REMARKS -CLEAN functions: 2016/08/05 16:25:46 20 Reset #RECS, MIN & MAX values in header. Insert Pad Values in Channel: Fluorescence:URU:Seapoint [mg/m^3] where channel Fluorescence:URU:Seapoint [mg/m^3] is in the range 14.82 to 15 0 data records in pad range. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2016-47\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2016/08/09 09:17:47 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2016-47\Processing\hydro\2016-47-0008.samavg Secondary file: P:\Cruise_Data_Processing\2016-47\Processing\hydro\2016-47-0008.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2016-47\Processing\hydro\2016-47-0008.mrgcln1s ------------------------------------------------------------------------ -CLEAN functions: 2016/08/08 08:49:34 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2016/08/08 08:50:00 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2016/08/09 09:17:54 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name -CALIB parameters: 2016/08/23 09:39:33 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Salinity is computed Calibration file = P:\Cruise_Data_Processing\2016-47\Processing\doc\2016-47-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 5 Temperature:Primary deg C (IT 10 -0.2000000E-02 0.1000000E+01 19 Oxygen:Dissolved:SBE mL/L 10 0.3770000E-01 0.1020800E+01 Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T0:C0 PSS-78 130 Pressure Temperature:Primary Conductivity:Primary -CALIB parameters: 2016/08/23 09:39:50 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2016-47\Processing\doc\2016-47-recal2.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T0:C0 PSS-78 10 0.4000000E-02 0.1000000E+01 18 Salinity:T1:C1 PSS-78 10 0.2000000E-02 0.1000000E+01 -SORT parameters: 2016/08/23 09:40:04 Sorted in ascending order of channel Pressure* -REMOVECH 2016/08/23 09:40:16 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temp* Salinity reference channel: Salin* 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salin* - No units changed -HEADER EDITS: 2016/08/23 09:42:57 Applied edit header: P:\Cruise_Data_Processing\2016-47\Processing\doc\HYDRO\2016-47-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: Oxygen:Dissolved:SBE [mL/L] Format: F11.3 ==> F7.2 Channel 14: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 16: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 19: Silicate [umol/L] Units: ==> umol/L Channel 21: Phosphate [umol/L] Units: ==> umol/L Channel 8: PAR1 [uE/m^2/sec] Name: PAR:1 ==> PAR1 Format: F11.3 ==> F7.1 -HEADER EDITS: 2016/09/13 09:17:34 Applied edit header: P:\Cruise_Data_Processing\Temp\2016-47-temp\Bottle\2016-47-HDR2.TXT -SORT parameters: 2020/08/10 19:06:13 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 16:00:44 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-047_Nov2021\Processing\ IOS\2016-047-0008.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-047_Nov2021\Processing\ IOS\2016-047-0008.hplc -SORT parameters: 2021/11/25 16:00:54 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 16:01:02 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 16:02:25 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016_047\Processing\IOS\ 2016-047-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 23: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 16:03:21 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016_047\Processing\IOS\ 2016-047-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2016-47\2016-47-0008.hex Software Version Seasave V 7.23.2 Temperature SN = 2106 Conductivity SN = 2280 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = May 26 2016 05:52:10 NMEA Latitude = 48 37.31 N NMEA Longitude = 125 05.65 W NMEA UTC (Time) = May 26 2016 05:45:36 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Mission: 2016-47 Ship: J.P. Tully Station: LB03 Depth: 95 System UTC = May 26 2016 05:52:10 # nquan = 20 # nvalues = 241 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = sbeox0V: Oxygen raw, SBE 43 [V] # name 11 = par: PAR/Irradiance, Biospherical/Licor # name 12 = par1: PAR/Irradiance, Biospherical/Licor, 2 # name 13 = altM: Altimeter [m] # name 14 = dz/dtM: Descent Rate [m/s] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = May 26 2016 05:45:36 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 2106 # 17-Dec-14 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.14703785e-003 # 6.31044927e-004 # 2.13121431e-005 # 2.18594910e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2280 # 