*2020/07/21 14:57:48.82 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2015/06/02 20:04:40.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 799BB25A NUMBER OF CHANNELS : 54 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 319 338 2 Bottle_Number n/a 1 20 3 Bottle:Firing_Sequence n/a 1 20 4 Pressure decibar 5 1999.5 5 Temperature:Primary 'deg C (ITS90)' 1.8962 11.9798 6 Transmissivity %/metre 43.5 66.4 7 Fluorescence:URU:Seapoint mg/m^3 0.85E-01 5.093 8 Salinity:T0:C0 PSS-78 31.0843 34.5966 9 Oxygen:Dissolved:SBE mL/L 0.24 7.09 10 Oxygen:Dissolved:SBE umol/kg 10.3 309.1 11 Number_of_bin_records n/a 241 241 12 Temperature:Draw 'deg C (ITS90)' 3.8 12 13 Salinity:Bottle PSS-78 31.086 34.596 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 0.236 7.117 16 Oxygen:Dissolved umol/kg 10.3 310.2 17 Flag:Oxygen:Dissolved n/a 18 Nitrate_plus_Nitrite umol/L 0 46.19 19 Flag:Nitrate_plus_Nitrite n/a 20 Silicate umol/L 1.98 176.35 21 Flag:Silicate n/a 22 Phosphate umol/L 0.318 3.245 23 Flag:Phosphate n/a 24 Ammonium umol/L 0.1E-01 0.21 25 Flag:Ammonium n/a 26 Chlorophyll:Extracted mg/m^3 1.21 3.56 27 Flag:Chlorophyll:Extracted n/a 28 Phaeo-Pigment:Extracted mg/m^3 0.33 5.32 29 HPLC:Chl-c3 mg/m^3 0.11E-01 0.11E-01 30 HPLC:Chlide-a mg/m^3 0.18E-01 0.18E-01 31 HPLC:MgDVP mg/m^3 0.36E-01 0.36E-01 32 HPLC:Chl-c2 mg/m^3 0.73E-01 0.73E-01 33 HPLC:Chl-c1 mg/m^3 0.6E-02 0.6E-02 34 HPLC:Me-chlide mg/m^3 0.21E-01 0.21E-01 35 HPLC:Peri mg/m^3 0.65E-01 0.65E-01 36 HPLC:Pheide-a mg/m^3 0 0 37 HPLC:But-fuco mg/m^3 0.4E-02 0.4E-02 38 HPLC:Fuco mg/m^3 0.104 0.104 39 HPLC:Neo mg/m^3 0.4E-01 0.4E-01 40 HPLC:Pras mg/m^3 0.105 0.105 41 HPLC:Viola mg/m^3 0.62E-01 0.62E-01 42 HPLC:Hex-fuco mg/m^3 0.29E-01 0.29E-01 43 HPLC:Diadino mg/m^3 0.56E-01 0.56E-01 44 HPLC:Allo mg/m^3 0.103 0.103 45 HPLC:Diato mg/m^3 0.5E-02 0.5E-02 46 HPLC:Zea mg/m^3 0.45E-01 0.45E-01 47 HPLC:Lut mg/m^3 0.28E-01 0.28E-01 48 HPLC:Chl-b mg/m^3 0.362 0.362 49 HPLC:DVChl-a mg/m^3 0 0 50 HPLC:Chl-a mg/m^3 1.082 1.082 51 HPLC:Phe-a mg/m^3 0 0 52 HPLC:B-Car mg/m^3 0.24E-01 0.24E-01 53 HPLC:TChl-a mg/m^3 1.121 1.121 54 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 9 F R4 4 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 6 F ' ' 1 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 8 F R4 3 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2015-20 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : CS00 EVENT NUMBER : 134 LATITUDE : 50 27.84000 N ! (deg min) LONGITUDE : 129 55.12000 W ! (deg min) WATER DEPTH : 2170 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 1763 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 5013 Conductivity:2 ' ' 3394 'Oxygen:SBE 43' ' ' 1438 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1396DR Altimeter ' ' 62354 PAR/Irradiance:Biospherical/Licor ' ' 4565 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2015/08/06 15:31:16 4820 4820 CLEAN 5.2.1 2015/08/06 15:39:44 4820 4820 ADDSAMP 3.6 2015/08/06 16:50:13 4820 4820 BINAVE 4.2 2015/08/06 16:50:42 4820 20 MERGE 3.5 2015/09/01 14:51:23 20 20 CLEAN 5.2.1 2015/09/01 14:52:49 20 20 CALIB 11.8.1 2015/09/29 13:26:22 20 20 SORT 3.6 2015/09/29 13:27:32 20 20 REMOVECH 8.2 2015/09/29 13:28:25 20 20 CHGUNITS 3.1 2015/09/29 13:30:56 20 20 CHGUNITS 3.1 2015/09/29 13:31:28 20 20 REORDER 1.3.1 2015/09/29 13:32:34 ? ? HDREDIT2 3.0.2 2015/09/30 13:12:57 ? ? SORT 3.6 2020/07/17 14:49:05 20 20 REORDER 1.3.1 2020/07/17 14:57:52 ? ? MERGE 3.5.1 2020/07/21 14:48:18 20 20 SORT 3.6 2020/07/21 14:49:04 20 20 HDREDIT2 3.2 2020/07/21 14:57:17 ? ? HDREDIT2 3.2 2020/07/21 14:57:48 ? ? $END $REMARKS -CLEAN functions: 2015/08/06 15:39:17 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2015-20\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2015/09/01 14:51:23 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0134.samavg Secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0134.