*2023/03/19 10:46:54.20 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/07/02 22:29:25.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 784230BC NUMBER OF CHANNELS : 26 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Bottle:Firing_Sequence n/a 4 16 2 Bottle_Number n/a 4 16 3 Pressure decibar 1.4 343.2 4 Temperature:Primary 'deg C (ITS90)' 6.6648 13.1999 5 Transmissivity %/metre 20.4 62.4 6 Fluorescence:URU:Seapoint mg/m^3 0.52E-01 13.572 7 Salinity:T0:C0 PSS-78 16.9241 32.8539 8 Oxygen:Dissolved:SBE mL/L 3.48 8.19 9 Oxygen:Dissolved:SBE umol/kg 151.6 361.2 10 Number_of_bin_records n/a 50 241 11 Sample_Number n/a 88 100 12 Temperature:Draw 'deg C (ITS90)' 8.1 14.2 13 Salinity:Bottle PSS-78 16.9252 32.7487 14 Flag:Salinity:Bottle n/a 15 Chlorophyll:Extracted mg/m^3 1.49 7.11 16 Flag:Chlorophyll:Extracted n/a 17 Phaeo-Pigment:Extracted mg/m^3 0.21 0.77 18 Oxygen:Dissolved mL/L 3.477 8.167 19 Oxygen:Dissolved umol/kg 151.4 360.2 20 Flag:Oxygen:Dissolved n/a 21 Nitrate_plus_Nitrite umol/L 0.1 27.7 22 Flag:Nitrate_plus_Nitrite n/a 23 Phosphate umol/L 0.109 2.186 24 Flag:Phosphate n/a 25 Silicate umol/L 8.985985 52.95 26 Silicate:Flag n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 3 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 ' ' ' ' 5 I I 0 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 9 F R4 4 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 8 F R4 3 19 -99 ' ' 6 F ' ' 1 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2014-20 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : WCVI Moorings / Douglas Channel SCIENTIST : Spear D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI / Douglas Channel STATION : DOUG11 EVENT NUMBER : 13 LATITUDE : 53 49.04000 N ! (deg min) LONGITUDE : 128 49.11000 W ! (deg min) WATER DEPTH : 352 ALTIMETER (M) : 4.93 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------------------------- -------------- ---------- Temperature ' ' 4054 Conductivity ' ' 1766 'Pressure:Digiquartz with TC' ' ' 0585 Temperature:2 ' ' 4700 Conductivity:2 ' ' 3321 PAR/Irradiance:Biospherical/Licor ' ' 4615 Altimeter ' ' 1204 'Transmissometer:WET Labs C-Star' ' ' 1396DR 'Oxygen:SBE 43' ' ' 1119 Fluorometer:Seapoint ' ' 3642 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.22.4 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! --------------------- ------ ---------- -------- --------- --------- SBE_IOS 3.4.1 2014/09/03 15:38:17 3370 3370 CLEAN 5.1 2014/09/03 15:38:36 ? ? ADDSAMP 3.6 2014/09/04 09:34:49 3370 3370 BINAVE 4.2 2014/09/04 09:35:06 3370 19 MERGE 3.5 2014/09/14 15:09:07 13 13 CLEAN 5.1 2014/09/14 15:09:13 13 13 CALIB 11.8 2014/09/23 16:00:51 13 13 SORT 3.6 2014/09/23 16:45:32 13 13 REMOVECH 8.2 2014/09/23 16:46:09 13 13 CHGUNITS 3.1 2014/09/23 16:48:38 13 13 CHGUNITS 3.1 2014/09/23 16:48:55 13 13 REORDER 1.3 2014/09/23 16:49:31 ? ? HDREDIT2 2.6 2014/09/23 16:52:00 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:46:44 13 13 Silicate_Correction 1.0 2018/02/20 14:30:11 13 13 Silicate_Modification 1.2 2023/03/19 10:46:54 13 13 $END $REMARKS -CLEAN functions: 2014/09/03 15:38:31 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: P:\Cruise_Data_Processing\2014-20\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2014/09/14 15:09:07 Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Event_Number, Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Phaeo-Pigment:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Temperature:Draw, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium, pH, Flag:pH, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : P:\Cruise_Data_Processing\2014-20\Processing\hydro\2014-20-0013.samavg Secondary file: P:\Cruise_Data_Processing\2014-20\Processing\hydro\2014-20-0013.mrgcln1s -SORT parameters: 2014/09/14 15:08:53 Sorted in ascending order of channel Bottle_Number -CLEAN functions: 2014/09/14 15:09:12 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2014/09/23 16:00:51 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = P:\Cruise_Data_Processing\2014-20\Processing\doc\2014-20-recal1.