*2022/05/25 12:08:32.78 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2015/10/19 01:54:15.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 2 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 5F684AE5 NUMBER OF CHANNELS : 13 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 2 2 Bottle:Firing_Sequence n/a 1 2 3 Pressure decibar 300.7 1200.8 4 Temperature:Primary 'deg C (ITS90)' 2.9172 6.1325 5 Transmissivity %/metre 65.3 65.7 6 Fluorescence:URU:Seapoint mg/m^3 0.36E-01 0.39E-01 7 Salinity:T0:C0 PSS-78 33.925 34.4249 8 Oxygen:Dissolved:SBE mL/L 0.36 2.25 9 Oxygen:Dissolved:SBE umol/kg 15.8 97.7 10 Number_of_bin_records n/a 241 241 11 Sample_Number n/a 72 73 12 Salinity:Bottle PSS-78 33.933 34.432 13 Flag:Salinity:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 5 I I 0 11 -99 ' ' 5 I I 0 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2015-61 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : World Class Oil Tanker / Cape Scott Environment SCIENTIST : Romaine S. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-West Coast Vancouver Island STATION : MT-14 EVENT NUMBER : 104 LATITUDE : 51 18.09000 N ! (deg min) LONGITUDE : 130 18.18000 W ! (deg min) WATER DEPTH : 1257 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 5725 Conductivity ' ' 4448 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 5724 Conductivity:2 ' ' 4434 Fluorometer:Seapoint ' ' 3685 'Oxygen:SBE 43' ' ' 1119 'Transmissometer:WET Labs C-Star' ' ' 1185DR pH ' ' 0692 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 62354 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.23.2 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2016/04/07 08:44:15 482 482 CLEAN 5.2.1 2016/04/07 08:45:51 482 482 ADDSAMP 3.6 2016/04/07 08:48:08 482 482 BINAVE 4.2 2016/04/07 08:48:21 482 2 MERGE 3.5 2016/04/07 08:48:30 2 2 CALIB 11.8.1 2016/04/07 08:48:44 2 2 SORT 3.6 2016/04/07 09:03:55 2 2 REMOVECH 8.2 2016/04/07 09:04:13 2 2 CHGUNITS 3.1 2016/04/07 09:07:00 2 2 CHGUNITS 3.1 2016/04/07 09:07:04 2 2 REORDER 1.3.1 2016/04/07 09:08:04 ? ? HDREDIT2 3.0.2 2016/04/08 16:17:13 ? ? CLEAN 5.3 2022/05/25 12:08:32 2 2 $END $REMARKS -CLEAN functions: 2016/04/07 08:45:46 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2015-61\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2016/04/07 08:48:30 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2015-61\Processing\hydro\2015-61-0104.samavg Secondary file: P:\Cruise_Data_Processing\2015-61\Processing\hydro\2015-61-0104.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2015-61\Processing\hydro\2015-61-0104.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2016/03/31 15:54:33 Sorted in ascending order of channel Bottle_Number -CALIB parameters: 2016/04/07 08:48:44 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2015-61\Processing\doc\2015-61-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 19 Oxygen:Dissolved:SBE mL/L 10 0.8060000E-01 0.1036300E+01 -SORT parameters: 2016/04/07 09:03:55 Sorted in ascending order of channel Pressure* -REMOVECH 2016/04/07 09:04:13 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] pH:SBE [pH Units] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2016/04/08 16:17:13 Applied edit header: P:\Cruise_Data_Processing\2015-61\Processing\doc\HYDRO\2015-61-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 13: Flag:Salinity:Bottle [n/a] Units: ==> n/a -CLEAN functions: 2022/05/25 12:08:09 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* Insert Pad Values in Channel: Temperature:Primary [deg C (ITS90)] where channel Temperature:Primary [deg C (ITS90)] is in the range -10000 to - 0 data records in pad range. $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2015-61\2015-61-0104.hex Software Version Seasave V 7.23.2 Temperature SN = 5725 Conductivity SN = 4448 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Oct 19 2015 01:59:57 NMEA Latitude = 51 18.09 N NMEA Longitude = 130 18.18 W NMEA UTC (Time) = Oct 19 2015 01:54:15 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Mission: 2015-61 Ship: J.P. Tully Station: MT-14 Depth: 1257 System UTC = Oct 19 2015 01:59:57 # nquan = 20 # nvalues = 482 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = sbeox0V: Oxygen raw, SBE 43 [V] # name 11 = par: PAR/Irradiance, Biospherical/Licor # name 12 = ph: pH # name 13 = altM: Altimeter [m] # name 14 = dz/dtM: Descent Rate [m/s] # name 15 = pumps: Pump Status # name 16 = sal00: Salinity, Practical [PSU] # name 17 = sal11: Salinity, Practical, 2 [PSU] # name 18 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 19 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Oct 19 2015 01:54:15 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 5725 # 24-Feb-15 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.38076113e-003 # 6.41260711e-004 # 2.29020108e-005 # 2.15082043e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 4448 # 25-Feb-15 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.84642248e+000 # 1.66418068e+000 # -2.33043975e-003 # 2.81191758e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0585 # 30-Dec-13 # -3.951550e+004 # -4.415130e-001 # 1.282560e-002 # 3.560600e-002 # 0.000000e+000 # 3.030045e+001 # -4.415690e-004 # 4.342710e-006 # 1.736800e-009 # 0.99994600 # -2.11246 # 0.000000e+000 # 1.288270e-002 # -8.164490e+000 # # # # # # 5724 # 29-Jan-15 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.37933003e-003 # 6.40586592e-004 # 2.28632824e-005 # 2.16518905e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 4434 # 12-Feb-15 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.80804546e+000 # 1.71248163e+000 # -1.05284368e-003 # 1.74572291e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 3685 # # # 2 # 0.000 # # # # # # # # # 1119 # 21-Jan-14 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.4901e-001 # -0.5263 # -1.9196e-003 # 8.5361e-005 # -1.2856e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.0400 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 1185DR # Feb 2014 # 19.6968 # -1.1227 # 0.000 # # # # # # 0692 # Jan 2015 # 4.6327 # 2.5317 # # # # # # 4615 # 16-Mar-2011 # 1.00000000 # 0.00000000 # 3367003367.00000000 # 1.00000000 # -0.40341896 # # # # # # 62354 # # 15.000 # 0.000 # # # # # # # datcnv_date = Apr 07 2016 08:40:01, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2015-61\RAW\CTD\2015-61-0104.hex P:\Crui se_Data_Processing\2015-61\Processing\doc\2015-61-ctd2.XMLCON # datcnv_ox_hysteresis_correction = no # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were at IOS in Room 2423 ~3 months after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Precision Statement: Chlorophyll values ranged from 0.61-2.89 ug/l. Average %CV for this cruise was an excellent 1.7% with 0 out of 25 duplicate pairs having a CV>15% and 0 out of 25 duplicate pairs having a CV>50%. Our average dataset %CV is 4 % for 2013 - 2014 so the overall quality of this dataset is excellent. For details see worksheet “CV%” in file QF2015-61CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365 nm filter controlled by LVO2_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2015-61OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 36 to 42 days after collection. For details including a duplicate analysis, see document QF2015-61SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples is collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) is collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a precision and accuracy statement, see document QF2015-61nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence, pH and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. The comparison of CTD salinity with bottle salinity showed a lot of variability. The analyst found the salinity analysis precision to be poor, but noted that there were only 4 duplicates available. The bottle salinity values appear to be too high, on average, based on a post-cruise calibration of one set of temperature/conductivity sensors. This is likely due to a combination of small effects: evaporation and adsorption of samples and incomplete flushing of Niskin bottles. The primary salinity for the first configuration was recalibrated based on the post-cruise calibration. No correction was applied to the primary salinity for the second configuration. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2015-61-proc.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.806E-01 1.0363) $END !1- 2- --3--- ---4---- --5-- ---6--- ---7---- --8--- --9-- -10- -11- ---12--- 13 !Bo Bo Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Samp Salinity Fl !tt tt re ure: missi cence: :T0:C0 : n: er_o le_ :Bottle ag !~u ~u Primary vity URU: Dissol Disso ~bin Numb ~o !mb en Seapoin ved: lved: _rec er tt !er ce t SBE SBE ords le !-- -- ------ -------- ----- ------- -------- ------ ----- ---- ---- -------- -- *END OF HEADER 2 2 300.7 6.1325 65.3 0.039 33.9250 2.25 97.7 241 73 33.9330 0 1 1 1200.8 2.9172 65.7 0.036 34.4249 0.36 15.8 241 72 34.4320 0