*2021/11/25 15:03:42.47 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/05/29 16:15:05.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 19 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 8A5BEE53 NUMBER OF CHANNELS : 54 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 91 109 2 Bottle_Number n/a 1 19 3 Bottle:Firing_Sequence n/a 1 19 4 Pressure decibar 5.3 1165.3 5 Temperature:Secondary 'deg C (ITS90)' 3.4225 13.81 6 Transmissivity %/metre 56.5 67.5 7 Fluorescence:URU:Seapoint mg/m^3 0.49E-01 1.01 8 Salinity:T1:C1 PSS-78 31.5627 34.4118 9 Oxygen:Dissolved:SBE mL/L 0.24 6.97 10 Oxygen:Dissolved:SBE umol/kg 10.4 303.7 11 Number_of_bin_records n/a 94 241 12 Temperature:Draw 'deg C (ITS90)' 6.3 13 13 Salinity:Bottle PSS-78 34.0836 34.3661 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 0.256 6.97 16 Oxygen:Dissolved umol/kg 11.1 303.7 17 Flag:Oxygen:Dissolved n/a 18 Nitrate_plus_Nitrite umol/L 0 47.2 19 Flag:Nitrate_plus_Nitrite n/a 20 Silicate umol/L 2.9 134.88 21 Flag:Silicate n/a 22 Phosphate umol/L 0.272 3.317 23 Flag:Phosphate n/a 24 Ammonium umol/L 0.9E-01 0.29 25 Flag:Ammonium n/a 26 Chlorophyll:Extracted mg/m^3 0.51 0.62 27 Flag:Chlorophyll:Extracted n/a 28 Phaeo-Pigment:Extracted mg/m^3 0.11 0.13 29 HPLC:Chl-c3 mg/m^3 0.3E-01 0.3E-01 30 HPLC:Chlide-a mg/m^3 0.36E-01 0.36E-01 31 HPLC:MgDVP mg/m^3 0.4E-02 0.4E-02 32 HPLC:Chl-c2 mg/m^3 0.63E-01 0.63E-01 33 HPLC:Chl-c1 mg/m^3 0.5E-02 0.5E-02 34 HPLC:Me-chlide mg/m^3 0.33E-01 0.33E-01 35 HPLC:Peri mg/m^3 0.12E-01 0.12E-01 36 HPLC:Pheide-a mg/m^3 0 0 37 HPLC:But-fuco mg/m^3 0.11E-01 0.11E-01 38 HPLC:Fuco mg/m^3 0.139 0.139 39 HPLC:Neo mg/m^3 0 0 40 HPLC:Pras mg/m^3 0.8E-02 0.8E-02 41 HPLC:Viola mg/m^3 0.9E-02 0.9E-02 42 HPLC:Hex-fuco mg/m^3 0.45E-01 0.45E-01 43 HPLC:Diadino mg/m^3 0.59E-01 0.59E-01 44 HPLC:Allo mg/m^3 0.18E-01 0.18E-01 45 HPLC:Diato mg/m^3 0.4E-02 0.4E-02 46 HPLC:Zea mg/m^3 0.17E-01 0.17E-01 47 HPLC:Lut mg/m^3 0.2E-02 0.2E-02 48 HPLC:Chl-b mg/m^3 0.25E-01 0.25E-01 49 HPLC:DVChl-a mg/m^3 0 0 50 HPLC:Chl-a mg/m^3 0.367 0.367 51 HPLC:Phe mg/m^3 0 0 52 HPLC:B-Car mg/m^3 0.8E-02 0.8E-02 53 HPLC:TChl-a mg/m^3 0.435 0.435 54 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 8 F ' ' 3 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 6 F ' ' 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 8 F R4 3 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 7 F R4 2 27 -99 ' ' 3 NQ C ' ' 28 -99 ' ' 7 F R4 2 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-21 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : LaPerouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : LB14 EVENT NUMBER : 30 LATITUDE : 48 8.49000 N ! (deg min) LONGITUDE : 125 59.90000 W ! (deg min) WATER DEPTH : 1179 ALTIMETER (M) : 10.77 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 4700 Conductivity:2 ' ' 3321 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 'Transmissometer:WET Labs C-Star' ' ' 1396DR 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3642 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/08/11 10:24:12 4432 4432 CLEAN 5.1 2014/08/11 10:24:57 ? ? ADDSAMP 3.6 2014/08/11 10:42:04 4432 4432 BINAVE 4.1.1 2014/08/11 10:42:42 4432 19 MERGE 3.5 2014/08/22 12:10:22 19 19 CLEAN 5.1 2014/08/22 12:10:25 19 19 CALIB 11.8 2014/08/22 12:10:41 19 19 SORT 3.6 2014/08/22 12:10:46 19 19 REMOVECH 8.2 2014/08/22 12:12:37 19 19 CHGUNITS 3.1 2014/08/22 12:14:44 19 19 CHGUNITS 3.1 2014/08/22 12:14:59 19 19 REORDER 1.3 2014/08/22 12:15:39 ? ? HDREDIT2 2.6 2014/08/22 12:16:40 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:46:40 19 19 SORT 3.6 2020/08/03 15:27:21 19 19 REORDER 1.3.1 2021/11/25 13:50:05 ? ? MERGE 3.5.1 2021/11/25 13:50:16 19 19 SORT 3.6 2021/11/25 13:50:27 19 19 CLEAN 5.2.4 2021/11/25 13:50:35 19 19 HDREDIT2 3.2 2021/11/25 15:03:16 ? ? HDREDIT2 3.2 2021/11/25 15:03:42 ? ? $END $REMARKS -CLEAN functions: 2014/08/11 10:24:49 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-21\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/08/22 12:10:22 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-21\Processing\hydro\2014-21-0030.samavg Secondary file: P:\Cruise_Data_Processing\2014-21\Processing\hydro\2014-21-0030.mrgcln1s -CLEAN functions: 2014/08/22 12:10:05 20 Reduce header to sections: FIL ADM LOC DEP REC INS HIS RAW CAL COM Remarks removed from kept sections. -SORT parameters: 2014/08/22 12:10:10 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/08/22 12:10:24 