*2021/11/25 15:09:01.88 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/09/06 05:26:51.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 5 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 2B401E73 NUMBER OF CHANNELS : 52 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 6 10 2 Bottle_Number n/a 1 5 3 Bottle:Firing_Sequence n/a 1 5 4 Pressure decibar 5.9 46.9 5 Temperature:Primary 'deg C (ITS90)' 9.5476 11.5833 6 Transmissivity %/metre 55 62.1 7 Fluorescence:URU:Seapoint mg/m^3 0.455 1.523 8 PAR uE/m^2/sec 0 0 9 Salinity:T0:C0 PSS-78 31.3508 32.2365 10 Oxygen:Dissolved:SBE mL/L 3.65 5.31 11 Oxygen:Dissolved:SBE umol/kg 159 231.5 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 10.7 12.7 14 Oxygen:Dissolved mL/L 3.609 5.3 15 Oxygen:Dissolved umol/kg 157.2 231.1 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 19.61 26.06 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 33.76 38.88 20 Flag:Silicate n/a 21 Phosphate umol/L 1.735 2.106 22 Flag:Phosphate n/a 23 Ammonium umol/L 0.86 1.33 24 Flag:Ammonium n/a 25 Chlorophyll:Extracted mg/m^3 1.46 3.89 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.14 0.56 28 HPLC:Chl-c3 mg/m^3 0.2E-01 0.34E-01 29 HPLC:Chlide-a mg/m^3 0.8E-02 0.31E-01 30 HPLC:MgDVP mg/m^3 0 0.15E-01 31 HPLC:Chl-c2 mg/m^3 0.99E-01 0.242 32 HPLC:Chl-c1 mg/m^3 0.41E-01 0.104 33 HPLC:Me-chlide mg/m^3 0.3E-01 0.112 34 HPLC:Peri mg/m^3 0 0.25E-01 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0 0.7E-02 37 HPLC:Fuco mg/m^3 0.508 1.048 38 HPLC:Neo mg/m^3 0 0 39 HPLC:Pras mg/m^3 0 0 40 HPLC:Viola mg/m^3 0 0.3E-02 41 HPLC:Hex-fuco mg/m^3 0 0.15E-01 42 HPLC:Diadino mg/m^3 0.18E-01 0.91E-01 43 HPLC:Allo mg/m^3 0 0.15E-01 44 HPLC:Diato mg/m^3 0.6E-02 0.11E-01 45 HPLC:Zea mg/m^3 0 0.2E-02 46 HPLC:Chl-b mg/m^3 0 0.23E-01 47 HPLC:DVChl-a mg/m^3 0 0 48 HPLC:Chl-a mg/m^3 0.675 1.789 49 HPLC:Phe mg/m^3 0 0 50 HPLC:B-Car mg/m^3 0.7E-02 0.15E-01 51 HPLC:TChl-a mg/m^3 0.715 1.932 52 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ---------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ---------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-22 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : LaPerouse - Zooplankton Monitoring SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LB02 EVENT NUMBER : 2 LATITUDE : 48 39.02000 N ! (deg min) LONGITUDE : 125 2.47000 W ! (deg min) WATER DEPTH : 58 ALTIMETER (M) : 10.84 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 2106 Conductivity ' ' 2280 'Pressure:Digiquartz with TC' ' ' 0443 Temperature:2 ' ' 2663 Conductivity:2 ' ' 2754 'Oxygen:SBE 43' ' ' 0997 'Transmissometer:WET Labs C-Star' ' ' 1396DR Fluorometer:Seapoint ' ' 3642 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! -------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/12/18 14:20:48 1205 1205 CLEAN 5.2.1 2014/12/18 14:21:25 ? ? ADDSAMP 3.6 2015/01/28 09:42:32 1205 1205 BINAVE 4.2 2015/02/03 16:16:55 1205 5 MERGE 3.5 2015/02/03 16:17:15 5 5 CLEAN 5.2.1 2015/02/18 10:20:29 5 5 CALIB 11.8.1 2015/03/30 09:29:35 5 5 SORT 3.6 2015/03/30 09:30:37 5 5 REMOVECH 8.2 2015/03/30 09:31:18 5 5 CHGUNITS 3.1 2015/03/30 10:21:16 5 5 CHGUNITS 3.1 2015/03/30 10:21:35 5 5 REORDER 1.3.1 2015/03/30 10:21:40 ? ? HDREDIT2 3.0.2 2015/03/30 10:21:48 ? ? SORT 3.6 2020/08/01 11:08:24 5 5 REORDER 1.3.1 2021/11/25 15:07:23 ? ? MERGE 3.5.1 2021/11/25 15:07:34 5 5 SORT 3.6 2021/11/25 15:07:45 5 5 CLEAN 5.2.4 2021/11/25 15:07:56 5 5 HDREDIT2 3.2 2021/11/25 15:08:38 ? ? HDREDIT2 3.2 2021/11/25 15:09:01 ? ? $END $REMARKS -CLEAN functions: 2014/12/18 14:21:25 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-22\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2015/02/03 16:17:15 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-22\Processing\hydro\2014-22-0002.samavg Secondary file: P:\Cruise_Data_Processing\2014-22\Processing\hydro\2014-22-0002.mrgcln1s -CLEAN functions: 2015/01/28 10:08:04 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2015/01/28 10:08:14 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2015/02/18 10:20:29 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag:* Set event to last 4 characters of file name Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2015/03/30 09:29:35 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\Temp\2014-22 temp\2014-22\DOC\2014-22-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure decibar 10 0.6000000E+00 0.1000000E+01 14 Oxygen:Dissolved:SBE mL/L 10 -0.1960000E+00 0.1032500E+01 -SORT parameters: 2015/03/30 09:30:37 Sorted in ascending order of channel Pressure* -REMOVECH 2015/03/30 09:31:18 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T1:C1 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2015/03/30 10:21:48 Applied edit header: P:\Cruise_Data_Processing\Temp\2014-22 temp\corrections\2014-22-bot-hdr.txt Channel 2: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 1: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 15: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 16: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 19: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 20: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.2 ==> F7.2 Channel 21: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 22: Silicate [umol/L] Units: ==> umol/L Channel 23: Flag:Silicate [n/a] Units: ==> n/a Channel 24: Phosphate [umol/L] Units: ==> umol/L Channel 25: Flag:Phosphate [n/a] Units: ==> n/a Channel 27: Flag:Ammonium [n/a] Units: ==> n/a -SORT parameters: 2020/08/01 11:08:24 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 15:07:34 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-022_Nov2021\Processing\ IOS\2014-022-0002.