*2023/03/19 10:47:07.06 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2016/06/18 08:40:16.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 22 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : ECCB0842 NUMBER OF CHANNELS : 56 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 167 188 2 Bottle_Number n/a 1 22 3 Bottle:Firing_Sequence n/a 1 22 4 Pressure decibar 1.6 373.7 5 Temperature:Secondary 'deg C (ITS90)' 9.1882 16.8045 6 Transmissivity %/metre 14.8 59.9 7 Fluorescence:URU:Seapoint mg/m^3 0.87E-01 6.758 8 PAR uE/m^2/sec 0 1.1 9 PAR:Reference uE/m^2/sec 14 15.9 10 pH:SBE:Nominal n/a 7.608 8.423 11 Salinity:T1:C1 PSS-78 20.326 31.1632 12 Oxygen:Dissolved:SBE mL/L 2.77 6.83 13 Oxygen:Dissolved:SBE umol/kg 120.9 299.6 14 Number_of_bin_records n/a 35 241 15 Temperature:Draw 'deg C (ITS90)' 9.3 17 16 Salinity:Bottle PSS-78 30.9826 30.9826 17 Flag:Salinity:Bottle ' ' 18 Oxygen:Dissolved mL/L 2.787 7.142 19 Oxygen:Dissolved umol/kg 121.5 312.2 20 Flag:Oxygen:Dissolved ' ' 21 Nitrate_plus_Nitrite umol/L 0.5E-01 27.95 22 Flag:Nitrate_plus_Nitrite ' ' 23 Silicate umol/L 8.34 63.64 24 Silicate:Flag ' ' 25 Phosphate umol/L 0.171 2.798 26 Flag:Phosphate ' ' 27 Chlorophyll:Extracted mg/m^3 1.49 10.36 28 Flag:Chlorophyll:Extracted ' ' 29 Phaeo-Pigment:Extracted mg/m^3 0.36 2.66 30 HPLC:Chl-c3 mg/m^3 0.31E-01 0.31E-01 31 HPLC:Chlide-a mg/m^3 0.57E-01 0.57E-01 32 HPLC:MgDVP mg/m^3 0.1E-01 0.1E-01 33 HPLC:Chl-c2 mg/m^3 0.164 0.164 34 HPLC:Chl-c1 mg/m^3 0.46E-01 0.46E-01 35 HPLC:Me-chlide mg/m^3 0.16 0.16 36 HPLC:Peri mg/m^3 0.73E-01 0.73E-01 37 HPLC:Pheide-a mg/m^3 0 0 38 HPLC:But-fuco mg/m^3 0.69E-01 0.69E-01 39 HPLC:Fuco mg/m^3 0.557 0.557 40 HPLC:Neo mg/m^3 0.19E-01 0.19E-01 41 HPLC:Pras mg/m^3 0.13E-01 0.13E-01 42 HPLC:Viola mg/m^3 0.11E-01 0.11E-01 43 HPLC:Hex-fuco mg/m^3 0.16E-01 0.16E-01 44 HPLC:Diadino mg/m^3 0.28 0.28 45 HPLC:Allo mg/m^3 0.62E-01 0.62E-01 46 HPLC:Diato mg/m^3 0.27E-01 0.27E-01 47 HPLC:Zea mg/m^3 0.18E-01 0.18E-01 48 HPLC:Lut mg/m^3 0.6E-02 0.6E-02 49 HPLC:Chl-b mg/m^3 0.101 0.101 50 HPLC:C2mgdg mg/m^3 0 0 51 HPLC:DVChl-a mg/m^3 0 0 52 HPLC:Chl-a mg/m^3 1.416 1.416 53 HPLC:Phe mg/m^3 0 0 54 HPLC:B-Car mg/m^3 0.217 0.217 55 HPLC:TChl-a mg/m^3 1.633 1.633 56 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 7 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F ' ' 4 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 9 F R4 4 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 8 F R4 3 19 -99 ' ' 6 F ' ' 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 3 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 8 F R4 3 55 -99 ' ' 8 F R4 3 56 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2016-07 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Strait of Georgia Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca STATION : 39 EVENT NUMBER : 58 LATITUDE : 49 9.79000 N ! (deg min) LONGITUDE : 123 32.98000 W ! (deg min) WATER DEPTH : 383 ALTIMETER (M) : 4.88 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4484 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0550 Temperature:2 ' ' 4054 Conductivity:2 ' ' 3531 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3865 'Transmissometer:WET Labs C-Star' ' ' 1396DR Altimeter ' ' 1253 pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' '4565 QSP200L4S' Unavailable ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.23.1 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! --------------------- ------ ---------- -------- --------- --------- SBE_IOS 3.5 2016/09/29 14:04:00 4310 4310 CLEAN 5.2.1 2016/09/29 14:04:36 4310 4310 ADDSAMP 3.6 2016/09/29 17:06:31 4310 4310 BINAVE 4.2 2016/09/29 17:08:31 4310 22 MERGE 3.5 2016/09/29 17:35:41 22 22 CLEAN 5.2.1 2016/09/29 17:35:45 22 22 CALIB 11.9 2016/10/12 09:39:39 22 22 SORT 3.6 2016/10/12 09:40:20 22 22 REMOVECH 8.2 2016/10/12 09:40:27 22 22 CHGUNITS 3.1.1 2016/10/12 09:42:09 22 22 CHGUNITS 3.1.1 2016/10/12 09:42:27 22 22 REORDER 1.3.1 2016/10/12 09:42:43 ? ? HDREDIT2 3.0.2 2016/10/12 09:42:48 ? ? Silicate_Correction 1.0 2018/02/20 14:33:30 22 22 SORT 3.6 2020/08/09 15:12:30 22 22 REORDER 1.3.1 2021/11/25 15:47:18 ? ? MERGE 3.5.1 2021/11/25 15:47:31 22 22 SORT 3.6 2021/11/25 15:47:40 22 22 CLEAN 5.2.4 2021/11/25 15:47:53 22 22 HDREDIT2 3.2 2021/11/25 15:48:51 ? ? HDREDIT2 3.2 2021/11/25 15:49:15 ? ? Silicate_Modification 1.2 2023/03/19 10:47:07 22 22 $END $REMARKS -CLEAN functions: 2016/09/29 14:04:21 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2016-07\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2016/09/29 17:35:41 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2016-07\Processing\hydro\2016-07-0058.samavg Secondary file: P:\Cruise_Data_Processing\2016-07\Processing\hydro\2016-07-0058.