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/08/22 12:10:41 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-21\Processing\doc\2014-21-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Salinity:T1:C1 PSS-78 10 -0.5300000E-02 0.1000000E+01 14 Oxygen:Dissolved:SBE mL/L 10 -0.2590000E-01 0.1040000E+01 -SORT parameters: 2014/08/22 12:10:46 Sorted in ascending order of channel Pressure* -REMOVECH 2014/08/22 12:12:37 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Salinity:T0:C0 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Secondary Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T1:C1 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/08/22 12:16:40 Applied edit header: P:\Cruise_Data_Processing\2014-21\Processing\doc\HYDRO\2014-21-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 20: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 21: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Channel 22: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 23: Silicate [umol/L] Units: ==> umol/L Channel 24: Flag:Silicate [n/a] Units: ==> n/a Channel 25: Phosphate [umol/L] Units: ==> umol/L Channel 26: Flag:Phosphate [n/a] Units: ==> n/a Channel 28: Flag:Ammonium [n/a] Units: ==> n/a -SORT parameters: 2020/08/03 15:27:21 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/25 13:50:16 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-021_Nov2021\Processing\ IOS\2014-021-0030.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-021_Nov2021\Processing\ IOS\2014-021-0030.hplc -SORT parameters: 2021/11/25 13:50:27 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/25 13:50:34 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/25 15:03:16 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_021\Processing\IOS\ 2014-021-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Bottle:Firing_Sequence [n/a] Format: I3 ==> I5 Channel 29: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 51: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 52: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 53: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/25 15:03:42 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014_021\Processing\IOS\ 2014-021-bot-hdr2.txt $END *COMMENTS Sample_Number 94: OXY: Sample was redrawn Sample_Number 96: OXY: Sample was redrawn Sample_Number 99: OXY: Residue on inside wall of flask. Large flakes swirling in sample took about 30 seconds to dissolve after initiating the titration. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship or at IOS in room 1310 at IOS ~5 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-21CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2-3 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2014-021HPLC*.xlsx. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-21OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 3 to 14 days after collection. For details including a duplicate analysis, see document QF2014-21SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20 freezer. One set of samples was collected and frozen immediately. Another set of samples from 400m and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis. They were analyzed using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For details see document QF2014-21nuts*.xls. The ammonium method used at IOS is a simplification of the fluorometric technique of Holmes et al, 1999. This method applies to a wide range of ammonium concentrations, uses the addition of a single working reagent and reduces contamination. Typically, samples are collected during the day and stored in the cold room. The working reagent is added to standards and samples at the same time, and the fluorescence is read approximately 8 hours later using a calibrated TD 700 Fluorometer. For full details including a precision study see file 2014-21NH4*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 5. Holmes, R.M., Aminto, A., Kérouel, R., Hooker, Bethanie A., and Peterson, Bruce J. 1999. A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 6. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Oxygen:Dissolved:SBE was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2014-21_Processing_Report.doc. --------------------------------------------------------------------------------- Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2014\2014-021_Nov2021\Processing\IOS\2014-021-0030. hplc --------------------------------------------------------------------------- Sample_Number 108: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Salinity:T1:C1 PSS-78 10 -99 () (-0.53E-02 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.259E-01 1.04) $END !