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0134.mrgcln1s ------------------------------------------------------------------------ -CLEAN functions: 2015/09/01 13:42:13 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2015/09/01 13:42:24 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2015/09/01 14:52:47 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name -CALIB parameters: 2015/09/29 13:26:22 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2015-20\Processing\doc\2015-20-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T1:C1 PSS-78 10 0.1600000E-02 0.1000000E+01 18 Oxygen:Dissolved:SBE mL/L 10 0.2480000E-01 0.1023500E+01 -SORT parameters: 2015/09/29 13:27:32 Sorted in ascending order of channel Pressure* -REMOVECH 2015/09/29 13:28:25 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2015/09/30 13:12:57 Applied edit header: P:\Cruise_Data_Processing\2015-20\Processing\doc\HYDRO\2015-20-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 16: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 20: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 21: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 22: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 23: Silicate [umol/L] Units: ==> umol/L Channel 24: Flag:Silicate [n/a] Units: ==> n/a Channel 25: Phosphate [umol/L] Units: ==> umol/L Channel 26: Flag:Phosphate [n/a] Units: ==> n/a Channel 28: Flag:Ammonium [n/a] Units: ==> n/a -SORT parameters: 2020/07/17 14:49:05 Sorted in ascending order of channel Sample_number -The following MERGE parameters were used: 2020/07/21 14:48:18 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:Pheide-a, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Chl-b, HPLC:DVChl-a, HPLC:Chl-a, HPLC:Phe-a, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC Primary file : D:\Telework\HPLC\2015-020\Processing\2015-020-0134.CHE2 Secondary file: D:\Telework\HPLC\2015-020\Processing\2015-020-0134.hplc -SORT parameters: 2020/07/21 14:49:04 Sorted in ascending order of channel Pressure -HEADER EDITS: 2020/07/21 14:57:17 Applied edit header: D:\Telework\HPLC\2015-020\Processing\DOC\2015-020-bot-hdr1.txt Channel 11: Number_of_bin_records [n/a] Pad: ' ' ==> -99 -HEADER EDITS: 2020/07/21 14:57:48 Applied edit header: D:\Telework\HPLC\2015-020\Processing\DOC\2015-020-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = E:\Data\2015-20\2015-20-0134.hex Software Version Seasave V 7.22.4 Temperature SN = 2023 Conductivity SN = 1763 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jun 02 2015 20:06:10 NMEA Latitude = 50 27.84 N NMEA Longitude = 129 55.12 W NMEA UTC (Time) = Jun 02 2015 20:04:40 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds advance voltage 6 0.000 seconds advance voltage 7 0.000 seconds S> Ship: J P Tully Cruise: 2015-20 Depth: 2170 Station: CS00 System UTC = Jun 02 2015 20:06:10 # nquan = 19 # nvalues = 4820 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = sbeox0V: Oxygen raw, SBE 43 [V] # name 11 = par: PAR/Irradiance, Biospherical/Licor # name 12 = altM: Altimeter [m] # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = pumps: Pump Status # name 15 = sal00: Salinity, Practical [PSU] # name 16 = sal11: Salinity, Practical, 2 [PSU] # name 17 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 18 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jun 02 2015 20:04:40 