*2023/01/18 09:24:22.27 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2015/08/21 22:22:11.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 78390F2E NUMBER OF CHANNELS : 55 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 179 195 2 Bottle_Number n/a 2 21 3 Bottle:Firing_Sequence n/a 2 18 4 Pressure decibar 3.1 300.1 5 Temperature:Secondary 'deg C (ITS90)' 6.0922 13.5124 6 Transmissivity %/metre 42.2 64.3 7 Fluorescence:URU:Seapoint mg/m^3 0.95E-01 5.64 8 PAR uE/m^2/sec 0 70.3 9 Salinity:T1:C1 PSS-78 32.1429 33.9656 10 Oxygen:Dissolved:SBE mL/L 1.88 6.88 11 Oxygen:Dissolved:SBE umol/kg 81.9 299.9 12 Number_of_bin_records n/a 206 241 13 Nitrate_plus_Nitrite umol/L 0.32 36.6 14 Flag:Nitrate_plus_Nitrite n/a 15 Silicate umol/L 2.27 59.59 16 Flag:Silicate n/a 17 Phosphate umol/L 0.409 2.573 18 Flag:Phosphate n/a 19 Dimethyl_Sulphide nmol/L 0 1.92 20 Flag:Dimethyl_Sulphide n/a 21 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 22 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 23 Dimethylsulfoniopropionate_Total nmol/L -99 -99 24 Flag:Dimethylsulfoniopropionate_Total ' ' 25 Chlorophyll:Extracted mg/m^3 0.9E-01 4.07 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.7E-01 1.25 28 HPLC:Chl-c3 mg/m^3 0.78E-01 0.91E-01 29 HPLC:Chlide-a mg/m^3 0.118 0.264 30 HPLC:MgDVP mg/m^3 0.72E-01 0.8E-01 31 HPLC:Chl-c2 mg/m^3 0.395 0.42 32 HPLC:Chl-c1 mg/m^3 0.55E-01 0.58E-01 33 HPLC:Me-chlide mg/m^3 0 0.92E-01 34 HPLC:Peri mg/m^3 0.24E-01 0.66E-01 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0 0 37 HPLC:Fuco mg/m^3 1.597 1.834 38 HPLC:Neo mg/m^3 0.79E-01 0.99E-01 39 HPLC:Pras mg/m^3 0.106 0.137 40 HPLC:Viola mg/m^3 0.41E-01 0.64E-01 41 HPLC:Hex-fuco mg/m^3 0.27E-01 0.44E-01 42 HPLC:Diadino mg/m^3 0.114 0.289 43 HPLC:Allo mg/m^3 0.22E-01 0.3E-01 44 HPLC:Diato mg/m^3 0 0.16E-01 45 HPLC:Zea mg/m^3 0.18E-01 0.22E-01 46 HPLC:Lut mg/m^3 0 0.1E-01 47 HPLC:Chl-b mg/m^3 0.399 0.492 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 3.241 3.485 50 HPLC:Phe mg/m^3 0 0 51 HPLC:B-Car mg/m^3 0.51E-01 0.56E-01 52 HPLC:TChl-a mg/m^3 3.486 3.633 53 Flag:HPLC ' ' 54 pH ' ' 7.3817 7.916 55 Flag:pH ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 7 F R4 2 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 0 ' ' 3 NQ C ' ' 54 -99 ' ' ' ' F8.4 R4 ' ' 55 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2015-10 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P4 EVENT NUMBER : 31 LATITUDE : 48 39.00000 N ! (deg min) LONGITUDE : 126 39.98000 W ! (deg min) WATER DEPTH : 1310 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2663 Conductivity:2 ' ' 2754 'Oxygen:SBE 43' ' ' 0997 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1396DR PAR/Irradiance:Biospherical/Licor ' ' '4565 QSP200L4S' Altimeter ' ' 62354 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.23.2 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2015/11/30 11:17:08 4287 4287 CLEAN 5.2.1 2015/11/30 11:20:19 4287 4287 ADDSAMP 3.6 2015/11/30 11:30:46 4287 4287 BINAVE 4.2 2015/11/30 11:31:32 4287 18 MERGE 3.5 2015/12/01 11:30:27 17 17 CLEAN 5.2.1 2015/12/03 13:41:10 17 17 CALIB 11.8.1 2015/12/10 13:55:20 17 17 SORT 3.6 2015/12/11 11:18:24 17 17 REMOVECH 8.2 2015/12/11 11:24:07 17 17 CHGUNITS 3.1 2015/12/11 11:35:05 17 17 CHGUNITS 3.1 2015/12/11 11:35:41 17 17 REORDER 1.3.1 2015/12/11 11:38:19 ? ? HDREDIT2 3.0.2 2015/12/11 13:48:48 ? ? SORT 3.6 2019/11/27 09:28:27 17 17 HDREDIT2 3.1.1 2019/11/27 09:28:34 ? ? MERGE 3.5 2019/11/27 09:28:50 17 17 SORT 3.6 2019/11/27 09:43:54 17 17 HDREDIT2 3.1.1 2019/11/27 09:44:06 ? ? REMOVECH 8.2 2020/07/27 12:54:56 17 17 SORT 3.6 2020/07/27 12:55:53 17 17 MERGE 3.5.1 2020/07/27 12:59:42 17 17 SORT 3.6 2020/07/27 13:04:36 17 17 CLEAN 5.2.4 2020/07/27 13:06:15 17 17 SORT 3.6 2020/12/11 10:57:34 17 17 REORDER 