*2021/12/06 10:25:24.41 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2016/08/30 04:18:16.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 7A5F3A78 NUMBER OF CHANNELS : 54 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 809 828 2 Bottle_Number n/a 1 22 3 Bottle:Firing_Sequence n/a 1 20 4 Pressure decibar 4.7 1333.5 5 Temperature:Secondary 'deg C (ITS90)' 2.8142 12.7579 6 Transmissivity %/metre 26.9 60.3 7 Fluorescence:URU:Seapoint mg/m^3 0.61E-01 6.902 8 PAR uE/m^2/sec 0 0 9 Salinity:T1:C1 PSS-78 32.2988 34.4856 10 Oxygen:Dissolved:SBE mL/L 0.25 6.9 11 Oxygen:Dissolved:SBE umol/kg 10.9 300.7 12 Number_of_bin_records n/a 126 241 13 Temperature:Draw 'deg C (ITS90)' 5.9 13.1 14 Salinity:Bottle PSS-78 32.323 34.464 15 Flag:Salinity:Bottle ' ' 16 Oxygen:Dissolved mL/L 0.24 6.934 17 Oxygen:Dissolved umol/kg 10.4 302.2 18 Flag:Oxygen:Dissolved ' ' 19 Nitrate_plus_Nitrite umol/L 0.8E-01 45.22 20 Flag:Nitrate_plus_Nitrite ' ' 21 Silicate umol/L 1.74 153.53 22 Flag:Silicate ' ' 23 Phosphate umol/L 0.331 3.247 24 Flag:Phosphate ' ' 25 Chlorophyll:Extracted mg/m^3 0.58 6.46 26 Flag:Chlorophyll:Extracted ' ' 27 Phaeo-Pigment:Extracted mg/m^3 0.91 6.95 28 HPLC:Chl-c3 mg/m^3 0.76E-01 0.76E-01 29 HPLC:Chlide-a mg/m^3 0.435 0.435 30 HPLC:MgDVP mg/m^3 0.31E-01 0.31E-01 31 HPLC:Chl-c2 mg/m^3 0.743 0.743 32 HPLC:Chl-c1 mg/m^3 0.91E-01 0.91E-01 33 HPLC:Me-chlide mg/m^3 0.216 0.216 34 HPLC:Peri mg/m^3 0.147 0.147 35 HPLC:Pheide-a mg/m^3 1.822 1.822 36 HPLC:But-fuco mg/m^3 0.63E-01 0.63E-01 37 HPLC:Fuco mg/m^3 2.827 2.827 38 HPLC:Neo mg/m^3 0 0 39 HPLC:Pras mg/m^3 0 0 40 HPLC:Viola mg/m^3 0 0 41 HPLC:Hex-fuco mg/m^3 0.5E-02 0.5E-02 42 HPLC:Diadino mg/m^3 0.602 0.602 43 HPLC:Allo mg/m^3 0.15E-01 0.15E-01 44 HPLC:Diato mg/m^3 0.24E-01 0.24E-01 45 HPLC:Zea mg/m^3 0.25E-01 0.25E-01 46 HPLC:Lut mg/m^3 0 0 47 HPLC:Chl-b mg/m^3 0 0 48 HPLC:C2mgdg mg/m^3 0 0 49 HPLC:DVChl-a mg/m^3 0 0 50 HPLC:Chl-a mg/m^3 2.552 2.552 51 HPLC:Phe mg/m^3 0 0 52 HPLC:B-Car mg/m^3 0 0 53 HPLC:TChl-a mg/m^3 3.203 3.203 54 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 9 F R4 4 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2016-08 AGENCY : IOS, Ocean Sciences Division, Sidney COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P4 EVENT NUMBER : 112 LATITUDE : 48 38.67000 N ! (deg min) LONGITUDE : 126 40.05000 W ! (deg min) WATER DEPTH : 1333 ALTIMETER (M) : 9.33 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4752 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2710 Conductivity:2 ' ' 2754 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1185DR Altimeter ' ' 62354 PAR/Irradiance:Biospherical/Licor ' ' 70613 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.26.1.8 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.5 2016/11/16 13:50:38 4624 4624 CLEAN 5.2.1 2016/11/16 13:51:29 4624 4624 ADDSAMP 3.6 2016/11/16 17:16:06 4624 4624 BINAVE 4.2 2016/11/16 17:16:25 4624 20 MERGE 3.5 2016/12/06 16:50:44 20 20 CLEAN 5.2.1 2016/12/06 17:03:55 20 20 CALIB 11.9 2016/12/06 17:04:06 20 20 SORT 3.6 2016/12/06 17:04:23 20 20 REMOVECH 8.2 2016/12/06 17:04:34 20 20 CHGUNITS 3.1.1 2016/12/06 17:04:48 20 20 CHGUNITS 3.1.1 2016/12/06 17:05:02 20 20 REORDER 1.3.1 2016/12/06 17:05:18 ? ? HDREDIT2 3.0.2 2016/12/08 09:47:26 ? ? SORT 3.6 2020/08/09 13:09:25 20 20 REORDER 1.3.1 2021/12/06 10:21:56 ? ? MERGE 3.5.1 2021/12/06 10:23:15 20 20 SORT 3.6 2021/12/06 10:23:46 20 20 CLEAN 5.2.4 2021/12/06 10:23:55 20 20 HDREDIT2 3.2 2021/12/06 10:25:04 ? ? HDREDIT2 3.2 2021/12/06 10:25:24 ? ? $END $REMARKS -CLEAN functions: 2016/11/16 13:50:43 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2016-08\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2016/12/06 16:50:44 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2016-08\Processing\hydro\2016-08-0112.samavg Secondary file: P:\Cruise_Data_Processing\2016-08\Processing\hydro\2016-08-0112.