*2023/03/19 10:46:55.37 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/06/17 21:24:04.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 2BDA0136 NUMBER OF CHANNELS : 29 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 17 2 Bottle_Number n/a 1 17 3 Pressure decibar 1.6 372.3 4 Temperature:Secondary 'deg C (ITS90)' 8.1833 16.0979 5 Transmissivity %/metre 9.4 56 6 Fluorescence:URU:Seapoint mg/m^3 0.62E-01 4.531 7 PAR uE/m^2/sec 0 1450.3 8 PAR:Reference uE/m^2/sec 1050.3 1134 9 pH:SBE:Nominal n/a 8.274 9.443 10 Salinity:T1:C1 PSS-78 19.7528 31.1471 11 Oxygen:Dissolved:SBE mL/L 3.67 9.04 12 Oxygen:Dissolved:SBE umol/kg 160.1 398 13 Number_of_bin_records n/a 241 241 14 Sample_Number n/a 144 160 15 Temperature:Draw 'deg C (ITS90)' 10.5 16.7 16 Salinity:Bottle PSS-78 31.0605 31.0605 17 Flag:Salinity:Bottle n/a 18 Chlorophyll:Extracted mg/m^3 4.95 10.93 19 Flag:Chlorophyll:Extracted n/a 20 Phaeo-Pigment:Extracted mg/m^3 0.19 1.18 21 Oxygen:Dissolved mL/L 3.697 8.85 22 Oxygen:Dissolved umol/kg 161.2 389.7 23 Flag:Oxygen:Dissolved n/a 24 Nitrate_plus_Nitrite umol/L 0.1 31.5 25 Flag:Nitrate_plus_Nitrite n/a 26 Phosphate umol/L 0.117 2.632 27 Flag:Phosphate n/a 28 Silicate umol/L 26.79 59.73 29 Silicate:Flag n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 9 F ' ' 4 11 -99 ' ' 7 F ' ' 2 12 -99 ' ' 6 F ' ' 1 13 ' ' ' ' 5 I I 0 14 -99 ' ' 5 I I 0 15 -99 ' ' 6 F R4 1 16 -99 ' ' 9 F R4 4 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 8 F R4 3 22 -99 ' ' 6 F ' ' 1 23 0 ' ' 3 NQ C ' ' 24 -99 ' ' 6 F R4 1 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 3 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-23 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF Water Properties Survey SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia/Juan de Fuca Strait STATION : 39 EVENT NUMBER : 45 LATITUDE : 49 9.74000 N ! (deg min) LONGITUDE : 123 32.99000 W ! (deg min) WATER DEPTH : 376 ALTIMETER (M) : 2.69 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0724 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4397 Conductivity ' ' 2992 'Pressure:Digiquartz with TC' ' ' 90559 Temperature:2 ' ' 4402 Conductivity:2 ' ' 2984 'Oxygen:SBE 43' ' ' 1483 PAR/Irradiance:Biospherical/Licor ' ' 4656 Fluorometer:Seapoint ' ' 3640 pH ' ' 0691 Altimeter ' ' 43281 'Transmissometer:WET Labs C-Star' ' ' 983DR Unavailable ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.23.1 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! --------------------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/10/31 09:12:09 4097 4097 CLEAN 5.1 2014/10/31 09:13:09 ? ? ADDSAMP 3.6 2014/10/31 09:32:50 4097 4097 BINAVE 4.2 2014/10/31 09:33:23 4097 17 MERGE 3.5 2014/11/04 09:33:14 17 17 CLEAN 5.1 2014/11/04 09:33:27 17 17 CALIB 11.8 2014/11/06 14:51:23 17 17 SORT 3.6 2014/11/10 15:56:55 17 17 REMOVECH 8.2 2014/11/10 17:10:46 17 17 CHGUNITS 3.1 2014/11/10 17:11:20 17 17 CHGUNITS 3.1 2014/11/10 17:11:42 17 17 REORDER 1.3 2014/11/10 17:12:27 ? ? HDREDIT2 2.6 2014/11/12 13:29:46 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:46:45 17 17 Silicate_Correction 1.0 2018/02/20 14:30:17 17 17 Silicate_Modification 1.2 2023/03/19 10:46:55 17 17 $END $REMARKS -CLEAN functions: 2014/10/31 09:12:58 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-23\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/11/04 09:33:14 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-23\Processing\hydro\2014-23-0045.samavg