1.3.1 2021/12/01 15:10:32 ? ? MERGE 3.5.1 2021/12/01 15:10:40 17 17 SORT 3.6 2021/12/01 15:10:56 17 17 CLEAN 5.2.4 2021/12/01 15:11:05 17 17 HDREDIT2 3.2 2021/12/01 15:13:27 ? ? HDREDIT2 3.2 2021/12/01 15:13:47 ? ? $END $REMARKS -CLEAN functions: 2015/11/30 11:20:08 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2015-10\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2015/12/01 11:30:27 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2015-10\Processing\hydro\2015-10-0031.samavg Secondary file: P:\Cruise_Data_Processing\2015-10\Processing\hydro\2015-10-0031.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2015-10\Processing\hydro\2015-10-0031.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2015/12/01 11:30:15 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2015/12/03 13:41:08 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name -CALIB parameters: 2015/12/10 13:55:20 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2015-10\Processing\doc\2015-10-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Oxygen:Dissolved:SBE mL/L 10 0.4260000E-01 0.1015100E+01 -SORT parameters: 2015/12/11 11:18:24 Sorted in ascending order of channel Pressure* -REMOVECH 2015/12/11 11:24:07 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Descent_Rate [m/s] Altimeter [metres] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 - No units changed -HEADER EDITS: 2015/12/11 13:48:48 Applied edit header: P:\Cruise_Data_Processing\2015-10\Processing\doc\HYDRO\2015-10-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 14: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 17: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 18: Silicate [umol/L] Units: ==> umol/L Channel 19: Flag:Silicate [n/a] Units: ==> n/a Channel 20: Phosphate [umol/L] Units: ==> umol/L Channel 21: Flag:Phosphate [n/a] Units: ==> n/a Channel 22: Dimethyl_Sulphide [nmol/L] Units: ==> nmol/L Channel 23: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a -SORT parameters: 2019/11/27 09:28:27 Sorted in ascending order of channel Sample_Number -HEADER EDITS: 2019/11/27 09:28:34 -The following MERGE parameters were used: 2019/11/27 09:28:50 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\2015-010\Processing\Bottle\2015-010-0031.rem Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2015-010\Processing\Bottle\2015-010-0031. dmsp -SORT parameters: 2019/11/27 09:43:54 Sorted in ascending order of channel Pressure -HEADER EDITS: 2019/11/27 09:44:06 Applied edit header: Q:\OSD_DataProcessing\Cruise_Data\DMSP\2015-010\Processing\DOC\2015-010-dmsp- hdr.txt -REMOVECH 2020/07/27 12:54:56 The following CHANNEL(S) were removed: Dimethylsulfoniopropionate_Dissolved [nmol/L] Flag:Dimethylsulfoniopropionate_Dissolve Dimethylsulfoniopropionate_Total [nmol/L] Flag:Dimethylsulfoniopropionate_Total -SORT parameters: 2020/07/27 12:55:53 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2020/07/27 12:59:42 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolved, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2015-010\Processing\2015-010- 0031.sort1 Secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2015-010\Processing\2015-010- 0031.dmsp -SORT parameters: 2020/07/27 13:04:36 Sorted in ascending order of channel Pressure -CLEAN functions: 2020/07/27 13:06:12 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag* -SORT parameters: 2020/12/11 10:57:34 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/12/01 15:10:40 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-010_Nov2021\Processing\ IOS\2015-010-0031.