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-022_Nov2021\Processing\ IOS\2014-022-0002.hplc -SORT parameters: 2021/11/25 15:07:45 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 15:07:56 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 15:08:38 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_022\Processing\IOS\ 2014-022-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 15:09:01 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_022\Processing\IOS\ 2014-022-bot-hdr2.txt $END *COMMENTS Sample_Number 10: OXY: Niskin spigot leaking prior to sampling. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS in Room 1409 about 8 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-22CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1-2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2014-022HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-22OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed at IOS in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 38 to 47 days after collection. For details including a duplicate analysis, see document QF2014-22SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-22nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2014-22NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity and fluorescence data were removed below 510db for events #1-72. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Post-cruise calibration reports indicate that the primary temperature and conductivity sensors had insignificant drifts. Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that an offset in the fit was allowed. The Oxygen:Dissolved:SBE data had an unusual fit against titrated samples, but it was similar to that found during the latter half of 2014-19 and all of 2014-60 when the same equipment was used. For details on the processing see document: 2014-22_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-022_Nov2021\Processing\IOS\2014-022-0002. hplc --------------------------------------------------------------------------- Sample_Number 10: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Pressure decibar 10 -99 () (0.6 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.196 1.0325) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14-- --15- 16 --17-- 18 --19-- 20 ---21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- 52 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Oxygen: Oxyge Fl Nitrat Fl Silica Fl Phospha Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T0:C0 : n: er_o ratur Dissolv n: ag e_ ag te ag te ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Primary vity URU: Dissol Disso ~bin e: ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er er Sequ Seapoin ved: lved: _rec Draw lved lv Nitrit ri ca ha ni ted ct Extrac HP ! ence t SBE SBE ords ed e te te te um ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- ------- ----- -- ------ -- ------ -- ------- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 10 5 5 5.9 11.5833 55.0 1.309 0.0 31.3508 5.31 231.5 241 12.7 5.300 231.1 3 19.61 6 33.76 6 1.735 6 0.86 6 3.47 6 0.14 0.024 0.012 0.011 0.188 0.100 0.031 0.022 0.000 0.000 0.880 0.000 0.000 0.000 0.014 0.091 0.013 0.006 0.002 0.023 0.000 1.775 0.000 0.014 1.817 36 9 4 4 11.0 11.3344 55.5 1.523 0.0 31.3597 5.08 221.4 241 12.3 5.065 220.9 0 20.43 0 34.26 0 1.774 0 0.90 6 3.89 6 0.15 0.034 0.031 0.015 0.242 0.104 0.112 0.025 0.000 0.005 1.048 0.000 0.000 0.003 0.015 0.083 0.015 0.007 0.002 0.015 0.000 1.789 0.000 0.015 1.932 6 8 3 3 20.8 10.3567 61.2 0.610 0.0 31.7924 4.26 185.5 241 11.4 4.121 179.6 6 23.84 0 36.70 0 1.984 0 1.33 6 2.34 6 0.33 0.034 0.008 0.000 0.149 0.060 0.040 0.000 0.000 0.000 0.776 0.000 0.000 0.000 0.000 0.026 0.009 0.006 0.000 0.000 0.000 1.105 0.000 0.011 1.153 6 7 2 2 31.4 10.1305 62.1 0.455 0.0 31.8673 3.88 169.1 241 11.1 3.871 168.7 0 24.72 0 38.00 0 2.043 0 -99.00 0 1.46 6 0.35 0.020 0.010 0.006 0.099 0.041 0.030 0.004 0.000 0.000 0.508 0.000 0.000 0.000 0.000 0.018 0.000 0.011 0.000 0.000 0.000 0.675 0.000 0.008 0.715 6 6 1 1 46.9 9.5476 60.1 0.543 0.0 32.2365 3.65 159.0 241 10.7 3.609 157.2 0 26.06 0 38.88 0 2.106 0 -99.00 0 1.49 6 0.56 0.022 0.015 0.002 0.112 0.054 0.039 0.005 0.000 0.007 0.559 0.000 0.000 0.000 0.000 0.022 0.000 0.006 0.000 0.000 0.000 0.844 0.000 0.007 0.899 6