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2016-07\Processing\hydro\2016-07-0058.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2016/09/29 17:35:31 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2016/09/29 17:35:45 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name -CALIB parameters: 2016/10/12 09:39:39 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2016-07\Processing\doc\2016-07-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 20 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1016800E+01 -SORT parameters: 2016/10/12 09:40:20 Sorted in ascending order of channel Pressure* -REMOVECH 2016/10/12 09:40:27 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2016/10/12 09:42:48 Applied edit header: P:\Cruise_Data_Processing\2016-07\Processing\doc\HYDRO\2016-07-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F11.3 ==> F7.2 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 16: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 18: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 20: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 21: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 24: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 26: Silicate [umol/L] Units: ==> umol/L Channel 28: Phosphate [umol/L] Units: ==> umol/L Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a -SORT parameters: 2020/08/09 15:12:30 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 15:47:31 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-007_Nov2021\Processing\ IOS\2016-007-0058.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-007_Nov2021\Processing\ IOS\2016-007-0058.hplc -SORT parameters: 2021/11/25 15:47:40 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 15:47:53 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 15:48:51 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016_007\Processing\IOS\ 2016-007-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 32: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 54: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 55: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 56: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 57: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 15:49:15 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016_007\Processing\IOS\ 2016-007-bot-hdr2.txt $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: 39, Sample Number: 187, Silicate corrected using CTD salinity. ===================================================================================== SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2016-07\2016-07-0058.hex Software Version Seasave V 7.23.1 Temperature SN = 4484 Conductivity SN = 1766 Number of Bytes Per Scan = 40 Number of Voltage Words = 5 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jun 18 2016 01:41:56 NMEA Latitude = 49 09.79 N NMEA Longitude = 123 32.98 W NMEA UTC (Time) = Jun 18 2016 08:40:16 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 surface PAR voltage added to scan A/D offset = 5 Latitude/Longitude added to scan GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds advance voltage 6 0.000 seconds advance voltage 7 0.000 seconds S> Vector: 2016-07 Station: 39 Depth: 383 System UTC = Jun 18 2016 08:41:56 # nquan = 21 # nvalues = 4310 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = sbeox0V: Oxygen raw, SBE 43 [V] # name 11 = par: PAR/Irradiance, Biospherical/Licor # name 12 = spar: SPAR/Surface Irradiance # name 13 = ph: pH # name 14 = altM: Altimeter [m] # name 15 = dz/dtM: Descent Rate [m/s] # name 16 = pumps: Pump Status # name 17 = sal00: Salinity, Practical [PSU] # name 18 = sal11: Salinity, Practical, 2 [PSU] # name 19 