19-Dec-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.00904009e+001 # 1.35149315e+000 # -1.84720682e-003 # 1.90856808e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0443 # 17-Dec-14 # -4.435292e+004 # -1.635794e-001 # 1.192740e-002 # 3.979900e-002 # 0.000000e+000 # 2.993627e+001 # -3.271008e-004 # 3.759160e-006 # 1.565300e-009 # 0.99991613 # -0.54760 # 0.000000e+000 # 1.282462e-002 # -8.599824e+000 # # # # # # 2663 # 15-Jan-15 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36565531e-003 # 6.42337654e-004 # 2.40578991e-005 # 2.42263656e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2754 # 19-Dec-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.05920237e+001 # 1.61356129e+000 # -1.94911294e-003 # 2.41671700e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0997 # 17-Jan-15 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.0785e-001 # -0.6967 # -3.5082e-003 # 1.2934e-004 # -1.8411e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.6200 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3640 # # # 1 # 0.000 # # # # # # 1185DR # APR 27. 2016 # 19.3479 # -1.1028 # 0.250 # # # # # # # # # 62354 # # 15.000 # 0.000 # # # # # # # # # 70613 # 03/21/16 # 1.00000000 # 0.00000000 # 11876484560.57000000 # 1.00000000 # -0.08460813 # # # # # # 4615 # 16-Mar-2011 # 1.00000000 # 0.00000000 # 3367003367.00000000 # 1.00000000 # -0.40341896 # # # # datcnv_date = Aug 05 2016 16:15:51, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2016-47\RAW\CTD\2016-47-0008.hex P:\Crui se_Data_Processing\2016-47\Processing\doc\2016-47-ctd1.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 within 2 weeks of the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.20-29.56 ug/l. Average %CV for this cruise was 4.32 with 3 out of 135 duplicate pairs having a V>15% and 0 out of 135 duplicate pairs having a CV>50% . Our average dataset %CV is 2.83 % for 2013 - 2015. This dataset was within 1 standard deviation of this 3 year average. For details see worksheet “CV%” in file QF2016-47CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 weeks after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2016-047_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2016-47OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 31 to 41 days after collection. For details including a duplicate analysis, see document QF2016-47SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2016-47nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. Standards are made in LNSW collected at 250m station LB14 For full details including a precision study see file 2016-47NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. There were 2 Biospherical/Licor PAR sensors. The one identified as PAR refers to a new sensor (S/N 70613) and PAR1 refers to an older sensor (S/N 4615). For details on the processing see the report: 2016-47_Processing_Report.doc. --------------------------------------------------------------------------------- NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. -------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-047_Nov2021\Processing\IOS\2016-047-0008. hplc --------------------------------------------------------------------------- Sample_Number 25: HPLC: >10%CV for TChl-a, poor extraction due to incorrect sampling volume , likely underestimate *CALIBRATION $TABLE: CALCULATED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 130 -99 (Pressure Temperature:Primary Conductivity:Primary) () $END $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !---------------------- --------------- ---- ------ ------------ Temperature:Primary 'deg C (ITS90)' 10 -99 () (-0.2E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.377E-01 1.0208) Salinity:T0:C0 PSS-78 10 -99 () (0.4E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (0.2E-02 1) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10--- --11-- --12- -13- --14-- 15 --16-- 17 ---18-- 19 --20-- 21 --22-- ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- 49 !Samp Bott Bott Pressu Temperat Trans Fluores PAR PAR1 Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o e_ ag te ag te ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec Nitrit ri ca ha ted ct Extrac HP ! ence t SBE SBE ords e te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 25 1 1 4.4 11.9951 28.3 3.966 0.0 0.1 30.7968 6.60 287.8 241 15.52 0 32.19 0 1.335 0 5.15 6 1.10 0.067 0.089 0.057 0.442 0.055 0.117 0.508 0.000 0.058 0.995 0.110 0.082 0.075 0.071 0.381 0.427 0.047 0.013 0.017 0.500 0.031 0.000 4.256 0.000 0.206 4.462 36