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.1040400E+01 -SORT parameters: 2014/09/23 16:45:32 Sorted in ascending order of channel Pressure* -REMOVECH 2014/09/23 16:46:09 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] PAR [uE/m^2/sec] Salinity:T1:C1 [PSS-78] Descent_Rate [m/s] Altimeter [metres] Status:Pump Flag -CHANGE units: Temperature reference channel: Temperature:Primary Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -CHANGE units: Temperature reference channel: Temperature:Draw Salinity reference channel: Salinity:T0:C0 'Oxygen:Dissolved' changed from mL/L to umol/kg -HEADER EDITS: 2014/09/23 16:52:00 Applied edit header: P:\Cruise_Data_Processing\2014-20\Processing\doc\HYDRO\2014-20-bot-hdr.txt Channel 1: Bottle:Firing_Sequence [n/a] Name: Bottle_Number ==> Bottle:Firing_Sequence Channel 2: Bottle_Number [n/a] Name: Bottle:Position ==> Bottle_Number Channel 3: Pressure [decibar] Format: F10.3 ==> F7.1 Channel 8: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 12: Temperature:Draw [deg C (ITS90)] Units: ==> deg C (ITS90) Format: F7.2 ==> F6.1 Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 14: Flag:Salinity:Bottle [n/a] Units: ==> n/a Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 16: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 17: Phaeo-Pigment:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 18: Oxygen:Dissolved [mL/L] Units: ==> mL/L Channel 20: Flag:Oxygen:Dissolved [n/a] Units: ==> n/a Channel 21: Nitrate_plus_Nitrite [umol/L] Units: ==> umol/L Format: F6.1 ==> F7.2 Channel 22: Flag:Nitrate_plus_Nitrite [n/a] Units: ==> n/a Channel 23: Silicate [umol/L] Units: ==> umol/L Channel 24: Flag:Silicate [n/a] Units: ==> n/a Channel 25: Phosphate [umol/L] Units: ==> umol/L Channel 26: Flag:Phosphate [n/a] Units: ==> n/a $END *COMMENTS ===================================================================================== Silicate correction was applied after the original processing. 2023/03/19 ------------------------------------------------------------------------------------- Silicate data has been adjusted to account for salinity effect and analysis on the Water Properties Group Astoria Pacific continuous flow nutrient analyser. Adjustment was made for salinity values (when available) of <= 25 psu. Adjustment equation: Silicate:Corrected = Silicate * [1+((-0.003)*(32-S))] where, Silicate:Corrected = corrected silicate concentration in micromoles/litre Silicate = uncorrected silicate concentration in micromoles/litre -0.003 = salt correction factor 32 = salt concentration of artificial seawater used by the WPG Astoria Pacific continuous flow analyser S = salinity of the sample At Station: DOUG11, Sample Number: 99, Silicate corrected using Bottle salinity. ===================================================================================== Sample_Number 98: CHL:CV%>15 Sample_Number 88: OXY-2: Redrawn in new flask. A few minutes passed between sampling duplicate A to duplicate B. Sample_Number 91: OXY: Sample redrawn in new flask. Sample_Number 92: OXY: Niskin spigot was leaking prior to sampling. Sample_Number 94: OXY-2: Serial line hiccup near end of titration led to program crash. Endpoint titer salvaged and value calculated manually. Sample_Number 98: OXY: Noisy titration. Many particles in sample Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours in the lab and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship during the cruise or at IOS in Room 2423 about 5 weeks later. The average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see worksheet “CV%” in file QF2014-20CHL*.xls. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details including a duplicate analysis, see document QF2014-20OXY*.xls. Salinity samples were collected in 200 mL type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 9 to 23 days after collection. For details including a duplicate analysis, see document QF2014-20SAL*.xls. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in a -20C freezer. All analysis was done on frozen samples. They were analyzed using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For details see document QF2014-20nuts*.xls. References: 1. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. * For PDF versions of these papers see folder \\Cruise_Data\DOCUMENTS\Analysis Reference Papers --------------------------------------------------------------------------------- CTD Data Processing Notes: -------------------------- Transmissivity and Fluorescence data are nominal and unedited. For details on how the transmissivity calibration parameters were calculated see the document in folder "\cruise_data\documents\transmissivity". Dissolved oxygen was calibrated using the method described in SeaBird Application Note #64-2, June 2012 revision, except that a small offset in the fit was allowed. For details on the processing see document: 2014-20_Processing_Report.doc. --------------------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0 1.0404) $END !1- 2- --3--- ---4---- --5-- ---6--- ---7---- --8--- --9-- -10- -11- --12- ---13--- 14 --15-- 16 --17-- ---18-- --19- 20 --21-- 22 ---23-- 24 --25-- 26 !Bo Bo Pressu Temperat Trans Fluores Salinity Oxygen Oxyge Numb Samp Tempe Salinity Fl Chloro Fl Phaeo- Oxygen: Oxyge Fl Nitrat Fl Phospha Fl Silica Si !tt tt re ure: missi cence: :T0:C0 : n: er_o le_ ratur :Bottle ag phyll: ag Pigmen Dissolv n: ag e_ ag te ag te li !~u ~u Primary vity URU: Dissol Disso ~bin Numb e: ~o Extrac ~a t: ed Disso ~o plus_ ~t ~p ~: !en mb Seapoin ved: lved: _rec er Draw tt ted ct Extrac lved lv Nitrit ri ha Fl !ce er t SBE SBE ords le ed ted ed e te te ag !-- -- ------ -------- ----- ------- -------- ------ ----- ---- ---- ----- -------- -- ------ -- ------ ------- ----- -- ------ -- ------- -- ------ -- *END OF HEADER 16 16 1.4 13.1999 44.5 0.345 16.9241 8.19 361.2 53 100 14.2 16.9252 0 1.49 6 0.21 8.167 360.2 6 -99.00 0 -99.000 0 -99.00 0 15 15 1.4 13.1893 43.7 0.338 16.9382 8.18 360.8 50 99 -99.0 16.9800 0 -99.00 0 -99.00 -99.000 -99.0 0 0.10 6 0.109 6 8.99 6 14 14 10.2 8.5535 20.4 13.572 28.6725 6.93 302.9 241 98 9.8 -99.0000 0 7.11 36 0.77 6.413 280.1 3 13.90 0 1.263 0 25.52 0 13 13 20.3 7.4887 53.2 1.474 30.4661 5.34 233.1 241 97 9.0 -99.0000 0 3.80 6 0.75 5.346 233.2 0 21.20 0 1.725 0 36.08 0 12 12 30.6 6.7075 59.1 0.363 31.0771 5.38 234.4 241 96 8.6 -99.0000 0 -99.00 0 -99.00 5.362 233.7 0 24.70 0 1.937 0 40.66 0 11 11 50.2 6.6648 60.1 0.233 31.4916 5.27 229.5 241 95 8.3 -99.0000 0 -99.00 0 -99.00 5.240 228.3 0 24.90 0 1.941 0 41.06 0 10 10 75.4 7.0455 61.9 0.107 32.2884 4.32 188.1 241 94 8.5 -99.0000 0 -99.00 0 -99.00 4.297 187.1 26 26.50 6 2.063 6 46.00 6 9 9 100.9 7.2111 62.4 0.073 32.5137 3.93 171.2 241 93 8.4 -99.0000 0 -99.00 0 -99.00 3.912 170.3 0 26.60 0 2.083 0 48.39 0 8 8 151.0 7.2474 61.5 0.065 32.6688 3.48 151.6 241 92 8.4 -99.0000 0 -99.00 0 -99.00 3.477 151.4 3 27.70 0 2.186 0 52.95 0 7 7 200.7 7.2036 61.1 0.057 32.7391 3.75 163.4 241 91 8.4 32.7487 0 -99.00 0 -99.00 3.777 164.4 2 27.10 0 2.104 0 48.54 0 6 6 250.0 7.1612 61.5 0.061 32.7861 3.81 166.0 241 90 8.1 -99.0000 0 -99.00 0 -99.00 3.812 165.9 0 27.20 0 2.077 0 47.23 0 5 5 300.9 7.1252 58.2 0.084 32.8348 3.77 164.0 241 89 8.1 -99.0000 0 -99.00 0 -99.00 3.777 164.4 0 27.30 0 2.090 0 47.21 0 4 4 343.2 7.1126 58.7 0.052 32.8539 3.74 162.8 241 88 8.3 -99.0000 0 -99.00 0 -99.00 3.767 164.0 36 27.40 0 2.082 0 47.17 0