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 2023 # 31-Jan-13 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.11056177e-003 # 6.24714349e-004 # 1.97891287e-005 # 1.88702998e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1763 # 01-Jan-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.22314873e+000 # 5.07768024e-001 # -5.15940128e-004 # 5.09668877e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0506 # 30-Dec-13 # -4.957807e+004 # -1.280011e+000 # 1.485710e-002 # 4.021200e-002 # 0.000000e+000 # 3.037224e+001 # -6.696188e-004 # 3.897170e-006 # 3.287590e-009 # 0.99997945 # -0.25000 # 0.000000e+000 # 1.280810e-002 # -9.210198e+000 # # # # # # 5013 # 27-Feb-13 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36833110e-003 # 6.37693324e-004 # 2.08227492e-005 # 1.72454648e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3394 # 03-Jan-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.62060268e+000 # 1.47483016e+000 # -1.36190582e-003 # 1.93968125e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1438 # 03-Jan-14 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.7181e-001 # -0.5187 # -2.2511e-003 # 1.3917e-004 # -2.6436e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.4300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3640 # # # 2 # 0.000 # # # # # # 1396DR # Feb 5tht 2014 # 19.0844 # -0.0191 # 0.250 # # # # # # # # # 62354 # # 15.000 # 0.000 # # # # # # # # # 4565 # Mar-16-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # # datcnv_date = Aug 06 2015 08:53:49, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2015-20\RAW\CTD\2015-20-0134.hex P:\Crui se_Data_Processing\2015-20\Processing\doc\2015-20-ctd.xmlcon # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0134.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0134.oxy ------------------------------------------------------------------- Sample_Number 321: OXY: Sample redrawn Sample_Number 327: OXY: Leaky spigot Sample_Number 332: OXY: Sample redrawn Comments from secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0134.nut ------------------------------------------------------------------- Sample_Number 334: NO3, PO4: Chauvenet outlier in duplicate study Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~2 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2015-20CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF2015-020HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2015-20OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 46 to 57 days after collection. For details including a duplicate analysis, see document QF2015-20SAL*.xls. NOTE: Salinity is given to only 3 decimal places as recommended by the analyst based on lower than usual precision. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2015-20nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2015-20NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. The fluorescence cable was installed incorrectly for events #87 to 115 so the Fluorescence:URU:Seapoint channel was removed from those files. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2015-20_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (0.16E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.248E-01 1.0235) $END !-1-- 2- 3- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- --12- ---13--- 14 ---15-- --16- 17 --18-- 19 --20-- 21 ---22-- 23 --24-- 25 --26-- 27 --28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- 54 !Samp Bo Bo Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ tt tt re ure: missi cence: :T0:C0 : n: er_o ratur :Bottle ag Dissolv n: ag e_ ag te ag te ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe-a Car TChl-a ag !Numb ~u ~u Primary vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er mb en Seapoin ved: lved: _rec Draw tt lved lv Nitrit ri ca ha ni ted ct Extrac HP ! er ce t SBE SBE ords le ed e te te te um ed ted LC !