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-010_Nov2021\Processing\ IOS\2015-010-0031.hplc -SORT parameters: 2021/12/01 15:10:56 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/12/01 15:11:05 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/12/01 15:13:27 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-010\Processing\Doc\ 2015-010-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/12/01 15:13:47 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-010\Processing\Doc\ 2015-010-bot-hdr2.txt -SORT parameters: 2021/12/01 17:04:14 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/12/01 17:04:39 Merge Channel: Sample_Number Merge Scheme Used: 2: Add Secondary to Closest Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic [ ], Flag:Carbon:Dissolved:Inorganic [ ], Alkalinity:Total [ ], Flag:Alkalinity:Total [ ], pH [ ], Flag:pH [ ] Primary file : C:\Users\huntingtons\Desktop\Carbon Additions\2015-010_Nov2021\2015-010-0031.srt1 Secondary file: C:\Users\huntingtons\Desktop\Carbon Additions\2015-010_Nov2021\2015-010-0031.dic 6 secondary records matched to primary records. -SORT parameters: 2021/12/01 17:05:00 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/12/01 17:06:11 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/12/01 17:06:36 Applied edit header: C:\Users\huntingtons\Desktop\Carbon Additions\2015-010\Processing\DOC\2015- 010_carbon_header.txt Channel 54: Carbon:Dissolved:Inorganic [umol/kg] Units: ==> umol/kg Channel 55: Flag:Carbon:Dissolved:Inorganic [n/a] Units: ==> n/a Channel 56: Alkalinity:Total [umol/kg] Units: ==> umol/kg Channel 57: Flag:Alkalinity:Total [n/a] Units: ==> n/a -REMOVECH 2023/01/18 09:24:22 The following CHANNEL(S) were removed: Carbon:Dissolved:Inorganic [umol/kg] Flag:Carbon:Dissolved:Inorganic Alkalinity:Total [umol/kg] Flag:Alkalinity:Total $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = C:\CTD Data\2015-10\2015-10-0031.hex Software Version Seasave V 7.23.2 Temperature SN = 2106 Conductivity SN = 2280 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Aug 21 2015 22:27:38 NMEA Latitude = 48 39.00 N NMEA Longitude = 126 39.98 W NMEA UTC (Time) = Aug 21 2015 22:22:11 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds S> Mission: 2015-10 Ship: J.P. Tully Station: P4 Depth: 1310 DMS cast System UTC = Aug 21 2015 22:27:38 # nquan = 19 # nvalues = 4287 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = sbeox0V: Oxygen raw, SBE 43 [V] # name 11 = par: PAR/Irradiance, Biospherical/Licor # name 12 = dz/dtM: Descent Rate [m/s] # name 13 = altM: Altimeter [m] # name 14 = pumps: Pump Status # name 15 = sal00: Salinity, Practical [PSU] # name 16 = sal11: Salinity, Practical, 2 [PSU] # name 17 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 18 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Aug 21 2015 22:22:11 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 2106 # 17-Dec-14 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.14703785e-003 # 6.31044927e-004 # 2.13121431e-005 # 2.18594910e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2280 # 19-Dec-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.00904009e+001 # 1.35149315e+000 # -1.84720682e-003 # 1.90856808e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0443 # 17-Dec-14 # -4.435292e+004 # -1.635794e-001 # 1.192740e-002 # 3.979900e-002 # 0.000000e+000 # 2.993627e+001 # -3.271008e-004 # 3.759160e-006 # 1.565300e-009 # 0.99991613 # 0.05243 # 0.000000e+000 # 1.282462e-002 # -8.599824e+000 # # # # # # 2663 # 15-Jan-15 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36565531e-003 # 6.42337654e-004 # 2.40578991e-005 # 2.42263656e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 2754 # 19-Dec-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -1.05920237e+001 # 1.61356129e+000 # -1.94911294e-003 # 2.41671700e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0997 # 17-Jan-15 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.0785e-001 # -0.6967 # -3.5082e-003 # 1.2934e-004 # -1.8411e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.7500e-002 # 1.6200 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3640 # # # 2 # 0.000 # # # # # # 1396DR # 5 Feb 2014 # 19.0844 # -0.0191 # 0.250 # # # # # # # # # 4565 QSP200L4S # 16-Mar-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # 62354 # # 15.000 # 0.000 # # # # # # # # # # datcnv_date = Nov 30 2015 11:14:17, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2015-10\RAW\CTD\2015-10-0031.hex P:\Crui se_Data_Processing\2015-10\Processing\doc\2015-10-ctd.