*2021/11/25 15:03:43.97 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/06/02 02:32:41.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 15 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 76E27747 NUMBER OF CHANNELS : 53 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 325 339 2 Bottle_Number n/a 1 15 3 Bottle:Firing_Sequence n/a 1 15 4 Pressure decibar 4.5 91.8 5 Temperature:Secondary 'deg C (ITS90)' 7.195 12.2859 6 Transmissivity %/metre 12.1 65.4 7 Fluorescence:URU:Seapoint mg/m^3 0.14 11.475 8 PAR uE/m^2/sec 0 24.1 9 Salinity:T1:C1 PSS-78 30.7817 33.3747 10 Oxygen:Dissolved:SBE mL/L 3.61 5.53 11 Oxygen:Dissolved:SBE umol/kg 157 240.9 12 Number_of_bin_records n/a 241 241 13 Temperature:Draw 'deg C (ITS90)' 7.6 12.1 14 Oxygen:Dissolved mL/L 3.591 8.336 15 Oxygen:Dissolved umol/kg 156.2 363.7 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 0.2 27.7 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 7.54 40.48 20 Flag:Silicate n/a 21 Phosphate umol/L 0.33 2.135 22 Flag:Phosphate n/a 23 Ammonium umol/L 0.3E-01 2.06 24 Flag:Ammonium n/a 25 Chlorophyll:Extracted mg/m^3 0.13 14.79 26 Flag:Chlorophyll:Extracted n/a 27 Phaeo-Pigment:Extracted mg/m^3 0.25 1.4 28 HPLC:Chl-c3 mg/m^3 0.17E-01 0.139 29 HPLC:Chlide-a mg/m^3 0 0.812 30 HPLC:MgDVP mg/m^3 0 0.72E-01 31 HPLC:Chl-c2 mg/m^3 0.14E-01 1.832 32 HPLC:Chl-c1 mg/m^3 0 0.465 33 HPLC:Me-chlide mg/m^3 0 1.34 34 HPLC:Peri mg/m^3 0 0.301 35 HPLC:Pheide-a mg/m^3 0 0 36 HPLC:But-fuco mg/m^3 0 0.36E-01 37 HPLC:Fuco mg/m^3 0.51E-01 4.871 38 HPLC:Neo mg/m^3 0 0.27E-01 39 HPLC:Pras mg/m^3 0 0.3E-01 40 HPLC:Viola mg/m^3 0 0.21E-01 41 HPLC:Hex-fuco mg/m^3 0.12E-01 0.86E-01 42 HPLC:Diadino mg/m^3 0.4E-02 0.844 43 HPLC:Allo mg/m^3 0 0.51E-01 44 HPLC:Diato mg/m^3 0 0.76E-01 45 HPLC:Zea mg/m^3 0 0.67E-01 46 HPLC:Lut mg/m^3 0 0.9E-02 47 HPLC:Chl-b mg/m^3 0.7E-02 0.144 48 HPLC:DVChl-a mg/m^3 0 0 49 HPLC:Chl-a mg/m^3 0.93E-01 5.948 50 HPLC:Phe mg/m^3 0 0 51 HPLC:B-Car mg/m^3 0 0.136 52 HPLC:TChl-a mg/m^3 0.93E-01 8.101 53 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 -99 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-21 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : LaPerouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LG02 EVENT NUMBER : 90 LATITUDE : 49 18.70000 N ! (deg min) LONGITUDE : 126 38.38000 W ! (deg min) WATER DEPTH : 100 ALTIMETER (M) : 10.06 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 4700 Conductivity:2 ' ' 3321 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 'Transmissometer:WET Labs C-Star' ' ' 1396DR 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3642 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/08/11 10:24:32 3615 3615 CLEAN 5.1 2014/08/11 10:25:14 ? ? ADDSAMP 3.6 2014/08/11 10:42:21 3615 3615 BINAVE 4.1.1 2014/08/11 10:42:51 3615 15 MERGE 3.5 2014/08/22 12:10:24 15 15 CLEAN 5.1 2014/08/22 12:10:26 15 15 CALIB 11.8 2014/08/22 12:10:43 15 15 SORT 3.6 2014/08/22 12:10:47 15 15 REMOVECH 8.2 2014/08/22 12:12:47 15 15 CHGUNITS 3.1 2014/08/22 12:14:45 15 15 CHGUNITS 3.1 2014/08/22 12:15:00 15 15 REORDER 1.3 2014/08/22 12:15:40 ? ? HDREDIT2 2.6 2014/08/22 12:16:42 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:46:41 15 15 SORT 3.6 2020/08/03 15:27:21 15 15 REORDER 1.3.1 2021/11/25 13:50:06 ? ? MERGE 3.5.1 2021/11/25 13:50:16 15 15 SORT 3.6 2021/11/25 13:50:27 15 15 CLEAN 5.2.4 2021/11/25 13:50:36 15 15 HDREDIT2 3.2 2021/11/25 15:03:17 ? ? HDREDIT2 3.2 2021/11/25 15:03:43 ? ? $END $REMARKS -CLEAN functions: 2014/08/11 10:24:49 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-21\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/08/22 12:10:24 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-21\Processing\hydro\2014-21-0090.samavg