*2021/12/01 14:52:26.74 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2015/06/10 19:58:40.000 END TIME : UTC 2015/06/10 19:58:40.667 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : A91B7B04 NUMBER OF CHANNELS : 53 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 163 179 2 Bottle_Number n/a 1 18 3 Bottle:Firing_Sequence n/a 1 17 4 Pressure decibar 3.2 300.9 5 Temperature:Primary 'deg C (ITS90)' 5.3174 13.3025 6 Transmissivity %/metre 56.4 65.5 7 Fluorescence:URU:Seapoint mg/m^3 0.99E-01 1.867 8 PAR uE/m^2/sec 0 458.1 9 Salinity:T0:C0 PSS-78 32.2864 33.875 10 Oxygen:Dissolved:SBE mL/L 3.09 6.77 11 Oxygen:Dissolved:SBE umol/kg 134.2 294.9 12 Number_of_bin_records n/a 115 241 13 Nitrate_plus_Nitrite umol/L 0 33.58 14 Flag:Nitrate_plus_Nitrite n/a 15 Silicate umol/L 1.85 60.18 16 Flag:Silicate n/a 17 Phosphate umol/L 0.376 2.336 18 Flag:Phosphate n/a 19 Dimethyl_Sulphide nmol/L 0 2.4 20 Flag:Dimethyl_Sulphide n/a 21 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 22 Flag:Dimethylsulfoniopropionate_Dissolved ' ' 23 Dimethylsulfoniopropionate_Total nmol/L -99 -99 24 Flag:Dimethylsulfoniopropionate_Total ' ' 25 Chlorophyll:Extracted mg/m^3 0.11 0.52 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.2E-01 0.22 28 HPLC:Chl-c3 mg/m^3 0.4E-02 0.94E-01 29 HPLC:Chlide-a mg/m^3 0 0 30 HPLC:MgDVP mg/m^3 0 0.5E-02 31 HPLC:Chl-c2 mg/m^3 0.6E-02 0.73E-01 32 HPLC:Chl-c1 mg/m^3 0 0.5E-02 33 HPLC:Me-chlide mg/m^3 0 0 34 HPLC:Peri mg/m^3 0 0 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0.11E-01 0.81E-01 37 HPLC:Fuco mg/m^3 0.11E-01 0.43E-01 38 HPLC:Neo mg/m^3 0 0.7E-02 39 HPLC:Pras mg/m^3 0 0 40 HPLC:Viola mg/m^3 0 0 41 HPLC:Hex-fuco mg/m^3 0.2E-01 0.271 42 HPLC:Diadino mg/m^3 0.18E-01 0.36E-01 43 HPLC:Allo mg/m^3 0 0.4E-02 44 HPLC:Diato mg/m^3 0.4E-02 0.8E-02 45 HPLC:Zea mg/m^3 0.8E-02 0.19E-01 46 HPLC:Lut mg/m^3 0.1E-02 0.11E-01 47 HPLC:Chl-b mg/m^3 0 0.49E-01 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 0.8E-01 0.409 50 HPLC:Phe mg/m^3 0 0 51 HPLC:B-Car mg/m^3 0 0.4E-02 52 HPLC:TChl-a mg/m^3 0.8E-01 0.409 53 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 7 F R4 2 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2015-09 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P12 EVENT NUMBER : 23 LATITUDE : 48 58.18000 N ! (deg min) LONGITUDE : 130 39.93000 W ! (deg min) WATER DEPTH : 3233 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2023 Conductivity ' ' 1763 'Pressure:Digiquartz with TC' ' ' 0506 Temperature:2 ' ' 5013 Conductivity:2 ' ' 3394 'Oxygen:SBE 43' ' ' 1438 Fluorometer:Seapoint ' ' 3640 'Transmissometer:WET Labs C-Star' ' ' 1396DR Altimeter ' ' 62354 PAR/Irradiance:Biospherical/Licor ' ' 4565 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2015/07/31 14:44:38 3934 3934 CLEAN 5.2.1 2015/07/31 14:46:30 3934 3934 ADDSAMP 3.6 2015/08/11 16:23:49 3934 3934 BINAVE 4.2 2015/08/11 16:23:53 3934 17 MERGE 3.5 2015/08/28 11:55:22 17 17 CLEAN 5.2.1 2015/08/28 13:40:52 17 17 CALIB 11.8.1 2015/08/28 13:41:27 17 17 SORT 3.6 2015/08/28 13:41:42 17 17 REMOVECH 8.2 2015/08/28 13:42:41 17 17 CHGUNITS 3.1 2015/08/28 13:49:42 17 17 CHGUNITS 3.1 2015/08/28 13:50:02 17 17 REORDER 1.3.1 2015/08/28 13:50:07 ? ? HDREDIT2 3.0.2 2015/08/28 13:50:39 ? ? SORT 3.6 2019/06/19 11:08:08 17 17 MERGE 3.5 2019/06/19 11:08:14 17 17 SORT 3.6 2019/06/19 11:08:42 17 17 HDREDIT2 3.2 2020/01/22 12:37:30 ? ? CLEAN 5.2.3 2020/02/06 14:50:36 17 17 HDREDIT2 3.2 2020/02/06 14:51:17 ? ? SORT 3.6 2020/12/11 10:13:59 17 17 