*2023/03/19 10:46:56.06 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/06/23 22:27:14.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 748A8655 NUMBER OF CHANNELS : 24 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle_Number n/a 1 13 2 Bottle:Firing_Sequence n/a 1 13 3 Pressure decibar 1.6 339.8 4 Temperature:Secondary 'deg C (ITS90)' 8.1305 15.4119 5 Transmissivity %/metre 26 55.9 6 Fluorescence:URU:Seapoint mg/m^3 0.49E-01 2.928 7 PAR uE/m^2/sec 0 272.5 8 PAR:Reference uE/m^2/sec 534.5 739.6 9 pH:SBE:Nominal n/a 8.2 9.048 10 Salinity:T1:C1 PSS-78 21.2105 31.0057 11 Oxygen:Dissolved:SBE mL/L 2.94 7.07 12 Oxygen:Dissolved:SBE umol/kg 128.3 310.8 13 Number_of_bin_records n/a 241 241 14 Sample_Number n/a 130 142 15 Temperature:Draw 'deg C (ITS90)' 8.7 15.8 16 Oxygen:Dissolved mL/L 2.945 6.883 17 Oxygen:Dissolved umol/kg 128.4 302.7 18 Flag:Oxygen:Dissolved n/a 19 Nitrate_plus_Nitrite umol/L 1.81 31.99 20 Flag:Nitrate_plus_Nitrite n/a 21 Phosphate umol/L 0.299 2.924 22 Flag:Phosphate n/a 23 Silicate umol/L 19.45 83.59 24 Silicate:Flag n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 ' ' ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 8 F R4 3 17 -99 ' ' 6 F ' ' 1 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' $END $REMARKS Data quality is expressed with the following flags: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-28 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : PARR Shellfish Carrying Capacity SCIENTIST : Sutherland T. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Baynes Sound STATION : BS 40 EVENT NUMBER : 98 LATITUDE : 49 27.09000 N ! (deg min) LONGITUDE : 124 28.35000 W ! (deg min) WATER DEPTH : 340 ALTIMETER (M) : 4.03 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 1189 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 5830 Conductivity ' ' 4327 'Pressure:Digiquartz with TC' ' ' 1189 Temperature:2 ' ' 5831 Conductivity:2 ' ' 4339 'Oxygen:SBE 43' ' ' 1483 PAR/Irradiance:Biospherical/Licor ' ' 4656 Fluorometer:Seapoint ' ' 3640 pH ' ' 0691 Altimeter ' ' 43281 'Transmissometer:WET Labs C-Star' ' ' 983DR Unavailable ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.23.1 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! --------------------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2015/03/09 09:59:49 3133 3133 CLEAN 5.2.1 2015/03/09 10:00:07 3133 3133 ADDSAMP 3.6 2015/03/09 10:06:34 3133 3133 BINAVE 4.2 2015/03/09 10:18:23 3133 13 MERGE 3.5 2015/03/09 10:39:49 13 13 CLEAN 5.2.1 2015/03/09 10:39:53 13 13 CALIB 11.8.1 2015/03/14 14:44:38 13 13 SORT 3.6 2015/03/14 15:50:17 13 13 REMOVECH 8.2 2015/03/14 15:54:40 13 13 CHGUNITS 3.1 2015/03/14 16:01:53 13 13 CHGUNITS 3.1 2015/03/14 16:02:16 13 13 REORDER 1.3.1 2015/03/14 16:02:24 ? ? HDREDIT2 3.0.2 2015/03/16 16:25:41 ? ? Silicate_Correction 1.0 2018/02/20 14:30:28 13 13 Silicate_Modification 1.2 2023/03/19 10:46:56 13 13 $END $REMARKS -CLEAN functions: 2015/03/09 09:59:55 20 Reset #RECS, MIN & MAX values in header. Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-28\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2015/03/09 10:39:49 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-28\Processing\hydro\2014-28-0098.samavg Secondary file: P:\Cruise_Data_Processing\2014-28\Processing\hydro\2014-28-0098.mrgcln1s -SORT parameters: 2015/03/09 10:39:36 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2015/03/09 10:39:52 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2015/03/14 14:44:38 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-28\Processing\doc\2014-28-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure decibar 10 0.7000000E+00 0.1000000E+01 14 Salinity:T0:C0 PSS-78 10 0.2500000E-02 0.1000000E+01 15 Salinity:T1:C1 PSS-78 10 0.1000000E-02 0.1000000E+01 16 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1034800E+01 -SORT parameters: 2015/03/14 15:50:17 Sorted in ascending order of channel Pressure* -REMOVECH 2015/03/14 15:54:40 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T0:C0 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2015/03/16 