*2014/11/20 09:46:40.34 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2014/05/31 06:48:42.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 7 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 5282F3D8 NUMBER OF CHANNELS : 16 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 1 7 2 Bottle_Number n/a 1 7 3 Pressure decibar 5.393 83.253 4 Temperature:Secondary 'deg C (ITS90)' 8.2024 11.3371 5 Transmissivity %/metre 29.5 60.3 6 Fluorescence:URU:Seapoint mg/m^3 0.119 10.295 7 PAR uE/m^2/sec 0 0.17E-01 8 Salinity:T1:C1 PSS-78 28.9786 32.4916 9 Oxygen:Dissolved:SBE mL/L 3.541 7.979 10 Oxygen:Dissolved:SBE umol/kg 154.2 348.5 11 Number_of_bin_records n/a 241 241 12 Sample_Number n/a 116 122 13 Temperature:Draw 'deg C (ITS90)' 8.3 11.7 14 Oxygen:Dissolved mL/L 3.538 7.633 15 Oxygen:Dissolved umol/kg 154.0921 333.433 16 Flag:Oxygen:Dissolved n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 ' ' ' ' 5 I I 0 12 -99 ' ' 5 I I 0 13 -99 ' ' 6 F R4 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-21 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : LaPerouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : EFF12 EVENT NUMBER : 53 LATITUDE : 48 58.03000 N ! (deg min) LONGITUDE : 125 10.50000 W ! (deg min) WATER DEPTH : 93 ALTIMETER (M) : 10.06 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 4700 Conductivity:2 ' ' 3321 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 'Transmissometer:WET Labs C-Star' ' ' 1396DR 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3642 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/08/11 10:24:15 1687 1687 CLEAN 5.1 2014/08/11 10:25:00 ? ? ADDSAMP 3.6 2014/08/11 10:42:07 1687 1687 BINAVE 4.1.1 2014/08/11 10:42:43 1687 7 MERGE 3.5 2014/08/22 12:10:23 7 7 CLEAN 5.1 2014/08/22 12:10:25 7 7 CALIB 11.8 2014/08/22 12:10:42 7 7 SORT 3.6 2014/08/22 12:10:46 7 7 REMOVECH 8.2 2014/08/22 12:12:46 7 7 CHGUNITS 3.1 2014/08/22 12:14:44 7 7 CHGUNITS 3.1 2014/08/22 12:14:59 7 7 REORDER 1.3 2014/08/22 12:15:39 ? ? HDREDIT2 2.6 2014/08/22 12:16:40 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:46:40 7 7 $END $REMARKS -CLEAN functions: 2014/08/11 10:24:49 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-21\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/08/22 12:10:23 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-21\Processing\hydro\2014-21-0053.samavg Secondary file: P:\Cruise_Data_Processing\2014-21\Processing\hydro\2014-21-0053.mrgcln1s -CLEAN functions: 2014/08/22 12:10:05 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2014/08/22 12:10:11 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/08/22 12:10:24 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/08/22 12:10:42 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-21\Processing\doc\2014-21-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Salinity:T1:C1 PSS-78 10 -0.5300000E-02 0.1000000E+01 14 Oxygen:Dissolved:SBE mL/L 10 -0.2590000E-01 0.1040000E+01 -SORT parameters: 2014/08/22 12:10:46 Sorted in ascending order of channel Pressure* -REMOVECH 2014/08/22 12:12:46 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Salinity:T0:C0 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/08/22 12:16:40 Applied edit header: P:\Cruise_Data_Processing\2014-21\Processing\doc\HYDRO\2014-21-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 13: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 14: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 16: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a $END *COMMENTS Sample_Number 121: OXY: Titration wavy and rounded. Endpoint placement ambiguous. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship or at IOS in room 1310 at IOS ~5 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-21CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-21OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 3 to 14 days after collection. For details including a duplicate analysis, see document QF2014-21SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-21nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2014-21NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Oxygen:Dissolved:SBE was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2014-21_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.53E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.259E-01 1.04) $END !1- 2- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- -12- --13- ---14-- --15- 16 !Bo Bo Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Samp Tempe Oxygen: Oxyge Fl !tt tt re ure: missi cence: :T1:C1 : n: er_o le_ ratur Dissolv n: ag !~u ~u Secondar vity URU: Dissol Disso ~bin Numb e: ed Disso ~o !en mb y Seapoin ved: lved: _rec er Draw lved lv !ce er t SBE SBE ords ed !-- -- ------ -------- ----- ------- ------ -------- ------ ----- ---- ---- ----- ------- ----- -- *END OF HEADER 7 7 5.4 11.3371 40.2 2.271 0.0 28.9786 7.98 348.5 241 122 11.7 7.633 333.4 0 6 6 9.9 9.1416 29.5 10.295 0.0 31.1277 7.19 313.5 241 121 8.9 5.432 236.8 4 5 5 20.6 8.5747 51.6 1.702 0.0 31.5730 4.39 191.4 241 120 8.6 4.333 188.8 0 4 4 30.2 8.3575 60.3 0.397 0.0 31.7540 4.15 180.9 241 119 8.4 4.083 177.9 0 3 3 50.3 8.2024 53.8 0.141 0.0 32.1762 3.54 154.2 241 118 8.3 3.538 154.1 6 2 2 75.5 8.2360 44.1 0.119 0.0 32.4538 3.69 160.8 241 117 8.3 3.687 160.5 0 1 1 83.3 8.2186 40.1 0.130 0.0 32.4916 3.65 158.8 241 116 8.4 3.662 159.5 0