Secondary file: P:\Cruise_Data_Processing\2014-23\Processing\hydro\2014-23-0045.mrgcln1s -SORT parameters: 2014/10/31 09:38:29 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/11/04 09:33:26 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/11/06 14:51:23 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-23\Processing\doc\2014-23-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 16 Oxygen:Dissolved:SBE mL/L 10 0.3700000E-02 0.1040000E+01 -SORT parameters: 2014/11/10 15:56:55 Sorted in ascending order of channel Pressure* -REMOVECH 2014/11/10 17:10:46 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T0:C0 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Secondary [deg C (ITS90)] Salinity reference channel: Salinity:T1:C1 [PSS-78] 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw [ ] Salinity reference channel: Salinity:T1:C1 [PSS-78] 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/11/12 13:29:46 Applied edit header: P:\Cruise_Data_Processing\2014-23\Processing\doc\HYDRO\2014-23-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 15: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 16: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 17: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 18: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 19: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 20: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 21: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 23: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 24: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 25: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 26: Silicate [umol/L] Units: ==> umol/L Channel 27: Flag:Silicate [n/a] Units: ==> n/a Channel 28: Phosphate [umol/L] Units: ==> umol/L Channel 29: Flag:Phosphate [n/a] Units: ==> n/a Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: pH:SBE:Nominal [n/a] Name: pH:SBE ==> pH:SBE:Nominal Units: pH Units ==> n/a $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: 39, Sample Number: 160, Silicate corrected using CTD salinity. At Station: 39, Sample Number: 159, Silicate corrected using CTD salinity. ===================================================================================== Sample_Number 149: OXY: Stopper was quite loose. Sample may not have been sealed properly. Sample_Number 150: OXY: Stirrer was off when titration initialized. Endpoint was overshot due to too much Thio being dispensed. Sample lost. Sample_Number 157: OXY: Small bubbles under stopper. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 2423 about 6 weeks after the cruise. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-23CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-23OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 41 to 45 days after collection. For details see document QF2014-23SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. All analysis was performed on frozen samples. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-23nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence, pH, PAR and PAR:Reference data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. WARNING: The pH:SBE:Nominal data should be used with caution; no field calibration data were available at the time of processing. Calibration is required for each cast to get absolute values, although general trends within a cast are likely real. For details on the processing see the report: 2014-23-proc.