*2020/07/21 14:57:47.10 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2015/05/29 00:45:24.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 15 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 17EB203E NUMBER OF CHANNELS : 53 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 58 72 2 Bottle_Number n/a 1 15 3 Bottle:Firing_Sequence n/a 1 15 4 Pressure decibar 4.8 503.8 5 Temperature:Primary 'deg C (ITS90)' 5.0296 11.881 6 Transmissivity %/metre 47.4 65.8 7 Fluorescence:URU:Seapoint mg/m^3 0.97E-01 1.751 8 PAR uE/m^2/sec 0 104.2 9 Salinity:T0:C0 PSS-78 31.8481 34.1048 10 Oxygen:Dissolved:SBE mL/L 0.68 7.27 11 Oxygen:Dissolved:SBE umol/kg 29.4 316.8 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 4.4 11.7 14 Oxygen:Dissolved mL/L 0.675 7.269 15 Oxygen:Dissolved umol/kg 29.3 316.6 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 0 42.43 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 0.41 87.04 20 Flag:Silicate n/a 21 Phosphate umol/L 0.95E-01 3.048 22 Flag:Phosphate n/a 23 Ammonium umol/L 0.1E-01 1.14 24 Flag:Ammonium n/a 25 Chlorophyll:Extracted mg/m^3 1.17 2.77 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 1.93 4.65 28 HPLC:Chl-c3 mg/m^3 0.16E-01 0.16E-01 29 HPLC:Chlide-a mg/m^3 0.55E-01 0.55E-01 30 HPLC:MgDVP mg/m^3 0.11E-01 0.11E-01 31 HPLC:Chl-c2 mg/m^3 0.9E-01 0.9E-01 32 HPLC:Chl-c1 mg/m^3 0.34E-01 0.34E-01 33 HPLC:Me-chlide mg/m^3 0.13E-01 0.13E-01 34 HPLC:Peri mg/m^3 0.17E-01 0.17E-01 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0.7E-02 0.7E-02 37 HPLC:Fuco mg/m^3 0.385 0.385 38 HPLC:Neo mg/m^3 0.17E-01 0.17E-01 39 HPLC:Pras mg/m^3 0.17E-01 0.17E-01 40 HPLC:Viola mg/m^3 0.18E-01 0.18E-01 41 HPLC:Hex-fuco mg/m^3 0.1E-01 0.1E-01 42 HPLC:Diadino mg/m^3 0.75E-01 0.75E-01 43 HPLC:Allo mg/m^3 0.9E-02 0.9E-02 44 HPLC:Diato mg/m^3 0.9E-02 0.9E-02 45 HPLC:Zea mg/m^3 0.24E-01 0.24E-01 46 HPLC:Lut mg/m^3 0.6E-02 0.6E-02 47 HPLC:Chl-b mg/m^3 0.124 0.124 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 0.88 0.88 50 HPLC:Phe-a mg/m^3 0 0 51 HPLC:B-Car mg/m^3 0.13E-01 0.13E-01 52 HPLC:TChl-a mg/m^3 0.948 0.948 53 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2015-20 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LB12 EVENT NUMBER : 34 LATITUDE : 48 12.89000 N ! (deg min) LONGITUDE : 125 51.88000 W ! (deg min) WATER DEPTH : 505 ALTIMETER (M) : 9.16 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 1763 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 5013 Conductivity:2 ' ' 3394 'Oxygen:SBE 43' ' ' 1438 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1396DR Altimeter ' ' 62354 PAR/Irradiance:Biospherical/Licor ' ' 4565 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2015/08/06 15:30:56 3615 3615 CLEAN 5.2.1 2015/08/06 15:39:23 3615 3615 ADDSAMP 3.6 2015/08/06 16:49:54 3615 3615 BINAVE 4.2 2015/08/06 16:50:32 3615 15 MERGE 3.5 2015/09/01 14:51:22 15 15 CLEAN 5.2.1 2015/09/01 14:52:47 15 15 CALIB 11.8.1 2015/09/29 13:26:20 15 15 SORT 3.6 2015/09/29 13:27:30 15 15 REMOVECH 8.2 2015/09/29 13:28:16 15 15 CHGUNITS 3.1 2015/09/29 13:30:55 15 15 CHGUNITS 3.1 2015/09/29 13:31:27 15 15 REORDER 1.3.1 2015/09/29 13:32:32 ? ? HDREDIT2 3.0.2 2015/09/30 13:12:54 ? ? SORT 3.6 2020/07/17 14:49:04 15 15 REORDER 1.3.1 2020/07/17 14:57:51 ? ? MERGE 3.5.1 2020/07/21 14:48:16 15 15 SORT 3.6 2020/07/21 14:49:02 15 15 HDREDIT2 3.2 2020/07/21 14:57:15 ? ? HDREDIT2 3.2 2020/07/21 14:57:47 ? ? $END $REMARKS -CLEAN functions: 2015/08/06 15:39:17 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2015-20\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2015/09/01 14:51:22 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0034.samavg Secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0034.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0034.mrgcln1s ------------------------------------------------------------------------ -CLEAN functions: 2015/09/01 13:42:13 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2015/09/01 13:42:23 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2015/09/01 14:52:47 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name -CALIB parameters: 2015/09/29 13:26:20 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2015-20\Processing\doc\2015-20-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 17 Salinity:T1:C1 PSS-78 10 0.1600000E-02 0.1000000E+01 18 Oxygen:Dissolved:SBE mL/L 10 0.2480000E-01 0.1023500E+01 -SORT parameters: 2015/09/29 13:27:30 Sorted in ascending order of channel Pressure* -REMOVECH 2015/09/29 13:28:16 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2015/09/30 13:12:54 Applied