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\2015-10\Processing\hydro\2015-10-0031.dms ------------------------------------------------------------------- Sample_Number 186: DMS: Top valve open Comments from secondary file: Q:\OSD_DataProcessing\Cruise_Data\DMSP\Joe's Work\2015-010\Processing\2015-010-0031.dmsp --------------------------------------------------------------------------- Sample_Number 180: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 181: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 182: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 188: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 191: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 192: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Chlorophyll values ranged from 0.03-20.58 ug/l. Precision Statement: Average %CV for this cruise was a very good 3.81% with 3 out of 68 duplicate pairs having a CV>15% and 0 out of 68 duplicate pairs having a CV>50% . Our average dataset %CV is 4 % for 2013 - 2014 so the overall quality of this dataset is very good. For details see worksheet “CV%” in file QF2015-10CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed 6 to 8 weeks after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF2015-010HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2015-10OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 3 to 19 days after collection. For details including a duplicate analysis, see document QF2015-10SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2015-10nuts*.xls. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100C (with a dewar containing boiling water) onto a Choromasorb 330 column which eluted onto a Flame Photometric Detector (PFD). All samples were run as soon as possible after being collected. For more detail see file 2015-10 DMS report.doc and for data and duplicate analysis see "DMS summary (2015-10 data).xls." The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.10nmol/L. Dissolved inorganic carbon (DIC) was determined using coulometric analysis of unfiltered samples. Total alkalinity (Alk) was determined by potentiometric titration. pH on the total hydrogen ion concentration scale was determined photometrically and is reported at 25C and surface pressure. Complete documentation on DIC, ALK and pH sampling, analysis and precision estimates can be found in the Carbon Excel file from the cruise located in the cruise "DOC" directory. DMSP-D: 20-75mL of seawater was allowed to flow directly from the niskin into a magnetic filtration funnel containing a 0.7um GF/F filter. The first 3.5mL was collected in a polypropylene tube containing 50uL of a 50% sulphuric acid solution. DMPS-T: 3.5mL of seawater was collected directly from the niskin into a polypropylene tube containing 50uL of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. For details on analysis and raw data, see document "QF 2015-010 dmsp*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2015-10_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.426E-01 1.0151) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13-- 14 --15-- 16 ---17-- 18 --19-- 20 --21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- 53 ---54-- 55 