Secondary file: P:\Cruise_Data_Processing\2014-21\Processing\hydro\2014-21-0090.mrgcln1s -CLEAN functions: 2014/08/22 12:10:05 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2014/08/22 12:10:11 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/08/22 12:10:24 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/08/22 12:10:43 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-21\Processing\doc\2014-21-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Salinity:T1:C1 PSS-78 10 -0.5300000E-02 0.1000000E+01 14 Oxygen:Dissolved:SBE mL/L 10 -0.2590000E-01 0.1040000E+01 -SORT parameters: 2014/08/22 12:10:47 Sorted in ascending order of channel Pressure* -REMOVECH 2014/08/22 12:12:47 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T0:C0 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/08/22 12:16:42 Applied edit header: P:\Cruise_Data_Processing\2014-21\Processing\doc\HYDRO\2014-21-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 15: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 16: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 17: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 19: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 20: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 21: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 22: Silicate [umol/L] Units: ==> umol/L Channel 23: Flag:Silicate [n/a] Units: ==> n/a Channel 24: Phosphate [umol/L] Units: ==> umol/L Channel 25: Flag:Phosphate [n/a] Units: ==> n/a Channel 27: Flag:Ammonium [n/a] Units: ==> n/a -SORT parameters: 2020/08/03 15:27:21 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 13:50:16 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-021_Nov2021\Processing\ IOS\2014-021-0090.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-021_Nov2021\Processing\ IOS\2014-021-0090.hplc -SORT parameters: 2021/11/25 13:50:27 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 13:50:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 15:03:17 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_021\Processing\IOS\ 2014-021-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 28: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 15:03:43 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_021\Processing\IOS\ 2014-021-bot-hdr2.txt $END *COMMENTS -------------------------------------------------------------------------------------- NOTE: CTD primary conductivity, salinity and dissolved oxygen data were bad above 50db of the upcast. -------------------------------------------------------------------------------------- Sample_Number 328: OXY: Software crash after endpoint. Value calculated manually. Sample_Number 331: OXY: Titration was incomplete. Sample over-titrated and value recalculated. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship or at IOS in room 1310 at IOS ~5 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-21CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2-3 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2014-021HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-21OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 3 to 14 days after collection. For details including a duplicate analysis, see document QF2014-21SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-21nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2014-21NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Oxygen:Dissolved:SBE was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2014-21_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-021_Nov2021\Processing\IOS\2014-021-0090. hplc --------------------------------------------------------------------------- Sample_Number 