REORDER 1.3.1 2021/12/01 14:41:18 ? ? MERGE 3.5.1 2021/12/01 14:45:19 17 17 SORT 3.6 2021/12/01 14:46:15 17 17 CLEAN 5.2.4 2021/12/01 14:46:42 17 17 HDREDIT2 3.2 2021/12/01 14:52:05 ? ? HDREDIT2 3.2 2021/12/01 14:52:26 ? ? $END $REMARKS -CLEAN functions: 2015/07/31 14:46:19 20 Reset #RECS, MIN & MAX values in header. Interpolation by Channel 1: Scan_Number [n/a] in Pressure Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2015-09\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2015/08/28 11:55:22 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2015-09\Processing\hydro\2015-09-0023.samavg Secondary file: P:\Cruise_Data_Processing\2015-09\Processing\hydro\2015-09-0023.mrgcln1s Comments from secondary file: P:\Cruise_Data_Processing\2015-09\Processing\hydro\2015-09-0023.mrgcln1s ------------------------------------------------------------------------ -SORT parameters: 2015/08/28 11:51:21 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2015/08/28 13:40:50 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name -CALIB parameters: 2015/08/28 13:41:27 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2015-09\Processing\doc\2015-09-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 18 Oxygen:Dissolved:SBE mL/L 10 0.4520000E-01 0.1024600E+01 -SORT parameters: 2015/08/28 13:41:42 Sorted in ascending order of channel Pressure* -REMOVECH 2015/08/28 13:42:41 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 - No units changed -HEADER EDITS: 2015/08/28 13:50:39 Applied edit header: P:\Cruise_Data_Processing\2015-09\Processing\doc\HYDRO\2015-09-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F9.4 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Format: F8.3 ==> F7.2 Channel 14: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 17: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 18: Silicate [umol/L] Units: ==> umol/L Channel 19: Flag:Silicate [n/a] Units: ==> n/a Channel 20: Phosphate [umol/L] Units: ==> umol/L Channel 21: Flag:Phosphate [n/a] Units: ==> n/a Channel 22: Dimethyl_Sulphide [nmol/L] Units: ==> nmol/L Channel 23: Flag:Dimethyl_Sulphide [n/a] Units: ==> n/a -SORT parameters: 2019/06/19 11:08:08 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2019/06/19 11:08:14 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved, Flag:Dimethylsulfoniopropionate_Dissolve, Dimethylsulfoniopropionate_Total, Flag:Dimethylsulfoniopropionate_Total Primary file : P:\Cruise_Data_Processing\DMSP\2015-09\original\2015-009-0023.che1 Secondary file: P:\Cruise_Data_Processing\DMSP\2015-09\original\2015-009-0023.dmsp -SORT parameters: 2019/06/19 11:08:42 Sorted in ascending order of channel Pressure -HEADER EDITS: 2020/01/22 12:37:30 - none. -CLEAN functions: 2020/02/06 14:50:36 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set header Start and End times from the data. -HEADER EDITS: 2020/02/06 14:51:17 Channel 25: Flag:Dimethylsulfoniopropionate_Dissolved [] Name: Flag:Dimethylsulfoniopropionate_Dissolve ==> Flag:Dimethylsulfoniopropionate_Dissolved -SORT parameters: 2020/12/11 10:13:59 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/12/01 14:45:19 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-009_Nov2021\Processing\ IOS\2015-009-0023.