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2016-08\Processing\hydro\2016-08-0112.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2016/12/06 16:50:04 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2016/12/06 17:03:50 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name -CALIB parameters: 2016/12/06 17:04:06 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2016-08\Processing\doc\2016-08-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 16 Salinity:T0:C0 PSS-78 10 0.4000000E-02 0.1000000E+01 18 Oxygen:Dissolved:SBE mL/L 10 0.5100000E-01 0.1017600E+01 -SORT parameters: 2016/12/06 17:04:23 Sorted in ascending order of channel Pressure* -REMOVECH 2016/12/06 17:04:34 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2016/12/08 09:47:26 Applied edit header: P:\Cruise_Data_Processing\2016-08\Processing\doc\HYDRO\2016-08-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F11.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Format: F9.4 ==> F8.3 Channel 16: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 18: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 19: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 22: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 24: Silicate [umol/L] Units: ==> umol/L Channel 26: Phosphate [umol/L] Units: ==> umol/L -SORT parameters: 2020/08/09 13:09:25 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/12/06 10:23:15 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-008_Nov2021\Processing\ IOS\2016-008-0112.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-008_Nov2021\Processing\ IOS\2016-008-0112.hplc -SORT parameters: 2021/12/06 10:23:46 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/12/06 10:23:52 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/12/06 10:25:04 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016_008\Processing\IOS\ 2016-008-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 14: Salinity:Bottle [PSS-78] Format: F8.3 ==> F9.4 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/12/06 10:25:24 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016_008\Processing\IOS\ 2016-008-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2016-08\2016-08-0112.hex Software Version Seasave V 7.26.1.8 Temperature SN = 4752 Conductivity SN = 2280 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Aug 30 2016 04:22:45 NMEA Latitude = 48 38.67 N NMEA Longitude = 126 40.05 W NMEA UTC (Time) = Aug 30 2016 04:18:16 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Mission: 2016-08 Ship: J.P. Tully Station: P04 Depth: 1333 Bottles fired out of order. Loop samples taken System UTC = Aug 30 2016 04:22:45 # nquan = 19 # nvalues = 4624 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = par: PAR/Irradiance, Biospherical/Licor # name 11 = sbeox0V: Oxygen raw, SBE 43 [V] # name 12 = altM: Altimeter [m] # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = pumps: Pump Status # name 15 = sal00: Salinity, Practical [PSU] # name 16 = sal11: Salinity, Practical, 2 [PSU] # name 17 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 18 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Aug 30 2016 04:18:16 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4752 # 16-Dec-15 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.35917908e-003 # 6.36752535e-004 # 2.08584233e-005 # 1.76255754e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2280 # 19-Dec-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.00904009e+001 # 1.35149315e+000 # -1.84720682e-003 # 1.90856808e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0443 # 17-Dec-14 # -4.435292e+004 # -1.635794e-001 # 1.192740e-002 # 3.979900e-002 # 0.000000e+000 # 2.993627e+001 # -3.271008e-004 # 3.759160e-006 # 1.565300e-009 # 0.99991613 # -1.00000 # 0.000000e+000 # 1.282462e-002 # -8.599824e+000 # # # # # # 2710 # 16-Dec-15 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36717385e-003 # 6.46681437e-004 # 2.34978657e-005 # 2.22502310e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2754 # 19-Dec-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.05920237e+001 # 1.61356129e+000 # -1.94911294e-003 # 2.41671700e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0997 # 17-Jan-15 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.0785e-001 # -0.6967 # -3.5082e-003 # 1.2934e-004 # -1.8411e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.6200 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3640 # # # 2 # 0.000 # # # # # # 1185DR # APR 27. 2016 # 19.3479 # -1.1028 # 0.250 # # # # # # # # # 62354 # # 15.000 # 0.000 # # # # # # # # # 70613 # 03/21/16 # 1.00000000 # 0.00000000 # 11876484560.57000000 # 1.00000000 # -0.08460813 # # # # # # # datcnv_date = Nov 16 2016 13:49:36, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2016-08\RAW\CTD\2016-08-0112.hex P:\Crui se_Data_Processing\2016-08\Processing\doc\2016-08-ctd.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2016-08\Processing\hydro\2016-08-0112.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2016-08\Processing\hydro\2016-08-0112.sal ------------------------------------------------------------------- Sample_Number 811: SAL: Sample analyzed approximately 1 month after all others. Sample_Number 812: SAL: Sample analyzed approximately 1 month after all others. Sample_Number 823: SAL: Sample analyzed approximately 1 month after all others. Comments from secondary file: P:\Cruise_Data_Processing\2016-08\Processing\hydro\2016-08-0112.oxy ------------------------------------------------------------------- Sample_Number 809: OXY: Niskin vent was leaking prior to sampling. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 within ~4 weeks of the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.02-43.38 ug/l. Average %CV for this cruise was 3.66% with 2 out of 63 duplicate pairs having a CV>15% and 0 out of 63 duplicate pairs having a CV>50%. Our average dataset %CV is 2.83 % for 2013 - 2015 so the overall quality of this dataset is very good. For details see worksheet “CV%” in file QF2016-08CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 weeks after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2016-008_HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2016-08OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8410A Portasal Salinometer (S/N 58879) standardized with IAPSO standard seawater within 50 - 64 days after collection. Data are reported to the third decimal place on account of the reduced accuracy and precision from the delay in analysis and the slightly less accurate instrument (±0.001 PSU less accurate the the 8400B Autosal). For details including a duplicate analysis, see document QF2016-08SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2016-08nuts*.xls. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100 deg C (with a dewar containing boiling water) onto a Choromasorb 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. For more detail see file 2016-08DMS report.doc and for data and duplicate analysis see "DMS summary (2016-08 data).xls." The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.1nmol/L. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2016-08_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-008_Nov2021\Processing\IOS\2016-008-0112. hplc --------------------------------------------------------------------------- Sample_Number 824: HPLC: >10%CV for TChl-a, sample likely poorly extracted, underestimate *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.4E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.51E-01 1.0176) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14--- 15 ---16-- --17- 18 --19-- 20 --21-- 22 ---23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- 54 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag e_ ag te ag te ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec Draw tt lved lv Nitrit ri ca ha ted ct Extrac HP ! ence t SBE SBE ords le ed e te te te ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -------- -- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 823 15 19 4.7 12.7548 27.1 6.902 0.0 32.3034 6.90 300.7 126 13.0 32.3230 2 6.910 301.2 0 0.09 0 1.77 0 0.331 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 824 16 20 4.7 12.7579 26.9 6.788 0.0 32.2988 6.90 300.7 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.00 0 -99.00 0 -99.000 0 6.46 6 6.15 0.076 0.435 0.031 0.743 0.091 0.216 0.147 1.822 0.063 2.827 0.000 0.000 0.000 0.005 0.602 0.015 0.024 0.025 0.000 0.000 0.000 0.000 2.552 0.000 0.000 3.203 36 820 12 18 9.8 12.7428 27.3 6.704 0.0 32.3175 6.89 300.2 241 13.1 -99.0000 0 6.934 302.2 0 0.08 0 1.74 0 0.369 0 5.87 0 6.95 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 819 11 17 25.8 10.8274 43.7 2.327 0.0 32.4583 6.20 270.1 241 11.6 -99.0000 0 6.279 273.6 0 2.93 0 5.22 0 0.675 0 2.99 6 3.87 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 818 10 16 49.6 9.4750 56.5 0.293 0.0 32.6693 5.67 246.9 241 10.3 -99.0000 0 5.713 248.8 0 8.79 0 9.20 0 0.886 0 0.58 0 0.91 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 822 14 13 100.2 8.2305 58.2 0.117 0.0 33.5231 3.76 163.7 241 9.4 -99.0000 0 3.796 165.2 6 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 828 22 15 100.2 8.2278 58.1 0.113 0.0 33.5210 3.77 164.1 241 9.8 -99.0000 0 3.793 165.1 6 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 817 9 12 100.3 8.2308 58.2 0.109 0.0 33.5237 3.74 162.8 241 9.4 -99.0000 0 3.666 159.5 6 24.79 0 28.54 0 1.762 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 827 21 14 100.3 8.2288 58.2 0.111 0.0 33.5222 3.77 164.0 241 9.6 -99.0000 0 3.800 165.4 6 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 816 8 11 149.8 7.2871 58.2 0.089 0.0 33.8768 2.72 118.3 241 8.6 -99.0000 0 2.737 119.1 0 30.55 0 43.26 0 2.140 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 815 7 10 199.7 6.9058 58.9 0.079 0.0 33.9355 2.29 99.7 241 8.3 -99.0000 0 2.294 99.8 0 33.07 0 49.59 0 2.315 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 814 6 9 400.1 5.4635 59.2 0.064 0.0 34.0277 1.14 49.3 241 7.3 -99.0000 0 1.137 49.4 0 40.15 0 74.52 0 2.823 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 813 5 8 599.9 4.6526 60.0 0.061 0.0 34.1414 0.51 22.1 241 6.8 -99.0000 0 0.506 22.0 0 40.14 6 95.78 6 2.847 6 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 812 4 7 800.8 4.0864 60.0 0.061 0.0 34.2542 0.28 12.2 241 6.6 34.2540 2 0.287 12.5 0 44.62 0 113.59 0 3.199 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 821 13 4 1000.4 3.5545 60.3 0.061 0.0 34.3763 0.25 10.9 241 6.7 -99.0000 0 0.254 11.0 6 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 825 19 5 1000.4 3.5561 60.3 0.061 0.0 34.3756 0.25 10.9 178 6.7 -99.0000 0 0.258 11.2 6 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 811 3 3 1000.6 3.5548 60.3 0.061 0.0 34.3757 0.25 10.9 223 6.2 34.3790 2 0.240 10.4 6 45.19 0 129.99 0 3.247 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 826 20 6 1000.6 3.5553 60.3 0.061 0.0 34.3762 0.25 10.9 241 6.7 -99.0000 0 0.249 10.8 6 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 810 2 2 1250.3 3.0212 60.1 0.061 0.0 34.4574 0.41 17.6 241 5.9 34.4640 6 0.394 17.1 0 45.22 0 146.36 0 3.217 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 809 1 1 1333.5 2.8142 58.7 0.061 0.0 34.4856 0.52 22.5 241 6.1 -99.0000 0 0.531 23.1 3 44.75 0 153.53 0 3.233 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0