16:25:41 Applied edit header: P:\Cruise_Data_Processing\2014-28\Processing\doc\HYDRO\2014-28-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 16: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 18: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 19: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 20: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 21: Silicate [umol/L] Units: ==> umol/L Channel 22: Flag:Silicate [n/a] Units: ==> n/a Channel 23: Phosphate [umol/L] Units: ==> umol/L Channel 24: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: BS 40, Sample Number: 142, Silicate corrected using CTD salinity. At Station: BS 40, Sample Number: 141, Silicate corrected using CTD salinity. ===================================================================================== Sample_Number 130: OXY: Two separate titrations for same sample ID. Titration restarted? Sample_Number 135: OXY: Titration quickly jumped to plateau likely overshooting the endpoint. Sample_Number 136: OXY: Titration quickly jumped to plateau likely overshooting the endpoint. Sample_Number 138: OXY: Titration quickly jumped to plateau likely overshooting the endpoint. Analysis methods: ----------------- Oxygen samples were analyzed at sea on an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-28OXY*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples at IOS. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For raw data, precision and duplicate details see spreadsheet QF2014-28nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- Data Processing Notes: ---------------------- Transmissivity, Fluorescence, pH, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2014-28_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure decibar 10 -99 () (0.7 1) Salinity:T0:C0 PSS-78 10 -99 () (0.25E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (0.1E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0348) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9--- ---10--- --11-- --12- -13- -14- --15- ---16-- --17- 18 --19-- 20 ---21-- 22 --23-- 24 !Bo Bo Pressu Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Samp Tempe Oxygen: Oxyge Fl Nitrat Fl Phospha Fl Silica Si !tt tt re ure: missi cence: Refere Nominal :T1:C1 : n: er_o le_ ratur Dissolv n: ag e_ ag te ag te li !~u ~u Secondar vity URU: nce Dissol Disso ~bin Numb e: ed Disso ~o plus_ ~t ~p ~: !mb en y Seapoin ved: lved: _rec er Draw lved lv Nitrit ri ha Fl !er ce t SBE SBE ords ed e te te ag !-- -- ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ---- ----- ------- ----- -- ------ -- ------- -- ------ -- *END OF HEADER 13 13 1.6 15.4119 26.0 2.928 272.5 732.3 9.048 21.2105 7.07 310.8 241 142 15.8 6.883 302.7 0 1.81 0 0.299 0 36.53 0 12 12 5.5 14.4861 37.9 1.973 36.7 731.1 8.936 24.4713 6.04 265.1 241 141 14.9 6.237 273.5 0 1.92 0 0.324 0 26.90 0 11 11 11.0 14.5043 44.8 2.258 6.2 713.6 8.964 27.0194 6.44 281.9 241 140 13.9 6.196 271.2 0 4.62 0 0.659 0 19.45 0 10 10 25.2 10.8291 53.4 0.349 0.5 723.3 8.601 29.1484 5.10 222.6 241 139 11.1 5.089 222.3 0 19.67 0 1.732 0 39.62 0 9 9 50.6 9.5016 55.9 0.122 0.0 739.6 8.417 29.7082 4.39 191.6 241 138 9.9 4.883 213.1 4 25.78 0 2.197 0 47.02 0 8 8 75.8 9.0623 55.4 0.111 0.0 734.6 8.329 29.8932 3.94 172.0 241 137 9.6 3.944 172.1 0 29.35 0 2.431 0 52.31 0 7 7 101.3 8.3671 54.4 0.061 0.0 729.5 8.303 30.3773 4.06 177.2 241 136 9.0 4.486 195.7 4 31.21 0 2.548 0 56.04 0 6 6 151.1 8.1305 54.4 0.051 0.0 739.2 8.273 30.6554 3.82 166.7 241 135 8.7 3.852 168.0 4 31.99 0 2.592 0 62.58 0 5 5 201.1 8.3390 52.8 0.049 0.0 534.5 8.243 30.8916 3.33 145.3 241 134 8.9 3.357 146.4 0 31.69 6 2.742 6 68.12 6 4 4 250.6 8.4608 48.9 0.049 0.0 634.6 8.223 30.9613 3.06 133.5 241 133 9.1 3.109 135.5 0 31.68 0 2.749 0 72.16 0 3 3 335.9 8.4735 42.9 0.050 0.0 601.2 8.201 31.0054 2.95 128.6 241 132 9.1 2.980 129.9 6 31.37 0 2.924 0 77.76 0 2 2 338.3 8.4750 42.3 0.050 0.0 629.0 8.200 31.0056 2.94 128.3 241 131 9.1 2.986 130.2 0 31.31 0 2.885 0 77.29 0 1 1 339.8 8.4755 42.5 0.049 0.0 578.0 8.200 31.0057 2.94 128.3 241 130 9.1 2.945 128.4 4 30.31 0 2.839 0 83.59 0