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-009_Nov2021\Processing\ IOS\2015-009-0023.hplc -SORT parameters: 2021/12/01 14:46:15 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/12/01 14:46:41 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/12/01 14:52:05 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-009\Processing\Doc\ 2015-009-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/12/01 14:52:26 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-009\Processing\Doc\ 2015-009-bot-hdr2.txt $END *COMMENTS SBE HEADER Sea-Bird SBE 9 Data File: FileName = E:\Data\2015-09\2015-09-0023.hex Software Version Seasave V 7.22.4 Temperature SN = 2023 Conductivity SN = 1763 Number of Bytes Per Scan = 37 Number of Voltage Words = 4 Number of Scans Averaged by the Deck Unit = 1 System UpLoad Time = Jun 10 2015 19:59:50 NMEA Latitude = 48 58.18 N NMEA Longitude = 130 39.93 W NMEA UTC (Time) = Jun 10 2015 19:58:40 Store Lat/Lon Data = Append to Every Scan SBE 11plus V 5.1e number of scans to average = 1 pressure baud rate = 9600 NMEA baud rate = 4800 GPIB address = 1 advance primary conductivity 0.073 seconds advance secondary conductivity 0.073 seconds advance voltage 6 0.000 seconds advance voltage 7 0.000 seconds S> Ship: J P Tully Cruise: 2015-09 Depth: 3233 Station: P12 System UTC = Jun 10 2015 19:59:50 # nquan = 19 # nvalues = 3934 # units = specified # name 0 = scan: Scan Count # name 1 = bpos: Bottle Position in Carousel # name 2 = nbf: Bottles Fired # name 3 = prDM: Pressure, Digiquartz [db] # name 4 = t090C: Temperature [ITS-90, deg C] # name 5 = t190C: Temperature, 2 [ITS-90, deg C] # name 6 = c0S/m: Conductivity [S/m] # name 7 = c1S/m: Conductivity, 2 [S/m] # name 8 = CStarTr0: Beam Transmission, WET Labs C-Star [%] # name 9 = flSP: Fluorescence, Seapoint # name 10 = sbeox0V: Oxygen raw, SBE 43 [V] # name 11 = par: PAR/Irradiance, Biospherical/Licor # name 12 = altM: Altimeter [m] # name 13 = dz/dtM: Descent Rate [m/s] # name 14 = pumps: Pump Status # name 15 = sal00: Salinity, Practical [PSU] # name 16 = sal11: Salinity, Practical, 2 [PSU] # name 17 = sbeox0ML/L: Oxygen, SBE 43 [ml/l] # name 18 = flag: 0.000e+00 # interval = seconds: 0.0416667 # start_time = Jun 10 2015 19:58:40 [NMEA time, header] # bad_flag = -9.990e-29 # # # # # 2023 # 31-Jan-13 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.11056177e-003 # 6.24714349e-004 # 1.97891287e-005 # 1.88702998e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 1763 # 01-Jan-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -4.22314873e+000 # 5.07768024e-001 # -5.15940128e-004 # 5.09668877e-005 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 0506 # 30-Dec-13 # -4.957807e+004 # -1.280011e+000 # 1.485710e-002 # 4.021200e-002 # 0.000000e+000 # 3.037224e+001 # -6.696188e-004 # 3.897170e-006 # 3.287590e-009 # 0.99997945 # -0.25000 # 0.000000e+000 # 1.280810e-002 # -9.210198e+000 # # # # # # 5013 # 27-Feb-13 # 1 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.000 # 4.36833110e-003 # 6.37693324e-004 # 2.08227492e-005 # 1.72454648e-006 # 1000.000 # 1.00000000 # 0.0000 # # # # # # 3394 # 03-Jan-14 # 1 # # 0.0000 # 2000.0000 # 0 # # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.00000000e+000 # 0.0 # -9.57000000e-008 # # # -9.62060268e+000 # 1.47483016e+000 # -1.36190582e-003 # 1.93968125e-004 # -9.57000000e-008 # 3.2500e-006 # # 0.00000000e+000 # # 1.00000000 # 0.00000 # # # # # # 1438 # 03-Jan-14 # 1 # # # 0.0000 # 0.0000e+000 # 0.0000 # 0.00e+000 # 0.0000 # 0.0 # # # # 4.7181e-001 # -0.5187 # -2.2511e-003 # 1.3917e-004 # -2.6436e-006 # 2.5826e+000 # 1.92634e-004 # -4.64803e-002 # 3.6000e-002 # 1.4300 #

-3.3000e-002

#

5.0000e+003

#

1.4500e+003