-1-- -2-- -3-- --4--- ---5---- --6-- ---7--- ---8---- --9--- --10- -11- --12- ---13--- 14 ---15-- --16- 17 --18- 19 --20-- 21 ---22-- 23 --24-- 25 --26-- 27 --28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- 54 !Samp Bott Bott Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Tempe Salinity Fl Oxygen: Oxyge Fl Nitra Fl Silica Fl Phospha Fl Ammoni Fl Chloro Fl Phaeo- HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re ure: missi cence: :T1:C1 : n: er_o ratur :Bottle ag Dissolv n: ag te_ ag te ag te ag um ag phyll: ag Pigmen Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb ~ng_ Secondar vity URU: Dissol Disso ~bin e: ~o ed Disso ~o plus_ ~t ~i ~p ~o Extrac ~a t: a chlide a fuco fuco : !er er Sequ y Seapoin ved: lved: _rec Draw tt lved lv Nitri ri ca ha ni ted ct Extrac HP ! ence t SBE SBE ords le ed te te te te um ed ted LC !---- ---- ---- ------ -------- ----- ------- -------- ------ ----- ---- ----- -------- -- ------- ----- -- ----- -- ------ -- ------- -- ------ -- ------ -- ------ ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 109 19 19 5.3 13.8095 56.6 0.583 31.5630 6.22 271.5 241 -99.0 -99.0000 0 -99.000 -99.0 0 -99.0 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 108 18 18 5.4 13.8100 56.5 0.556 31.5627 6.22 271.5 94 13.0 -99.0000 0 6.226 271.5 0 0.0 0 2.90 0 0.273 0 0.29 6 0.62 6 0.13 0.030 0.036 0.004 0.063 0.005 0.033 0.012 0.000 0.011 0.139 0.000 0.008 0.009 0.045 0.059 0.018 0.004 0.017 0.002 0.025 0.000 0.367 0.000 0.008 0.435 36 107 17 17 9.8 13.8067 56.7 0.644 31.5649 6.22 271.2 241 13.0 -99.0000 0 6.231 271.7 0 0.0 0 2.99 0 0.272 0 0.09 6 0.61 6 0.11 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 106 16 16 20.5 11.4620 61.3 0.877 32.2134 6.97 303.7 241 11.6 -99.0000 0 6.970 303.7 0 0.8 0 6.65 0 0.520 0 0.22 6 0.51 6 0.12 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 105 15 15 30.0 10.3128 62.9 0.704 32.2588 6.88 299.8 241 10.8 -99.0000 0 6.904 300.8 0 2.3 6 7.31 6 0.622 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 104 14 14 50.3 9.0420 63.4 1.010 32.3618 6.42 279.7 241 9.9 -99.0000 0 6.420 279.6 0 7.6 0 9.84 0 0.919 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 103 13 13 75.5 7.7419 66.6 0.210 32.8438 5.28 229.7 241 9.0 -99.0000 0 5.237 228.0 0 18.9 0 21.40 0 1.528 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 102 12 12 100.7 7.5866 67.1 0.063 33.2952 4.28 186.1 241 9.0 -99.0000 0 4.319 188.0 0 24.2 0 27.57 0 1.798 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 101 11 11 124.9 7.7739 65.8 0.052 33.6575 3.02 131.5 241 9.1 -99.0000 0 3.030 131.8 6 29.9 0 36.10 0 2.154 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 100 10 10 149.7 7.5660 65.4 0.049 33.7983 2.70 117.3 241 8.9 -99.0000 0 2.702 117.5 0 31.6 0 39.87 0 2.242 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 99 9 9 174.9 7.3546 64.4 0.050 33.8776 2.53 110.2 241 8.7 -99.0000 0 2.575 112.0 3 32.8 0 42.35 0 2.287 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 98 8 8 200.7 7.1024 66.6 0.049 33.9260 2.35 102.4 241 8.4 -99.0000 0 2.359 102.6 0 34.1 0 45.93 0 2.355 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 97 7 7 250.1 6.7983 65.9 0.050 33.9560 1.99 86.7 241 8.2 -99.0000 0 2.029 88.2 0 36.1 0 50.91 0 2.493 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 96 6 6 300.3 6.3059 66.3 0.049 33.9973 1.48 64.5 241 7.8 -99.0000 0 1.516 65.9 2 39.0 0 59.63 0 2.698 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 95 5 5 400.3 5.6074 67.5 0.049 34.0306 1.10 47.8 241 7.4 -99.0000 0 1.125 48.9 0 41.7 0 71.24 0 2.891 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 94 4 4 501.2 5.1946 66.5 0.049 34.0824 0.77 33.6 241 6.8 34.0836 0 0.803 34.9 2 43.7 6 81.79 6 3.039 6 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 93 3 3 750.3 4.3155 66.7 0.049 34.2585 0.27 11.5 241 6.4 34.2598 0 0.290 12.6 6 46.2 0 108.30 0 3.275 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 92 2 2 1000.0 3.7672 66.5 0.049 34.3656 0.24 10.4 241 6.3 34.3661 6 0.256 11.1 0 47.0 0 124.77 0 3.317 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 91 1 1 1165.3 3.4225 64.3 0.049 34.4118 0.30 12.9 241 6.6 -99.0000 0 0.321 14.0 0 47.2 0 134.88 0 3.310 0 -99.00 0 -99.00 0 -99.00 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0