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl pH Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o e_ ag te ag te ag yl_ ag ylsulf ag ylsulf ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a t: a chlide a fuco fuco : : !er er Sequ y Seapoin ved: lved: _rec Nitrit ri ca ha de hi te_Dis lv ionate ot ted ct Extrac HP pH ! ence t SBE SBE ords e te te te de solved ed _Total al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- ------- -- *END OF HEADER 192 14 18 3.1 13.4958 42.2 3.304 70.3 32.1530 6.50 283.2 241 1.78 0 4.08 0 0.527 0 1.22 0 -99.00 1 -99.00 1 3.81 0 0.98 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.0000 0 191 13 16 4.9 13.5065 43.1 4.169 47.1 32.1536 6.50 283.1 241 1.64 0 4.11 0 0.501 0 1.17 0 -99.00 1 -99.00 1 3.60 0 1.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.0000 0 195 17 17 4.9 13.5003 43.2 4.297 48.1 32.1536 6.50 283.2 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 3.84 6 1.04 0.091 0.264 0.080 0.415 0.058 0.092 0.063 0.000 0.000 1.632 0.079 0.129 0.064 0.044 0.289 0.030 0.016 0.022 0.010 0.492 0.000 3.277 0.000 0.056 3.633 6 -99.0000 0 190 12 15 9.8 13.5124 43.5 3.950 17.3 32.1543 6.49 283.0 241 1.66 6 4.09 6 0.489 6 1.22 0 -99.00 0 -99.00 0 3.59 0 1.06 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.0000 0 189 11 13 15.4 13.4695 43.2 4.817 7.2 32.1526 6.49 282.7 241 1.64 0 4.11 0 0.498 0 1.01 0 -99.00 0 -99.00 0 3.34 0 0.95 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.0000 0 194 16 14 15.4 13.4691 43.2 4.960 7.6 32.1526 6.48 282.5 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 3.88 6 1.03 0.080 0.202 0.072 0.395 0.057 0.043 0.066 0.000 0.000 1.597 0.092 0.106 0.054 0.027 0.248 0.026 0.011 0.018 0.000 0.399 0.000 3.241 0.000 0.051 3.486 36-99.0000 0 188 10 12 20.3 13.3814 45.0 5.193 4.7 32.1491 6.45 281.0 241 1.69 0 4.09 0 0.500 0 1.04 6 -99.00 1 -99.00 1 3.73 6 1.13 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.0000 0 187 9 11 24.9 13.3377 43.8 5.640 3.4 32.1468 6.43 280.3 241 1.82 0 4.12 0 0.534 0 1.23 0 -99.00 0 -99.00 0 4.04 0 1.24 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 7.9160 0 186 8 9 29.9 13.1668 44.6 4.878 2.1 32.1468 6.40 278.8 206 1.73 0 3.97 0 0.536 0 1.04 2 -99.00 0 -99.00 0 4.07 0 1.23 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.0000 0 193 15 10 29.9 13.2026 45.4 4.915 2.1 32.1429 6.39 278.7 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 3.84 6 1.25 0.078 0.118 0.076 0.420 0.055 0.000 0.024 0.000 0.000 1.834 0.099 0.137 0.041 0.033 0.114 0.022 0.000 0.021 0.000 0.421 0.000 3.485 0.000 0.054 3.603 6 -99.0000 0 185 7 8 40.5 11.2659 57.0 1.445 0.7 32.4320 6.88 299.9 241 0.32 0 2.27 0 0.409 0 1.92 0 -99.00 0 -99.00 0 0.58 0 0.46 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.0000 0 184 6 7 49.8 10.7979 59.6 1.027 0.3 32.4560 6.60 287.5 241 1.58 0 3.09 0 0.499 0 0.95 0 -99.00 0 -99.00 0 0.47 0 0.40 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 7.8661 0 183 5 6 75.1 8.9554 63.8 0.295 0.0 32.8712 5.35 232.7 241 13.34 0 13.45 0 1.166 0 0.24 0 -99.00 0 -99.00 0 0.17 0 0.22 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 7.7167 0 182 4 5 100.0 7.9167 64.3 0.171 0.0 33.1988 4.92 214.3 241 19.54 0 21.87 0 1.517 0 0.00 0 -99.00 1 -99.00 1 0.09 0 0.07 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 7.6440 0 181 3 4 174.9 7.2892 63.8 0.111 0.0 33.8591 3.11 135.1 241 29.39 0 40.06 0 2.092 0 0.16 0 -99.00 1 -99.00 1 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 7.4972 0 180 2 3 200.4 7.1129 63.8 0.095 0.0 33.8956 2.82 122.7 241 30.87 0 43.52 0 2.190 0 0.19 0 -99.00 1 -99.00 1 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 -99.0000 0 179 21 2 300.1 6.0922 64.2 0.110 0.0 33.9656 1.88 81.9 241 36.60 0 59.59 0 2.573 0 0.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 7.3817 0