# # # # # # # 3640 # # # 2 # 0.000 # # # # # # 1396DR # Feb 5tht 2014 # 19.0844 # -0.0191 # 0.250 # # # # # # # # # 62354 # # 15.000 # 0.000 # # # # # # # # # 4565 # Mar-16-2011 # 1.00000000 # 0.00000000 # 4115226337.44999980 # 1.00000000 # -0.36780000 # # # # # # # datcnv_date = Jul 31 2015 12:21:50, 7.23.2 # datcnv_in = P:\Cruise_Data_Processing\2015-09\RAW\CTD\2015-09-0023.hex P:\Crui se_Data_Processing\2015-09\Processing\doc\2015-09-ctd.XMLCON # datcnv_ox_hysteresis_correction = yes # datcnv_ox_tau_correction = yes # datcnv_bottle_scan_range_source = BL file # datcnv_scans_per_bottle = 241 END* Comments from secondary file: P:\Cruise_Data_Processing\DMSP\2015-09\original\2015-009-0023.dmsp ------------------------------------------------------------------ Sample_Number 164: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 165: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 166: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 172: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 175: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Sample_Number 176: DMSP-D & DMSP-T: Elevated levels in the blank therefore sample data not valid Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 ~3 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2015-09CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed 4 to 6 weeks after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF2015-009HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2015-09OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 13 to 37 days after collection. For details including a duplicate analysis, see document QF2015-09SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details including a duplicate analysis, see document QF2015-09nuts*.xls. DMS samples were collected in 250mL ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100mL/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100C (with a deware containing boiling water) onto a Choromasorb 330 column which eluted onto a Flame Photometric Detector (PFD). All samples were run as soon as possible after being collected. For more detail see file 2015-09 DMS report.doc and for data and duplicate analysis see "DMS summary (2015-09 data).xls." The minimum detectable level for DMS is 0.10 nmol/L, so “0” values should be interpreted as <0.10nmol/L. DMSP-D: Approximately 20-75mL of seawater was allowed to flow directly from the Niskin into a filtration funnel containing a 0.7um GF/F filter. The first 3.5mL was collected in a polypropylene tube (15mL) containing 50uL of a 50% sulphuric acid solution. DMPS-T: 3.5mL of seawater was collected directly from the Niskin into a polypropylene tube (15mL) containing 50uL of a 50% sulphuric acid solution (50%). DMSP-D and DMSP-T: Samples are stored in the dark at 4 degrees C for a minimum of 24 hours. They are hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. For details on analysis and raw data, see document "2015-09 dmsp QF summary.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see the report: 2015-09_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2015\2015-009_Nov2021\Processing\IOS\2015-009-0023. hplc --------------------------------------------------------------------------- Sample_Number 179: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.452E-01 1.0246) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13-- 14 --15-- 16 ---17-- 18 --19-- 20 --21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- 53 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T0:C0 : n: er_o e_ ag te ag te ag yl_ ag ylsulf ag ylsulf ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Nitrit ri ca ha de hi te_Dis lv ionate ot ted ct Extrac HP ! ence t SBE SBE ords e te te te de solved ed _Total al ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 176 18 17 3.2 13.3024 61.9 0.223 458.1 32.3973 6.21 270.8 241 0.00 0 1.87 0 0.376 0 2.40 0 -99.00 1 -99.00 1 0.11 0 0.02 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 179 17 16 5.2 13.2933 61.8 0.210 326.1 32.3975 6.22 270.9 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 0.12 6 0.02 0.004 0.000 0.000 0.006 0.000 0.000 0.000 0.000 0.011 0.011 0.000 0.000 0.000 0.020 0.018 0.000 0.005 0.008 0.001 0.000 0.000 0.080 0.000 0.000 0.080 36 175 13 15 5.4 13.3025 61.8 0.211 311.8 32.3978 6.22 271.0 115 0.06 0 1.87 0 0.377 0 1.73 0 -99.00 1 -99.00 1 0.12 0 0.02 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 174 12 14 10.0 13.2234 61.7 0.225 199.9 32.3949 6.23 271.3 241 0.00 0 1.87 0 0.379 0 1.86 0 -99.00 0 -99.00 0 0.12 0 0.02 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 173 11 13 15.0 13.1074 61.5 0.235 131.2 32.3903 6.22 271.0 241 0.00 0 1.86 0 0.387 0 1.92 0 -99.00 0 -99.00 0 0.14 0 0.02 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 172 10 12 20.1 13.0987 61.5 0.250 100.0 32.3906 6.22 271.2 241 0.00 0 1.86 0 0.380 0 1.93 6 -99.00 1 -99.00 1 0.12 0 0.02 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 171 9 11 25.4 13.0886 61.4 0.271 88.0 32.3906 6.23 271.6 241 0.00 0 1.86 0 0.383 0 1.97 0 -99.00 0 -99.00 0 0.16 0 0.03 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 170 8 10 30.1 13.0505 61.4 0.300 82.5 32.3911 6.25 272.2 241 0.00 0 1.85 0 0.395 0 2.20 0 -99.00 0 -99.00 0 0.14 0 0.03 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 169 7 9 39.5 11.2599 57.6 1.011 65.2 32.3873 6.73 293.3 241 0.31 0 2.35 0 0.418 0 2.24 0 -99.00 0 -99.00 0 0.38 6 0.09 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 168 6 8 51.0 10.9204 56.4 1.310 40.4 32.3569 6.77 294.9 241 0.85 0 3.52 0 0.459 0 2.19 0 -99.00 0 -99.00 0 0.45 0 0.12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 178 16 7 51.1 10.9268 57.2 1.305 41.2 32.3579 6.76 294.5 204 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 0.41 6 0.10 0.058 0.000 0.003 0.050 0.002 0.000 0.000 0.000 0.044 0.043 0.000 0.000 0.000 0.187 0.036 0.004 0.008 0.013 0.007 0.024 0.000 0.322 0.000 0.004 0.322 6 177 15 6 60.4 10.3066 56.8 1.867 25.0 32.2864 6.62 288.3 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 0.51 6 0.19 0.094 0.000 0.005 0.073 0.005 0.000 0.000 0.000 0.081 0.043 0.007 0.000 0.000 0.271 0.036 0.002 0.004 0.019 0.011 0.049 0.000 0.409 0.000 0.002 0.409 6 167 5 5 74.5 10.4254 60.4 1.714 10.3 32.4373 6.53 284.2 241 1.94 6 3.19 6 0.519 6 1.02 0 -99.00 0 -99.00 0 0.52 0 0.22 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 166 4 4 100.3 8.8107 64.9 0.438 2.3 32.8260 5.34 232.4 241 14.05 0 15.67 0 1.217 0 0.37 0 -99.00 1 -99.00 1 0.18 0 0.09 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 165 3 3 175.4 7.7527 65.3 0.117 0.1 33.8536 4.58 199.3 241 22.13 0 29.71 0 1.522 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 164 2 2 199.7 7.3428 65.2 0.109 0.0 33.8750 4.38 190.7 241 23.89 0 34.34 0 1.671 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 163 1 1 300.9 5.3174 65.5 0.099 0.0 33.8506 3.09 134.2 241 33.58 0 60.18 0 2.336 0 0.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 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