331: HPLC: sample likely poorly extracted, underestimate *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.53E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.259E-01 1.04) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- --8--- ---9---- --10-- --11- -12- --13- ---14-- --15- 16 --17- 18 --19-- 20 ---21-- 22 --23-- 24 --25-- 26 --27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- 53 !Samp Bott Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Tempe Oxygen: Oxyge Fl Nitra Fl Silica Fl Phospha Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur Dissolv n: ag te_ ag te ag te ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec Draw lved lv Nitri ri ca ha ni ted ct Extrac HP ! ence t SBE SBE ords ed te te te te um ed ted LC !---- ---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- ------- ----- -- ----- -- ------ -- ------- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 331 7 15 4.5 12.2859 12.9 11.383 24.1 30.7817 -99.00 -99.0 241 12.1 8.336 363.7 3 0.2 0 9.45 0 0.330 0 0.03 6 14.79 6 1.40 0.139 0.812 0.072 1.832 0.465 1.340 0.301 0.000 0.000 4.871 0.027 0.000 0.021 0.045 0.844 0.051 0.076 0.029 0.000 0.081 0.000 5.948 0.000 0.136 8.101 36 339 15 14 4.6 12.2719 12.1 11.475 21.8 30.7908 -99.00 -99.0 241 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 330 6 12 9.8 10.2493 53.1 1.481 6.2 32.0381 -99.00 -99.0 241 10.1 6.450 281.0 0 3.4 0 7.54 0 0.763 0 1.09 6 1.56 6 0.64 0.119 0.040 0.020 0.169 0.005 0.084 0.160 0.000 0.027 0.378 0.018 0.030 0.017 0.085 0.063 0.047 0.007 0.067 0.007 0.144 0.000 0.974 0.000 0.023 1.097 6 338 14 13 9.9 10.2389 54.5 1.551 6.1 32.0316 -99.00 -99.0 241 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 329 5 11 20.2 9.7162 58.6 1.140 1.6 32.1585 -99.00 -99.0 241 9.6 6.111 266.2 0 5.9 0 10.63 0 0.961 0 2.06 6 1.02 6 0.54 0.138 0.000 0.011 0.108 0.000 0.000 0.037 0.000 0.036 0.319 0.015 0.016 0.010 0.086 0.028 0.045 0.001 0.018 0.009 0.125 0.000 0.744 0.000 0.014 0.744 6 337 13 10 20.2 9.5806 59.3 0.955 1.7 32.1656 -99.00 -99.0 241 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 328 4 8 29.6 9.1351 63.3 0.407 0.4 32.2940 -99.00 -99.0 241 9.1 5.910 257.4 2 9.3 0 13.94 0 1.126 0 -99.00 0 0.35 6 0.34 0.055 0.000 0.003 0.040 0.000 0.000 0.011 0.000 0.011 0.135 0.000 0.007 0.000 0.033 0.010 0.012 0.000 0.000 0.000 0.028 0.000 0.274 0.000 0.005 0.274 6 336 12 9 30.0 9.1210 63.7 0.412 0.4 32.2950 -99.00 -99.0 241 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 332 8 7 41.0 8.3642 65.4 0.148 0.2 32.4727 -99.00 -99.0 241 -99.0 -99.000 -99.0 0 13.4 0 16.68 0 1.240 0 -99.00 0 0.15 6 0.25 0.017 0.000 0.000 0.015 0.000 0.000 0.000 0.000 0.006 0.063 0.000 0.000 0.000 0.014 0.005 0.000 0.000 0.000 0.000 0.007 0.000 0.107 0.000 0.000 0.107 6 327 3 5 50.6 8.0893 64.9 0.162 0.1 32.5725 5.53 240.9 241 8.3 5.490 239.0 6 16.2 6 19.72 6 1.419 6 -99.00 0 0.13 6 0.26 0.019 0.000 0.000 0.014 0.000 0.000 0.000 0.000 0.012 0.051 0.000 0.000 0.000 0.012 0.004 0.000 0.000 0.000 0.000 0.016 0.000 0.093 0.000 0.000 0.093 6 335 11 6 50.6 8.0794 64.9 0.160 0.1 32.5777 5.53 240.6 241 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 334 10 3 74.8 7.6112 52.7 0.177 0.0 33.0265 3.85 167.5 241 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 326 2 4 74.9 7.6175 52.8 0.193 0.0 33.0227 3.87 168.3 241 7.9 3.859 168.0 0 24.9 0 40.20 0 2.032 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 325 1 1 91.6 7.1971 41.1 0.153 0.0 33.3709 3.62 157.6 241 7.6 3.591 156.2 0 27.7 0 40.48 0 2.135 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 333 9 2 91.8 7.1950 41.3 0.140 0.0 33.3747 3.61 157.0 241 -99.0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0