edit header: P:\Cruise_Data_Processing\2015-20\Processing\doc\HYDRO\2015-20-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Channel 14: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 15: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 16: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 19: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 20: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 21: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 22: Silicate [umol/L] Units: ==> umol/L Channel 23: Flag:Silicate [n/a] Units: ==> n/a Channel 24: Phosphate [umol/L] Units: ==> umol/L Channel 25: Flag:Phosphate [n/a] Units: ==> n/a Channel 27: Flag:Ammonium [n/a] Units: ==> n/a -SORT parameters: 2020/07/17 14:49:04 Sorted in ascending order of channel Sample_number -The following MERGE parameters were used: 2020/07/21 14:48:16 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3, HPLC:Chlide-a, HPLC:MgDVP, HPLC:Chl-c2, HPLC:Chl-c1, HPLC:Me-chlide, HPLC:Peri, HPLC:Pheide-a, HPLC:But-fuco, HPLC:Fuco, HPLC:Neo, HPLC:Pras, HPLC:Viola, HPLC:Hex-fuco, HPLC:Diadino, HPLC:Allo, HPLC:Diato, HPLC:Zea, HPLC:Lut, HPLC:Chl-b, HPLC:DVChl-a, HPLC:Chl-a, HPLC:Phe-a, HPLC:B-Car, HPLC:TChl-a, Flag:HPLC Primary file : D:\Telework\HPLC\2015-020\Processing\2015-020-0034.CHE2 Secondary file: D:\Telework\HPLC\2015-020\Processing\2015-020-0034.hplc -SORT parameters: 2020/07/21 14:49:02 Sorted in ascending order of channel Pressure -HEADER EDITS: 2020/07/21 14:57:15 Applied edit header: D:\Telework\HPLC\2015-020\Processing\DOC\2015-020-bot-hdr1.txt Channel 12: Number_of_bin_records [n/a] Pad: ' ' ==> -99 -HEADER EDITS: 2020/07/21 14:57:47 Applied edit header: D:\Telework\HPLC\2015-020\Processing\DOC\2015-020-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = E:\Data\2015-20\2015-20-0034.hex Software Version Seasave V 7.22.4 Temperature SN = 2023 Conductivity SN = 1763 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = May 29 2015 00:46:52 NMEA Latitude = 48 12.89 N NMEA Longitude = 125 51.88 W NMEA UTC (Time) = May 29 2015 00:45:24 Store Lat/Lon Data = Append to Every Scan Ship: J P Tully Cruise: 2015-20 Depth: 505 Station: LB12 System UTC = May 29 2015 00:46:52 # nquan = 19 # nvalues = 3615 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = sbeox0V: Oxygen raw, SBE 43 [V] # name 11 = par: PAR/Irradiance, Biospherical/Licor # name 12 = altM: Altimeter [m] # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = pumps: Pump Status # name 15 = sal00: Salinity, Practical [PSU] # name 16 = sal11: Salinity, Practical, 2 [PSU] # name 17 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 18 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = May 29 2015 00:45:24 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 2023 # 31-Jan-13 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.11056177e-003 # 6.24714349e-004 # 1.97891287e-005 # 1.88702998e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1763 # 01-Jan-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.22314873e+000 # 5.07768024e-001 # -5.15940128e-004 # 5.09668877e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0506 # 30-Dec-13 # -4.957807e+004 # -1.280011e+000 # 1.485710e-002 # 4.021200e-002 # 0.000000e+000 # 3.037224e+001 # -6.696188e-004 # 3.897170e-006 # 3.287590e-009 # 0.99997945 # -0.25000 # 0.000000e+000 # 1.280810e-002 # -9.210198e+000 # # # # # # 5013 # 27-Feb-13 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36833110e-003 # 6.37693324e-004 # 2.08227492e-005 # 1.72454648e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3394 # 03-Jan-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.62060268e+000 # 1.47483016e+000 # -1.36190582e-003 # 1.93968125e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1438 # 03-Jan-14 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.7181e-001 # -0.5187 # -2.2511e-003 # 1.3917e-004 # -2.6436e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.4300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3640 # # # 2 # 0.000 # # # # # # 1396DR # Feb 5tht 2014 # 19.0844 # -0.0191 # 0.250 # # # # # # # # # 62354 # # 15.000 # 0.000 # # # # # # # # # 4565 # Mar-16-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # # datcnv_date = Aug 06 2015 08:51:29, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2015-20\RAW\CTD\2015-20-0034.hex P:\Crui se_Data_Processing\2015-20\Processing\doc\2015-20-ctd.xmlcon # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0034.mrgcln1s ------------------------------------------------------------------------ Comments from secondary file: P:\Cruise_Data_Processing\2015-20\Processing\hydro\2015-20-0034.oxy ------------------------------------------------------------------- Sample_Number 58: OXY: Niskin vent was not sealed. Sample_Number 66: OXY: Orange biological matter on spigot prior to sample collection. Sample_Number 71: OXY-1: Large particle in sample. Titration seemed ok. Sample_Number 72: OXY: Top end cap was not sealed resulting in a significant leak prior to sampling. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~2 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2015-20CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF2015-020HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2015-20OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 46 to 57 days after collection. For details including a duplicate analysis, see document QF2015-20SAL*.xls. NOTE: Salinity is given to only 3 decimal places as recommended by the analyst based on lower than usual precision. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2015-20nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2015-20NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. The fluorescence cable was installed incorrectly for events #87 to 115 so the Fluorescence:URU:Seapoint channel was removed from those files. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2015-20_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (0.16E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.248E-01 1.0235) $END !-1-- 2- 3- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14-- --15- 16 --17-- 18 --19-- 20 ---21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- 53 !Samp Bo Bo Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ tt tt re ure: missi cence: :T0:C0 : n: er_o ratur Dissolv n: ag e_ ag te ag te ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe-a Car TChl-a ag !Numb ~u ~u Primary vity URU: Dissol Disso ~bin e: ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er mb en Seapoin ved: lved: _rec Draw lved lv Nitrit ri ca ha ni ted ct Extrac HP ! er ce t SBE SBE ords ed e te te te um ed ted LC !---- -- -- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 72 15 15 4.8 11.8810 50.4 0.967 104.2 31.8481 7.21 314.2 241 11.7 7.227 315.0 3 0.00 0 0.41 0 0.095 0 0.01 6 1.17 6 4.32 0.016 0.055 0.011 0.090 0.034 0.013 0.017 0.000 0.007 0.385 0.017 0.017 0.018 0.010 0.075 0.009 0.009 0.024 0.006 0.124 0.000 0.880 0.000 0.013 0.948 6 71 14 14 10.1 11.4582 47.4 1.343 49.7 31.8627 7.27 316.8 241 7.5 7.269 316.6 26 0.00 0 0.48 0 0.100 0 0.03 6 1.33 6 4.65 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 70 13 13 19.6 10.3302 52.9 1.751 11.8 32.1984 6.02 262.3 241 10.3 6.054 263.7 0 3.18 0 4.86 0 0.633 0 1.14 6 2.77 6 1.93 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 69 12 12 29.9 10.0800 61.7 0.427 4.1 32.3663 5.91 257.3 241 10.0 5.939 258.7 0 5.18 0 7.01 0 0.800 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 68 11 11 49.7 8.3742 62.4 0.351 1.0 32.8486 4.99 217.1 241 8.5 5.003 217.8 0 16.85 0 20.19 0 1.450 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 67 10 10 75.4 7.6823 63.2 0.261 0.2 33.2030 4.38 190.4 241 7.9 4.375 190.4 0 22.11 0 28.31 0 1.723 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 66 9 9 100.8 7.4301 64.2 0.343 0.0 33.5705 4.00 174.2 241 7.7 4.017 174.8 2 24.92 0 32.11 0 1.857 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 65 8 8 125.3 7.2938 64.8 0.182 0.0 33.7870 3.29 142.9 241 7.5 3.281 142.7 0 28.49 0 38.92 0 2.047 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 64 7 7 150.8 7.1069 64.9 0.196 0.0 33.8791 2.90 126.3 241 7.4 2.883 125.4 0 30.64 0 43.42 0 2.178 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 63 6 6 174.4 6.9038 65.1 0.223 0.0 33.9202 2.57 111.7 241 7.2 2.567 111.6 0 32.30 0 47.21 0 2.299 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 62 5 5 201.2 6.6683 64.8 0.152 0.0 33.9302 2.43 105.6 241 7.1 2.426 105.5 0 33.37 6 50.34 6 2.348 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 61 4 4 250.4 6.4002 65.8 0.130 0.0 33.9611 1.98 86.1 241 6.9 1.972 85.8 0 35.62 0 55.95 0 2.509 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 60 3 3 300.9 6.0563 65.1 0.108 0.0 33.9749 1.68 73.0 241 4.4 1.682 73.1 6 37.41 0 61.92 0 2.635 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 59 2 2 400.4 5.4853 65.5 0.112 0.0 34.0322 1.10 48.0 241 6.3 1.100 47.8 0 40.43 0 74.41 0 2.870 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 58 1 1 503.8 5.0296 64.3 0.097 0.0 34.1048 0.68 29.4 241 6.1 0.675 29.3 3 42.43 0 87.04 0 3.048 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000