*2016/04/11 17:08:58.65 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2015/11/02 13:33:40.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 5 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 439A6C4B NUMBER OF CHANNELS : 22 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 5 2 Bottle:Firing_Sequence n/a 1 5 3 Pressure decibar 10.14 238.33 4 Temperature:Secondary 'deg C (ITS90)' 7.9171 10.8498 5 Transmissivity %/metre 53.7 57.8 6 Fluorescence:URU:Seapoint mg/m^3 0.13 0.659 7 PAR uE/m^2/sec 0 0.263 8 Salinity:T1:C1 PSS-78 30.6738 32.9804 9 Oxygen:Dissolved:SBE mL/L 2.709 5.329 10 Oxygen:Dissolved:SBE umol/kg 117.9 232.5 11 Number_of_bin_records n/a 241 241 12 Sample_Number n/a 432 436 13 Temperature:Draw 'deg C (ITS90)' 8.2 10.8 14 Oxygen:Dissolved mL/L 2.715 5.395 15 Oxygen:Dissolved umol/kg 118.1731 235.3273 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 16.62 28.72 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 27.41 52.61 20 Flag:Silicate n/a 21 Phosphate umol/L 1.353 2.061 22 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 ' ' ' ' 5 I I 0 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2015-54 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : WC - Douglas Channel SCIENTIST : Wright C. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Douglas Channel STATION : SC80 EVENT NUMBER : 298 LATITUDE : 52 54.79000 N ! (deg min) LONGITUDE : 129 15.96000 W ! (deg min) WATER DEPTH : 241 ALTIMETER (M) : 5.25 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2663 Conductivity:2 ' ' 2754 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1396DR PAR/Irradiance:Biospherical/Licor ' ' 4565 Altimeter ' ' 1253 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.23.1 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2016/02/09 15:06:40 1205 1205 CLEAN 5.2.1 2016/02/09 15:07:39 1205 1205 ADDSAMP 3.6 2016/02/09 15:08:23 1205 1205 BINAVE 4.2 2016/02/09 15:09:46 1205 5 MERGE 3.5 2016/02/18 16:47:37 5 5 CLEAN 5.2.1 2016/02/18 16:47:53 5 5 CALIB 11.8.1 2016/02/18 16:48:00 5 5 SORT 3.6 2016/02/25 15:38:41 5 5 REMOVECH 8.2 2016/02/25 16:12:11 5 5 CHGUNITS 3.1 2016/02/25 16:13:00 5 5 CHGUNITS 3.1 2016/02/25 16:13:26 5 5 REORDER 1.3.1 2016/02/25 16:14:02 ? ? MERGEHDR 1.3 2016/04/11 17:06:39 5 5 HDREDIT2 3.0.2 2016/04/11 17:08:58 ? ? $END $REMARKS -CLEAN functions: 2016/02/09 15:07:09 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2015-54\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2016/02/18 16:47:37 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2015-54\Processing\hydro\2015-54-0298.samavg Secondary file: P:\Cruise_Data_Processing\2015-54\Processing\hydro\2015-54-0298.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2015-54\Processing\hydro\2015-54-0298.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2016/02/18 16:47:17 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2016/02/18 16:47:50 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name -CALIB parameters: 2016/02/18 16:48:00 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2015-54\Processing\doc\2015-54-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Pressure decibar 10 -0.6000000E+00 0.1000000E+01 18 Oxygen:Dissolved:SBE mL/L 10 0.3090000E-01 0.1022500E+01 -SORT parameters: 2016/02/25 15:38:41 Sorted in ascending order of channel Pressure* -REMOVECH 2016/02/25 16:12:11 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2016/04/11 17:08:58 Applied edit header: P:\Cruise_Data_Processing\2015-54\Processing\doc\HYDRO\2015-54-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 17: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 18: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 19: Silicate [umol/L] Units: ==> umol/L Channel 20: Flag:Silicate [n/a] Units: ==> n/a Channel 21: Phosphate [umol/L] Units: ==> umol/L Channel 22: Flag:Phosphate [n/a] Units: ==> n/a $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2015-54\2015-54-0298.hex Software Version Seasave V 7.23.1 Temperature SN = 2106 Conductivity SN = 2280 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Nov 02 2015 05:33:47 NMEA Latitude = 52 54.79 N NMEA Longitude = 129 15.96 W NMEA UTC (Time) = Nov 02 2015 13:33:40 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 Latitude/Longitude added to scan GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Vector: 2015-54 STATION: SC80 Depth: 241 System UTC = Nov 02 2015 13:33:47 # nquan = 19 # nvalues = 1205 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = sbeox0V: Oxygen raw, SBE 43 [V] # name 11 = par: PAR/Irradiance, Biospherical/Licor # name 12 = altM: Altimeter [m] # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = pumps: Pump Status # name 15 = sal00: Salinity, Practical [PSU] # name 16 = sal11: Salinity, Practical, 2 [PSU] # name 17 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 18 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Nov 02 2015 13:33:40 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 2106 # 17-Dec-14 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.14703785e-003 # 6.31044927e-004 # 2.13121431e-005 # 2.18594910e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2280 # 19-Dec-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.00904009e+001 # 1.35149315e+000 # -1.84720682e-003 # 1.90856808e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0443 # 17-Dec-14 # -4.435292e+004 # -1.635794e-001 # 1.192740e-002 # 3.979900e-002 # 0.000000e+000 # 2.993627e+001 # -3.271008e-004 # 3.759160e-006 # 1.565300e-009 # 0.99991613 # 0.05243 # 0.000000e+000 # 1.282462e-002 # -8.599824e+000 # # # # # # 2663 # 15-Jan-15 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36565531e-003 # 6.42337654e-004 # 2.40578991e-005 # 2.42263656e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2754 # 19-Dec-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.05920237e+001 # 1.61356129e+000 # -1.94911294e-003 # 2.41671700e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0997 # 17-Jan-15 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.0785e-001 # -0.6967 # -3.5082e-003 # 1.2934e-004 # -1.8411e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.7500e-002 # 1.6200 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3640 # # # 2 # 0.000 # # # # # # 1396DR # Feb 5tht 2014 # 19.0844 # -0.0191 # 0.250 # # # # # # # # # 4565 # Mar-16-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # # # # 1253 # # 15.000 # 0.000 # # # # # # # datcnv_date = Feb 03 2016 16:13:26, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2015-54\RAW\CTD\2015-54-0298.hex P:\Crui se_Data_Processing\2015-54\Processing\doc\2015-54-ctd.xmlcon # datcnv_ox_hysteresis_correction = no # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were at IOS in Room 2423 ~4 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Precision Statement: Chlorophyll values ranged from 0.02-1.75 ug/l. Average %CV for this cruise was an excellent 4.41% with 3 out of 114 duplicate pairs having a CV>15% and 0 out of 114 duplicate pairs having a CV>50%. Our average dataset %CV is 4 % for 2013 - 2014 so the overall quality of this dataset is excellent. For details see worksheet “CV%” in file QF2015-54CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365 nm filter controlled by LVO2_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2015-54OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 21 to 42 days after collection. For details see document QF2015-54SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a precision and accuracy statement, see document QF2015-54nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision. There were many problems with the sounder so many water depth entries were corrected based on log records or maximum pressure sampled and altimetry. For details see file 2015-54-water_depth_study.xlsx. For details on the processing see the report: 2015-54-proc.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure decibar 10 -99 () (-0.6 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.309E-01 1.0225) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- -12- --13- ---14-- --15- 16 --17-- 18 --19-- 20 ---21-- 22 !Bo Bo Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Samp Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl !tt tt re ure: missi cence: :T1:C1 : n: er_o le_ ratur Dissolv n: ag e_ ag te ag te ag !~u ~u Secondar vity URU: Dissol Disso ~bin Numb e: ed Disso ~o plus_ ~t ~i ~p !mb en y Seapoin ved: lved: _rec er Draw lved lv Nitrit ri ca ha !er ce t SBE SBE ords ed e te te te !-- -- ------ -------- ----- ------- ------ -------- ------ ----- ---- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- *END OF HEADER 5 5 10.1 10.7503 54.9 0.659 0.3 30.6738 5.33 232.5 241 436 10.7 5.395 235.3 0 16.95 0 29.69 0 1.422 0 4 4 19.5 10.7733 56.6 0.551 0.0 30.7267 5.28 230.3 241 435 10.7 5.324 232.2 6 17.09 0 29.81 0 1.446 0 3 3 74.2 10.8498 57.0 0.404 0.0 31.7417 5.08 221.6 241 434 10.8 5.141 224.1 0 16.62 6 27.41 6 1.353 6 2 2 99.7 10.6606 57.8 0.331 0.0 31.8791 4.83 210.6 241 433 10.4 4.901 213.6 0 17.81 0 29.22 0 1.389 0 1 1 238.3 7.9171 53.7 0.130 0.0 32.9804 2.71 117.9 241 432 8.2 2.715 118.2 0 28.72 0 52.61 0 2.061 0