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 20 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jun 18 2016 08:40:16 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 4484 # 18-Dec-14 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.39931830e-003 # 6.40333195e-004 # 2.14332102e-005 # 1.81777421e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1766 # 20-Aug-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.12823288e+000 # 4.88293788e-001 # -6.13168477e-004 # 5.30399930e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0550 # 17-Dec-14 # -4.232943e+004 # 1.065076e-001 # 1.464900e-002 # 3.694200e-002 # 0.000000e+000 # 3.041883e+001 # -3.536199e-004 # 4.388420e-006 # 2.583800e-009 # 1.00002764 # 0.67335 # 0.000000e+000 # 1.286170e-002 # -9.445820e+000 # # # # # # 4054 # 20-Aug-14 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38634996e-003 # 6.44413405e-004 # 2.32318430e-005 # 2.13707967e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3531 # 06-Feb-13 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.02073624e+001 # 1.56180514e+000 # -2.18950789e-003 # 2.53511714e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1119 # 19-Dec-15 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.6004e-001 # -0.5129 # -3.1802e-003 # 1.7259e-004 # -3.0507e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.8700 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3865 # # # 2 # 0.000 # # # # # # 1396DR # Feb 2nd 2016 # 19.3228 # -0.0193 # 0.250 # # # # # # # # # 1253 # # 15.000 # 0.000 # # # # # # # # # 0692 # 12-Jan-16 # 4.6015 # 2.5353 # # # # # # 4565 QSP200L4S # 16-Mar-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # # # # 20518 # 21-MAR-2016 # 1627.06600000 # 1.00000000 # # # # datcnv_date = Sep 29 2016 08:54:53, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2016-07\RAW\ctd\2016-07-0058.hex P:\Crui se_Data_Processing\2016-07\Processing\doc\2016-07-ctd.XMLCON # datcnv_ox_hysteresis_correction = no # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2016-07\Processing\hydro\2016-07-0058.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2016-07\Processing\hydro\2016-07-0058.oxy ------------------------------------------------------------------- Sample_Number 173: OXY: Small bubble in sample before adding acid. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 within 7 weeks of the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. Precision Statement: Chlorophyll values ranged from 0.5-10.53 ug/l. Average %CV for this cruise was 2.99% with 1 out of 77 duplicate pairs having a CV>15% and 0 out of 77 duplicate pairs having a CV>50%. Our average dataset %CV is 2.83 % for 2013 - 2015 so the overall quality of this dataset is very good. For details see worksheet “CV%” in file QF2016-07CHL*.xls. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2016-007HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2016-07OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 15 to 20 days after collection. There were no duplicates taken, so there is no precision analysis. For details see document QF2017-07SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2016-07nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence, pH, PAR and PAR:Reference data are nominal & unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. NOTE: While the CTD fluorescence data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2016-07_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2016\2016-007_Nov2021\Processing\IOS\2016-007-0058. hplc --------------------------------------------------------------------------- Sample_Number 187: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0168) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- --9--- ---10-- ---11--- --12-- --13- -14- --15- ---16--- 17 ---18-- --19- 20 --21-- 22 --23-- 24 ---25-- 26 --27-- 28 --29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- ---54-- ---55-- 56 !Samp Bott Bott Pressu Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Si Phospha Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: Refere Nominal :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag e_ ag te li te ag phyll: ag Pigmen 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