---- -- -- ------ -------- ----- ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 338 20 20 5.0 11.9798 53.1 1.019 31.0843 6.83 298.1 241 12.0 31.0860 0 6.854 298.9 0 0.00 0 8.22 0 0.318 0 0.01 6 1.21 6 2.25 0.011 0.018 0.036 0.073 0.006 0.021 0.065 0.000 0.004 0.104 0.040 0.105 0.062 0.029 0.056 0.103 0.005 0.045 0.028 0.362 0.000 1.082 0.000 0.024 1.121 6 337 19 19 10.5 11.4938 43.5 3.961 31.1782 7.09 309.1 241 7.7 31.1790 0 7.117 310.2 6 0.17 0 9.42 0 0.402 0 0.08 6 3.56 6 0.33 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 336 18 18 19.3 11.8837 57.3 1.616 31.9551 6.46 281.6 241 11.8 31.8880 0 6.510 283.7 0 0.13 0 2.09 0 0.380 0 0.21 6 1.37 6 5.32 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 335 17 17 30.3 11.7049 61.4 0.889 32.2719 6.35 276.7 241 11.7 32.2700 0 6.371 277.6 0 2.28 0 9.01 0 0.348 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 334 16 16 49.3 10.7253 54.4 5.093 32.3543 6.43 280.2 241 11.7 32.3320 0 6.458 281.4 0 1.17 36 1.98 6 0.432 36 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 333 15 15 75.3 10.1174 64.7 0.487 32.5605 5.94 258.7 241 10.1 32.5640 0 5.955 259.4 0 5.65 0 6.65 0 0.704 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 332 14 14 101.2 8.0739 65.1 0.173 33.0880 4.87 212.1 241 8.5 33.0890 0 4.861 211.6 2 19.02 0 22.33 0 1.474 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 331 13 13 125.0 7.4647 65.0 0.138 33.4487 4.73 205.7 241 5.4 33.4400 0 4.738 206.1 6 21.56 0 26.65 0 1.564 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 330 12 12 149.9 7.2448 65.0 0.125 33.6572 4.62 200.8 241 7.7 33.6740 0 4.574 199.0 0 23.24 0 31.00 0 1.618 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 329 11 11 175.5 6.6751 64.9 0.116 33.8109 4.12 179.3 241 7.3 33.8150 0 4.127 179.5 0 26.63 0 39.73 0 1.827 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 328 10 10 200.1 6.3132 64.9 0.113 33.8466 3.83 166.4 241 7.1 33.8440 0 3.848 167.4 0 28.47 0 45.18 0 1.952 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 327 9 9 250.4 5.6236 65.3 0.109 33.8596 3.07 133.5 241 6.6 33.8650 0 3.084 134.1 3 32.95 0 55.94 0 2.245 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 326 8 8 300.7 5.1436 65.5 0.106 33.8671 2.71 117.8 241 6.3 33.8730 0 2.710 117.8 0 35.39 0 63.32 0 2.396 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 325 7 7 399.9 4.6663 66.1 0.098 33.9339 1.75 75.9 241 6.1 33.9320 0 1.756 76.4 0 40.07 6 77.80 6 2.731 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 324 6 6 500.9 4.4295 66.4 0.092 34.0536 0.96 41.8 241 5.9 34.0550 0 0.931 40.5 0 42.94 0 91.61 0 2.955 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 323 5 5 750.4 3.8881 66.4 0.085 34.2544 0.27 11.9 241 3.8 34.2510 0 0.287 12.5 6 45.56 0 116.96 0 3.207 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 322 4 4 1000.9 3.2732 66.4 0.086 34.3736 0.24 10.3 241 5.3 34.3770 0 0.236 10.3 0 46.12 0 137.24 0 3.245 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 321 3 3 1250.9 2.7362 66.4 0.085 34.4568 0.38 16.3 241 4.7 34.4560 0 0.374 16.3 2 46.19 0 153.73 0 3.213 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 320 2 2 1500.3 2.4008 66.4 0.085 34.5124 0.64 27.9 241 4.5 34.5090 6 0.647 28.1 0 45.50 0 163.17 0 3.121 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 319 1 1 1999.5 1.8962 65.7 0.085 34.5966 1.39 60.2 241 4.6 34.5960 0 1.398 60.7 0 43.44 0 176.35 0 3.007 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000