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.37E-02 1.04) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9--- ---10--- --11-- --12- -13- -14- --15- ---16--- 17 --18-- 19 --20-- ---21-- --22- 23 --24- 25 ---26-- 27 --28-- 29 !Bo Bo Pressu Temperat Trans Fluores PAR PAR: pH:SBE: Salinity Oxygen Oxyge Numb Samp Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitra Fl Phospha Fl Silica Si !tt tt re ure: missi cence: Refere Nominal :T1:C1 : n: er_o le_ ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag te_ ag te ag te li !~u ~u Secondar vity URU: nce Dissol Disso ~bin Numb e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~p ~: !en mb y Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitri ri ha Fl !ce er t SBE SBE ords le ed ted ed te te te ag !-- -- ------ -------- ----- ------- ------ ------ ------- -------- ------ ----- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ----- -- ------- -- ------ -- *END OF HEADER 17 17 1.6 16.0979 9.4 4.531 1450.3 1117.4 9.443 19.7528 9.04 398.0 241 160 16.7 -99.0000 0 10.93 6 1.18 8.850 389.7 0 0.2 0 0.264 0 36.90 0 16 16 5.1 15.4750 30.3 1.221 37.9 1124.7 9.277 22.4294 7.66 336.3 241 159 15.9 -99.0000 0 -99.00 0 -99.00 7.518 330.3 6 0.1 0 0.117 0 27.36 0 15 15 10.0 13.0442 38.8 2.321 5.3 1130.2 8.852 26.9818 6.20 271.1 241 158 14.6 -99.0000 0 8.92 6 0.19 6.069 265.7 0 4.2 0 0.551 0 26.79 0 14 14 20.1 10.1565 46.2 1.672 0.4 1126.6 8.498 29.1299 4.86 212.2 241 157 12.4 -99.0000 0 4.95 6 0.28 4.844 211.6 3 19.4 0 1.781 0 39.38 0 13 13 30.3 9.6106 52.4 0.699 0.1 1127.2 8.446 29.4820 4.68 204.4 241 156 11.8 -99.0000 0 -99.00 0 -99.00 4.684 204.5 0 23.5 6 2.092 6 43.20 6 12 12 39.8 9.2039 55.5 0.277 0.0 1126.2 8.415 29.7247 4.62 201.4 241 155 11.4 -99.0000 0 -99.00 0 -99.00 4.622 201.8 0 25.6 0 2.221 0 45.50 0 11 11 50.0 8.9505 56.0 0.195 0.0 1126.5 8.387 29.8822 4.56 198.8 241 154 11.1 -99.0000 0 -99.00 0 -99.00 4.563 199.2 0 27.1 0 2.305 0 47.49 0 10 10 74.5 8.7591 55.5 0.103 0.0 1122.1 8.364 30.0932 4.51 196.8 241 153 10.9 -99.0000 0 -99.00 0 -99.00 4.516 197.1 0 28.3 0 2.352 0 49.18 0 9 9 99.9 8.5032 54.9 0.072 0.0 1131.4 8.339 30.3043 4.45 194.3 241 152 10.6 -99.0000 0 -99.00 0 -99.00 4.471 195.1 0 29.5 6 2.408 6 51.58 6 8 8 125.7 8.3449 53.2 0.063 0.0 1125.4 8.315 30.4418 4.33 188.9 241 151 10.5 -99.0000 0 -99.00 0 -99.00 4.328 188.8 0 30.2 0 2.462 0 54.35 0 7 7 151.3 8.2726 52.1 0.062 0.0 1128.5 8.296 30.5458 4.18 182.3 241 150 10.5 -99.0000 0 -99.00 0 -99.00 -99.000 -99.0 1 30.5 0 2.521 0 56.52 0 6 6 176.0 8.1833 52.8 0.068 0.0 1134.0 8.274 30.6906 3.99 174.1 241 149 10.5 -99.0000 0 -99.00 0 -99.00 4.012 175.0 4 31.5 0 2.596 0 59.66 0 5 5 201.1 8.2228 46.6 0.067 0.0 1132.3 8.281 30.7694 3.98 173.5 241 148 11.0 -99.0000 0 -99.00 0 -99.00 3.985 173.8 6 31.1 0 2.598 0 59.73 0 4 4 250.7 8.4636 40.4 0.077 0.0 1074.3 8.293 30.9364 3.81 166.3 241 147 11.3 -99.0000 0 -99.00 0 -99.00 3.870 168.8 0 30.0 0 2.529 0 56.82 0 3 3 299.4 8.5227 35.6 0.085 0.0 1050.3 8.299 31.0065 3.77 164.4 241 146 11.4 -99.0000 0 -99.00 0 -99.00 3.787 165.2 0 29.9 0 2.540 0 56.81 0 2 2 348.6 8.5243 31.4 0.131 0.0 1079.1 8.293 31.0551 3.71 161.5 241 145 11.4 31.0605 0 -99.00 0 -99.00 3.723 162.4 0 30.2 0 2.632 0 57.49 0 1 1 372.3 8.5537 30.5 0.088 0.0 1070.0 8.298 31.1471 3.67 160.1 241 144 11.8 -99.0000 0 -99.00 0 -99.00 3.697 161.2 0 29.8 0 2.573 0 56.79 0